Coal
Coal
For other uses, see Coal (disambiguation). tralia with 328 million tonnes (27.1% of world coal ex-
Coal (Old English col) is a combustible black or port) and Indonesia with 316 million tonnes (26.1%),[4]
while the largest importers were Japan with 207 million
tonnes (17.5% of world coal import), China with 195 mil-
lion tonnes (16.6%) and South Korea with 126 million
tonnes (10.7%).[5]
1 Etymology
The word originally took the form col in Old English,
from Proto-Germanic *kula(n), which in turn is hypothe-
sized to come from the Proto-Indo-European root *g(e)u-
lo- “live coal”.[6] Germanic cognates include the Old
Frisian kole, Middle Dutch cole, Dutch kool, Old High
German chol, German Kohle and Old Norse kol, and the
Irish word gual is also a cognate via the Indo-European
root.[6] In Old Turkic languages, kül is “ash(es), cinders”,
Bituminous coal öčür is “quench”. The compound “charcoal” in Turkic is
öčür(ülmüş) kül, literally “quenched ashes, cinders, coals”
brownish-black sedimentary rock usually occurring in with elided anlaut ö- and inflection affixes -ülmüş.[7]
rock strata in layers or veins called coal beds or coal The word took on the meaning “mineral consisting of fos-
seams. The harder forms, such as anthracite coal, can silized carbon” in the thirteenth century.[6]
be regarded as metamorphic rock because of later expo-
sure to elevated temperature and pressure. Coal is com-
posed primarily of carbon, along with variable quantities
of other elements, chiefly hydrogen, sulfur, oxygen, and 2 Formation
nitrogen.[1] A fossil fuel, coal forms when dead plant mat-
ter is converted into peat, which in turn is converted into
lignite, then sub-bituminous coal, after that bituminous
coal, and lastly anthracite. This involves biological and
geological processes that take place over time.
H
Throughout history, coal has been used as an energy re- O
1
2 3 RANKS
3 Ranks
3.2 Content
derstood to derive from the way it was carried to London 5.1 Coal as fuel
by sea.[29] In 1257–59, coal from Newcastle upon Tyne
was shipped to London for the smiths and lime-burners Further information: Electricity generation, Clean coal
building Westminster Abbey.[27] Seacoal Lane and New- technology, Coal electricity, Global warming, and List
castle Lane, where coal was unloaded at wharves along of coal power stations
the River Fleet, are still in existence.[30] (See Industrial
processes below for modern uses of the term.)
Coal is primarily used as a solid fuel to produce electric-
These easily accessible sources had largely become ex- ity and heat through combustion. World coal consump-
hausted (or could not meet the growing demand) by the tion was about 7.25 billion tonnes in 2010[34] (7.99 billion
13th century, when underground extraction by shaft min- short tons) and is expected to increase 48% to 9.05 billion
ing or adits was developed.[21] The alternative name was tonnes (9.98 billion short tons) by 2030.[35] China pro-
“pitcoal”, because it came from mines. The develop- duced 3.47 billion tonnes (3.83 billion short tons) in 2011.
ment of the Industrial Revolution led to the large-scale India produced about 578 million tonnes (637.1 million
use of coal, as the steam engine took over from the water short tons) in 2011. 68.7% of China’s electricity comes
wheel. In 1700, five-sixths of the world’s coal was mined from coal. The US consumed about 13% of the world to-
in Britain. Britain would have run out of suitable sites for tal in 2010, i.e. 951 million tonnes (1.05 billion short
watermills by the 1830s if coal had not been available as tons), using 93% of it for generation of electricity.[36]
a source of energy.[31] In 1947, there were some 750,000 46% of total power generated in the US was using coal.[37]
miners in Britain,[32] but by 2004, this had shrunk to some The United States Energy Information Administration es-
5,000 miners working in around 20 collieries.[33] timates coal reserves at 948×109 short tons (860 Gt).[38]
One estimate for resources is 18,000 Gt.[39]
When coal is used for electricity generation, it is usually
pulverized and then burned in a furnace with a boiler.[40]
5 Uses today The furnace heat converts boiler water to steam, which is
then used to spin turbines which turn generators and cre-
ate electricity.[41] The thermodynamic efficiency of this
process has been improved over time; some older coal-
fired power stations have thermal efficiencies in the vicin-
ity of 25%[42] whereas the newest supercritical and “ultra-
supercritical” steam cycle turbines, operating at temper-
atures over 600 °C and pressures over 27 MPa (over
3900 psi), can achieve thermal efficiencies in excess of
45% (LHV basis) using anthracite fuel,[43][44] or around
43% (LHV basis) even when using lower-grade lignite
fuel.[45] Further thermal efficiency improvements are also
achievable by improved pre-drying (especially relevant
with high-moisture fuel such as lignite or biomass) and
cooling technologies.[46]
An alternative approach of using coal for electricity gen-
Castle Gate Power Plant near Helper, Utah, USA
eration with improved efficiency is the integrated gasifi-
cation combined cycle (IGCC) power plant. Instead of
5.3 Gasification 5
electricity, but the versatility of syngas also allows it to greater than those released in the extraction and refine-
be converted into transportation fuels, such as gasoline ment of liquid fuel production from crude oil. If CCS
and diesel, through the Fischer-Tropsch process; alterna- technologies are employed, reductions of 5–12% can be
tively, syngas can be converted into methanol, which can achieved in Coal to Liquid (CTL) plants and up to a 75%
be blended into fuel directly or converted to gasoline via reduction is achievable when co-gasifying coal with com-
the methanol to gasoline process.[57] Gasification com- mercially demonstrated levels of biomass (30% biomass
bined with Fischer-Tropsch technology is currently used by weight) in coal/biomass-to-liquids plants.[64] For fu-
by the Sasol chemical company of South Africa to make ture synthetic fuel projects, carbon dioxide sequestration
motor vehicle fuels from coal and natural gas. Alter- is proposed to avoid releasing CO2 into the atmosphere.
natively, the hydrogen obtained from gasification can be Sequestration adds to the cost of production.
used for various purposes, such as powering a hydrogen
economy, making ammonia, or upgrading fossil fuels.
During gasification, the coal is mixed with oxygen and 5.5 Refined coal
steam while also being heated and pressurized. Dur-
ing the reaction, oxygen and water molecules oxidize the Main article: Refined coal
coal into carbon monoxide (CO), while also releasing
hydrogen gas (H2 ). This process has been conducted in Refined coal is the product of a coal-upgrading tech-
both underground coal mines and in the production of nology that removes moisture and certain pollutants
town gas which was piped to customers to burn for illu- from lower-rank coals such as sub-bituminous and lignite
mination, heating, and cooking. (brown) coals. It is one form of several precombustion
treatments and processes for coal that alter coal’s charac-
C (as Coal) + O2 + H2 O → H2 + CO teristics before it is burned. The goals of precombustion
coal technologies are to increase efficiency and reduce
emissions when the coal is burned. Depending on the sit-
If the refiner wants to produce gasoline, the syngas is col- uation, precombustion technology can be used in place
lected at this state and routed into a Fischer-Tropsch re- of or as a supplement to postcombustion technologies to
action. If hydrogen is the desired end-product, however, control emissions from coal-fueled boilers.
the syngas is fed into the water gas shift reaction, where
more hydrogen is liberated.
5.6 Industrial processes
CO + H2 O → CO2 + H2
Finely ground bituminous coal, known in this application
as sea coal, is a constituent of foundry sand. While the
5.4 Liquefaction molten metal is in the mould, the coal burns slowly, re-
leasing reducing gases at pressure, and so preventing the
Main article: Coal liquefaction metal from penetrating the pores of the sand. It is also
contained in 'mould wash', a paste or liquid with the same
function applied to the mould before casting.[65] Sea coal
Coal can also be converted into synthetic fuels equivalent can be mixed with the clay lining (the “bod”) used for
to gasoline or diesel by several different direct processes the bottom of a cupola furnace. When heated, the coal
(which do not intrinsically require gasification or indirect decomposes and the bod becomes slightly friable, easing
conversion).[58] In the direct liquefaction processes, the the process of breaking open holes for tapping the molten
coal is either hydrogenated or carbonized. Hydrogena- metal.[66]
tion processes are the Bergius process,[59] the SRC-I and
SRC-II (Solvent Refined Coal) processes, the NUS Cor-
poration hydrogenation process[60][61] and several other 5.7 Production of chemicals
single-stage and two-stage processes.[62] In the process of
low-temperature carbonization, coal is coked at tempera- Coal is an important feedstock in production of a
tures between 360 and 750 °C (680 and 1,380 °F). These wide range of chemical fertilizers and other chemical
temperatures optimize the production of coal tars richer products.[67] The main route to these products is coal
in lighter hydrocarbons than normal coal tar. The coal tar gasification to produce syngas. Primary chemicals that
is then further processed into fuels. An overview of coal are produced directly from the syngas include methanol,
liquefaction and its future potential is available.[63] hydrogen and carbon monoxide, which are the chemical
Coal liquefaction methods involve carbon dioxide (CO2 ) building blocks from which a whole spectrum of deriva-
emissions in the conversion process. If coal liquefaction tive chemicals are manufactured, including olefins, acetic
is done without employing either carbon capture and stor- acid, formaldehyde, ammonia, urea and others. The ver-
age (CCS) technologies or biomass blending, the result satility of syngas as a precursor to primary chemicals and
is lifecycle greenhouse gas footprints that are generally high-value derivative products provides the option of us-
6.1 Coal as a traded commodity 7
Historically, production of chemicals from coal has been In addition to the NYMEX contract, the Intercontinental
used since the 1950s and has become established in the Exchange (ICE) has European (Rotterdam) and South
market. According to the 2010 Worldwide Gasification African (Richards Bay) coal futures available for trading.
Database,[68] a survey of current and planned gasifiers, The trading unit for these contracts is 5,000 tonnes (5,500
from 2004 to 2007 chemical production increased its short tons), and are also quoted in U.S. dollars and cents
gasification product share from 37% to 45%. From 2008 per ton.[74]
to 2010, 22% of new gasifier additions were to be for The price of coal increased from around $30.00 per short
chemical production. ton in 2000 to around $150.00 per short ton as of Septem-
Because the slate of chemical products that can be made ber 2008. As of October 2008, the price per short ton had
via coal gasification can in general also use feedstocks de- declined to $111.50. Prices further declined to $71.25 as
rived from natural gas and petroleum, the chemical in- of October 2010.[75] In early 2015, it was trading near
dustry tends to use whatever feedstocks are most cost- $56/ton.[76]
effective. Therefore, interest in using coal tends to in-
crease for higher oil and natural gas prices and during
periods of high global economic growth that may strain 7 Environmental and health effects
oil and gas production. Also, production of chemicals
from coal is of much higher interest in countries like Main article: Environmental impact of the coal industry
South Africa, China, India and the United States where
there are abundant coal resources. The abundance of coal
combined with lack of natural gas resources in China
is strong inducement for the coal to chemicals industry 7.1 Health effects
pursued there. In the United States, the best example
of the industry is Eastman Chemical Company which The use of coal as fuel causes adverse health impacts and
has been successfully operating a coal-to-chemicals plant deaths.[77]
at its Kingsport, Tennessee, site since 1983. Similarly,
Sasol has built and operated coal-to-chemicals facilities The deadly London smog was caused primarily by the
in South Africa. heavy use of coal. In the United States coal-fired power
plants were estimated in 2004 to cause nearly 24,000 pre-
Coal to chemical processes do require substantial quan- mature deaths every year, including 2,800 from lung can-
tities of water. As of 2013 much of the coal to cer.[78] Annual health costs in Europe from use of coal to
chemical production was in the People’s Republic of generate electricity are €42.8 billion, or $55 billion.[79]
China[69][70] where environmental regulation and water Yet the disease and mortality burden of coal use today
management[71] was weak.[72] falls most heavily upon China.[80][81][82]
Breathing in coal dust causes coalworker’s pneumoconio-
sis which is known colloquially as “black lung”, so-called
6 Coal industry because the coal dust literally turns the lungs black from
their usual pink color.[83] In the United States alone, it is
Main pages: Category:Coal companies, Coal mining, estimated that 1500 former employees of the coal indus-
Coal industry in China, Coal industry in Pakistan, Coal try die every
[84]
year from the effects of breathing in coal
industry in India, Coal industry in New Zealand, and mine dust.
Coal companies of Australia Around 10% of coal is ash,[85] Coal ash is hazardous
8 7 ENVIRONMENTAL AND HEALTH EFFECTS
separates them, and compresses the CO2 into a liquid. 10 Energy density and carbon im-
Plans are to inject the CO2 into depleted natural gas fields
or other geological formations. Vattenfall opines that this
pact
technology is considered not to be a final solution for CO2
reduction in the atmosphere, but provides an achievable See also: Energy value of coal
solution in the near term while more desirable alternative
solutions to power generation can be made economically The energy density of coal, i.e. its heating value, is
practical.[121] roughly 24 megajoules per kilogram[131] (approximately
6.7 kilowatt-hours per kg). For a coal power plant with a
40% efficiency, it takes an estimated 325 kg (717 lb) of
coal to power a 100 W lightbulb for one year.[132]
As of 2006, the average efficiency of electricity-
8 Bioremediation generating power stations was 31%; in 2002, coal repre-
sented about 23% of total global energy supply, an equiv-
alent of 3.4 billion tonnes of coal, of which 2.8 billion
The white rot fungus Trametes versicolor can grow on
[122] tonnes were used for electricity generation.[133]
and metabolize naturally occurring coal. The bacteria
Diplococcus has been found to degrade coal, raising its The US Energy Information Agency’s 1999 report on
temperature.[123] CO2 emissions for energy generation quotes an emission
factor of 0.963 kg CO2 /kWh for coal power, compared to
0.881 kg CO2 /kWh (oil), or 0.569 kg CO2 /kWh (natural
gas).[134]
9 Economic aspects
11 Underground fires
Coal (by liquefaction technology) is one of the backstop Main article: Coal seam fire
resources that could limit escalation of oil prices and miti-
gate the effects of transportation energy shortage that will
occur under peak oil. This is contingent on liquefaction Thousands of coal fires are burning around the world.[135]
production capacity becoming large enough to satiate the Those burning underground can be difficult to locate and
very large and growing demand for petroleum. Estimates many cannot be extinguished. Fires can cause the ground
of the cost of producing liquid fuels from coal suggest that above to subside, their combustion gases are dangerous to
domestic U.S. production of fuel from coal becomes cost- life, and breaking out to the surface can initiate surface
competitive with oil priced at around $35 per barrel,[124] wildfires. Coal seams can be set on fire by spontaneous
with the $35 being the break-even cost. With oil prices as combustion or contact with a mine fire or surface fire.
low as around $40 per barrel in the U.S. as of December Lightning strikes are an important source of ignition. The
2008, liquid coal lost some of its economic allure in the coal continues to burn slowly back into the seam un-
U.S., but will probably be re-vitalized, similar to oil sand til oxygen (air) can no longer reach the flame front. A
projects, with an oil price around $70 per barrel. grass fire in a coal area can set dozens of coal seams on
fire.[136][137] Coal fires in China burn an estimated 120
In China, due to an increasing need for liquid energy in
million tons of coal a year, emitting 360 million metric
the transportation sector, coal liquefaction projects were tons of CO2 , amounting to 2–3% of the annual worldwide
given high priority even during periods of oil prices be-
production of CO2 from fossil fuels.[138][139] In Centralia,
low $40 per barrel.[125] This is probably because China Pennsylvania (a borough located in the Coal Region of
prefers not to be dependent on foreign oil, instead utiliz- the United States), an exposed vein of anthracite ignited
ing its enormous domestic coal reserves. As oil prices in 1962 due to a trash fire in the borough landfill, located
were increasing during the first half of 2009, the coal liq- in an abandoned anthracite strip mine pit. Attempts to
uefaction projects in China were again boosted, and these extinguish the fire were unsuccessful, and it continues to
projects are profitable with an oil barrel price of $40.[126] burn underground to this day. The Australian Burning
China is the largest producer of coal in the world. It is Mountain was originally believed to be a volcano, but the
the world’s largest energy consumer, and relies on coal smoke and ash come from a coal fire that has been burn-
to supply 69% of its energy needs.[127] An estimated 5 ing for some 6,000 years.[140]
million people worked in China’s coal-mining industry in At Kuh i Malik in Yagnob Valley, Tajikistan, coal de-
2007.[128] posits have been burning for thousands of years, creat-
Coal pollution costs the EU €43 billion each year.[129] ing vast underground labyrinths full of unique minerals,
Measures to cut air pollution may have beneficial long- some of them very beautiful. Local people once used this
term economic impacts for individuals.[130] method to mine ammoniac. This place has been well-
12.1 World coal reserves 11
duction levels and proved reserves level for the countries • Coal assay
shown, and makes no assumptions of future production
or even current production trends. Countries with annual • Coal blending
production higher than 100 million tonnes are shown. For
• Coal homogenization
comparison, data for the European Union is also shown.
Shares are based on data expressed in tonnes oil equiva- • Coal measures (stratigraphic unit)
lent.
• Coal phase out
• Fossil fuel
12.4 Major coal exporters
• Fossil fuel phase-out
Countries with annual gross export higher than 10 mil-
lion tonnes are shown. In terms of net export the largest • Gytta
exporters are still Australia (328.1 millions tonnes),
Indonesia (316.2) and Russia (100.2). • Major coal producing regions
Countries with annual gross import higher than 20 mil- • The Coal Question
lion tonnes are shown. In terms of net import the largest
importers are still Japan (206.0 millions tonnes), China • Tonstein
(172.4) and South Korea (125.8).[155]
• World Coal Association
13 Cultural usage
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[125] Tingting, Si; Jing, Li (12 December 2008). “Coal- [145] Lipton, Eric (19 December 2012). “Power Company
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by 2013”. Bloomberg. 7 January 2009. Retrieved 10 Jan- House to exam coal exports”. The San Francisco Chron-
uary 2009. icle. Associated Press. Archived from the original on 26
March 2013. Retrieved March 26, 2013.
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The Coal Is Stained With Blood”. TIME. Retrieved 25
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24 hours a day for a year?". Howstuffworks. Retrieved 25
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2012.
05-11.
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Eia.gov. Retrieved on 24 August 2012.
[137] “Snapshots 2003” (PDF). fire.blm.gov. Archived (PDF)
from the original on 18 February 2006. Retrieved 9 [156] “Kentucky: Secretary of State – State Mineral”. 20 Oc-
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on 31 July 2005. Retrieved 9 September 2005. [157] “Utah State Rock – Coal”. Pioneer: Utah’s Online Library.
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2005.
16 Further reading
[140] “Fire in The Hole”. Retrieved 5 June 2011.
[141] “North Dakota’s Clinker”. Retrieved 9 September 2005. • Walter Licht, Thomas Dublin (2005). The Face of
Decline: The Pennsylvania Anthracite Region in the
[142] “BLM-Environmental Education- The High Plains”. Twentieth Century. Cornell University Press. ISBN
Archived from the original on 12 March 2005. Retrieved 0-8014-8473-1. OCLC 60558740.
9 September 2005.
• Long, Priscilla (1991). Where the Sun Never Shines:
[143] Lyman, Robert M.; Volkmer, John E. (March 2001).
A History of America’s Bloody Coal Industry. New
“Pyrophoricity (spontaneous combustion) of Powder
York, NY: Paragon House. ISBN 1-55778-465-5.
River Basin coals–: Considerations for coalbed methane
development” (PDF). Archived from the original (PDF) OCLC 25236866.
on 12 September 2005. Retrieved 9 September 2005. • Rottenberg, Dan (2003). In the Kingdom of Coal;
[144] “EIA projects little change in U.S. coal production in An American Family and the Rock That Changed the
2013”. U.S. Energy Information Agency. 3 December World. Routledge. ISBN 0-415-93522-9. OCLC
2012. Retrieved 20 December 2012. 52348860.
17
17 External links
• "Coal". Encyclopædia Britannica. 6 (11th ed.).
1911. pp. 574–593.
• World Coal Association
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