WHAT IS REVERSE OSMOSIS?

Reverse osmosis is a method used to separate a high percentage of pollutants from water by
forcing it through a semi-permeable membrane.

Issues regarding freshwater production have persisted throughout human history. Several factors
such as location, contaminants, temperature, salinity, dissolved solids, and others have hampered
the distribution of clean water in many regions. Fortunately, the introduction of reverse osmosis
has provided an efficient solution to this problem. This article is intended for those who do not
have a clear understanding with reverse osmosis water and will illustrate the basics of reverse
osmosis technology and its applications.

Reverse osmosis operates by utilizing advanced filtration technology which removes dissolved
ions from water. Osmosis is an elemental force that draws water to water with higher salt
content. This is a process by which dissolved ions are removed from water. This elemental force
can be surmounted by applied pressure with the usage of pumps and semi-permeable
membranes, which forces water through the membrane and filters out dissolved salt from the
water.

 Understanding the Definition of Osmosis and Reverse Osmosis Water?

 How does a Reverse Osmosis System work?
 What are the Basic Components of a Reverse Osmosis System?
 What Types of Commercial/Industrial Applications do RO systems Serve?
 What Types of Water Sources Does Reverse Osmosis Treat?
 Is Pretreatment Necessary?
 Is it Necessary to get a Water Analysis?
 What Determines the Precise Pretreatments for a Particular RO?
 Does the Feed Water need to be Softened by the RO?
 What is Dechlorination used for?
 Is Acid Injection Necessary?
 What does Antiscalant do?
 Do all Reverse Osmosis Systems Require Chemical Cleaning?
 Summary
 Request a quote
  UNDERSTANDING THE DEFINITION OF
OSMOSIS AND REVERSE OSMOSIS WATER?

Reverse osmosis is a hot topic in the water treatment industry. With the lowest energy
requirements, some of the highest recovery rates, and one of the best rejection rates on the
market, it's no wonder people are interested in learning more about it. What is the definition of
reverse osmosis, though? How does it work? Let's take a look into the heart of a Pure Aqua RO
system and break it down for you to understand all about RO.
As anyone could guess, it is the process of osmosis backwards. Osmosis is the passage of water
through a reverse osmosis membrane (like our skin, or the inside of a plant cell) to equalize the
concentration of particles dissolved in the water. As the diagram above shows, the semi-
permeable membrane allows water to pass through, but molecules larger than water (things like
minerals, salts, and bacteria) cannot. Water flows back and forth until the concentration is equal
on both sides of the membrane, and an equilibrium is formed.

Let's apply this knowledge to water purification. We want to drink water from a lake or stream,
but it contains too high concentration of contaminants like salt, minerals, and bacteria, that make
it undrinkable. By applying pressure to water as it passes through a membrane, the water can be
forced to move away from the membrane rather than attempting to form an equilibrium like
normal. This against-flow motion is where the "reverse" in "reverse osmosis" comes from. A
pump works well for this process. Water is forced through the membrane, which like a super-fine
particle filter, blocks an extreme majority of contaminants from coming through.

As a water purification process, it has a number of advantages as well as disadvantages. In water

treatment, TFC membranes can usually remove between 96 and 99% of most contaminants,
including salts and minerals, dyes, particles, bacteria, and hazardous metals. Because of the way
reverse osmosis works, however, you can never truly remove all of a contaminant. You may
purify down to a fraction of a fraction of a percent, but the contaminant can never be truly
eliminated with reverse osmosis. Water purification systems also requires a superior quality, high
pressure pump, because the rejection rate is primarily dependent on the pressure applied to the
membrane. That being said, smaller units have smaller ratios of permeate (clean, purified
product) to waste water. This makes media filtration or other conventional filtration more
effective in smaller scales (like residential settings).

Now that we've answered the biggest question about membranes systems by Pure Aqua, let's take
a closer look at how we build our advanced water treatment systems and how reverse osmosis
works.

 HOW DOES A REVERSE OSMOSIS SYSTEM

WORK?
Reverse Osmosis works by filtering unwanted pollutants such as bacteria, viruses and other
microbiological organisms from water by pressuring the treated water which forces water
substances through a semipermeable membrane. Throughout the process, the pollutants are
separated from the water and flushed out, which produces ultra pure water.
The reverse osmosis process works by utilizing high pressure pumps to elevate the pressure on
the concentrated side of the RO system and push the water through membrane(s). It is a highly
effective water treatment process that needs a higher degree of pressure depending on the total
amount of contaminants existing in the feed water.

The purified water that is removed of its dissolved solids is now referred to as permeate or
product water. The concentrated stream of contaminants left behind in the brine is referred to as
reject water and is ultimately discharged.

The reverse osmosis membranes sole responsibility is to ensure efficient filtration of all
unwanted salts and minerals from the feed water as it passes through the system. Membranes
from top-branded manufacturers (Dupont Filmtec, Hydranautics) are capable of eliminating up
to 99% of dissolved solids from the water source. The rejected stream is not always thrown
away, it can be recycled through the reverse osmosis system for water conservation.

The reverse osmosis process is more similar to a cross-flow filtration method than a conventional
one. Cross-flow filtration is more effective since it consists of two outlets for the solution to go
in order to handle higher concentrations of pollutants. The flow of the permeate and concentrated
water in opposite directions allows the membrane surface to remain clean and greatly minimizes
buildup. This filtration method ensures a longer-life span of the system and components and
reduced the need for membrane cleaning.

Now that we know how reverse osmosis works, let's take that and apply it to a real, working
TWRO or BWRO system. If it only needed the membranes and a pump, it certainly wouldn't be
so big, right?
Here is the complete reverse osmosis process, including the pretreatment and post-treatment that
is generally required for highly contaminated water:

A) Pre-Chlorination Dosing System

If the feed water contains traces of heavy metals or contaminated, it is highly recommended to
dose some chlorine to change the dissolved heavy metals to physical form, the media filter will
be able to filter most of it.

B) Raw Water Storage Tank

Although some RO Systems can draw water right out of a well or pipe feed, most reverse
osmosis systems start with a large tank that stores the contaminated water. Not having enough
feed water can damage a pump, so having a large storage tank for your intake water is an easy
way to make sure your pump lasts for as long as possible.

C) Feed Water Pump

A commercial or industrial pump provides the initial pressure for the Treatment System. This
motor usually provides enough water pressure to get through any pretreatment as well as the RO
membranes, but if it doesn't a booster pump may be necessary farther down the line.

D) Multi-Layer or Media Filter

As much as we hate to admit it, there are some things that membranes can't purify. Nitrates, a
common contaminant found in fertilizers and animal waste, are a good example of particles that
dissolve too well in water for reverse osmosis to catch them. Things like foul odor and taste
usually aren't prevented by reverse osmosis, either. A Multi-Layer filter can be filled with media
that specifically targets the things your RO system can't catch. If you need to eliminate these
contaminants, a multi-layer filter is a must. An example of MMF or multi media filters is
our water media filters MF-1000 Series.

E) Activated Carbon Filter

Activated carbon filters are a good solution to reduce organic, bad taste, smell and chlorine from
the water.

F) Automatic Water Softener

Automatic water softeners are designed to remove water hardness, calcium and magnesium ions,
for small RO systems, we usually recommend water softeners instead of the antiscalant chemical
dosing.

G) Antiscalant Chemical Dosing System

For larger RO systems, we use antiscalant dosing systems to dose our PA0100 antiscalant RO
chemical, which helps in preventing membrane fouling. For more information, please visit our
CDS-Series chemical dosing pumps.

H) Reverse Osmosis System

We finally have our reverse osmosis system. If a booster pump is necessary, it will typically be
just before this step. The reverse osmosis system can produce up to one million gallons of
product water a day from a steady intake, as well as a sizable amount of waste. Usually the
wastewater can be dumped down the drain, but check with your local water authorities in case it
needs to be handled with care.

I) Product Water Storage Tank

The permeate from the reverse osmosis system will usually go to a large tank, where it is held for
use. If it didn't, the system would need to be running in order to have access to fresh water,
which can be inconvenient. Sometimes, a RO system pumps water directly into a well
or aquifer for recharging instead of being used in many of the normal industries or applications
it is used in.

J) Post-Chlorination Dosing System

If the permeate water is intended to be stored for more than one day, it is highly recommended to
dose some chlorine to maintain clean and non contaminated water.

K) Product Water Pump (Re-pressurization)

This pump repressurizes the permeate water to the point of use ends. This is selected based on
the overall travelling distance and required head. This pump must be selected in stainless steel to
prevent any contamination to the permeate water.

L) Product Water UV Sterilizer

The UV sterilizer is placed after the storage tank, and as a final disinfection device. Most of the
time, we either use post chlorination as a disinfectant agent, or ultraviolet sterilization.

 WHAT ARE THE BASIC COMPONENTS OF A

REVERSE OSMOSIS SYSTEM?
A Reverse Osmosis System is built of five basic parts:

1) Pressure Vessels & Membranes

Obviously, a reverse osmosis system wouldn't get very far without membrane elements. The
proteins that make up membrane elements vary depending on the kind of intake water and
ending clarity. There are membrane elements for brackish water, seawater, hospital-grade
disinfection, and membranes designed to remove specific contaminants to name a few. If there is
a water treatment need, you can be sure there is certainly a membrane element for the job. The
size of the task (municipal, commercial, or industrial) will determine the size and number
of reverse osmosis membranes in a system. There can be anywhere from a single two and a half
inch membrane (like in an under-sink reverse osmosis water system) to hundreds of eight inch
membranes all working together (a typical reverse osmosis plant).
2) Reverse Osmosis Skid
The best way to make your reverse osmosis system as durable as possible is with a powder
coated, carbon steel frame to mount all of your components on. It's resistant to the elements,
designed for the heavy vibration of high-pressure pumps, and mounts to the ground to ensure
that it will last a lifetime.
3) Cartridge Filter
Most reverse osmosis water systems come with a cartridge filter to ensure that no particles large
enough to damage the membranes come anywhere near them. This cartridge is usually a five
micron spun polypropylene filter, but can vary upon request. The cartridge comes in a durable
casing that can handle the pressure from the main feed or booster pumps.
4) Reverse Osmosis High Pressure Pump
Without a high-grade pump, the rejection rate for a reverse osmosis system isn't viable in most
commercial or industrial settings. It is vital to the system to ensure that the pump is matched to
the membrane quantity and size appropriately. Usually, the higher the horsepower on the intake
pump, the better the rejection and recovery rates of permeate.
5) Control Panel

Lastly, the reverse osmosis system has to be controlled by a human operator. At Pure Aqua, we
use advanced PLCs or a solid-state microprocessor depending on how advanced the controls
need to be. The controls can also be used to manage multiple systems simultaneously, effectively
making a one-man water production plant.

A reverse osmosis system can have a number of other components built onto or into it as extra
components as well. The entire skid can be built into a containerized system, for example, so
your Desalination by RO System is always on the go. There are a number of supplemental skids
that can be attached to an RO System as well, for tasks like membrane cleaning, pretreatment,
chemical dosing, and a number of other jobs as necessary.

 WHAT TYPES OF COMMERCIAL/INDUSTRIAL

APPLICATIONS DO RO SYSTEMS SERVE?
If there is a necessity for water treatment, chances are a reverse osmosis system can do the job.
There's a wide array of industries that benefit from having highly pure reverse osmosis water, as
well as a large number of applications where water treatment is required. Because of the extreme
volumes of water required, a reverse osmosis system is often the ideal, economical solution,
requiring less energy than most large-scale treatment methods. Because they consume less
energy, a reverse osmosis system is often the environmentally friendly solution as well. At Pure
Aqua, we pride ourselves as being a go-to source for information and service helping you solve
your municipal, commercial, or industrial water treatment needs.

 Pretreatment of boilers
 Food and beverage treatment
 Industrial wastewater purification
 Deionized water filters
 Hotels and resorts
 Ice making
 Spot free car washes
 Pure ethanol
 Dairy industry
 Maple syrup
 Pharmaceuticals
 Water bottling
 Hospitals
 Agriculture
 Humidification

 WHAT TYPES OF WATER SOURCES DOES

REVERSE OSMOSIS TREAT?
Reverse Osmosis is an ideal water treatment solution in most types of water. Generally speaking,
all major water sources from a treatment standpoint can be broken down into three major
categories: tap water, also known as municipal sources, groundwater, which includes brackish
water, and saltwater. The biggest distinction between these three types is the Total Dissolved
Solids (TDS) content of each type. As a rule of thumb, the American Health Association requires
that drinking water is under 1,000 PPM TDS.
Tap water typically comes through a pre-existing infrastructure like city pipes or a damming
system. Reverse osmosis is often used in a tap water environment to reduce hardness, or the
debris deposited in water from traveling in metal pipes. Total dissolved solids is often a target of
water purification in tap water systems. RO water is ideal in applications like power plants,
pharmaceuticals, laboratories, and hospitals, where an extreme purity of water is crucial to the
industry. Tap water typically has a TDS of under 1,000 PPM.

Underground reservoirs of water are often brackish or highly brackish, meaning they contain
large volumes of salt, but not enough to be considered salt water. Groundwater reverse osmosis
is very common, and one of the best uses of a reverse osmosis system to date. Groundwater is
most often purified for the agriculture industry, the mining industry, and for residential use.
Groundwater is also a prized target of the bottling industry, because the unique mineral
combinations often have an appealing taste. Brackish water usually has a TDS of 5,000 PPM or
less, but can come in concentrations of up to 12,000 PPM.

Reverse osmosis salt water (sometimes referred to simply as desalination) is the turning of salt
water into drinking water. Ocean water has up to 45,000 PPM TDS. Typically, for environmental
reasons, a bore hole is dug in the ocean for this kind of reverse osmosis water, but an open intake
is more cost effective. The biggest uses of desalination come in providing water in areas that lack
a regular supply of fresh water.

 IS PRETREATMENT NECESSARY?

If you work with a reverse osmosis system, you understand that the feed water must be
preconditioned to protect the membranes from fouling and premature failure. An RO membrane
functions much like a cross flow filter. The membrane is constructed of a porous material that
allows water to pass through the membrane, but rejects up to 99% of the dissolved solids at the
membrane surface. The dissolved salts are concentrated in the reverse osmosis reject water, or
brine stream, where they are discharged to waste.
As the RO system continues to operate, the dissolved and suspended solids in the feed water
tend to accumulate along the membrane surface. If these solids are allowed to build up, they
eventually restrict the passage of the RO water through the membrane, resulting in a loss of
throughput. (The throughput capacity of the membranes is commonly referred to as the flux rate,
and is measured in gallons per square foot of membrane surface area per day.)

Early in the development of membrane systems, little was known about which impurities in
the reverse osmosis feed water are likely to cause fouling and a corresponding reduction in flux.
Today, many of these troublesome impurity treatments have been identified, and preventive
treatments have been devised that greatly reduce membranes fouling, thus prolonging the life of
the RO plant.

Autopsies of failed membranes modules have revealed a build-up of foulants caused by mineral
scales such as calcium carbonate; colloidal materials like clays and silica; dead and living
microorganisms; carbon particles; and chemical attached by oxidizing agents like chlorine,
ozone, or permanganate. Likewise, dissolved metals like iron and aluminum, whether naturally
occurring or added as a coagulant, can cause premature fouling and failure of the reverse
osmosis membrane.

 IS IT NECESSARY TO GET A WATER ANALYSIS?

A detailed chemical analysis of the RO feed water is an absolute necessity for identifying
potential foulants. This should include a measurement of the hardness (calcium and magnesium),
barium, strontium, alkalinity, pH, and chlorine. The data from the chemical analysis can be used
by the RO equipment designers to determine the optimum membrane array that will both
minimize the tendency of scale and deposit formation and maximize the recovery and flux rate.

For example, the Langelier Stability Index (LSI), a measure of the calcium carbonate scaling
tendency of the water, is computed from the water analysis to determine the maximum
permissible concentration of dissolved minerals in the reject stream before scale deposition
becomes a problem. Because of the number of variables that must be considered, these
calculations are difficult to do with pencil and paper. Fortunately, the membranes manufacturers
have developed computer programs that make these computations fast and easy to perform
where the user can project the performance of membranes at actual feed conditions.

Although a water analysis is helpful in predicting the tendency of dissolved minerals to cause
problems in the RO System, it does not always forecast the fouling tendency of colloids and
other finely dispersed suspended solids. The Silt Density Index (SDI) is a useful tool for
quantifying the fouling tendency of the feed water. This test is conducted by filtering a sample
through a 0.45 micron (µm) filter and measuring the time required to collect a unit volume of
filtrate. An index number is calculated from this data. Traditionally, a SDI value of less than 3.0
is desirable for reverse osmosis feed waters. The SDI measurement has certain limitations in that
it does not model the cross flow design of an RO membrane.

 WHAT DETERMINES THE PRECISE PRETREATMENTS

FOR A PARTICULAR RO?
In one word: analysis. Every source of water is different, and you never know what's in your
water until you have it analyzed. The water analysis, LSI, SDI, or CFI values are used to
determine the precise pretreatment requirements for a particular RO System. Since water
supplies vary considerably from one location to another, each pretreatment requirement will be
different. On average, most Reverse osmosis water systems need an antiscalant injector or water
softener to prevent damage to the RO membrane.

 DOES THE FEED WATER NEED TO BE

SOFTENED BY THE RO?
Ion exchange is a popular method for reducing the potential for mineral scale formation on the
membrane surface. Ion exchange softening uses sodium to replace scale-forming ions such as
calcium, magnesium, barium, strontium, iron, and aluminum to prevent damage to the membrane
elements. The sodium forms very soluble salts, which are readily rejected by the reverse osmosis
system and do not readily form mineral scales on the membrane surface. A sodium-cycle
softener is regenerated with sodium chloride brine. The spent regenerant, along with the softener
rinse water, must be discharged to waste. It is due to this process that ion exchange is
recommended for applications that have high metal contents in the treated water.

 WHAT IS DECHLORINATION USED FOR?

Generally speaking, chlorination is a double-edged sword when it comes to reverse osmosis
systems. As a method of disinfection, chlorination is not only efficient and practical, but it is
cost-effective as well. The only problem is that chlorine is too caustic for RO
membrane elements, and can cause serious damage. Dechlorination is a kind of chemical
injection that adds a chemical that forms salts with chlorine, making it readily rejected by the
membrane elements. In this circumstance, dechlorination is a must as far as water treatment is
concerned. Without dechlorination, reverse osmosis membranes are not only ineffective when it
comes to chlorinated water, but the chlorine will simply destroy the protein membrane.

 IS ACID INJECTION NECESSARY?

Just as acidic solutions aren't good for membranes, caustic solutions are equally damaging
to reverse osmosis membrane elements. Acid injection may be incorporated into the RO
pretreatment system to control pH and minimize the scale-forming tendency of the feed water.
Acid injection is indicated if the scale-forming tendency of the brine stream is above +0.3 as
measured by the LSI. Either sulfuric or hydrochloric acid can be used for this purpose. However,
sulfuric acid is less costly, and is more commonly used.

 WHAT DOES AN ANTISCALANT DO?

Antiscalants have been shown to be effective in extending the intervals between chemical
cleanings of the RO membranes. These products are generally formulated to include inorganic
phosphates, organophosphonates, and dispersants. Use antiscalant products that have been
approved by the membrane manufacturer, and follow all directions in applying and controlling
the product dosage. Some antiscalant contain negatively charged polymers and dispersants that
can react with cationic polymers that might be dosed up stream prior to the media filters. The
antiscalant must be compatible with these polymers; otherwise, the reaction product will foul the
membranes.

 DO ALL REVERSE OSMOSIS SYSTEMS REQUIRE

CHEMICAL CLEANING?
Despite all efforts to protect the RO system from fouling and loss of flux, eventually the
membranes will require chemical cleaning. A well-designed RO system will include provisions
for a cleaning skid to facilitate the cleaning process. The skid should include a chemical tank,
solution heater, recirculating pump, drains, hoses, and all other connection and fittings required
accomplishing a complete chemical cleaning of the RO modules.

Various chemical cleaning agents are available for maintaining RO membranes. The type and
amount of foulant will dictate the most effective cleaning agent. Acid cleaners’ best remove
mineral scale deposits. Hydrogen peroxide is commonly used to clean and sanitize membranes to
correct or prevent biofouling problems. In some cases, a mild solvent such as methanol is used.
Because of the number of variables involved in the selection and application of these cleaning
agents, contact the membrane manufacturer, equipment supplier, or a qualified chemical
consultant for specific advice and recommendations on how to accomplish an effective cleaning.

The operation of the RO System should be carefully monitored to predict when the membranes
would require cleaning. As a rule of thumb, cleaning is indicated when the normalized flux rate
decreases by 10%. Under ideal condition, assuming that the RO pretreatment system is properly
designed and operated, the frequency between membrane cleanings should be 3 months or more.
Cleaning every 1 to 3 months is considered a fair performance, and suggests that some
improvements in the pretreatment system should be considered. Cleaning frequencies every
month or more indicate a change in raw water quality, a problem with the pretreatment system,
or a problem with the operation of the RO unit.

 SUMMARY
Reverse osmosis is a reliable method for producing high-purity water. However, most water
supplies require some form of RO pretreatment such as softening, media filtration, activated
carbon, or chemical injection to protect the reverse osmosis membranes from premature fouling
or failure. The pretreatment requirements will vary from location to location, but the overall
objective remains the same: to maintain the design flux rates, minimize the membranes cleaning
frequency, and prolong the useful life of the RO equipment.