Page 1 of 7

MATERIAL SAFETY DATA SHEET OF MANCOZEB 455 G/L SC

Reference Mancozeb 455 g/L SC

Material Safety Data Sheet according to the Annex II of Regulation (EC) n°1907/2006 R.E.A.C.h modified by the
Annex I of Regulation (EU) n° 453/2010

----------------------------------------------------------------------------------------------------------------------------- -----------------
SECTION 1: Identification of the substance/mixture and of the company/undertaking
----------------------------------------------------------------------------------------------------------------------------- -----------------
1.1.Product identifier Mancozeb 455 g/L SC
Formulation Suspension Concentrate
1.2.Relevant identified uses of the Fungicide
substance or mixture
and uses advised against
1.3.Details of the supplier of the safety Coromandel International Ltd,
data sheet “Coromandel House”,
1-2-10, Sardar Patel Road, Secunderabad – 500 003,
Telangana, India
Tel: +91 40 27842034/+91 40 27847212
Tel: +91 40 27844117
Web Site : www.coromandel.biz
1.4.Emergency telephone number +91 2646 645941/42 (Ext 226)
------------------------------------------------------------------------------------------------------------------------------- ---------------
SECTION 2: Hazards identification
----------------------------------------------------------------------------------------------------------------------------- -----------------
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) 1272/2008
Statement of hazards Xn-Harmful. Xi-Irritating. N-Dangerous to the environment
Health hazards May cause respiratory irritation: H335
May cause an allergic skin reaction: H317
Risk hazards R20 Harmful by inhalation.
R37 Irritating to respiratory system
R43 May cause sensitisation by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-
term adverse effects in the aquatic environment.

2.2. Label elements

Labelling according to Regulation (EC) 1272/2008

HEALTH HAZARD HARMFUL

DANGEROUS FOR THE ENVIRONMENT

Signal word(s) WARNING

Safety statements S2 Keep out of the reach of children.
S13 Keep away from food, drink and animal feeding stuffs.
S20/21 When using do not eat, drink or smoke.
S22 Do not breathe dust.
S24 Avoid contact with skin.
S35 This material and its container must be disposed of in a safe way.
S37 Wear suitable gloves.
 Page 2 of 7

MATERIAL SAFETY DATA SHEET OF MANCOZEB 455 G/L SC

Reference Mancozeb 455 g/L SC

Material Safety Data Sheet according to the Annex II of Regulation (EC) n°1907/2006 R.E.A.C.h modified by the
Annex I of Regulation (EU) n° 453/2010

S61 Avoid release to the environment. Refer to special instructions/

2.3 Other Hazards Safety data sheets.

--
----------------------------------------------------------------------------------------------------------------------------- -----------------
SECTION 3: Composition/information on ingredients
----------------------------------------------------------------------------------------------------------------------------- -----------------
3.1. Substance
Chemical identification
Chemical Name Mancozeb
Manganese ethylenebis (dithiocarbamate) (polymeric) complex with zinc
IUPAC:
salt
EC No 006-076—00-1
CAS No 8018–01–7
3.2. Mixture
Mancozeb a.i. 455 g/L
Other Ingredients 545 g/L
Total 1000 g/L

------------------------------------------------------------------------------------------------ ----------------------------------------------
SECTION 4: First aid measures
----------------------------------------------------------------------------------------------------------------------------- -----------------
4.1. Description of first aid measures
In general Remove the affected person from the danger zone to a well-ventilated room
or to fresh air, and protect from chilling. Do not administer anything by oral
route and do not try to make vomit, call a treatment centre for poisoning
cases or a doctor. Take the label where possible.
After Inhalation Immediately remove to fresh air. Call a doctor immediately.
After eye contact Rinse immediately and thoroughly with plenty of water during at least 10 to
15 minutes. Eyelids should be held away from the eyeball to ensure thorough
rinsing. Seek medical advice if pain or redness persists.
After skin contact Remove contaminated clothing and thoroughly wash the affected parts of
the body with soap and water.
After Ingestion Call a doctor immediately and show the label. Rinse out mouth and
give water in small gulps to drink. DO NOT induce vomiting unless
directed to do so by a physician. If vomiting occurs give more water.

4.2. Most important symptoms and effects, both acute and delayed:
No further relevant information available.
4.3. Indication of any immediate medical attention and special treatment needed:
No further relevant information available.
Antidote: There is no specific antidote. Treat symptomatically.

----------------------------------------------------------------------------------------------------------------------------- -----------------
SECTION 5: Fire-fighting measures
----------------------------------------------------------------------------------------------------------------------------------------------
5.1. Extinguishing media Suitable: Foam, dry chemical powder, water spray or foam.
5.2. Special hazards arising from Thermal decomposition products may include toxic oxides of carbon,
the substance or mixture nitrogen and sulfur.
5.3. Advice for fire-fighters Move container from the fire area if possible. Fight fire from the maximum
distance, avoid breathing hazardous vapours, keep upwind. Stay away from
storage tank ends. Use agents suitable for type of surrounding Extinguish
only if flow can be stopped. Do not scatter spilled material with high
pressure water streams. Dike fire control water for later disposal.
 Page 3 of 7

MATERIAL SAFETY DATA SHEET OF MANCOZEB 455 G/L SC

Reference Mancozeb 455 g/L SC

Material Safety Data Sheet according to the Annex II of Regulation (EC) n°1907/2006 R.E.A.C.h modified by the
Annex I of Regulation (EU) n° 453/2010

Wear self-contained breathing apparatus. Cool tank/container with water

spray. If area is heavily exposed to fire and if conditions permit, let fire burn
itself out since water may increase the contamination hazard.

----------------------------------------------------------------------------------------------------------------------- -----------------------
SECTION 6: Accidental release measures
----------------------------------------------------------------------------------------------------------------------------- -----------------
6.1. Personal precautions, Wear protective adapted equipment and take back non protected people.
protective equipment and Withdrawal combustion and ignition sources and block bringing in oxygen
emergency procedures (ventilation).
6.2. Environmental precautions DO NOT CONTAMINATE SURFACE WATERS OR DITCHES with chemical or used
container.
Do not clean application equipment near surface water/Avoid contamination
via drains from farmyards and roads.

6.3. Methods and material for Collect contaminated products on the surface concerned, transfer to closed
containment and cleaning up drums before sending in a specialized incineration treatment centre.
Wash the contaminated surface with water and collect washing waters for
treatment.
Cover the contaminated zone using absorbent materials such as sand.
See section 8 for personal protection and section 13 for disposal
considerations.
6.4. Operator Protection Engineering control of operator exposure must be used where reasonably
practicable in addition to the following personal protective equipment:
Operators must WEAR SUITABLE PROTECTIVE CLOTHING, SUITABLE
PROTECTIVE GLOVES AND SUITABLE RESPIRATORY PROTECTIVE EQUIPMENT
(FACESHIELD) when handling the concentrate.
Avoid contact with skin and eyes.
Do not breathe spray.
WASH CONCENTRATE from skin or eyes immediately
WHEN USING, DO NOT EAT, DRINK OR SMOKE.
WASH HANDS AND EXPOSED SKIN before eating and drinking and after work.
If swallowed, seek medical advice immediately and show this container or
label.

----------------------------------------------------------------------------------------------------------------------------------------------
SECTION 7: Handling and storage
----------------------------------------------------------------------------------------------------------------------------- -----------------
7.1. Precautions for safe handling Do not eat, drink or smoke when using.
Wear appropriate protective clothes, adequate gloves (nitril), glasses or
mask.
Avoid all contact of skin, eyes or clothes with new or old product.
Respect good hygienic body conditions and cleanliness of the working
area.
Wash hands abundantly after handling.
Do not wash working clothes with household linen.
7.2. Conditions for safe storage, Keep away from food, drink and animal feeding stuffs.
including any incompatibilities Store in a well closed container, in a fresh and well ventilated place.
Store under cover, in an appropriate room, away from heat and sources
of fire.
7.3. Specific end uses No further relevant information available.

----------------------------------------------------------------------------------------------------------------------------- -----------------
SECTION 8: Exposure controls/personal protection
 Page 4 of 7

MATERIAL SAFETY DATA SHEET OF MANCOZEB 455 G/L SC

Reference Mancozeb 455 g/L SC

Material Safety Data Sheet according to the Annex II of Regulation (EC) n°1907/2006 R.E.A.C.h modified by the
Annex I of Regulation (EU) n° 453/2010

----------------------------------------------------------------------------------------------------------------------------- -----------------
8.1. Control parameters TLV not established

8.2. Exposure control

General measures When using refer in priority to information written on the label.
No special equipment is usually needed when occasionally handling
small quantities. The following instructions are for bulk handling or
where regular exposure in an occupational setting occurs without
proper containment systems.
Control of professional exposure
Respiratory protection Local exhaust or breathing protection.
Hand protection Wear impermeable gloves, resistant to organic solvents and to chemical
products.The glove material has to be impermeable and resistant to the
product/ the substance/ the preparation.
Eyes protection Preferably wear a mask, a face screen or protective glasses.
Skin protection Wear appropriate protective clothes, covering all parts of the body.
Control of environment exposure Respect European and National Regulations in term of environment.

----------------------------------------------------------------------------------------------------------------------------- -----------------
SECTION 9: Physical and chemical properties
----------------------------------------------------------------------------------------------------------------------------- -----------------
9.1. Information on basic physical and chemical properties
Appearance Yellow coloured Liquid Suspension.
Odour No specific odour.
pH 5-9
Flammability Non Flammable
Relative self-ignition temperature Does not self-ignite.
Explosives properties Non Explosive
Oxidising properties Does not to possess oxidising properties.
Density 1.2-1.4 g/ml at 200C
Suspensibility >85% min by Mass
Wet Sieving 2% Max Retention on 75 µm sieve
Persistence Foaming 25 ml Max after 1 minute
Pourability 5% Max Residue
Spontaneity of Dispersion >80% min by Mass
Solubility
- Water Forms suspension
Vapour Pressure 10.5 × 10-6 Pa (25°C) (Mancozeb Technical)
Partition Coefficient logP = 0.20 at 200C (Mancozeb Technical)
Corrosivity Non corrosive to Aluminium, copper, Zinc and Polyethylene
9.2. Other information No further relevant information available
----------------------------------------------------------------------------------------------------------------------------------------------
SECTION 10: Stability and reactivity
----------------------------------------------------------------------------------------------------------------------------- -----------------
10.1. Reactivity Non-Reactive/ Non-Oxidising.
10.2. Chemical stability Thermal decomposition / conditions to be avoided: No
decomposition if used according to specifications
10.3. Possibility of hazardous reactions No dangerous reactions known.
10.4. Conditions to avoid Never heat the compound above or near to melting point
temperature.
10.5. Incompatible materials Avoid acidic material, strong oxidizers.

----------------------------------------------------------------------------------------------------------------------------- -----------------
SECTION 11: Toxicological information
 Page 5 of 7

MATERIAL SAFETY DATA SHEET OF MANCOZEB 455 G/L SC

Reference Mancozeb 455 g/L SC

Material Safety Data Sheet according to the Annex II of Regulation (EC) n°1907/2006 R.E.A.C.h modified by the
Annex I of Regulation (EU) n° 453/2010

----------------------------------------------------------------------------------------------------------------------------- -----------------
Hazard classes Toxic if inhaled
Acute toxicity U, Unlikely to be Hazardous
by ingestion (rat) LD50 > 2000 mg/ Kg of Body Weight
by skin contact (rat) LD50 > 2000 mg/ Kg of Body Weight
by inhalation (rat) LC50 (4 h) > 4.94 mg/l air
Skin irritation (rabbit) Non Irritant
Eye irritation (rabbit) Non Irritant
Skin sensitization (guinea-pig) Weak Sensitizer
Subchronic toxicity NOEL (6 mo) for dogs 0.005 mg/kg b.w. (Technical)
Chronic toxicity
Carcinogenicity IARC Carcinogens: Not Listed
U.S. NTP Carcinogens: Not Listed
California Prop 65 Known Carcinogens: Not Listed
U.S. EPA Carcinogens: E, Unlikely
TRI Carcinogen: Not Listed
Teratology None
Toxicity to reproduction Reproductive toxicity - Mouse – Oral
Paternal Effects: Spermatogenesis (including genetic material,
sperm morphology, motility, and count).

----------------------------------------------------------------------------------------------------------------------------- -----------------
SECTION 12: Ecological information
----------------------------------------------------------------------------------------------------------------------------- -----------------
12.1. Toxicity
Aquatic organisms Fishes Acute (96h) LC50 = (96 h) 9.75 mg/l for Poecilia Reticulata
Daphnids Acute (48h) EC50 = o.43 mg/l.
Algae Acute (72h) ErC50 = 0.19 mg/l Pseudokirchneriella
subcapitata
NOEC = 0.02 mg/L
LOEC=0.04 mg/L
EyC50 = 0.051 mg/l Pseudokirchneriella
subcapitata
NOEC = 0.02 mg/L
LOEC=0.04 mg/L
Terrestrial organisms Birds Acute LD50 = > 2000 for Japanese quail
Bees Oral LD50 = (48 h) > 100 µg a.i./bee
Contact LD50 = (48 h) > 100 µg a.i./bee
Earthworms Acute LD50 = LC50 (14 d) > 1000 mg/kg dry weight of
soil
Soil Microorganism No long term effect on Carbon Transformation
of soil microorganism
No long term effect on Nitrogen
Transformation of soil microorganism

12.2. Persistence and degradability mancozeb is of low soil persistence

12.3. Bioaccumulative potential does not bioaccumulate
12.4. Mobility in soil Mancozeb has low solubility in water and moderate adsorption
capacity in soil. It can be hydrolyzed within one day and has a
field half day of 1 to 7 days
12.5. Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable
12.6. Other adverse effects Very toxic to aquatic life with long lasting effects.
----------------------------------------------------------------------------------------------------------------------------- -----------------
SECTION 13: Disposal considerations
------------------------------------------------------------------------------------------------------------------ ----------------------------
 Page 6 of 7

MATERIAL SAFETY DATA SHEET OF MANCOZEB 455 G/L SC

Reference Mancozeb 455 g/L SC

Material Safety Data Sheet according to the Annex II of Regulation (EC) n°1907/2006 R.E.A.C.h modified by the
Annex I of Regulation (EU) n° 453/2010

13.1. Waste treatment methods

Product/packaging Disposal of important amounts must be made by duly authorized specialists.
Incineration should be made in authorized and specialized plant.
Eliminate the product and its packaging with care and in a responsible way.
Do not throw near ponds, rivers, ditches or into sewers.
Wash contaminated surfaces with water and collect washing waters for
treatment. Make sure that local Regulations are respected.
Washing products Do not throw into sewer. Do not contaminate natural waters.
Clean up application materials on the treated area and eliminate waters by
spraying on one area.
----------------------------------------------------------------------------------------------------------------------------- -----------------
SECTION 14: Transport information
----------------------------------------------------------------------------------------------------------------------------- -----------------
Regulation RID/ADR IMDG OACI/IATA
(Terrestrial) (Maritime) (Aerial)
UN code 3082 3082 3082
Class 9 9 9
Specific point / code None None None
Packing group III III III
Environmental hazard classes Marine Pollutant
Wording ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Mancozeb).

----------------------------------------------------------------------------------------------------------------------------- -----------------
SECTION 15: Regulatory information
----------------------------------------------------------------------------------------------------------------------------------------------
15.1. Safety, health and environmental regulations / legislation specific for the substance or mixture
Information regarding relevant Community safety, health and environmental provisions
Xi - Irritant N – Dangerous for the Environment.
Risk hazards R20 Harmful by inhalation.
R37 Irritating to respiratory system
R43 May cause sensitisation by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-
term adverse effects in the aquatic environment
Signal word(s) WARNING
Safety statements S2 Keep out of the reach of children.
S13 Keep away from food, drink and animal feeding stuffs.
S20/21 When using do not eat, drink or smoke.
S22 Do not breathe dust.
S24 Avoid contact with skin.
S35 This material and its container must be disposed of in a
safe way.
S37 Wear suitable gloves.
S61 Avoid release to the environment. Refer to special
instructions/ Safety data sheets.
15.2. Chemical safety assessment: A Chemical Safety Assessment has not been carried out
 Page 7 of 7

MATERIAL SAFETY DATA SHEET OF MANCOZEB 455 G/L SC

Reference Mancozeb 455 g/L SC

Material Safety Data Sheet according to the Annex II of Regulation (EC) n°1907/2006 R.E.A.C.h modified by the
Annex I of Regulation (EU) n° 453/2010

-------------------------------------------------------------------------------------------------------------------------- --------------------
SECTION 16: Other information
--------------------------------------------------------------------------------------------------------------- -------------------------------
MSDS Date 15.06.2017
MSDS first revised date 23.05.2018
Material Safety Data Sheet according to the Annex II of Regulation (EC) n°1907/2006 R.E.A.C.H modified by the
Annex I of Regulation (EU) n° 453/2010

Disclaimer: The above information is intended to give general health and safety guidance on the storage and
transport of the substance or product to which it relates. The requirement or recommendation of any relevant site
or working procedure, system or policy in force or arising from any risk assessment involving the substance or
product should take precedence over any of the guidance contained in this safety data sheet where there is a
difference in the information given. The information provided in this safety data sheet is accurate at the date of
publication, and will be updated as and when appropriate. No liability will be accepted for any injury loss or
damage resulting from any failure to take account of information or advice contained in this safety data sheet.