Student's Solution Copy [Code - 27886]

BRAHMASTRA_Part Test-03 Advanced Paper - 1

12th JEE (M+A) - Phase 1
KOTA

Date: 27-Apr-2025 Duration: 3 Hours Max Marks: 180

Maths - Section A
1. Answer: A 2. Answer: C

Sol: Sol:

from the figure, using the definition of

tanθ in three right angled triangles with
angle θ, we get
a−1 7−a
tan θ = =
3 10−b

also
7−4 3
tan θ = =
b−3 b−3

hence
3 a−1 7−a
= =
b−3 3 10−b

Area of a quadrant = π

4
; Area of
1
ΔABC =
2

shaded region (a) = π

4
−
1

Area of =
1

2
−(
π

4
−
1

2
)= 1 −
π

Area of the required figure

π π π π π
st = 2(1 − )+ + = 2 − + = 2
from 1 two relations 4 4 4 2 2

3 a−1
=
b−3 3

9 = ab − b − 3a + 3

3a + 6 = ab − b ....(1)

from last two

a−1 7−a
=
3 10−b

10a − ab − 10 + b = 21 − 3a

13a − ab + b = 31

or ab − b = 13a − 31 ....(2)

hence from (1) and (2)

3a + 6 = 13a − 31 ⇒ 10a = 37

⇒ a = 3.7 Ans. ]

Aliter : Image of the point A(3, 4) in

the line y = 7 is (3, 10) and image of
the point B(7, 1) in the line x = 10 is
(13, 1) Hence equation of A'B' is y − 1
−9
= 10 (x − 13) put x = 10 ⇒ y = 10 =
37

3.7 Ans.]
3. Answer: C 4. Answer: D

Sol: Sol:

put
π cos 2x
= x T1 =
28 sin 3x

cos 2x sin x 1 sin 3x−sin x

= =
sin 3x sin x 2 sin 3x sin x

=
1

2
[cosecx − cosec 3x] etc.]

−−→ −
−→
1
∵ AM = AC
3

AM : MC = 1 : 2
→ → →
2 a + c
M =
3

∵ X lies on AB
→ →
X = r a ....... (1)

Let x divides NM in λ : 1 ratio

→ →
2 a + c →
→ → λ( )− c
→ 3

....... (2)
λ M+ N
X = =
λ+1 λ+1

From (1) & (2)

→ →
2 a λ c →
λ ( )+ − c
→ 3 3

r a =
λ+1

2λ → λ →
a +( −1 ) c
3 3
=
λ+1

→
On comparing coeff. of c both sides
λ
− 1 = 0 ⇒ λ = 3
3

This means X divides MN in 3 : 1 ratio

−
−→ −−→
3
∴ XN = MN
4
 Maths - Section B

5. Answer: A,C 6. Answer: B,C

Sol: Sol:

We know that F1M1 · F2M2 = 25 ∵

1
2
+ 2
1
= 1
Now, A.M. ≥ G.M. (using focus directrix
e f (e)

property of ellipse) 1 1
⇒ = 1 −
F1 M1 +F2 M2 f
2
(e) e
2

≥ √F1 M1 ⋅ F2 M2
2

F1M1 + F2M2 ≥ 2√25

2
e −1
=
F1M1 + F2M2 ≥ 10
2
e

Squaring both sides 2 e

2

⇒f (e)=
F1M1 2 + F2M22 + 2F1M1 · F2M2 ≥ 100 2
e −1

F1M1 2 + F2M22 + 2 × 25 ≥ 100 ⇒f (e)=

e

F1M1 2 + F2M22 ≥ 50 ] √e −1
2

f (e)
∴ f (f (e)) =
2
√f ( e ) −1

√ 2
e −1
= = e
2
e
√ −1
2
e −1

∴f (f (f (e))) = f (e)

∴ f (f (f . ........ f (e). ....))

e , if n is even
= { e
, if n is odd
2
√e −1

(i) If n is even then given integral

3 3
2
e
= ∫ e de = ( )
2
1
1

9−1
= = 4
2

(ii) If n is odd then given integral

3
e
= ∫ de
2
√e −1
1

3
2
= (√ e − 1) = √8 − 0
1

= 2√2 ]
7. Answer: A,C

Sol:
→
Any vector r in space can be written
as

→ → → →
→
r = λ a + μ b + k ( a × b )

→ →
take dot product with a × b , we get
5
k =
4

→
→ → →
Let r . a = λ; r ⋅ b = μ

→ →
→
∵ r ⋅ (3 a + 2 b ) = 0

⇒ 3λ + 2μ = 0

4
− μ 2λ
Given 3 x+1 x+1
∫ dx= ∫ dx
−2λ x +1
2 −2λ 2
x +1

2λ dx π
−1
= 2∫ = 2 tan (2λ)=
0 x +1
2 2

and
1 3
⇒ λ = μ = −
2 4

→ → → →
→ a 3 5
∴ r = − b + ( a × b )
2 4 4

∣ →∣
and
1 9 25
∣ r ∣ = √ + +
∣ ∣ 4 16 16

2
∣ →∣ 19
⇒ r =
∣ ∣ 8
 Maths - Section C

8. Answer: 5 9. Answer: 5

Sol: Sol:

∣â × ˆ
2
2 The successive co-ordinates of the
b∣ = sin θ
∣ ∣
particle's path are
2 2
(1 − cos θ = sin θ) −1 −1 −1 −1 1
(1, 1)(1, ),( , ),( , 2
),
k k k k k
2
sin θ
1 1
∴ g(θ)= ∫ 2
(2t + 1)dt ( , ), … …
2 2
− cos θ k k

Thus the total distance travelled by

sin θ

+ t)∣
2
=(t ∣
particle is given by d = 1 + 1 + 1+ 1 +
2
− cos θ
k k
4 2 4 2 1 1 1 1
= sin θ + sin θ −(cos θ − cos θ) + 2
+ + 2
+……∞
k k k k

4 4 1
= sin θ − cos θ + 1 d = 2(1 + )
k

2 1 1
2
= 1 + sin θ − cos θ (1 + + 2
+ … … ∞)
k k

2
= 1 − cos 2θ = 2 sin θ
1 1
d = 2(1 + )( )
Now, Volume of parallelopiped = k 1−
1

ˆ ˆ
[â â × b â × (â × b)]
2(k+1)
d = = 3
(k−1)

ˆ ˆ
= (â × (â × b) ⋅ (â × (â × b)))
2k + 2 = 3k – 3

∣ ˆ ∣
2 Hence, k = 5
V = ∣â × (â × b)∣

2
ˆ∣ 2
= ∣ ∣∣
∣â∣∣â × b∣ sin 90°

2
= sin θ

Now,
1 2 1
g(θ)= ⇒ 2 sin θ =
2 2

⇒ sin
2
θ =
1
hence V = 1

4 4

∴ (p + q)least = 5 Ans.
10. Answer: 39 11. Answer: 0008

Sol: Sol:
√3 Angle made by the line in new position
Given, area (ΔO1 O3 O5 )= 12√3⇒
4
is
(side)2 = 12√3
−1 −1 π
= cot 2 + cot 3 =
[Note: ΔO1O2O3 is equilateral with
4

length of each side equal 4r] Equation of the line in new position is
y + 4 = 1(x − 0)

⇒ x − y − 4 = 0

Centre and radius of the circle in IV

quadrant touching

⇒ (O1 O3 )= 4√3

Also, O1 O3 = 4r = 4√3

⇒ r = √3 (radius of circle)
MO3 coordinate axes are (h, – h) and h
In Δ BMO3 , = tan 30°
BM
respectively (h > 0).
√3
. Now applying
1
⇒ = ⇒ BM = 3 p = r
BM √3

∣ ∣
Also, BC = BM + MN + CN
h+h−4
( ) = h
∣ √2 ∣

⇒a = 3 + 4√3 + 3 or a = 6 + 4√3
2
⇒ h − 8h + 8 = 0
√3
So, area (Δ ABC)=
4
a
2

2
Hence
√3
= (6 + 4√3)
4
h1 = 4 + 2 √ 2

2
h2 = 4 − 2 √ 2
= √3(3 + 2√3)

(h1 + h2 ) = 8

= √3(21 + 12√3)
Therefore, the correct answer is 0008 .

= 36 + 21√3 = p + 21√q

(Given) ⇒ p = 36, q = 3.

Hence, (p + q) = 39.
12. Answer: 5 13. Answer: 50

Sol: Sol:

Image of A(h, 0) in the line mirror mx

–y=0

2 at3
=–1
2
×
t1 +t2 2
a(t −1) x−h y−0 mh
3
= = −2 ( )
m −1 m +1
2

2
1−t
2 3
= 2
t1 +t2 2t3 h(1−m )
x= , y=
2 mh
2 2
1+m m +1
4t3
t1 + t 2 = h(1−m )
2

C
2
1−t 2 mh
3 ∴ ≡ ( , )
2 2
1+m m +1

4t3
t1 + t 2 + t 3 = + t3 −h(1−m )
2

Similarly D
2 −2 mh
1−t
3 ≡( , )
2 2
3 3 1+m m +1
4t3 +t3 −t 5t3 −t
= =
3 3

2 2
1−t 1−t 2 2
3 3 h(1−m ) 2 2

AC =√(h −
4m h

If t1 + t 2 + t 3 = u then 1+m
2
) +
(1+m )
2
2

3
5t3 −t
u= ....(1)
3
4 2 2 2

=√
2 4m h 4m h
1−t
3
+
2 2
2 2

The Equation (1) suggests that t3 is a (1+m ) (1+m )

root of =
2 mh √1+m
2

t3 – ut2 – 5t + u = 0 ....(2) (1+m )

2

by symmetry t1 and t2 are also the root h(1−m )

2
2
2 2

of (2). Hence AD =√(h + 2

) +
4m h
2
1+m 2
(1+m )
t1 + t 2 + t 3 = u 2 2 2

and t1 t2 t3 = – u =√
4h
2
+
4m h
2

Hence t1 + t2 + t3 + t1 t2 t3 = 0
2 2
(1+m ) (1+m )

also t1t2 + t2t3 + t3t1 = – 5 =

2h
√1 + m2
2
(1+m )
∣ t1 + t2 + t3 + t1 t2 t3 + ∣
Hence ∣ ∣ =5 2
4 mh (1+m )
2

∣ t1 t2 + t2 t3 + t3 t1 ∣
∴ Area = AC · AD = 2

Ans.
2
(1+m )
2

=
4h
1
m+
m

Area|max = = 50 Ans.]
4×25

2
Maths - Section D
14. Answer: D 15. Answer: B

Sol: Sol:

(A)–R ; (B)–S ; (C)–P ; (D)–Q (P) The equation of plane ABC is y + z

2
2
– 1 = 0. Also, equation of line
y
(A)
x
+ = 1
9 4 y−0
(say)
x−0 z−2
L : = = = λ
0 1 1

So, any point on line L is (0, λ , λ + 2)

Put this point in equation of plane ABC,

we get λ = 2 .
−1

equation of tangent at P(θ) is −1 3

∴ (x0 , y0 , z0 )≡(0, , )
2 2
y
x cos θ

3
+
2
sin θ =1 ⇒(7x0 + 2y0 + 8z0 )= 11

equation of A'P : → →
(Q) [
→
a × b
→
b × c
→ →
c × a
]= 25

y=
2 sin θ
(x + 3) [ ] ∣ → → ] ∣= 5
3(1+cos θ) ⇒ [→
∣ a b c ∣

⇓ x = 0 →→
→ → → →
∴ [ a + b b + c c + a ]

2 sin θ
M (0, )
1+cos θ ∣ →→→ ∣
= 2∣[ a b c ]∣ = 2(5)= 10
∣ ∣
OQ2 – MQ2 = 4

(B) Let any point on hyperbola be (R) Let equation of plane be

y
= 1, which meets axes at
x z
+ +
a b c
P(asecθ, btanθ) P(a, 0, 0), Q(0, b, 0), R(0, 0, c)
2 2 2 2
a b (sec θ−tan θ)
p1 p2 = 2 2
=6 The centroid of Δ PQR is (
a
,
b
,
c
)
a +b
3 3 3

=6
a ×a×2

… (1)
1 1 1 λ
3a
2 ∴ 2
+ 2
+ 2
=
a c 9
b

⇒ a2 = 9 √3
Also,
1
=
2
⇒a=3
1 1 1
√ + +
2 2 2
a b c

… (2)
4 1 1 1
2 ⇒ = + +
(C) put x = ae, y =
b 3 2 2 2
a b c
a

∴ From (1) and (2), we get

in x2 = –2(y – 2)
4 λ
2 = ⇒ λ = 12
2 2 b −2a
a e = -2 (
a
)
3 9

∣ ˆ ∣
î ĵ k
a3e2 = – 2[a2e2 + a2 – 2a] →
→ ∣ ∣
(S) α × β =∣ −1 1 2 ∣
∣ ∣
‖ only
⇓
[a = 2] satisfies ∣ −1 −2 −1 ∣
→∣
(D) ˆ
∣→
= 3 î − 3 ĵ + 3k⇒ ∣ α × β ∣ = 3√3
∣ ∣

∴ Area of parallelogram
→ →
1 ∣ → ∣ ∣→ ∣
= ∣√ 3 α × 2 β ∣= √ 3 ∣ α × β ∣
2
∣ ∣ ∣ ∣

= √3(3√3) = 9

(S1F1)(S2F2) = (Semi Major Axis)2

∴ (S1F1)(S2F2) = 3
16. Answer: A 17. Answer: A

Sol:

(A) x2 + k2x2 – 20kx + 90 = 0

x2(1 + k2) – 20kx + 90 = 0

D<0

400k2 – 4 × 90(1 + k2) < 0

10k2 – 9 – 9k2 < 0

k2 – 9 < 0 ⇒ ∈ k [–3, 3]
p p
(B) 2(
2
× 5 +
2
× p)= −6
2
⇒ −5p + p + 6 = 0

⇒ p
2
− 5p + 6 = 0⇒ p = 2 or 3

(C) r
2
1
= λ
2
− 4 ≥ 0

λ ∈ (−∞, −2] ∪ [2, ∞) … (1)

2 2
r = 4λ − 8 ≥ 0
2

2
λ − 2 ≥ 0

λ ∈ (−∞, −√2] ∪ [√2, ∞) … (2)

(1)∩(2) is λ ∈ (−∞, −2] ∪ [2, ∞)

(D)

Ans. {1, 5}
Sol:

(A) ➝ R; (B) ➝ P; (C) ➝ S ; (D) ➝ Q

mOP =
2at−0 2
=
2 t
at −0

Equation of PQ is
−t 2
(y − 2 at) = (x − at )
2

2y2 − 2ky + (k2 − lh) = 0

As (1) and (2) are tangent to each

other, so

Discriminant = 0

⇒ 4k2 − 8(k2 − lh) = 0

Put y = 0, x = 4a + at2
⇒ k2 − 2k2 + 2lh = 0
Clearly projection of
⇒ k2 = 2lh
PQ on axis = MQ = | 4a + at2 − at2 |
∴ Required locus is y2 = 2lx
= 4a = l (Given)
⇒ Latus rectum = 2l ]
(B) Equation of normal at P(at2, 2at) is
(D) Clearly 2h = a + at2 ....
y = − tx + 2at + at3 (1)
Put y = 0, x = 2a + at2 and 2k = 2at .... (2)
∴ G(2a + at2, 0) ∴ On eliminating t from (1) & (2),
Now 2h = 2a + 2at2 .... (1)

and 2k = 2at .... (2)

we get locus of M(h, k) is

2 a
∴ On eliminating t from (1) & (2) y = 2a (x −
2
)

we get locus of M(h, k) is ⇒ Latus rectum = 2a =

l
(Given)
2

y2 = a(x − a)

⇒ Latus rectum = a =
l

4
(Given)

(C) We have y2 = lx (fixed parabola)

....(1)

Let variable parabola be

(y − k)2 = − l(x − h) ....(2)

∴ On solving (1) and (2), we get

y2 − 2ky + k2 = − y2 + lh
 Physics - Section A

1. Answer: C 3. Answer: A

Sol: Sol:

The coercitiuy of bar magnet is dB

E = − NA( )
. i.e., its required a
3 −1 dt
4 × 10 AM
magnetic intensity E NA d −200t −4
∴ i = = (75e )×10
R R dt
3

to get
H 4×10
∴ i = = = 8. 0 A
n 500 NA −200t −4
= [75 × (−200)e ]×10
dimafneticad Let 'i' be the current R

carried by solenoid having 'n' number 50×7×10

−8
−1
of twins per meter length , then =
30
[15000e ]

−5 −5

H = ni =
175×10
=
175×10
= 0. 64 × 10
−3
A = 0. 64 mA
e 2.73

Here,
3 −1
H = 4 × 10 Am 4. Answer: B
and twin/m
60
Sol:
N
n = = = 500
l 0.12

Resonant frequency
3 1
H 4×10 nr =
∴ i = = = 8 .0 A 2π√LC
n 500

2. Answer: B
1
=
−6
2π√5×80×10

Sol: 1
=
−6
2π√400×10
I 1
T = 2π√ ⇒ T ∝
M×BH √BH
100 25
= =
4π π

T1 ( BH ) 60/40 ( BH )

Therefore, the correct answer is (B)

2 2
⇒ = √ ⇒ = √ −5
T2 ( BH ) 2.5
1 0.1×10

−6
⇒ (BH ) = 0. 36 × 10 T
2
 Physics - Section B

5. Answer: A,B 6. Answer: B,D

Sol: Sol:

Direction of I1 and I2 is determined by

right hand thumb-rule.

Net magnetic field between wires,

μ0 I μ0 I 2
B = +
2πx 2π(d−x)

For minimum
dB
B, = 0
dx

d
⇒ x =
3
ε = Bv l

q = Cε = CBvl
dq
...
dv
i1 = = CB l
dt dt

(i)
Ldi2
= Bv l
dt

Bl
∫ di2 =( )∫ vdt
L

i2 x
Bl
∫ di2 = ∫ dx
0 L 0

i2 =(
Bl

L
)x ...(ii)

dv
m = F − Bi l
dt

mdv
= F − Bl(i1 + i2 )
dt

mdv
= F − Bli1 − Bli2
dt

dv dv Bl
m = 2mg − Bl(CB l )−Bl( )x
dt dt L

2 2 2 2 mgL
2 2 d x B l
(m + CB l ) 2
= − (x − 2 2
)
dt L B l

2 2 2
d x B l 2 mgL

2
= − (x − 2 2
)
2 mL B l
dt

2 2
[∵ CB l = m]

∴ angular frequency of SHM executed

by the rod is
Bl
ω =
√2 mL

The amplitude of SHM executed by the

rod is
2 mgL
A = 2 2
B l

The maximum horizontal displacement

of the rod
4 mgL
xmax = 2A = 2 2
B l
7. Answer: A,C

Sol:

At resonance

XL = XC and Z = Zmin = R

XL = ωL and 1
= XC
ωC

Not only at resonance, but at all

conditions voltage avron L and C
diffence in phasso by 180∘ when
connected in sereies.

(f = 900HZ ) < (fres = 1000HZ ) ,

So (XC ) > (XL ) ; circuit becones

capacitive and current leads emf
 Physics - Section C

8. Answer: 1 11. Answer: 6

Sol: Sol:

E =
1
(r)μ0 nk First we calculate the frequency using
2
the formula;
qrμ nk
Force =
0

2 ω =
1
=
1

√LC 2

qrμ nk(πr)
Work
0 1 2
=
2
=
2
mv
Using the relation q = Q cos (ωt + ϕ)

we get
μ0 qnkπ
⇒ v = r√
m
4 = Q cos (ωt + ϕ) ....(i)
9. Answer: 2.00 And using the relation
Sol:
i = −ωQ sin (ωt + ϕ) we get
1
→ → μ
0
I μ
0
I
π √5 = − Q sin (ωt + ϕ)
∫ B ⋅dℓ CDA + ×2 2
2 2π 6
= = 2
→ → μ
0
I μ
0
I
π
∫ B ⋅dℓ ABC 2
−
2π
(
6
) ×2
or −2√5 = Q sin (ωt + ϕ) ....
(ii)
10. Answer: 16.00
Squaring (i) and (ii) we get
Sol:
2

Induced emf between centre and Q

2
= 4
2
+ (−2√5) = 36
1 2
B1 = Ba ω
2

or maximum charge Q = 6C
Induced emf between centre and
B2 =
1
B(
a
)
2
⇒x = 6
2 2

1 2
12. Answer: 4
ω = Ba ω
8
Sol:
Induced emf between B2 and
3 2 We have
B1 = Ba ω
8
2
Q Q0
2
or
0 1
Current in the inductor 2C
=
2
Li
0
i0 =
√LC
2 Rt
3 Ba ω −
= (1 − e L
)
8 R i0 = Q 0 ω

At t =
L
ln 2 here q = Q0 cosωt
R

3 Ba
2
ω and i = i0 sinωt or di
= i0 ωcosωt
i = dt
16 R

di 2
= ω (Q0 cosωt)
dt

di 2
= ω q
dt

1 −3
= × 100 × 10
−6
2×5×10

di 4
= 10
dt
13. Answer: 06.00

Sol:
2
P = E0 I0 sin ωtcosϕ + E0 I0 sinωtcosωtsinϕ

E0 I 0 E0 l 0
P = (1 − cos 2ωt)cosϕ + sin 2ωtsinϕ
2 2

E 0 I0 E 0 I0
P = cosϕ − cos(2ωt + ϕ)
2 2

E 0 I0
Pmax = (cosϕ + 1) = 3P
2

E 0 I0
Pmin = (cosϕ − 1) = −P
2

1 π 2π
⇒ cosϕ = ⇒ ϕ = =
2 3 6
 Physics - Section D

14. Answer: A 16. Answer: A

Sol: Sol:

T =
2πm
=
2πm
(P) → (A) : electrical energy stored.
qB 5q
(Q) → (AB) energy supplied, increasing
Velocity gets reversed after internal energy
T
⋅ zmax = 2R
(R) → (none) energy reduces, heat
2
flows out, internal energy drops
15. Answer: A (S) → (ACD) Mass to energy
conversion
Sol: (T) → (A) Current flows leading to heat
generation

Therefore, the correct answer is (A)

A : If we consider four such identical

paths with similar orientation forming a
closed path then for all that path
→ → → →
∫ B ⋅ dl = μ0 i . By symmetry, ∫ B ⋅ dl
μ0 i
along the given path is 4
.

Two such given paths form a closed

surface around the conductor
→ →
b μ0 i
∴ ∫ B ⋅ dl =
a 2

C : From Ampere's law, as the given

path is closed around|the conductor,
→ →
∫ B ⋅ dl = μ0 i

→ →
b
D :∫a B ⋅ dl is same in magnitude
with each of the two conductors but
reverse in sign. Hence net value is
zero.
17. Answer: D

Sol:

After closing the switch, at time t,

Rr
50 − ¯
i1 = [1 − e L
]
25

R1 25 −1
= = 2. 5s
L 10

L 10
t1 = = = 0. 4 s
R1 25

t
−
i1 = 2[1 − e 0.4
]A

Charge through C is
t
−
R C
q2 = 50 × C[1 − e 2
]

1
−
50 R C
i2 = e 2

R2

3 −5
[∴ t2 = R2 C = 5 × 10 × 2 × 10 = 0. 1 s]

t
−3 −
= 10 × 10 e 0.1
A

−t/0.1
i2 = 0. 01e A

i1 (t << 0. 4) = 2[1 − 1] = 0

Potential difference across

C(for t > 0. 1 s) = 50 V

I2 (t << 0. 1) = 0. 01 A = 10 mA

Potential diff. across L ( for t < 0. 4 s)

= 50V

Now, i1 = i2 implies that

t t
− −
2[1 − e 0.4
]= 0. 01e 0.1
, t << 0. 1s

t t
2[1 − 1 + ]= 0. 01[1 − ]
0.4 0.1

5t = 0. 01 − 0. 1t

0.1 100
t = s = ms = 2 ms
51 51

Therefore, the correct answer is (D)

HINT : Apply the formula to calculate

current ie I = R [1 − e−R/L ]
V

Also use the formula of charge

−t/ Rc
θ = cv[1 − e ]
 Chemistry - Section A

1. Answer: D 2. Answer: D

Sol: Sol:
2

(i) r , r1 : r2 : r3 1:4:9
n

False
2 2

(ii) | P.E.| = , |K.E.| =

Ze Ze

r 2r
2

& |T.E.| = True

Ze

2r
8

(iii) = = 0.5 × 106 m

C 3×10
= 14
ν
6×10

= 500 × 10–9 m
= 500 nm True
Glyptal
(iv) =
h

√2(K.E.)m

H : He : λCH =
1
:
1
:
1

3. Answer: D
4
√1 √4 √16

= 1
:
1
:
1
4:2:1 True
Sol:
1 2 4

Ca(OH)2 + 2 NH4 Cl → 2NH3 + CaCl2 + 2H2 O

(A) (B)

NH3 + H2 O + CO2 ⟶ NH4 HCO3

(B) (exc) (C)

NH4 HCO3 + NaCl ⟶ NaHCO3 ⏐ + NH4 Cl

⏐
⏐
(C)
↓

Therefore, the correct option is (D)

4. Answer: B

Sol:

It contains COS
 Chemistry - Section B

5. Answer: A,B,D 6. Answer: A,C,D

Sol: Sol:

(A) K.E. = 45.5 eV From given reactions, Free energy of

the reaction :
45.5 > 13.6 (K.E. of electron in 1st
shell of H-atom) Δ

ZnO (g)
+ C−−−→ (s)
v > 2.18 × 106 1000°C

Zn(g) + CO(g) is negative. i.e.

(B) v = 2.18 × 106 × 2 o
(ΔG ) < 0

(C)
150
- >-
o o o
λ = √ A (ΔG ) (ΔG )
v C,CO Zn,ZnO

v =
150
= 3. 43 volt
So, C will able to reduce ZnO to Zn.
2
16π × 0.526× 0.526

−19
For this
K. E. = 3. 43 ev = 3. 43 × 1. 6 × 10 J

1 2
ΔG is a state function.
K. E. = mv
2
o o o
ΔG = ΔG + ΔG
−19 1 –31
(C,CO) (ZnO,Zn)
2
3. 43 × 1. 6 × 10 = × 9. 1 × 10 × v
2
o
ΔG = [−450 + (360)] kJ /mol

v = 1.09 ×106 m/sec

o
ΔG = −90kJ /mol
1240 1240
(D) K. E. = − = 6. 9 eV
124 400

K. E. = 6. 9eV = 6. 9 × 1. 6 × 10
–19
Joul
ΔG
o
< 0 , Reaction is spontaneous
1 2 ZnO is less stable than CO because ΔG of CO is higher than ZnO
K. E. = mv
2

−19 1 –31

Since option 2 is opposite to option 4

2
6. 9 × 1. 6 × 10 = × 9. 1 × 10 × v
2

v
2
= 242 × 10
12
and option 2 is correct, option 4 will be
v = 1. 56 × 10
6
incorrect.

Correct options are1,2 and 4.

7. Answer: A,B,C

Sol:

PE (Polyethylene) is an addition
polymer.
 Chemistry - Section C

8. Answer: 3 11. Answer: 9

Sol: Sol:

For parallal Reaction : Stereo centre = Optical centre + G.I.

k1 Ea1 +k2 Ea2 +k3 Ea3
centre
( Ea ) =
effective k1 +k2 +k3

∴ ( Ea ) =
effective
−4 −4 10 −4 5
10 ×10+3×10 × +6×10 ×
3 3

−4 −4 −4
= 3
10 +3×10 +6×10

9. Answer: 2 Stereogenic centre = 3 + (2 + 2 + 2)

=9
Sol: No. of chiral centre = 3
No. of G.I. Centre = 3 ( 6 stereogenic
Cathode:
3+
centre)
–
Al (melt) + 3e → Al

Anode :​C(s) + O
2−
(melt ) → CO(g) + 2e
–

C(s) + 2O
2−
(melt ) → CO2 (g) + 4e
– 3 + 6 = 9 stereo centre.

12. Answer: 4

Sol:
10. Answer: 0

Sol:
A( g) → 2 B( g) + C( g)
2α α
1−α

rB 2 2α 16
= = × √
rA 1 1−α 4

1
⇒ α =
3

1 3 0.4 −1
K = ln = = 0. 04 sec
10 2 10

13. Answer: 10
No. of unpaired electrons in central
atom of complex, B = 0 Sol:
∴ x × y = 0

4-Chiral centers, terminal groups same

Total stereoisomers = 24–1 + 2(4/2)-1 =

10
 Chemistry - Section D

14. Answer: A

Sol:

(A)
2 2 2
4×h n h
(r2 ) 2+ = (Using : rn = )
Li 2
4π ×mk×3e
2
4π
2
mkze
2
h
= 2
2
π mke ×3

2 2

(B)
2πkze 2π×k×2e
Vn = ⇒ ( V4 ) + =
nh He 4 h
2
kπe
=
h

(C)
−13.6×9
∴ (E2 ) 2+ = eV
Li 4

2 2 2 4

(D)
4π mk z e
fn = 3
3
n h

2 2 2 4 2 2 4
4π mk ×3 ×e 9π mk e
∴ (f2 ) 3+ = =
Li 3 3 3
2 ×h 2 h

15. Answer: C

Sol:

Cu(OH)2 cannot be precipitated in

acidic medium
Prussian blue is soluble in Oxalic acid
Cu(OH)2, AgBr, AgCl are soluble in
concentrated NH3 solution
16. Answer: B Sol:

For reaction A→B

[A]0
(P) For zero order reaction t1/2 = 2 K

to get relation between t1/2 and t

[A] [A]0 −Kt [A]0
1
t1/2 = = = − t
2 K 2 K 2 K 2

[A]0
1
t1/2 = − t
2 K 2

[A]0
y = c + mx
1
m = − c =
2 2 K

⇒ i.e. given graph is for zero order

reaction which is a complex reaction

(Q) For nth order reaction

1 1
= n−1
= (n − 1) Kt
n−1
[ A] [ A]
0

[A]0
at t = t3/4 [A] =
4

n−1
4 −1
for nth order : t3/4 = n−1
(n−1)[A]
0

for n − 1 > 0 ⇒ n > 1 t3/4 α

1
and
[ A]0

given graph follow

so correct for 2th, 3th 4th order

Ans. 1, 2, 3 option of list-II

(R) For nth order

1 1
n−1
= n−1
+ (n − 1) Kt
[ A] [ A]
0

1 1
3
= 3
+ (n − 1) Kt
[ A] [ A]
0

y = c + mx
 17. Answer: A

Sol:

(A)-p,r,s; (B)-q,r; (C)-p,r,s; (D)-p,r,s

m = slope = 3
when n – 1 = 3
n = 4 (order of reaction is 4th)

(S)

Rate = K [A]2
y = mx
line passing through origin for 2nd
order reaction.