Conforms to Hazardous Products Regulations (SOR/2015-17)

SAFETY DATA SHEET

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SECTION 1: Identification

1.1. Product identifier

Trade name
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1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
Industrial purposes
Uses advised against
None known.
1.3. Details of the supplier of the safety data sheet
Company and address
Scanningspray Vertriebs GmbH
Johann-Strauss-Str. 13
45657 Recklinghausen
Germany
+49 (0)2361 8903 357
[email protected]
Contact person
Max Liese
E-mail
[email protected]
SDS date
2023-05-30
SDS Version
1.0
1.4. Emergency telephone number
US Chemtrec: +1 800 424-9300 (24h)
CHEMTREC: +1 703 527-3887 (24h) Transport
(CCN 994267 / WISAG FMO Cargo Service GmbH &
Co. KG);

SECTION 2: Hazard(s) identification

2.1. Classification of the substance or mixture

Aerosol 1; H222, H229, Extremely flammable aerosol. Pressurised container: May burst if heated.
STOT SE 3; H336, May cause drowsiness or dizziness.
2.2. Label elements
Hazard pictogram(s)

Signal word
Danger
Hazard statement(s)
Extremely flammable aerosol. Pressurised container: May burst if heated. (H222, H229)
May cause drowsiness or dizziness. (H336)
Precautionary statement(s)
General
-
Prevention
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. (P210)

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Do not spray on an open flame or other ignition source. (P211)

Do not pierce or burn, even after use. (P251)
Avoid breathing spray. (P261)
Response
Call a POISON CENTER/doctor if you feel unwell. (P312)
Storage
Store in a well-ventilated place. Keep container tightly closed. (P403+P233)
Protect from sunlight. Do no expose to temperatures exceeding 50 °C/122°F. (P410+P412)
Disposal
Dispose of contents/container in accordance with local regulation. (P501)
Hazardous substances
cyclopentane
Additional labelling
Not applicable.
2.3. Other hazards
Additional warnings
In the event of leaks, high concentrations of gases can quickly form. They can be toxic, asphyxiating, or explosive.
This mixture/product does not contain any substances considered to meet the criteria classifying them as PBT
and/or vPvB.

SECTION 3: Composition/Information on Ingredients

3.1. Substances
Not applicable. This product is a mixture.
3.2. Mixtures
Product/substance Identifiers % w/w Classification Note

isobutane (containing ≥ 0,1 % CAS No.: 106-97-8 60-80% Flam. Gas 1A, H220
butadiene (203-450-8));butane Press. Gas (Liq.) , H280
(containing ≥ 0,1 % butadiene
(203-450-8))

propane CAS No.: 74-98-6 15-25% Flam. Gas 1A, H220

Press. Gas (Liq.) , H280

cyclopentane CAS No.: 287-92-3 10-15% Flam. Liq. 2, H225

Asp. Tox. 1, H304
STOT SE 3, H336

Cyclododecane CAS No.: 294-62-2 5-10%

isobutane (containing ≥ 0,1 % CAS No.: 75-28-5 1-3% Flam. Gas 1A, H220
butadiene (203-450-8));butane Press. Gas (Liq.) , H280
(containing ≥ 0,1 % butadiene
(203-450-8))

See full text of H-phrases in section 16. Occupational exposure limits are listed in section 8, if these are available.

Other information
None known.

SECTION 4: First-aid measures

4.1. Description of first aid measures

General information
If breathing is irregular, drowsiness, loss of consciousness or cramps: Call 911 and give immediate treatment (first
aid).
Contact a doctor if in doubt about the injured person’s condition or if the symptoms persist. Never give an
unconscious person water or other drink.
Inhalation
Upon breathing difficulties or irritation of the respiratory tract: Bring the person into fresh air and stay with
him/her.

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Skin contact
Upon irritation: rinse with water. In the event of continued irritation, seek medical assistance.
Eye contact
Upon irritation of the eye: Remove contact lenses and open eyes widely. Flush eyes with water or saline water (20-
30 °C) for at least 5 minutes. Seek medical assistance and continue flushing during transport.
Ingestion
If the person is conscious, rinse the mouth with water and stay with the person. Never give the person anything to
drink.
In case of malaise, seek medical advice immediately and bring the safety data sheet or label from the product. Do
not induce vomiting, unless recommended by the doctor. Have the person lean forward with head down to avoid
inhalation of or choking on vomited material.
Burns
Rinse with water until pain stops then continue to rinse for 30 minutes.
4.2. Most important symptoms and effects, both acute and delayed
None known.
4.3. Indication of any immediate medical attention and special treatment needed
Call a POISON CENTER/doctor if you feel unwell.
Information to medics
Bring this safety data sheet or the label from this product.

SECTION 5: Fire-fighting measures

5.1. Extinguishing media

Suitable extinguishing media: Alcohol-resistant foam, carbon dioxide, powder, water mist.
Unsuitable extinguishing media: Waterjets should not be used, since they can spread the fire.
5.2. Special hazards arising from the substance or mixture
Fire will result in dense smoke. Exposure to combustion products may harm your health. Closed containers, which are
exposed to fire, should be cooled with water. Do not allow fire-extinguishing water to enter the sewage system and
nearby surface waters.
If the product is exposed to high temperatures, e.g. in the event of fire, dangerous decomposition compounds are
produced. These are:
Carbon oxides (CO / CO2)
5.3. Advice for firefighters
Wear self-contained breathing apparatus and protective clothing to prevent contact. Upon direct exposure contact a
poison centre in order to obtain further advice. See section 1 “Emergency telephone number”.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Storages not yet ignited must be cooled by water mist. Remove flammable materials if conditions allow it. Ensure
sufficient ventilation.
Avoid inhalation of vapours from spilled material.
6.2. Environmental precautions
Avoid discharge to lakes, streams, sewers, etc.
6.3. Methods and material for containment and cleaning up
Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous
earth and place in container for disposal according to local regulations.
Wherever possible cleaning should be performed with normal cleaning agents. Avoid use of solvents.
6.4. Reference to other sections
See section 13 “Disposal considerations” on handling of waste.
See section 8 "Exposure controls/personal protection" for protective measures.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Because of the danger of self-ignition, any waste from the product, spray mist and soiled rags etc. are to be kept in a
fire-proof place in air-tight containers, alternatively the waste is to be burned.
Smoking, drinking and consumption of food is not allowed in the work area.
See section 8 "Exposure controls/personal protection" for information on personal protection.
7.2. Conditions for safe storage, including any incompatibilities

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Must be stored in a cool and well-ventilated area, away from possible sources of ignition.
Pressurized gas packs (spray cans, aerosol cans) must be stored behind a wire mesh, which allows gases to escape
and holds back packs flying around.
Recommended storage material
Keep only in original packaging.
Storage temperature
< 50°C
Incompatible materials
Strong oxidizing agents
7.3. Specific end use(s)
This product should only be used for applications quoted in section 1.2.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

ALBERTA

isobutane (containing ≥ 0,1 % butadiene (203-450-8));butane (containing ≥ 0,1 % butadiene (203-450-8))

Long term exposure limit (8 hours) (ppm): 1000

propane
Long term exposure limit (8 hours) (ppm): 1000

cyclopentane
Long term exposure limit (8 hours) (ppm): 600
Long term exposure limit (8 hours) (mg/m³): 1720

Occupational Health and Safety Code 2009 Order, Alta Reg 87/2009 (revised in 2018)
______________________________________________________________
BRITISH COLUMBIA
isobutane (containing ≥ 0,1 % butadiene (203-450-8));butane (containing ≥ 0,1 % butadiene (203-450-8))
Short-Term Exposure Limit (STEL) / Ceiling Limit (C): 1000 ppm
Annotations:
EX = The substance is a flammable asphyxiant or excursions above the exposure limit could approach 10% of the
lower explosive limit.

propane
Short-Term Exposure Limit (STEL) / Ceiling Limit (C): Simple asphyxiant / Asphyxiant simples
Annotations:
EX = The substance is a flammable asphyxiant or excursions above the exposure limit could approach 10% of the
lower explosive limit.

cyclopentane
Time-Weighted Average Limit (TWA): 600 ppm

isobutane (containing ≥ 0,1 % butadiene (203-450-8));butane (containing ≥ 0,1 % butadiene (203-450-8))

Short-Term Exposure Limit (STEL) / Ceiling Limit (C): 1000 ppm
Annotations:
EX = The substance is a flammable asphyxiant or excursions above the exposure limit could approach 10% of the
lower explosive limit.

OHS Regulation Part 5: Chemical Agents and Biological Agents.

______________________________________________________________
ONTARIO
isobutane (containing ≥ 0,1 % butadiene (203-450-8));butane (containing ≥ 0,1 % butadiene (203-450-8))
Short-Term Exposure Limit (STEL) / Ceiling Limit (C): 1000 ppm

propane
Time-Weighted Average Limit (TWA): 200 ppm

cyclopentane
Time-Weighted Average Limit (TWA): 600 ppm

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isobutane (containing ≥ 0,1 % butadiene (203-450-8));butane (containing ≥ 0,1 % butadiene (203-450-8))

Time-Weighted Average Limit (TWA): 5 ppm
Short-Term Exposure Limit (STEL) / Ceiling Limit (C): 10 ppm

Regulation 833 (Control of Exposure to Biological or Chemical Agents) and Ontario Regulation 490/09 (Designated
Substances)
______________________________________________________________
QUEBEC
isobutane (containing ≥ 0,1 % butadiene (203-450-8));butane (containing ≥ 0,1 % butadiene (203-450-8))
Long term exposure limit (8 hours) (ppm): 800
Long term exposure limit (8 hours) (mg/m³): 1900

propane
Long term exposure limit (8 hours) (ppm): 1000
Long term exposure limit (8 hours) (mg/m³): 1800

cyclopentane
Long term exposure limit (8 hours) (ppm): 600
Long term exposure limit (8 hours) (mg/m³): 1720

Regulation respecting occupational health and safety (Chapter S-2.1, r. 13)

______________________________________________________________
SASKATCHEWAN
isobutane (containing ≥ 0,1 % butadiene (203-450-8));butane (containing ≥ 0,1 % butadiene (203-450-8))
Long term exposure limit (8 hours) (ppm): 1000
Short term exposure limit (15 minutes) (ppm): 1250

propane
Long term exposure limit (8 hours) (ppm): 1000
Short term exposure limit (15 minutes) (ppm): 1250

cyclopentane
Long term exposure limit (8 hours) (ppm): 600
Short term exposure limit (15 minutes) (ppm): 900

isobutane (containing ≥ 0,1 % butadiene (203-450-8));butane (containing ≥ 0,1 % butadiene (203-450-8))

Long term exposure limit (8 hours) (ppm): 1000
Short term exposure limit (15 minutes) (ppm): 1250

The Occupational Health and Safety Regulations, 2020, Chapter S15.1 Reg 10.
8.2. Exposure controls
Compliance with the given occupational exposure limits values should be controlled on a regular basis.
General recommendations
Smoking, drinking and consumption of food is not allowed in the work area.
Exposure scenarios
There are no exposure scenarios implemented for this product.
Exposure limits
Professional users are subjected to the legally set maximum concentrations for occupational exposure. See
occupational hygiene limit values above.
Appropriate technical measures
Apply standard precautions during use of the product. Avoid inhalation of gas or dust.
Hygiene measures
In between use of the product and at the end of the working day all exposed areas of the body must be washed
thoroughly. Always wash hands, forearms and face.
Measures to avoid environmental exposure
No specific requirements.
Individual protection measures, such as personal protective equipment
Generally
Use only protective equipment with a recognized certification mark, e.g. the UL mark.
Respiratory Equipment

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Type Class Colour Standards

Combination filter Class 2 Brown/Gray/White EN14387
A2B2P2

Skin protection
Recommended Type/Category Standards
Dedicated work - -
clothing should be
worn.

Hand protection
Material Glove thickness (mm) Breakthrough time Standards
(min.)
Butyl 0,7 > 240 EN374-2, EN374-3, EN388,
EN421

Eye protection
Type Standards
Face shield EN166
alternatively safety
glasses with side
shields.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state
Aerosol
Colour
Colourless
Odour
Characteristic
Odour threshold (ppm)
Testing not relevant or not possible due to the nature of the product.
pH
Testing not relevant or not possible due to the nature of the product.
Density (g/cm³)
Testing not relevant or not possible due to the nature of the product.
Kinematic viscosity
Testing not relevant or not possible due to the nature of the product.
Phase changes
Melting point (°C)
Testing not relevant or not possible due to the nature of the product.
Boiling point (°C)
Testing not relevant or not possible due to the nature of the product.
Vapour pressure
Testing not relevant or not possible due to the nature of the product.
Vapour density
Testing not relevant or not possible due to the nature of the product.
Decomposition temperature (°C)
Testing not relevant or not possible due to the nature of the product.
Evaporation rate (n-butylacetate = 100)
Data on fire and explosion hazards
Flash point (°C)
-88.6 @ 1.013 hPa
Flammability (°C)

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Auto-ignition temperature (°C)
Testing not relevant or not possible due to the nature of the product.
Explosion limits (% v/v)
1.1 - 15
Solubility
Solubility in water
Testing not relevant or not possible due to the nature of the product.
n-octanol/water coefficient
Testing not relevant or not possible due to the nature of the product.
Solubility in fat (g/L)
Testing not relevant or not possible due to the nature of the product.
9.2. Other information
Other physical and chemical parameters
No data available.

SECTION 10: Stability and reactivity

10.1. Reactivity
No data available.
10.2. Chemical stability
The product is stable under the conditions, noted in section 7 “Handling and storage”.
10.3. Possibility of hazardous reactions
None known.
10.4. Conditions to avoid
Avoid static electricity.
Do not expose to any forms of heat (e.g. solar radiation). May lead to excess pressure.
10.5. Incompatible materials
Strong oxidizing agents
10.6. Hazardous decomposition products
The product is not degraded when used as specified in section 1.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity
Based on available data, the classification criteria are not met.
Skin corrosion/irritation
Based on available data, the classification criteria are not met.
Serious eye damage/irritation
Based on available data, the classification criteria are not met.
Respiratory sensitisation
Based on available data, the classification criteria are not met.
Skin sensitisation
Based on available data, the classification criteria are not met.
Germ cell mutagenicity
Based on available data, the classification criteria are not met.
Carcinogenicity
Based on available data, the classification criteria are not met.
Reproductive toxicity
Based on available data, the classification criteria are not met.
STOT-single exposure
May cause drowsiness or dizziness.
STOT-repeated exposure
Based on available data, the classification criteria are not met.
Aspiration hazard
Based on available data, the classification criteria are not met.
Long term effects
None known.

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Other information
None known.

SECTION 12: Ecological information

12.1. Toxicity
Product/substance isobutane (containing ≥ 0,1 % butadiene (203-450-8));butane (containing ≥ 0,1 % butadiene (203-450-8))
Species: Fish
Duration: 96 hours
Test: LC50
Result: 27,98 mg/L

Product/substance isobutane (containing ≥ 0,1 % butadiene (203-450-8));butane (containing ≥ 0,1 % butadiene (203-450-8))
Species: Algae
Duration: 96 hours
Test: EC50
Result: 7,71 mg/L

Product/substance propane
Species: Fish
Duration: 96 hours
Test: LC50
Result: 27,98 mg/L

Product/substance propane
Species: Algae
Duration: 96 hours
Test: EC50
Result: 7,71 mg/L

Product/substance cyclopentane
Species: Fish
Duration: 96 hours
Test: LL50
Result: 29.3 mg/L

Product/substance isobutane (containing ≥ 0,1 % butadiene (203-450-8));butane (containing ≥ 0,1 % butadiene (203-450-8))
Species: Fish
Duration: 96 hours
Test: LC50
Result: 27,98 mg/L

Product/substance isobutane (containing ≥ 0,1 % butadiene (203-450-8));butane (containing ≥ 0,1 % butadiene (203-450-8))
Species: Algae
Duration: 96 hours
Test: EC50
Result: 7,71 mg/L

12.2. Persistence and degradability

Product/substance cyclopentane
Biodegradable: No
Test method:
Result: 0% 28d

12.3. Bioaccumulative potential

Product/substance propane
Test method:
Potential bioaccumulation: No data available.
LogPow: 1,09 (pH: 7, 20 °C)
BCF: No data available.
Other information:

Product/substance cyclopentane
Test method:
Potential bioaccumulation: No data available.

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LogPow: 3 (pH: 7, 25 °C)

BCF: 70,8
Other information:

12.4. Mobility in soil

No data available.
12.5. Results of PBT and vPvB assessment
This mixture/product does not contain any substances considered to meet the criteria classifying them as PBT and/or
vPvB.
12.6. Other adverse effects
None known.

SECTION 13: Disposal considerations

Waste treatment methods

None of the components are listed
Specific labelling
Contaminated packing
Packaging containing residues of the product must be disposed of similarly to the product.

SECTION 14: Transport information

14.1 14.2 14.3 14.4 14.5 Other

UN / ID UN proper shipping name Hazard class(es) PG* Env** information:

DOT UN1950 AEROSOLS Transport hazard class: 2 - No Limited

Label: 2.1 quantities: 1 L
Classification code: 5F Tunnel
restriction
code: (D)
See below for
additional
information.

IMDG UN1950 AEROSOLS Transport hazard class: 2 - No Limited

Label: 2.1 quantities: 1 L
Classification code: 5F EmS: F-D S-U
See below for
additional
information.

IATA UN1950 AEROSOLS Transport hazard class: 2 - No See below for

Label: 2.1 additional
Classification code: 5F information.

* Packing group
** Environmental hazards
Additional information
ADR / See Table A, Section 3.2.1 for any information on special provisions, requirements, or warnings in connection
with transport. See section 5.4.3, for instructions in writing regarding mitigation of damages in relation to incidents or
accidents during transport.
IMDG / See section 3.2.1, for any information on special provisions, requirements, or warnings in connection with
transport.
IATA / See Table 4.2 for any information on special provisions, requirements, or warnings in connection with
transport.
This product is within scope of the regulations of transport of dangerous goods.
14.6. Special precautions for user
Not applicable.
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

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No data available.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.2. Canadian lists
DSL / NDSL
isobutane (containing ≥ 0,1 % butadiene (203-450-8));butane (containing ≥ 0,1 % butadiene (203-450-8)) is listed in
the non-confidential portion of DSL / NDSL
propane is listed in the non-confidential portion of DSL / NDSL
cyclopentane is listed in the non-confidential portion of DSL / NDSL
isobutane (containing ≥ 0,1 % butadiene (203-450-8));butane (containing ≥ 0,1 % butadiene (203-450-8)) is listed in
the non-confidential portion of DSL / NDSL
15.4. Restrictions for application
Restricted to professional users.
People under the age of 18 shall not be exposed to this product.
Pregnant women and women breastfeeding must not be exposed to this product. The risk, and possible technical
precautions or design of the workplace needed to eliminate exposure, must be considered.
15.5. Demands for specific education
No specific requirements.
Additional information
Not applicable.
15.7. Chemical safety assessment
No
Sources
Hazardous Products Regulations (SOR/2015-17)

SECTION 16: Other information

Full text of H-phrases as mentioned in section 3

H220, Extremely flammable gas.
H225, Highly flammable liquid and vapour.
H280, Contains gas under pressure; may explode if heated.
H304, May be fatal if swallowed and enters airways.
H336, May cause drowsiness or dizziness.
The full text of identified uses as mentioned in section 1
None known.
Abbreviations and acronyms
ANSI = American National Standards Institute
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
CAS = Chemical Abstracts Service
DSL = Domestic Substances List
NDSL = Non-domestic substances list
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
HHNOC = Health Hazards Not Otherwise Classified
IARC = International Agency for Research on Cancer
IATA = International Air Transport Association
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of
1978. ("Marpol" = marine pollution)
OECD = Organisation for Economic Co-operation and Development
PBT = Persistent, Bioaccumulative and Toxic
PHNOC = Physical Hazards Not Otherwise Classified
RID = The Regulations concerning the International Carriage of Dangerous Goods by Rail
SCL = A specific concentration limit.
SOR = Statutory Orders and Regulations
STEL = Short-term exposure limits
STOT-RE = Specific Target Organ Toxicity - Repeated Exposure
STOT-SE = Specific Target Organ Toxicity - Single Exposure

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TWA = Time weighted average

UN = United Nations
UVBC = Unknown or variable composition, complex reaction products or of biological materials
VOC = Volatile Organic Compound
vPvB = Very Persistent and Very Bioaccumulative
WHIMS = Workplace Hazardous Materials Information System
Additional information
The classification of the mixture in regard of health hazards is in accordance with the calculation methods given by
WHMIS 2015
The classification of the mixture in regard to physical hazards has been based on experimental data.
The safety data sheet is validated by
Max Liese
Other
A change (in proportion to the last essential change (first cipher in SDS version, see section 1)) is marked with a blue
triangle.
The information in this safety data sheet applies only to this specific product (mentioned in section 1) and is not
necessarily correct for use with other chemicals/products.
It is recommended to hand over this safety data sheet to the actual user of the product. Information in this safety
data sheet cannot be used as a product specification.
Country-language: CA-en

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