22 Practice Set-4

PRACTICE SET-4

1. 7.5 gs of a gas occupies 5.8 L of volume at STP. The gas 9. The proton and neutron are collectively called as:
is: a. Deutron b. Positron
a. NO b. N 2 O c. Meson d. Nucleon
c. CO d. CO 2 10. Which of the following has the same mass as that of an
electron?
2. The mass of a molecule of water is:
a. Photon b. Neutron
a. 3  10 26 kg b. 3  10 25 kg
c. Positron d. Proton
c. 1.5  10 26 kg d. 2.5  10 26 kg
11. The normality of 0.3 M phosphorus acid (H3 PO3 ) is:
3. Which of the following exists as covalent crystals in the
a. 0.1 b. 0.9
solid state?
c. 0.3 d. 0.6
a. Iodine b. Silicon
c. Sulphur d. Phosphorus 12. The oxidation number of sulphur in S8 , S2 F2 , H 2S
respectively, are:
4. Experimentally it was found that a metal oxide has
a. 0,  1 and  2 b.  2,  1 and  2
formula M 0.98O. Metal M, present as M 2 and M3 in its
c. 0,  1 and  2 d.  2,  1 and  2
oxide. Fraction of the metal which exists as M3 would be
a. 7.01% b. 4.08% 13. The standard reduction potentials E, for the half
c. 6.05% d. 5.08% reaction are as:
5. Which of the following solutions will have maximum Zn  Zn 2  2e , E  0.76 V
freezing point?
Fe  Fe2  2e , E  0.41 V
a. 0.01 M urea b. 0.01 M KCl
The emf for the cell reaction,
c. 0.01 M BaCl2 d. 0.01 M NaCl
Fe2  Zn 
 Zn 2  Fe is:
6. The osmotic pressure of a solution is given by the relation.
a.  0.35 V b.  0.35 V
a.   RT / c b.   cT / R
c. 1.17 V d. 1.17 V
c.   Rc / T d.  / c  RT
14. The standard reduction potentials of Cu 2 / Cu and
7. A liquid is equilibrium with its vapour at its boiling point.
On the average, the molecules in the two phases have
Cu 2 / Cu  are 0.337 V and 0.153 V respectively. The
equal: standard electrode potential of Cu  / Cu half-cell is:
a. inter-molecular forces a. 0.184 V b. 0.827 V
b. potential energy c. 0.521 V d. 0.490 V
c. kinetic energy
15. The ion that is isolectronic with CO is:
d. total energy
a. CN b. O 2
8. Rate of diffusion of a gas is:
c. O2 d. N 2
a. Directly proportional to its density
b. Directly proportional to its molecular weight 16. Carbon tetrachloride has no net dipole moment because of
c. Directly proportional to the square root of its molecular a. its planar structure.
weight b. its regular tetrahedral structure.
d. Inversely proportional to the square root of its c. similar sizes of carbon and chlorine atoms.
molecular weight d. similar electron affinities of carbon and chlorine.
17. The equilibrium constant for the reaction: The rate constant of reaction in s 1 is:
 Fe SCN 2 (aq) is 140 at
Fe3 (aq)  SCN  (aq)  a. 2 104 b. 3.45 105
298 K. The equilibrium constant for the reaction is: c. 1.386 104 d. 2 104
 2Fe SCN2 (aq)
2Fe3 (aq)  2SCN (aq)  23. The capacity to bring about coagulation increases with:
a. 280 b. 140 a. Ionic radii b. Atomic radii
c. 19600 d. 70 c. Valency of an ion d. Size of an ion
18. Consider the gaseous reactions at 300 K,(i)
24. Gold number gives:
 NO 2 (g)
NO(g)  12 O 2 (g)  : K1
a. The amount of gold present in the colloid.
 2NO(g)  O2 (g)
(ii) 2NO2 (g)  : K2 b. The amount of gold required to break the colloid.
The equilibrium constant K 1 and K 2 are related as: c. The amount of gold required to protect the colloid.
d. None of these
1 K1
a. K 2  b. K 2 
K1 2 25. Which of the following reactions defines H o ?
1 a. C(diamond)  O2 (g) 
 CO2 (g)
c. K 2  d. K 2  K 12
K12
b. 12 H 2 (g)  12 F2 (g) 
 HF(g)
19. According to Bronsted-Lowry concept, the correct order
of relative strength of bases follows the order c. N 2 (g)  3H 2 (g) 
 2NH 3 (g)
a. CH 3 COO   Cl   OH  d. CO(g)  12 O 2 (g) 
 CO 2 (g)
  
b. CH 3 COO  OH  Cl
26. Spontaneous adsorption of a gas on solid surface is an
c. OH   CH 3 COO   Cl 
exothermic process because
  
d. OH  Cl  CH 3 COO a.  H increases for system
20. H 2 SO 4  OH   SO 24   H 2 O Which is correct about b. S increases for gas
conjugate acid base pair c. S decreases for gas
a. HSO 2
is conjugate acid of base SO 2 d. G increases for gas
4 4

b. HSO 4 is conjugate base of acid SO 24  27. In a radioactive change: A.

A
P 
 AZ1Q 

Z
c. SO 4 is conjugate acid of base HSO 4 A4
 Z1  AZ14S radiation are emitted in the sequence.
R 
d.None of these
21. Consider the chemical reaction N2(g)+3H2(g) 
 2NH3
a.  ,  ,  b.  ,  , 

(g) The rate of this reaction can be expressed in terms of c.  ,  ,  d.  ,  , 

time derivatives of concentration of N2(g),H2(g) or NH3
28. During the fission of U-235, a large amount of energy of
(g). Identify the correct relationship amongst the rate
the order of 180 MeV is generated per nucleus fissioned.
expressions.
The amount of energy released by the fission of 0.235 g of
d[N 2 ] 1 d[H 2 ] 1 d[NH3 ]
a. Rate     U-235 is:
dt 3 dt 2 dt
a. 1.08  10 kJ b. 1.08  10 kJ
23 7
d[N 2 ] d[H 2 ] d[NH 3 ]
b. Rate    3 2
dt dt dt c. 1.73  10 kJ
16
d. 1.73  10 kJ
7

d[N 2 ] 1 d[H 2 ] 1 d[NH 3 ]

c. Rate   
dt 3 dt 2 dt 29. What is the decreasing order of strength of the bases?
d[N 2 ] d[H 2 ] d[NH 3 ] OH , NH2 ,H — C  C and CH3 — CH 2
d. Rate    
dt dt dt
22. In a first order reaction the concentration of reactant a. CH 3  CH 2  NH 2  H — C  C   OH 

decreases from 800 mol / dm3 to 50 mol/dm3 in 2 × 104 s. b. H — C  C   CH 3 — CH 2  NH 2  OH 

 c. OH  NH2  H — C  C  CH3 — CH2 CH 2 CH CH 2
a. CH 3CHClCH 2 Cl b. | | |
Cl Cl Cl
d. NH2  H — C  C  OH   CH3 — CH2
c. CH 3CH  CHCl d. ClCH 2CH  CH 2
30. In the following compounds:
OH OH OH OH 37. Which one of the following will produce a primary
alcohol by reacting with CH3MgI
a. Acetone b. Methyl cyanide
NO2
c. Ethylene oxide d. Ethyl acetate
CH3 NO2
38. The fermentation of starch to give alcohol occurs mainly
(I) (II) (III) (IV)
with the help of :
The order of acidity is:
a. O2 b. Air
a. III > IV > I > II b. I > IV > III > II
c. II > I > III > IV d. IV >III >I > II c. CO 2 d. Enzymes

31. Assign the IUPAC name of the following compound. 39. From which of the following tertiary butyl alcohol is
obtained by the action of methyl magnesium iodide?
CH3 – CH2 SO2 – O – CH3 a. HCHO b. CH3CHO

a. Ethyl 4-ethyl benzenesulphonate c. CH3COCH3 d. CO 2

b. Methyl 4-ethylbenzenesulphonate
40. CH3  CH 2  C  CH 
R
H 2O
 Butanone, R is:
c. Methyl 4-ethyl cyclohexanesulphonate
d. None of the above a. Hg  b. KMnO 4
32. Write the IUPAC name of the following compound. c. KClO3 d. K 2Cr2O7
CO – O – C2H5
41. Fats and oils are:
a. Acids b. Alcohols
CO – Cl c. Esters d. Hydrocarbons
a. 2-(ethoxycarbonyl) benzoyl chloride
b. Ethyl 2-(chlorocarbonyl) hexanoate 42. Vinegar obtained from sugarcane has:
c. Ethyl 2-(chlorocarbonyl) benzoate a. CH3COOH b. HCOOH
d. None of the above c. C6 H 5COOH d. CH3CH 2COOH

33. Baeyer’s reagents is? 43. Which of the following compound gives dye test?
a. alkaline permanganate solution. a. Aniline
b. acidified permanganate solution. b. Methylamine
c. neutral permanganate solution. c. Diphenylamine
d. aqueous bromine solution. d. Ethylamine
34. Acidic hydrogen is present in? 44. In hydrolysis of aniline, the reagent used is:
a. ethyne b. ethene a. Dil. HCl
c. benzene d. ethane b. Acetyl chloride
35. 1-chlorobutane on reaction with alcoholic KOH gives: c. CH3OH
a. 1-butene b. 1-butanol d. None of these
c. 2-butene d. 2-butanol
45. Which of the following is a protein?
36. The reaction of chlorine with propene at 400  600C a. Pepsin b. Adrenaline
gives mainly. c. ATP d. Glutamine
46. Carnallite is the mineral of: 6. (d)   CRT
a. Na b. Ca   / C  RT
c. Mg d. None of the Above
47. The wire of flash bulb is made up of: 7. (c) At liquid-vapour equilibrium at boiling point.
a. Mg b. Ag Molecules in two phases posses the same kinetic energy.
c. Cu d. Ba 1
8. (d) Rate of effusion  : definition.
48. The basic strength of which hydroxide is maximum m
a. LiOH b. NaOH
9. (d) Nucleus consists of proton and neutron both are called
c. Ca (OH)2 d. KOH.
as nucleon.
49. The composition of Sorels cement is
10. (c) Positron (1e0 ) has the same mass as that of an
a. KCl × MgCl2 × 6H2O
b. MgCl2 × 5MgO × (xH2O) electron (1e0 ).
c. MgCO3 × CaCO3
d. CaSO4 × 2H2O 11. (d) Phosphorus acid is a dibasic acid as:
50. Which of the following alkali metals has the least melting O
||
point? H P OH Only two replaceable hydrogens
|
a. Na b. K OH
c. Rb d. Cs.
Therefore, Normality
Answers and Solutions
 molarity basicity  basicity
1. (a)  5.8 L of gas has mass  7.5gm = 0.3 x 2 = 0.6
7.5
 22.4 L of gas has mass   22.4  28.96 12. (a) In S8 , oxidation number of S is 0, elemental state.
5.8
So molecular weight = 29 In S2 F2 ,F is n 1 oxidation state, hence S is in 1
So, molecular formula of compound is NO.
oxidation state.
2. (a) 6  10 molecules has mass  18 gm
23
In H2S,H is in  1 oxidation state, hence S is in  2
1 molecule has mass oxidation state.
18
  3  1023 gm  3  1026 kg.
6  1023
13. (b) Fe2  2e 
 Fe; E  0.41 V
3. (b) Silicon exists as covalent crystal in solid state.
(Network like structure, as seen in diamond).  Zn 2  2e ;
Zn  E  0.76 V

4. (b) From the valency of M 2 and M3 , it is clear three  Fe2  Zn 

 Zn 2  Fe; E  0.35 V
M 2 ions will be replaced by M3 causing a loss of one
14. (c) E is an intensive property:
M3 ion
E G  nEF
Metal oxide M0.98O, if x ions of M are in +3 state then
3x + (0.98 – x) 2 = 2 2 
(i) Cu  2e 
Cu 0.337 V  0.674 F
x = 0.04
2
0.04  100 (ii) Cu  e 
Cu 0.153V  0.153 F
Therefore % of M  3
 4.08%
0.98 Subtracting (ii) from (i) gives:
5. (a) 0.01 M urea will have maximum freezing point Cu   e 
 Cu G  0.521F  nEF
because it will have lowest depression in freezing point
 E  0.521 V n 1
(being non-electrolyte).
15. (a) CO has a total of 14 electrons and CN also has 14 24. (d) Gold no. is a measure of protective power of a
electrons: lyophilic colloid.

C(6e )  N(7e )  e 
 CN  (14e ) 25. (b) 1
2 H 2 (g)  12 F2 (g) 
 HF(g)
Here H   Standard molar enthalpy of formation of HF
16. (b) CCl 4 has a regular tetrahedral shape. (g).
Cl 26. (c) For spontaneous process G  0 Also;
μ
C μ Cl Net dipole = 0 G  H  TS for adsorption of gas on solid surface

Cl S  0. Therefore, in order to be G  0, H must be

Cl
negative.
[FeSCN 2  ]
17. (c) K   140 ; 27. (b) The complete sequence is:
[Fe 3 ][SCN  ]
  
A
P   ZA1Q   AZ14 R   AZ14S
[FeSCN 2  ]2 Z
K   (140) 2  19600
[Fe 3  ]2 [SCN  ]2
28. (d) Number of nuclei in 0.235 g U-235
[NO 2 ] 2
18. (c) K 1  1/ 2
and K 2  [NO] [O 2 ]  12 6.02 10  0.235
23
[NO][O 2 ] [NO 2 ] K1   6.02 1020
235
1
 K2  Amount of energy released  6.02 1020 180 MeV
K 12
19. (c) Relative strength of bases can be shown by their  6.02 1020 180 1.6 1016 kJ  1.73 107 kJ
conjugated acids. Conjugate acid of OH  is H 2 O which
29. (a) CH3CH 2  NH 2  H — C  C  HO

is a weak acid conjugate acid of CH 3 COO is
It is because, the order of acid-strength of their conjugate
CH 3 COOH which is stronger than H 2 O. while conjugate acid is:
acid of Cl is HCl which is strongest out of there. so the CH3CH2  NH3  H — C  C — H  H 2O :
order of relative strength of bases is Acid strength.
  
OH  CH 3 COO  Cl .
30. (d) Nitro group from para position exert electron
20. (a) HSO 4  OH   SO 24   H 2 O withdrawing resonance effect, increases acidity of phenol
Conjugate acid Conjugate base
the most. This is followed by meta nitrophenol in which
21. (a) For any general reaction, aA  bB 
 cC  dD nitro group exert electron withdrawing effect on acidity.
1 d[A] 1 d[B] 1 d[C] 1 d[D] CH3 — is an electron donating group, deceases acid
Rate     
a dt b dt C dt d dt strength. Hence, the overall order is:
 For N 2  3H 2 
 2NH3 IV > III > I > II
d[N 2 ] 1 d[H 2 ] 1 d[NH 3 ] 31. (b) The parent acid is 4-ethylbenzene sulphonic acid. The
Rate    
dt 3 dt 2 dt alkyl group which replaces the acidic H-atom is methyl
[A]0 group.
22. (c) For a first order reaction, kt  ln
[A] 32. (c) –COO– group has priority for citation as principal
1 [A]0 1 800 4ln 2 1 functional group. The acyl halide is expressed by a prefix
 k  ln  ln  s  1.386 104 s 1
t [A] 2  104 50 2 104 ’chlorocarbonyl’.

23. (c) The amount of electrolyte required to coagulate a fixed 33. (a) Baeyer’s reagent is cold, dilute, alkaline permanganate
amount of a sol depends upon the valency of flocculating solution, used to detect presence of olefinic bonds.
ion.
34. (a) Terminal alkynes are slightly acidic, forms salt with 44. (a) All amines react with mineral acids such as
very strong base like Na, NaNH 2 etc. HCl, H 2SO 4 , HNO3 etc. to form salts which are soluble in

 1 water.
H — C  C— H  Na   H — C  C Na   H2 
ethyne 2
45. (a) Pepsin is a protein.
35. (a) CH3CH 2 CH 2 CH 2 Cl 
 CH3CH 2CH  CH 2
alc. KOH 46. (c) Mg
Carnallite is an evaporite mineral a hydrated potassium
36. (d) CH 2  CH  CH 3    CH 2  CH  CH 2 Cl
Cl 2
400  600  C magnesium chloride. It is variably coloured yellow to
It is known as allylic substitution reaction. white, reddish or blue. It occurs with a sequence of
potassium and magnesium evaporite. It is an uncommon
37. (c) CH 2 — CH 2  CH 3 MgI 
 CH 2 — CH 2 

| | double chloride mineral that forms under specific
O CH 3 OMgI conditions. It is an important source of potash.
47. (a) Mg
I
CH 3 — CH 2 — CH 2 — OH  Mg Magnesium metal is used for the preparation of the wire
Pr opyl alcohol
OH of flash bulb.
48. (d) KOH.
38. (d) Starch 
Enzymes
 Alcohol The basic strength increases down the group and
decreases along a period.
39. (c) CH 3COCH 3  
CH3 MgI
 (CH 3 )3 COH 49. (b) MgCl2 × 5MgO × (xH2O)
Acetone tert  Butylalcohol
Mixture of MgCl2 and MgO is called Sorels cement. It is
40. (a) It is hydration of alkynes. MgCl2 × 5MgO × (xH2O)
O 50. (d) Cs.
||
Hg
CH3 — CH2 — C  CH 
 CH3 — CH2 — C— CH3
H2 O Atomic size increases as we move down the alkali group.
Butanone
As a result, the binding energies of their atoms in the
41. (c) Fats and oil jointly known as lipids which are the ester crystal lattice decrease. Also, the strength of metallic
of glycerol with high fatty acid. bonds decreases on moving down a group in the periodic
42. (a) Acetic acid is the chief constituent of vinegar and table. This causes a decrease in the melting point. Among
the given metals, Cs is the largest and has the least
hence its name (Latin: acetum = vinegar).
melting point.
43. (a) Basically all the Azo dye are derivatives of aniline.

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