16-03-2025

1001CJA101021240049 JA

PART-1 : PHYSICS

SECTION-I (i)

1) A bar of mas M = 1.00 kg and length L = 0.20 m is lying on a horizontal frictionless surface. A
small mass m = 0.10 kg is moving on the same horizontal surface with 5.00 m s−1 speed on a path
perpendicular to the bar. It hits the bar at a distance L/4 from the left end and returns back on the
same path with speed v. After this elastic collision, the bar rotates with an angular velocity ω. Which
of the following statement is correct?

(A)
ω= rad s−1 and v = m s−1

(B)
ω= rad s−1 and v = m s−1

(C)
ω= rad s−1 and v = m s−1

(D)
ω= rad s−1 and v = m s−1

2) A container has a base of 50 cm × 5 cm and height 50 cm, as shown in the figure. It has two
parallel electrically conducting walls each of area 50 cm × 50 cm. The remaining walls of the
container are thin and non-conducting. The container is being filled with a liquid of dielectric
constant 3 at a uniform rate of 250 cm3 s−1 . What is the value of the capacitance of the container
after 20 seconds ? [Given: Permittivity of free space ∈0 = 9 × 10− 12 C2 N−1 m−2 , the effects of the

non-conducting walls on the capacitance are negligible]

(A) 27 pF
(B) 63 pF
(C) 81 pF
(D) 135 pF

3) One mole of an ideal gas expands adiabatically from an initial state (P0, V0) to final state (PA, 5V0).
Another mole of the same gas expands isothermally from a same initial state (P0, V0) to the vol. (PB,
5V0). The ratio of the specific heats at constant pressure and constant volume of this ideal gas is γ.

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 What is the ratio ?

(A) 5γ – 1
(B) 51 – γ
(C) 5γ
(D) 51 + γ

4) Two satellites P and Q are moving in different circular orbits around the Earth (radius R). The
heights of P and Q from the Earth surface are hP and hQ, respectively, where hp = R/3. The
accelerations of P and Q due to Earth’s gravity are gP and gQ, respectively. If gP /gQ = 36/25, what is
the velocity of Q? (M = Mass of earth, G = Universal gravitational constant)

(A)

(B)

(C)

(D)

SECTION-I (ii)

1) A slide with a frictionless curved surface, which becomes horizontal at its lower end,, is fixed on
the terrace of a building of height 2h from the ground, as shown in the figure. A spherical ball of
mass m is released on the slide from rest at a height h from the top of the terrace. The ball leaves
the slide with a velocity and falls on the ground at a distance d from the building making an
angle θ with the horizontal. It bounces off with a velocity and reaches a maximum height h1. The
acceleration due to gravity is g and the collision is elastic. Which of the following statement(s)
is(are) correct ? [Take h = 20 m, g = 10 m/s2]. The ground is frictionless.

(A)

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 (B)
m/s
(C) θ = 60°

(D)

2) A plane polarized blue light ray is incident on a prism such that there is no reflection from the
surface of the prism. The angle of deviation of the emergent ray is δ = 60° (see Figure-1). The angle
of minimum deviation for red light from the same prism is δmin = 30° (see Figure-2). The refractive

index of the prism material for blue light is

(A) The blue light has its electric field in the plane of incidence
(B) The angle of the prism is 60°.
(C) The refractive index of the material of the prism for red light is .
(D) The angle of refraction for blue light in air at the exit plane of the prism is 45°.

3) In a circuit shown in the figure, the capacitor C is initially uncharged and the key K is open. In
this condition, a current of 3A flows through 1 Ω resistor. The key is closed at time t = t0. Which of

the following statement(s) is(are) correct? [Given: e–1 ≈ 0.35]

(A) The value of the resistance R is 1Ω.

(B) Long after the switch is closed, value of current I1 is 4 A.
(C) At t = t0 + 8 μs, the current in the capacitor branch is approxmately 0.7 A.
(D) For t → ∞, the charge on the capacitor is 16μC.

SECTION-I (iii)

1) List-I shows different radioactive decay processes and List-II provides possible emitted particles.
Match each entry in List-I with an appropriate entry from List-II, and choose the correct option.

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 List–I List–II

(P) (1) three β – particles and one α particle

(Q) (2) two β – particles and one α particle

(R) (3) one α particle and one β+ particle

(S) (4) one α particle and two β + particles

(5) one α particle and one β – particle

(A) P → 5;Q → 2;R → 1;S → 3
(B) P → 4;Q → 3;R → 4;S → 2
(C) P → 5;Q → 3;R → 1;S → 4
(D) P → 5;Q → 2;R → 4;S → 1

2) Match the temperature of a black body given in List-I with an appropriate statement in List-II, and

choose the correct option. [Given: Wien’s constant as 2.9 × 10−3 m-K and = 1.24 × 10−6 V-m]

List-I List-II

The radiation at peak emission wavelength will

(P) 2000 K (1) result in the widest central maximum of a single slit
diffraction.

The power emitted per unit area is 1/16 of that

(Q) 3000 K (2)
emitted by a blackbody at temperature 6000 K.

The radiation at peak wavelength is visible to human

(R) 5000 K (3)
eye.

10000 The radiation at peak emission wavelength can be

(S) (4)
K used to image human bones.

The radiation at peak wavelength can lead to

(5) emission of photoelectrons from a metal of work
function 4 eV
(A) P → 4;Q → 2;R → 1;S → 5
(B) P → 3;Q → 2;R → 4;S → 1
(C) P → 1;Q → 2;R → 3;S → 5
(D) P → 1;Q → 2;R → 5;S → 3

3) A series LCR circuit is connected to a 45 sin (ωt) Volt source. The resonant angular frequency of
the circuit is 105 rad s−1 and current amplitude at resonance is I0.. When the angular frequency of the
source is ω = 8 × 104 rad s−1, the current amplitude in the circuit is 0.05 I0. If L = 50 mH, match
each entry in List-I with an appropriate value from List-II and choose the correct option.

List–I List–II

(P) I0 in mA (1) 2250

(Q) The quality factor of the circuit (2) 500

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 (R) The bandwidth of the circuit in rad s–1 (3) 18

(S) The peak power dissipated at resonance in Watt (4) 400

(5) 44.4
(A) P → 3;Q → 1;R → 2;S → 4
(B) P → 3;Q → 1;R → 4;S → 2
(C) P → 4;Q → 5;R → 3;S → 1
(D) P → 4;Q → 5;R → 1;S → 3

4) A thin conducting rod MN of mass 20 gm, length 25 cm and resistance 10 Ω is held on frictionless,
long, perfectly conducting vertical rails as shown in the figure. There is a uniform magnetic field B
= 4 T directed perpendicular to the plane of the rod-rail arrangement. The rod is released from rest
at time t = 0 and it moves down along the rails. Assume air drag is negligible. Match each quantity
in List-I with an appropriate value from List-II, and choose the correct option. [Given : The

acceleration due to gravity g = 10 ms–2 and e–1 = 0.4]

List–I List–II

(P) At t = 0.2 s, the magnitude of the induced emf in Volt (1) 1.20

At t = 0.2 s, the magnitude of the magnetic force in

(Q) (2) 0.07
Newton

(R) At t = 0.2 s, the power dissipated as heat in Watt (3) 2.00

(S) The magnitude of terminal velocity of the rod in m s−1 (4) 0.12

(5) 0.14
(A) P → 5;Q → 2;R → 3;S → 1
(B) P → 1;Q → 4;R → 5;S → 3
(C) P → 4;Q → 3;R → 1;S → 2
(D) P → 4;Q → 1;R → 5;S → 3

SECTION-II

1) A Hydrogen-like atom has atomic number Z. Photons emitted in the electronic transitions from
level n = 5 to level n = 3 in these atoms are used to perform photoelectric effect experiment on a
target metal. The maximum kinetic energy of the photoelectrons generated is 1.86 eV. If the
photoelectric threshold wavelength for the target metal is 620 nm, the value of Z is _______. [Given:
hc = 1240 eV-nm and Rhc = 13.6 eV, where R is the Rydberg constant, h is the Planck’s constant

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 and c is the speed of light in vacuum]

2) An optical arrangement consists of two concave mirrors M1 and M2, and a convex lens L with a
common principal axis, as shown in the figure. The focal length of L is 10 cm. The radii of curvature
of M1 and M2 are 20 cm and 24 cm, respectively. The distance between L and M2 is 40 cm. A point
object S is placed at the mid-point between L and M2 on the axis. When the distance between L and
M1 is x cm, one of the images coincides with S. The value of x is _______. (Consider at least two

reflections)

3) In an experiment for determination of the focal length of a thin convex lens, the distance of the
object from the lens is 10 ± 0.1 cm and the distance of its real image from the lens is 15 ± 0.1 cm.
The error in the determination of focal length of the lens is _______ µm.

4) A closed container contains a homogeneous mixture of one mole of an ideal monatomic gas (γ =
5/3) and one mole of an ideal diatomic gas (γ = 7/5). Here, γ is the ratio of the specific heats at
constant pressure and constant volume of an ideal gas. The gas mixture does a work of 66 Joule
when heated at constant pressure. The change in its internal energy is ________ Joule.

5) A person of height 1.6 m is walking away from a lamp post of height 4 m along a straight path on
the flat ground. The lamp post and the person are always perpendicular to the ground. If the speed
of the person is 60 cm s−1, the speed of the tip of the person’s shadow on the ground with respect to
the ground is _______ cm s−1.

6) Two point-like objects of masses 20 gm and 30 gm are fixed at the two ends of a rigid massless
rod of length 10 cm. This system is suspended vertically from a rigid ceiling using a thin wire
attached to its center of mass, as shown in the figure. The resulting torsional pendulum undergoes
small oscillations of amplitude 0.01 rad. The torsional constant of the wire is 1.2 × 10−8 N m rad−1.

The maximum speed of 20 gm mass is _____ µ m/s.

PART-2 : CHEMISTRY

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 SECTION-I (i)

1) In the scheme given below, X, Y and P respectively, are

Metal halide White precipitate (P) + Filtrate (Q)

P X (a coloured species in solution)

Q Y (gives blue-coloration with KI-starch paper)

2–
(A) CrO4 , Br2 and MnO
2–
(B) MnO4 , Cl2 and Mn(OH)2
–
(C) MnO4 , Cl2 and Mn(OH)2
(D) MnSO4 , HOCl and MnO

2) Plotting 1/Λm (Y-axis) against cΛm (X-axis) for aqueous solutions of a monobasic weak acid (HX)
resulted in a straight line with y-axis intercept of P and slope of S. The Ka is
[Λm = molar conductivity
= limiting molar conductivity
c = molar concentration
Ka = dissociation constant of HX]

(A)

(B)

(C)

(D)

3) On decreasing the ฀H from 7 to 2, the solubility of a sparingly soluble salt (MX) of a weak acid
(HX) increased from 10−4 mol L−1 to 'x' mol L−1. Then 'x' is (Ka = 10–4) :

(A) 10–3
(B) 10–4
(C) 10–5
(D) 10–2

4) In the given reaction scheme, P is a phenyl alkyl ether, Q is an aromatic compound; R and S are

the major products. The correct statement about S is

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 (A) It primarily inhibits noradrenaline degrading enzymes.
(B) It inhibits the synthesis of prostaglandin.
(C) It is a narcotic drug.
(D) It is ortho-acetylbenzoic acid.

SECTION-I (ii)

1) The correct statement(s) related to processes involved in the extraction of metals is(are)

Zone refining of metals is based on the principle of greater mobility of pure metal than that of
(A)
impurity.
(B) Calcination of calamine produces sphalerite
(C) Copper pyrite is heated with silica in a reverberatory furnace to remove iron
(D) When Malachite is heated in a reverberatory furnace, cupric oxide is formed.

2) In the following reactions, P, Q, R, and S are the major products.

The correct statement(s) about P, Q, R, and S is(are)

(A) Both P and Q have asymmetric carbon(s).

(B) Both Q and R have asymmetric carbon(s).
(C) Both P and R have asymmetric carbon(s).
(D) P has asymmetric carbon(s), S does not have any asymmetric carbon.

3) Consider the following reaction scheme and choose the correct option(s) for the major products
Q, R and S.

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 (A)

(B)

(C)

(D)

SECTION-I (iii)

1) Match the reactions (in the given stoichiometry of the reactants) in List-I with one of their
products given in List-II and choose the correct option.

List-I List-II

(P) PCl3 + H3PO3 → (1) H3PO2

(Q) Red P4 + alkali → (2) H4P2O5

(R) C2H5OH + PCl3 → (3) H4P2O6

(S) H3PO2 + 2H2O + 4AgNO3 → (4) H3PO3

(5) H3PO4
(A) P → 2;Q → 3;R → 1;S → 5
(B) P → 3;Q → 5;R → 4;S → 2

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 (C) P → 5;Q → 2;R → 1;S → 3
(D) P → 2;Q → 3;R → 4;S → 5

2) Match the electronic configurations in List-I with appropriate metal complex ions in List-II and
choose the correct option.
[Atomic Number: Fe = 26, Mn = 25, Co = 27]

List-I List-II
–2
(P) (1) [NiF6]
3–
(Q) (2) [CoF6]
2+
(R) (3) [Cu(H2O)6]
–
(S) (4) [FeCl4]
2–
(5) [CoCl4]
(A) P → 1;Q → 4;R → 2;S → 3
(B) P → 1;Q → 2;R → 4;S → 5
(C) P → 3;Q → 2;R → 5;S → 1
(D) P → 1;Q → 3;R → 4;S → 2

3) Match the reactions in List-I with the features of their products in List-II and choose the correct
option.

List-I List-II

(P) (1) Inversion of configuration

(Q) (2) Retention of configuration

(R) (3) Mixture of enantiomers

(S) (4) Mixture of structural isomers

(5) Mixture of diastereomers

(A) P → 1;Q → 2;R → 5;S → 3
(B) P → 2;Q → 1;R → 3;S → 5
(C) P → 1;Q → 2;R → 5;S → 4
(D) P → 2;Q → 4;R → 3;S → 5

4) The major products obtained from the reactions in List-II are the reactants for the named
reactions mentioned in List-I. Match List-I with List-II and choose the correct option.

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 List-I List-II

(P) Etard reaction (1)

(Q) Gattermann reaction (2)

(R) Gattermann-Koch reaction (3)

(S) Rosenmund reduction (4)

(5)
(A) P → 2;Q → 4;R → 1;S → 3
(B) P → 1;Q → 3;R → 5;S → 2
(C) P → 3;Q → 2;R → 1;S → 4
(D) P → 3;Q → 4;R → 5;S → 2

SECTION-II

1) The stoichiometric reaction of 516 g of dimethyldichlorosilane with water results in a tetrameric

cyclic product X in 50% yield. The weight (in g) of X obtained is___.
[Use, molar mass (g mol−1): H = 1, C = 12, O = 16, Si = 28, Cl = 35.5]

2) A gas has molar volume of 0.4 dm3 mol−1 at a temperature of 800 K and pressure x atm. If it shows
ideal gas behaviour at the same temperature and pressure, the molar volume is 0.8 dm3 mol−1. The
value of x is ___.
[Use: Gas constant, R = 8 × 10−2 L atm K−1 mol−1]

3) The plot of log kf versus for a reversible reaction A (g) P (g) is shown.

Pre-exponential factors for the forward and backward reactions

15 −1 11 −1
are 10 s and 10 s , respectively. If the value of log Kb for the reaction at 250 K is –5, the value of
log K at 500 K is ______.
[K = equilibrium constant of the reaction
kf = rate constant of forward reaction
kb = rate constant of backward reaction]

4) One mole of an ideal monoatomic gas undergoes two reversible processes (A → B and B → C) as

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 shown in the given figure : A → B is an adiabatic
process. If the total entropy change in the entire process (A → B and B → C) is R ln , the value of
log V3 is _________.

[Use, molar heat capacity of the gas at constant pressure, Cp,m = R]

5) In a one-litre flask, 6 moles of A undergoes the reaction A(g) P(g). The progress of product
formation at two temperatures (in Kelvin), T1 and T2, is shown in the figure:

If T1 = 2T2 and ΔH = RT2 ln x, then the value of x is ______.

6) The total number of sp2 hybridised carbon atoms in the major product P (a non-heterocyclic
compound) of the following reaction is _______.

PART-3 : MATHEMATICS

SECTION-I (i)

1) Let f : (0, 1) → be the function defined as f(x) = if where .

Let g : (0, 1) → be a function such that for all x∈(0, 1). Then

(A) is equal to 2
(B) is equal to 1

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 (C) does NOT exist
(D) is equal to 3

2) Let Q be the cube with the set of vertices . Let F be the

set of all twelve lines containing the diagonals of the six faces of the cube Q. Let S be the set of all
four lines containing the main diagonals of the cube Q; for instance, the line passing through the
vertices (–1, –1, –1) and (1, 1, 1) is in S. For lines ℓ1 and ℓ2, let d(ℓ1, ℓ2) denote the shortest distance
between them. Then the maximum value of d(ℓ1, ℓ2), as ℓ1 varies over F and ℓ2 varies over S, is

(A)

(B)

(C)

(D)

3) Let X = . Three distinct points

P, Q and R are randomly chosen from X. Then the probability that P, Q and R form a triangle whose
area is a positive integer, is

(A)

(B)

(C)

(D)

4) Let P be a point on the parabola y2 = 4ax, where a > 0. The normal to the parabola at P meets
the x-axis at a point Q. The area of the triangle PFQ, where F is the focus of the parabola, is 90. If
the slope m of the normal and a are both positive integers, then the pair (a, m) is

(A) (2, 3)
(B) (3, 2)
(C) (2, 4)
(D) (4, 2)

SECTION-I (ii)

1) Let S = (–2, –1) ∪ (0, 1) ∪ (2, 3) ∪ (4, 5) and T = {0, 1, 2, 3, 4}. Then which of the following
statements is(are) true ?

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 (A) There are infinitely many functions from S to T
(B) There are infinitely many strictly increasing functions from S to T
(C) The number of continuous functions from S to T is at most 786
(D) Every continuous function from S to T is differentiable

2) Let T1 and T2 be two distinct common tangents to the ellipse E : x2 + 2y2 – 2x – 8y + 3 = 0 and the
parabola P : 12x = y2 – 4y + 16. Suppose that the tangent T1 touches P and E at the points A1 and A2 ,
respectively and the tangent T2 touches P and E at the points A4 and A3, respectively. Then which of
the following statements is(are) true ?

(A) The area of the quadrilateral A1A2A3A4 is 35 square units

(B) The area of the quadrilateral A1A2A3A4 is 36 square units
(C) The tangents T1 and T2 meet the x-axis at the point (–2, 2)
(D) The tangents T1 and T2 meet the x-axis at the point (–5, 2)

3) Let f : [0, 1] → [0, 1] be the function defined by 36f(x) = 12x3 – 36x2 + 20x + 17. Consider the
square region S = [0, 1]×[0,1]. Let G = {(x, y)∈S : y > f(x)} be called the green region and R ={(x,
y)∈S : y < f(x)} be called the red region. Let Lh = {(x, h)∈S : x∈[0, 1]} be the horizontal line drawn
at a height h ∈[0, 1]. Then which of the following statements is(are) true ?

(A) There exists an such that the area of the red region above the line Lh equals the area
of the green region below the line Lh

(B) There exists an such that the area of the red region above the line Lh equals the area
of the red region below the line Lh

(C) There exists an such that the area of the green region above the line Lh equals the
area of the red region below the line Lh

(D) There exists an such that the area of the green region above the line Lh equals the
area of the green region below the line Lh

SECTION-I (iii)

1) Let α, β and γ be real numbers. Consider the following system of linear equations
x + 2y + z = 4
x + αz = 10
2x – 3y + βz = γ + 1
Match each entry in List - I to the correct entries in List-II

List-I List-II

(P) (1) a unique solution

If (7α – 3) and γ = 28, then the system has

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 (Q) (2) no solution
If (7α – 3) and γ ≠ 28, then the system has

(R) (3) infinitely many solutions

If (7α –3) where α = 1 and γ ≠ 28, then the system has

x = 10, y = –3 and z = 0 as
(S) (4)
If (7α – 3) where α = 1 and γ = 28, then the system has a solution

x = –16, y = 3 and z = 0 as
(5)
a solution

The correct option is :

(A) P → 3;Q → 2;R → 5;S → 4
(B) P → 3;Q → 2;R → 1;S → 4
(C) P → 2;Q → 1;R → 4;S → 5
(D) P → 2;Q → 1;R → 1;S → 3

2)

Consider the given data with frequency distribution

xi 3 8 11 10 5 4
fi 5 2 3 2 4 4
Match each entry in List-I to the correct entries in List-II.
List-I List-II

(P) The mean of the above data is (1) 2.5

(Q) The median of the above data is (2) 5

The mean deviation about the mean of

(R) (3) 6
the above data is

The mean deviation about the median

(S) (4) 2.7
of the above data is

(5) 2.4

The correct option is :

(A) P → 3;Q → 3;R → 5;S → 5
(B) P → 3;Q → 2;R → 1;S → 5
(C) P → 2;Q → 3;R → 4;S → 1
(D) P → 3;Q → 2;R → 4;S → 5

3) Let ℓ1 and ℓ2 be the lines and , respectively. Let X be the

set of all the planes H that contain the line ℓ1. For a plane H, let d(H) denote the smallest possible
distance between the points of ℓ2 and H. Let H0 be plane in X for which d(H0) is the maximum value
of d(H) as H varies over all planes in X.
Match each entry in List-I to the correct entries in List-II.

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 List-I List-II

(P) The value of d(H0) is (1)

(Q) The distance of the point (0,1,2) from H0 is (2)

(R) The distance of origin from H0 is (3) 0

The distance of origin from the point of

(S) (4)
intersection of planes y = z, x = 1 and H0 is

(5)

The correct option is :

(A) P → 5;Q → 4;R → 3;S → 1
(B) P → 2;Q → 4;R → 5;S → 1
(C) P → 2;Q → 1;R → 3;S → 2
(D) P → 5;Q → 1;R → 4;S → 2

4) Let z be complex number satisfying , where denotes the complex

conjugate of z. Let the imaginary part of z be nonzero.
Match each entry in List-I to the correct entries in List-II.

List-I List-II

(P) 9 is equal to (1) 12

(Q) 9 is equal to (2) 4

(R) (3) 8
is equal to

(S) is equal to (4) 10

(5) 7

The correct option is :

(A) P → 1;Q → 3;R → 5;S → 4
(B) P → 2;Q → 4;R → 5;S → 1
(C) P → 2;Q → 1;R → 3;S → 5
(D) P → 2;Q → 3;R → 5;S → 4

SECTION-II

1) Let , for . Then the number of real solutions of the equation

in the set (–9π, –3π) ∪ (–3π, 3π) ∪ (3π, 9π) is equal to

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 2) Let n ≥ 2 be a natural number and f : [0, 1] → be the function defined by

If n is such that the area of the region bounded by the curves x = 0 , x = 1 , y = 0 and y = f (x) is 6,
then the maximum value of the function f is

3) Let denote the (r + 2) digit number where the first and the last digits are 7 and the

remaining r digits are 5. Consider the sum S = 77 + 757 + 7557 + … + . If

where m and n are natural numbers less than 3000, then the value of m + n is

4) Let . If A contains exactly one positive integer n,

then the value of n is

5) Let P be the plane and let

. Let
and be three distinct vectors in S such that . Let V be the volume of the

parallelepiped determined by vectors and . Then the value of is

6) Let a and b be two nonzero real numbers. If the coefficient of x7 in the expansion of

is equal to the coefficient of x–6 in the expansion of , then the value of

2b is

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 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. A C B B

SECTION-I (ii)

Q. 5 6 7
A. A,B,D A,B,C A,B,D

SECTION-I (iii)

Q. 8 9 10 11
A. A C D B

SECTION-II

Q. 12 13 14 15 16 17
A. 2 30 520 132 100 6

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 18 19 20 21
A. C C A B

SECTION-I (ii)

Q. 22 23 24
A. C,D A,B,C,D B

SECTION-I (iii)

Q. 25 26 27 28
A. D D B D

SECTION-II

Q. 29 30 31 32 33 34
A. 148 80 6 3 16 52

PART-3 : MATHEMATICS

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 SECTION-I (i)

Q. 35 36 37 38
A. A B C B

SECTION-I (ii)

Q. 39 40 41
A. A,C,D A,C A,B,C

SECTION-I (iii)

Q. 42 43 44 45
A. B D A C

SECTION-II

Q. 46 47 48 49 50 51
A. 9 12 1245 19 9 3

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 SOLUTIONS

PART-1 : PHYSICS

1) 0 = Mv1 ×
Mv1 – mv = mv0

e=1=

v1 + +v=5

v=5–7× =

2)

In t = 10 sec volume of liquid is

V = 5000 cc

C = Ca + Cd = 9ε0
= 9 × 9 × 10–12 = 81 Pf

3)

P0V0 = 5PBV0

PB =

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 4)

5)
d = 20 t

40 = 2h = × 10 × t2
t=2
d=

6)

i = θB = 60°

r1 = 30°
r1 + r2 = A

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 δ = (i + e) – A
60° = 60° + e – A
e=A

Solving
A = 60°
∴ e = 60°
For red light

8)
Conservation of charge

Z1 = Z2 + 2 N1 + N2 – N3 … (i)
Conservation of nucleons.
A1 = A2 + 4N1

… (ii)
From (i) and (ii)

(P)

(Q)

(R)

(S)

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 9)

⇒ For option (P) temperature is minimum hence λ will be maximum

⇒ β will also be maximum

⇒ For option (Q) T = 3000

= 0.96 × 10–6
= 966.6 nm
P3000 = 6A (3000)4
P6000 = 6A (6000)4

Q–4

⇒ For (R) T = 5000 K

= 580 nm
Visible to human eyes
R–2
⇒ For (S) T = 10,000 → maximum
Hence (3) is wrong as it has minimum (λm)

10)

V = 45 sin wt, L = 50 mH

= 2 × 10–9 F

ω = 8 × 104 rad/s = 0.8 ω0

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 = 2250.0

11) From force equation

Now

And

∴ v = 2 (1 – e–5t)
At t = 0.2 sec v = 2 (1 – e–5 × 0.2)

v = 2 (1 – 0.4)

v = 1.2 m/s

(P) Now at t = 0.2 sec

The magnitude of the induced emf = E = Bvℓ

Q) At t = 0.2 sec, the magnitude of magnetic force = BIℓsinθ

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 = 0.12 Newton

(R) At t = 0.2 sec, the power dissipated as heat

P = 0.144 watt

(S) Magnitude of terminal velocity

At terminal velocity, the net force become zero

∴ mg = Biℓ

vT = 2 m/s
Hence, Answer is (D)

12)

n=3 n=5
2
–1.51Z eV –0.544 Z2 eV
E = E4 – E3 = 0.96 Z2 eV
Kmax = E – W

∴Z=2

13)
Consider reflection 1st at M2

v = –30

y = 20

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 So, the distance is 30 cm.

14)

df =

15)

At constant pressure
W = nRΔT = 66
ΔU = n(CV)mixΔT

16)

4y – 4x = 1.6y
2.4 y = 4x
X = 0.6y

60 = 0.6 ×

∴ = 100 cm/s

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 17)

Where I = moment of inertia

I = (30) (4)2 + (20) (6)2
= 1200 gm-cm2
= 1.2 × 10–4 kg-m2

⇒ ω = (10–2)
v = Aω = 6 cm × 0.01 × 10–2 = 6 × 10–6 m/s

PART-2 : CHEMISTRY

18)

19) For weak acid, α =

⇒ Ka (1 – α) = Cα2

⇒ Ka =C

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 Divide by

Plot vs C has

Slope = =S

y-intercept = =P

20) At pH = 7 ⇒ pure water

solubility = S1 =
At pH = 2

⇒ MX(s) + aq M+(aq) + X–(aq)

s s–x
X–(aq) + H+(aq) HX(aq)
–2
s–x 10 x s
Approximation : s – x 0 [X– is limiting reagent]
⇒s x
⇒ s(s – x) = Ksp …… (1)

…… (2)

Multiply (1) × (2)

21) P is phenyl alkyl ether

Q is aromatic compound
R and S are the major product
i.e.

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 Correct ans is (B)
Aspirin inhibits the synthesis of chemicals known as prostaglandin's.

22) ⇒ Under roasting condition, the malachite will be converted into

⇒
⇒ Copper pyrites is heated in a reverberatory furnace after mixing with silica. In the furnace,
iron oxide 'slag of' as iron silicate and copper is produced in the form of copper matte.

23) Formation of P

Formation of Q

Formation of R

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 Formation of S

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 24)

25) (P) PCl3 + H3PO3 → H4P2O5

(Q) Red P4 + alkali → H4P2O6
(R) C2H5OH + PCl3 → [H3PO3]
(S) H3PO2 + 2H2O + 4AgNO3 → 4Ag + 4HNO3 + H3PO4

27)

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 28)

29)

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 % yield = 50

30) For gas : Z = 0.5, Vm = 0.4 L/mol

T = 800 K, P = X atm.

⇒
⇒ X = 80

31) For reaction A(g) P(g)

log kf = + log Af [Arrhenius equation for forward reaction]

From plot when, = 0.002, log kf = 9

⇒ 9= (0.002) + log (Af)

15 –1
Given : Af = 10 s

⇒ 9= (0.002) + 15

⇒ = 3000

⇒ log kb = + log Ab
At 250 K

–5 =

= 16 × 250 = 4000

Now, K =

log K = – +4=2+4=6

32) For A → B (γ = 5/3)

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 (Reversible adiabatic)
⇒ 600 (V1)2/3 = 60 (V2)2/3

⇒ 10 =

⇒ 10 =
⇒ V2 = 10(10)3/2 = 105/2

ΔS = R ℓn = R ℓn

101/2 =
V3 = 103
log V3 = 3

33) At T1 K : A(g) P(g)

t=0 6
t=∞ 6–x x = 4 (from plot)

⇒ At T1 K : =2
At T2 K : A(g) P(g)
t=0 6
t=∞ 6 –y y = 2 (from plot)

⇒ At T2 K : =

ΔH = 2T2 R ln 4 = T2 R ln 16

34)

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 Total number of sp2 hybridised C-atom in
P = 28 + 24 = 52

PART-3 : MATHEMATICS

35)

36)
DR'S of OG = 1, 1, 1
DR'S of AF = –1, 1, 1
DR'S of CE = 1, 1, –1
DR'S of BD = 1, –1, 1

Equation of OG ⇒

Equation of AB ⇒
Normal to both the line’s

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 S.D. =

37) Shift origin to (–1, –3). Thus, we get

& y2 < 5x
Solving corresponding equations

& y2 = 5x

X = {(1,1), (1,0), (1,–1), (1,2), (1,–2), (2, 3), (2,2), (2,1), (2,0), (2,–1), (2,–2), (2,–3)}

Let S be the sample space & E be the event n(S) = 12C3

For E
Selecting 3 points in which 2 points are either or x = 1 & x = 2 but distance b/w then is even
Triangles with base 2 :
= 3×7 + 5×5 = 46
Triangles with base 4 :
= 1×7 + 3×5 = 22
Triangles with base 6 :
= 1×5 = 5

38) Let point P (at2, 2at) normal at P is y = –tx + 2at + at3

y = 0, x = 2a + at2
Q(2a + at2, 0)

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 Area of ΔPFQ =
∵ m = –t
∵ a2 [1 + m2] m = 90
(a, m) = (3, 2) will satisfy

39) Number of functions :

Each element of S have 5 choice
Let n be the number of element in set S.
Number of function = 5n
Here n → ∞
⇒ Option (A) is correct.
Option (B) is incorrect (obvious)

(C)
For continuous function
Each interval will have 5 choices.
⇒ Number of continuous functions
= 54 = 625
⇒ Option (C) is correct.
(D) Every continuous function is piecewise constant function
⇒ Differentiable.
Option (D) is correct.

40) Shift origin to (1, 2) ⇒ E : , P : y2 = 12x

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 C2 = a2m2 + b2

⇒ m2 = 1
T1 & T2
y = x + 3, y = –x – 3
Cuts x-axis at (–3, 0)
A1(3, 6) A4(3, –6)
A2(–2, 1) A3(–2, –1)
A1A4 = 12, A2A3 = 2, MN = 5

Area =
Ans. (A, C)

41)

f '(x) = 0 at x = in [0, 1]
AR = Area of Red region
AG = Area of Green region

Total area = 1

⇒ AG =

AG = AR

(A) Option (D) is remaining coloured part of option (C), hence option (A) is also correct.

(B) Correct when

⇒ (B) is correct

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 (C) When

⇒ AR = AG for some
⇒ (C) is correct

(D) Correct when h = but

⇒ (D) is incorrect

42) Given x + 2y + z = 4 …. (1)

x + αz = 10 …. (2)
2x – 3y + βz = γ + 1 …. (3)

Now, Δ = =
2γα + 14α – 20β – 30

∴ if β =

Now, Δx =
= 21α + 14α – 20β – 30
∴ if γ = 28
⇒ Δx = 0
Similarly
∴ if γ = 28
⇒ Δy = 0
If γ = 28

∴ if γ = 28 and β =
⇒ system has infinite solution
and if γ ≠ 28
⇒ system has no solution
⇒ P → (3) ; Q → (2)

Now if β ≠
⇒ Δ ≠ 0 ⇒ system has unique solution
and for α = 1 clearly
y = –3 is always be the solution
∴ if γ ≠ 28
System has a unique solution
if γ = 28

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 ⇒ x = 10, y = –3 and z = 0 will be one of the solution
∴R→1;S→4
∴ option 'A' is correct

43) xi 3 4 5 8 10 11
fi 5 4 4 2 2 3
(P) Mean
(Q) Median
(R) Mean deviation about mean
(S) Mean deviation about median

xi fi xifi C.F. |xi – Mean| fi|xi – Mean| |xi – Median| fi|xi – Median|

3 5 15 5 3 15 2 10

4 4 16 9 2 8 1 4

5 4 20 13 1 4 0 0

8 2 16 15 2 4 3 6

10 2 20 17 4 8 5 10

11 3 33 20 5 15 6 18

Σfi = 20 Σxifi = 120 Σfi|xi – Mean| = 54 Σfi|xi – Median| = 48

(P)

(Q) observation = 10th observation = 5

(R) Mean deviation about mean =

(S) mean deviation about median =

44)

Let system of planes are

ax + by + cz = 0 ..... (1)
∵ It contain L1
∴a+b+c=0 …. (2)
For largest possible distance between plane (1) and L2 the line L2 must be parallel to plane (1)
∴a+c=0 …. (3)

∴ Plane H0 :
Now d(H0) = ⊥ distance from point (0, 1, –1) on L2 to plane.

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 ∴P→5

for 'Q' distance =

∴Q→4
∴ (0, 0, 0) lies on plane
∴R→3
for 'S' x = z ; y = z ; x = 1
∴ point of intersection p(1, 1, 1).
∴
∴S→2
∴ option [B] is correct

45) Replace 3z by z
…. (1)
Take conjugate both sides
…. (2)
By (1) – (2)

…. (3)
…. (4)
Let z = x + iy
∴ ∴ z = 1 + iy
Put in (1)
⇒ (1 + y2)3/2 + 2(1 – y2 + 2iy) + 4(1 – iy) – 8 = 0
⇒ (1 + y2)3/2 = 2(1 + y2)

Also
∴

Now z + 1 = 2 +
|z + 1|2 = 4 + 3 = 7
∴P→2;Q→1;R→3;S→5
∴ Option [C] is correct.

46) |cos x| = tan–1 tan

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 47)
Area = Area of (I + II + III) = 4

48) S = 77 + 757 + 7557 + … +

10S = 770 + 7570 + … + 75 … 570 + 755 ….. 570
______________________________________________

9S = –77 + +

= –77 + 1300 + + 13

m = 1236
n=9
m + n = 1245

49)

for positive integer

Im(A) = 0
21cosθ + 42sinθ = 0

; ;

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 50)
Given
⇒ ΔUVW is an equilateral Δ

Now distances of U, V, W from

⇒
Also, Distance of plane P from origin
⇒ OQ = 4

∴ OP = OQ – PQ ⇒

Hence, ⇒
Also, for ΔUVW, P is circumcenter
∴ for ΔUVW : US = Rcos30°
⇒ UV = 2Rcos30°

∴
∴ Volume of tetrahedron with coterminous edges

∴ parallelopiped with coterminous edges

∴ =9

51)

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 here 12 – 5r = 7
⇒r=1

∴ coeff. =

14 – 5r = –6 ⇒ r = 4

coeff. :

now

⇒ 2b = 3

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