Solutions-Class-Xii
Solutions-Class-Xii
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ASSIGNMENT
Chemistry Class: 12th ACADEMIC YEAR 2025-26
10. A maximum boiling azeotrope shows :
(1) Positive deviation (2) Negative deviation
(3) No deviation (4) Constant vapour pressure
Short Answer type Questions
11. Why does pressure have little effect on the solubility of solids in liquids?
12. A solution is prepared by dissolving 27.0 g of urea (NH2)2CO in 150.0 g of water. Calculate
the boiling point (in °C) of the solution. (Given : Kb for water = 0.512 °C Kg mol–1)
Long Answer type Questions
13. Given reasons :
(a) Measurement of osmotic pressure method is preferred for the determination of molar
masses of macromolecules such as proteins and polymers.
(b) Aquatic animals are more comfortable in cold water than in warm water.
(c) Elevation of boiling point of 1 M KCl solution is nearly double than that of 1 M sugar
solution [Assume Molarity = Molality].
Very Long Answer type Questions
14. (a) The observed osmotic pressure for given 0.10 M solution of Fe(NH 4)2(SO4)2 at 25°C is
10.8 atm.
Find:
(i) Expected value for i.
(ii) Experimental value for i.
(b) Why is the value of Van't Hoff factor for ethanoic acid in benzene close to 0.5?
Case Study Based Questions
15. A person suffering from dehydration is given a 0.9% (mass/volume) sodium chloride
solution intravenously to restore body fluids. The doctor explains that this solution is
isotonic with the patient’s blood, preventing harmful water movement. Based on this case
study, answer the following:
(a) Why is a 0.9% NaCl solution used for intravenous injection?
(b) How does this example illustrate the concept of osmosis?
(c) What would happen:
(i) If a hypertonic solution were injected instead?
(ii) If a hypotonic solution were used instead?
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