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ASSIGNMENT-6

The document consists of a series of questions related to colligative properties, osmotic pressure, and solutions in chemistry. It includes multiple-choice questions and calculations involving molar mass, freezing point depression, and osmotic pressure. The questions assess understanding of concepts such as van't Hoff factors, osmosis, and isotonic solutions.

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vimlesh kumar
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11 views1 page

ASSIGNMENT-6

The document consists of a series of questions related to colligative properties, osmotic pressure, and solutions in chemistry. It includes multiple-choice questions and calculations involving molar mass, freezing point depression, and osmotic pressure. The questions assess understanding of concepts such as van't Hoff factors, osmosis, and isotonic solutions.

Uploaded by

vimlesh kumar
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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ASSIGNMENT-6

1. Which of the following solution has maximum boiling point:


a. 1 molal glucose c. 1 molal urea
b. 1 molal NaCl d. 1 molal sucrose
2. In comparison to a 0.01 M solution of glucose, the depression in freezing point of a 0.01 M MgCl2 solution is:
a. The same c. About three times
b. About twice d. About six times

3. An unripe mango placed in a concentrated salt solution to prepare pickle shrivels because:
a. It gains water due to osmosis.
b. It loses water due to reverse osmosis.
c. It gains water due to reverse osmosis.
d. It loses water due to osmosis.
4. The values of van’t Hoff factors for KCl, NaCl and K2SO4 respectively are:
a. 2, 2 and 2 c. 1, 1 and 2
b. 2, 2 and 3 d. 1, 1 and 1
5. Consider the figure and mark the correct option:

a. Water will move from side (a) to side (b) if a pressure lower than osmotic pressure is applied on piston (b).
b. Water will move from side (b) to side (a) if a pressure greater than osmotic pressure is applied on piston (b).
c. Water will move from side (b) to side (a) if a pressure equal to osmotic pressure is applied on piston (b)
d. Water will move from side (a) to side (b) if pressure equal to osmotic pressure is applied.
6. Van’t Hoff factor (i) is given by the expression:
𝑛𝑜𝑟𝑚𝑎𝑙 𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠
a. 𝑖 =
𝑎𝑏𝑛𝑜𝑟𝑚𝑎𝑙 𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠
𝑎𝑏𝑛𝑜𝑟𝑚𝑎𝑙 𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠
b. 𝑖 = 𝑛𝑜𝑟𝑚𝑎𝑙 𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠
𝑜𝑏𝑠𝑒𝑟𝑣𝑒𝑑 𝑐𝑜𝑙𝑙𝑖𝑔𝑎𝑡𝑖𝑣𝑒 𝑝𝑟𝑜𝑝𝑒𝑟𝑡𝑦
c. 𝑖 = 𝑐𝑎𝑙𝑐𝑢𝑙𝑎𝑡𝑒𝑑 𝑐𝑜𝑙𝑙𝑖𝑔𝑎𝑡𝑖𝑣𝑒 𝑝𝑟𝑜𝑝𝑒𝑟𝑡𝑦
𝑐𝑎𝑙𝑐𝑢𝑙𝑎𝑡𝑒𝑑 𝑐𝑜𝑙𝑙𝑖𝑔𝑎𝑡𝑖𝑣𝑒 𝑝𝑟𝑜𝑝𝑒𝑟𝑡𝑦
d. 𝑖 = 𝑜𝑏𝑠𝑒𝑟𝑣𝑒𝑑 𝑐𝑜𝑙𝑙𝑖𝑔𝑎𝑡𝑖𝑣𝑒 𝑝𝑟𝑜𝑝𝑒𝑟𝑡𝑦
2. Assertion: Osomotic pressure is a colligative property.
Reason: Two solutions having same osmotic pressure at a given temperature are called isotonic
solutions.
a. Both Assertion and Reason are correct statements and Reason is the correct explanation of the Assertion.
b. Both Assertion and Reason are correct statements, but Reason is not the correct explanation of the Assertion.
c. Assertion is correct, but Reason is incorrect statement.
d. Assertion is incorrect, but Reason is correct statement.
7. At 300 K, 36 g of glucose present in a litre of its solution has an osmotic pressure of 4.98 bar. If the
osmotic pressure of the solution is 1.52 bars at the same temperature, what would be its concentration?
8. A Solution containing 15 g urea (molar mass = 60 g mol-1) per litre of solution in water has the same
osmotic pressure (isotonic) as a solution of glucose (molar mass = 180 g mol -1) in water. Calculate the
mass of glucose present in one litre of its solution.
9. Calculate the osmotic pressure in pascals exerted by a solution prepared by dissolving 1.0 g of polymer
of molar mass 185,000 in 450 mL of water at 37°C.
10. Which colligative property is generally used to calculate the molar mass of different solid solute and
why?

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