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Chemistry PC (3rd) Dec2020

This document outlines the examination paper for Physical Chemistry, including instructions for answering questions and the structure of the exam. It consists of three sections: Section A and B with multiple questions on thermodynamics and related concepts, and a compulsory Section C covering fundamental principles. Each question has specific marks assigned, with a total of 26 marks available.

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4 views2 pages

Chemistry PC (3rd) Dec2020

This document outlines the examination paper for Physical Chemistry, including instructions for answering questions and the structure of the exam. It consists of three sections: Section A and B with multiple questions on thermodynamics and related concepts, and a compulsory Section C covering fundamental principles. Each question has specific marks assigned, with a total of 26 marks available.

Uploaded by

ranaamnn77197
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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BS/2110 5213/ NH

Paper: III
SEM-III
Title of the Paper: Physical Chemistry

Time allowed: 3 hrs Maximum Marks: 26

Note: Attempt Five questions in all selecting Two questions each from each Section-A and B
and the Entire Section-C which is compulsory. Each question in Section-A and Section-
B carries 4 marks and compulsory question 9 carries 10 marks
Section A
1. a) Why do gases show Joule Thomson effect? Why is it zero for ideal gases?
b) Derive the mathematical expression for first law of thermodynamics.
2. a) Explain the term enthalpy of neutralization.
b) What is the thermodynamic basis of Stess’s law
c) The molar heat capacities at constant pressure of H2(g), Cl2(g) and HCl(g) are
respectively 29.3, 34.7 add 28.9 JK-1. If the heat of formation of HCl(g) at constant
pressure at 293 K is a -91.2 KJ, what will be the heat of formation of 313 K.
3. a) Show that
TVr -1 = constant
during adiabatic reversible expansion of an ideal gas
b) Show that the heat capacity of an ideal gas at constant volume having transitional
kinetic energy is equal to 3 cal/mol
4. a) State and explain car notes theorem show that the efficiency of a reversible car not
cycle is T2 - 31 / 82 where 21 hour the temperature of the source and sink
b) write short note on thermodynamic scale of temperature

Section B

5. a) Mixing of gases is always accompanied by increase in entropy. Justify by drawing


the required expression.
b) How can efficiency of carnot engine be increased.
6. a) How do the result of Nernst theorem lead to the enunciation of 3rd law of
thermodynamics
b) Define work function. Show how
-∆ = Wmax
7. a) Explain residual entropy calculate for FClO3.
b) Four moles of an ideal gas expands isothermally from 1 litre to 10 litre at 300K.
Calculate the change in the free energy of the gas (R = 8.314 JK-1 mol-1)
8. a) Derive Van’s Hoff equation giving the effect of temperature on equilibrium
constant
b) Predict suitable condition for getting maximum yield of Sulphur trioxide according
to Le-Chatelier's principle

Section C

9.

a. Give the difference between state and path function


b. What are the limitations of first law of thermodynamics?
c. What is the Clausius inequality. Show that for spontaneous cooling
dStotal > 0
d. Define thermodynamic equation of state
e. Derive the expression
Kp = Kc (RT)∆n

5213/ NH

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