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C2CL4 SDS

The document is a Safety Data Sheet (SDS) for PER235 - Perchloroethytene Catalyst, detailing its identification, hazards, first-aid measures, fire-fighting measures, and handling precautions. It highlights the health risks associated with the chemical, including toxicity and carcinogenicity, and provides emergency contact information. The SDS also outlines safe storage and disposal practices, as well as personal protective equipment recommendations.
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0% found this document useful (0 votes)
25 views

C2CL4 SDS

The document is a Safety Data Sheet (SDS) for PER235 - Perchloroethytene Catalyst, detailing its identification, hazards, first-aid measures, fire-fighting measures, and handling precautions. It highlights the health risks associated with the chemical, including toxicity and carcinogenicity, and provides emergency contact information. The SDS also outlines safe storage and disposal practices, as well as personal protective equipment recommendations.
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
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Iosue date: 04-10-2028, Revision dat: 09-11-2023 Supersedes date: 05-09-2023 Version number: 09 SAFETY DATA SHEET SECTION 1. Identification of the hazardous chemical substance or mixture and of the supplier or manufacturer Name of the hazardous PER235 - Perchloroethytene Catalyst chemical substance or mixture Other means of identification ‘Common name(s), Tetrachloroethylene * Perchlorethylene * Perchlor * PERC * C2Cl synonym(s) Product code 80006349, 80006364, 80008351 Recommended use of the hazardous chemical substance or mixture, and restrictions of use Recommended use Solvent. Degreaser. Recommended restrictions None known. ‘Suppliers details ‘Company name Westlake Corporation Address 2801 Post Oak Blvd, Suite 600 Houston, TX 77058 United States: Telephone 1-713-960-9111 Website wr. westlake.com E-mail [email protected] Emergency phone number CHEMTREC. 1-800-424-9300 CHEMTREC Intemational +1 703-741-5970 SECTION 2. Hazard identification Classification of the substance or mixture Physical hazards Not classified Health hazards Acute toxicty, oral Category § Acute toxic, inhalation Category 4 ‘Skin corrosionvirtation Category 2 Serious eye damageloye ination Category 28 Carcinogenicity Category + Specific target organ toxicity, single exposure Category 3 narcotic affects Aspiration hazard Category 1 Elements of labeling, including precautionary statements and warning pictograms Signal word Danger Hazard statement 303 May be harmful f swallowed. #304 May be fatal f swallowed and enters airways. Hats Causes skin iritaion Hate Causes serious eye intaion 332 Karmful ifinhaled 336 May cause drowsiness or dizziness. 350 May cause cancer. Precautionary statement Prevention 201 Oblain special instructions before use. 202 Do not handle untill safety precautions have been read and understood. ‘atari name: PERZIS -Perchoroatnione Cataat parry 170 110 Iosue date: 04-10-2028, Revision dat: 09-11-2023 Supersedes date: 05-09-2023 Version number: 09 261 Avoid breathing mistvapors. 268 Wash thoroughly ater handling, pari Use only outdoors or in a well-ventilated area, 280 Wear protective glovesiprotective clothingleye protectioniface protection. Response aot + Pai0 SWALLOWED: Immediately calla POISON CENTERIdoctor. 331 De NOT induce vomiting, 302 + P3562 ON SKIN: Wash with plenty of water. 304 + P340 INHALED: Remove person to fresh air and keep comfortable for breathing 30s + P35s + 338 IF IN EYES: Rinse cautiously with water for several minules. Remove contact lenses, if present land easy fo do, Continue rinsing aos + Pais ‘exposed ar concerned: Get medical advic/attention, 332 + P3138 If skin iritaon occurs: Get mecical advicelattention P337 + P3i3 IF eye iritation persists: Get medical advicelattention 362 + P364 ‘Take off contaminated clothing and wash it before reuse. Storage aga + P233 Store in a wel-ventlated place. Keep container tightly closed. 405 ‘Store locked up. Disposal 501 Dispose of contents/cantainer in accordance with localregionalinationalintemational regulations. Other hazards which do net None known, result in classification ‘Supplemental information None. ‘SECTION 3. Composition/information on ingredients Mixtures, Chemical identity ‘Common name(s), synonym(s) CAS number and ther Concentration unique identifi Perchlorosthylene 127-184 20-100 SECTION 4. First-aid measures Description of necessary first-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or artificial respiration if needed. Calla poison center or dectr/physician if you feel unwell ‘Skin contact Remove contaminated clothing. Wash with plonty of soap and water. If skin irtation occurs: Get ‘medical advice/attenton, Wash contaminates clothing before reuse Eye contact Immediately fush eyes with plenty of water fr at least 15 minutes. Remove contact lenses, if present and easy to 60. Continue rinsing. Get medical attention if tation develops and persists. Ingestion Calla physician or poison control center immediately. Rinse mouth. Do not induce vomiting. Vomiting occurs, Keep head low eo thal stomach cantent dosen't get into the Iungs. Most important Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness or dizziness. symptomsietfects, acute and Headache. Nausea, vomiting. Severe eye ration. Symptoms may include stinging, tearing, delayed redness, swaling, and blurred vison. Skin iitation, May cause redness and pain, Indication of immediate Provide general supportive measures and treat symptomaticaly, Keep victim warm, Keep victim ‘medical attention and special under observation. Symptoms may be delayed. treatment needed General information I exposed or concerned: Get medical adviceattention. Ensure that medical personnel are aware ‘ofthe materials) involved, and take precautions to protect themselves. Show this safely dala sheet tothe doctor in atlendance. SECTION 5. Fire-fighting measures ‘Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing Do not use waler et as an extinguisher, as this wil spread the fre, Specific hazards arising from Containers may explode when heated. During fre, gases hazardous to health may be formed, the chemical ‘atari name: PERZIS -Perchoroatnione Cataat awe 170 2/10 ‘Special protective actions for firefighters Firefighting ‘equipmentinstructions Specific methods Gener fire hazards Iosue date: 04-10-2028, Revision dat: 09-11-2023 Supersedes date: 05-09-2023 Version number: 09 ‘Sel-contained breathing apparatus and full protective clothing must be wom in case of fre, Move containers from fire area if you can do so without risk. Use standard firefighting procedures and consider the hazards of other involved materials. No unusual fre or explosion hazards noted SECTION 6. Measures that must be taken in the event of accidental spillage or an accidental leak Personal precautionary measures, protective equipment and emergency procedure For non-emergency person For emergency responders. Environmental precautions Methods and materials for containing and cleaning up spills or releases ‘SECTION 7. Hani Precautions for safe handling Conditions for safe storage, including any incompatibil ‘Avoid breathing mistvapors. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing, Do not touch or walk through spied materal Keap unnecessary personnel away. Ensure adequate ventilation, Avoid breathing mistivapors Local authorities should be advieed if signficant spllages cannot be contained, Use personal protection recommended in Section 8 of the SDS. ‘Avoid discharge into drains, water courses or onto the ground. Prevent entry into waterways, sewer, basements or confined areas. Large Spill: Stop the flow of material, if this fs without risk, Dke the spilled material, where this is possible. Absoro in vermiculte, dry sand or earth and place into containers, Following product recovery fish area with water ‘Small Spil: Wipe up with absorbent material (eg. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never retum spills to original containers for re-use. Put materalin suitable, covered, labeled containers. For waste disposal, see section 13 of the SDS, 1g and storage ‘Obtain special instructions before use. Do not handle untill safety precautions have been reac {and understood. Do not taste or swallow. Avoid breathing mistivapors. Avoid contact with eyes, ‘kin, and clothing, Avoid prolonged exposure, When using, do not eat, drink or smoke, Should be handled in closed systems, if possible, Use anly outdoors or in a well-ventilated area, Wear ‘appropriate personel protective equipment, Wash hands thoroughly after handing, Observe good industrial nygiene practices. Depending upon consitions, this material ori is vapors when in Contact with flames, hot glowing surfaces or slectnc arcs can decompose to form hydrogen Chloride gas ana possible traces of phosgene. Oo not use culting or welding torches on drums that Contained ths product unless properly purged and cleaned. Do not ship lightly stabilized grades in ‘aluminum trailers. Do rot ship in containers made of zinc, aluminum, or copper dus to product incompatiity ‘Store locked up. Protec fom sunlight. Store in tightly closed container. Store in a woll-ventiated place. Store away from incompatisle materals (see Section 10 ofthe SDS). Store in accordance with localregional/nationalinternatonal regulation. Do not store above the following temperature 35°C (95°F). Do not store or stack aluminum in contact with this product to prevent possible Solvent decomposition (stacking corrosion), Containers that have been opened must be carefully rosealed and kept uprght to provent leakage. Do not store in unlabeled containers. Liquid oxygen for other strong oxidants can form explosive mixtures of perchloroethylene. SECTION 8. Exposure controls/personal protection Controt parameters. Occupational exposure limits Moxico. Occupational Exposure Limit Values ‘Components. Type Value Perchloroethylene (CAS STEL 100 ppm 127-18-4) Twa 25 ppm US. ACGIH Threshold Limit Values ‘Components Type Value Perchloroethylene (CAS STEL 100 ppm 127-18-4) TWA 25 ppm ‘atari name: PERZIS -Perchoroatnione Cataat owen 170 3/10 Iosue date: 04-10-2028, Revision dat: 09-11-2023 Supersedes date: 05-09-2023 Version number: 09 Mexico. Biological Exposure Indices ‘Components Value Determinant Specimen Sampling Time Parchloroetnylene (AS OS mail Tetrardoreatle Blood * 127-18-4) no 3 ppm Tetrarcloroetile Endexhaled : + For sampling details, please see the source document ACGIH Biological Exposure Indices ‘Components. Value Determinant Specimen Sampling Time Parchloroetnylene (CAS 05 mail TTetrachioroethy Blood . 127-184) lene 3 ppm Tetrachloroethy — End-exhaled : lene aie Control banding approach Appropriate engineering controls For sampling details, please see the source document. Not availabe. ‘Good general ventilation should be used. Ventilation rates should be matched to conditions. I applicable, use process enclosures, local exhaust ventilation, or other engineering controls to ‘maintain arbome levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station and safety shower, Individual protection measures, such as personal protective equipment (PPE) Eyelface protection ‘Skin protection Hand protection other Respiratory protection ‘Thermal hazards General hygiene considerations ‘Chemical respirator with organic vapor cartridge and ful facepiece, Wear appropriate chemical resistant gloves. \Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended (Chemical respirator with organic vapor cartridge and ful facepiece. \Wear appropriate thermal protective clothing, when necessary ‘Observe any medical suveiiance requirements. Keep away from food and drink. Aways observe {good personal hygiene measures, such as washing after handling the material and before eating, drinking, andlor smoking. Routinely wash work clothing and protective equipment to remove ‘contaminants SECTION 9. Physical and chemical properties Appearance Physical state Form Color Odor (Odor threshold pH ‘Melting pointitreezing point Initia boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Liquid Liquid Colorless Ethereal Not available 6-75 “8.14 °F (223°C) estimated 248,08 - 260.88 °F (120.6 - 121.6 °C) Not available (0.1 (ether (anhysrous) = 1) Not applicable. Upperiiower flammability or explosive limits Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Relative density Not available Not available 14.2 mm Hg @ 20°C Not available Not available ‘atari name: PERZIG -Perchoroalny 170 2 Galahat awe 4/10 Solubility(ies) ‘Solubility (water) Partition coefficient (n-octanoliwater) ‘Auto-igntion temperature Decomposition temperature Viscosity Molecular weight Other information Density Explosive properties Oxidizing properties Percent volatile ‘Specific gravity voc Iosue date: 04-10-2028, Revision dat: 09-11-2023 Supersedes date: 05-09-2023 Version number: 09 <01% Not available. Not avaiable Not available 0.88

10000 mglkg, 24 Hours 20200 mgim3, 6 Hours Rat 2400 mag Causes skin iritation Causes serious eye inftaion ‘atari name: PERZIG -Perchoroalny 170 2 Galahat awmne 5/10 Respiratory or skin sensitization Respiratory sensitization ‘Skin sensitization Gorm coll mutagonicity Carcinogenicity ACGIH Carcinogens Perchloroethylene (CAS 127-18-4) Iosue date: 04-10-2028, Revision dat: 09-11-2023 Supersedes date: 05-09-2023 Version number: 09 Nota respiratory sensitizer This product is not expected to cause skin sensitization No data available o indicate product or any components present al greater than 0.1% are ‘mutagenic or genotoxic, May cause cancer, 'A3 Confirmed animal carcinogen with unknown relevance to humans. IARC Monographs. Overall Evaluation of Carcinogenicity Perchloroethylene (CAS 127-18-4) Reproductive toxicity Specific target organ tox! single exposure ‘Specific target organ toxicity - repeated exposure ty Aspiration hazard Other information 2A Probably carcinogenic to humans. This product isnot expacted to cause reproductive or developmental effects. May cause drowsiness or dizziness. Not classified ‘May be fatal f swallowed and enters airways. Not available. SECTION 12. Ecotoxicological information Toxicity The product isnot classified as environmentally hazardous. However, this does not exclude the possibilty that large or frequent spills can have a harmful or damaging effet onthe environment, Components, Spocies Test Results Parchloroethyiene (GAS 127-16-4) ‘Aquatic Acute Crustacea cso Water fea (Daphnia magna) >=6.1-<= 9 mgil, 48 hours Fish Loso Rainbow trout donaldson trout >= 4.73~ <= 5.27 mall, 96 hours Persistence and degradability Bioaccumulative potential (Oncorhynchus mykiss) No datais available on the degradabiltyof any ingredients in the mixture Partition coefficient n-octanol / water (log Kow) Perchloroethylene Mobility in soil Other adverse effects 34 No data available. ‘The product contains volatile organic compounds which have a photochemical ozone creation potential SECTION 13. Disposal considerations Disposal methods Disposal instructions Local disposal regulations. Hazardous waste code Waste from residues / unused products Contaminated packaging Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of Contents/cantainer in accordance with localiregionalinationalinterational regulations. Dispose in accordance wit al applicable regulations. ‘The waste code should be assigned in discussion between the user, the producer and the waste cisposal company. Dispose of in accordance with local regulations. Emoty containers or liners may retain some product residues, This material and its container must be disposed of in a safe manner (see: Disposal instructions). ‘Since emptied containers may retain product residue, folow label warnings even after container is. ‘emptied. Empty containers should be taken to an approved waste handling ste for recycling or disposal SECTION 14. Transport information set UN number Proper shipping name uN1897 TETRACHLOROETHYLENE (Perchloroethylone) ‘atari name: PERZIG -Perchoroalny 170 6/10 2 Galahat ‘Transport hazard class(es) Class Subsidiary risk Packing group Environmental hazards ‘Special precautions for user por UN number Proper shipping name Transport hazard class(es) Class ‘Subsidiary risk Labels) Packing group Environmental hazards Marine pollutant ‘Special precautions for user ‘Special provisions Packaging exceptions Packaging non bulk Packaging bulk ADR UN number Proper shipping name ‘Transport hazard class(es) Class Subsidiary risk Label(s) Hazard No. (ADR) ‘Tunnel restriction code Packing group Environmental hazards ‘Special precautions for user RID UN number Proper shipping name ‘Transport hazard class(es) Class Subsidiary risk Label(s) Packing group Environmental hazards ‘Special precautions for user ADN. UN number Proper shipping name ‘Transport hazard class(es) Class Subsidiary risk Labelis) Packing group Environmental hazards ‘Special precautions for user lata UN number Proper shipping name ‘Transport hazard class(es) Class Subsidiary risk Iosue date: 04-10-2028, Revision dat: 09-11-2023 Supersedes date: 05-09-2023 Version number: 09 6a No. Read safely instructions, SDS and emergency procedures before handing. uN1897 Totrachloroethylene (Perchloroethylene RQ = 101 LBS), MARINE POLLUTANT 6a 6a u Yes Read safety instructions, SDS and emergency procedures before handling. 123, N36, T4, TPt 153 203 28% UN1897 TETRACHLOROETHYLENE SOLUTION (Perchloroethylene) 6a 6a 60 M Yes Read safety instructions, SDS and emergency procedures before handing. UN1897 TETRACHLOROETHYLENE (Perchloroethylene) 6a 6a MW Yes Read safety instructions, SDS and emergency procedures before handing. UN1897 TETRACHLOROETHYLENE (Perchloroathylene) 6a 6a MW Yes Read safety instructions, SDS and emergency procedures before handing. uN1897 Tetrachloroethylene 6a ‘atari name: PERZIS -Perchoroalny 170 2 Galahat por’ 7110 Packing group Environmental hazards ERG Code ‘Special precautions for user ther information Passenger and cargo alreraft ‘Cargo aircraft only imps. UN number Proper shipping name ‘Transport hazard class(es) Class Subsidiary risk Packing group Environmental hazards Marine pollutant Ems. ‘Special precautions for user Transport in bulk according to ‘Annex Il of MARPOL 73/78 and the IBC Code Iosue date: 04-10-2028, Revision dat: 09-11-2023 Supersedes date: 05-09-2023 u Yes 6 Read safety instructions, SDS and emergency procedures before handling. ‘Allowed with rstictions. ‘Allowed with restctions. UN1897 TETRACHLOROETHYLENE, MARINE POLLUTANT 6a Yes EASA Read safety instructions, SDS and emergency procedures before handing. Not established ‘ADN; ADR; IATA; IMDG; RID; SCT por Marine pollutant General information IMDG Regulated Marine Pollutant. Version number: 09 ‘atari name: PERZIG -Perchoroalny 170 2 Galahat 8/10 SECTION 15. Regulatory information Safety, he environmental regulations —_(NON-O18-STPS-2018) ‘specific for the hazard ‘chemical substance or mixture in question Moxico. Substances subject to reporting for the pollutant ri Not sted. International regulations Montreal Protocol nd transfer registry (PRTR) Not applicable. ‘Stockholm Convention Not applicable. Rotterdam Convention Not applicable, kyoto protocol Not applicable. Not applicable. International Inventories Country(s) or region Inventory name Australia ‘Australian Inventory of Industrial Chemicals (AICIS) Canada Domestic Substances List (OSL} Canada Non-Domestic Substances List (NDSL) China Inventory of Existing Chemical Substances in China (IECSC) Europe European Inventory of Existing Commercial Chemical Substances (EINECS) Europe European List of Notfied Chemical Substances (ELINCS) Japan Inventory of Existing and New Chemical Substances (ENCS) Korea isting Chemicals List (ECL) New Zealand New Zealand Inventory Philippines Philippine Inventory of Chemicals and Chemical Substances (ices) Taiwan ‘Taiwan Chemical Substance Inventory (TCS!) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Iosue date: 04-10-2028, Revision dat: 09-11-2023 Supersedes date: 05-09-2023 Version number: 09 th and This safety data sheot was prepared in accordance withthe Official Mexican Standard On inventory (yesino}* Yes Yes No Yes Yes No Yes Yes Yes Yes Yes Yes “*A"Yes" indicates that all componens ofthis product comply wit he inventory requirements administered bythe governing county) [APNo"indates that one or more componants ofthe product are not eg or exam om ting on the ventory administered by the governing county). SECTION 16. Other included information relevant to the preparation and updating of safety data sheets Issue date 04-18-2023 Revision date 9-11-2023 Version # 03 List of abbreviations ACGIH: American Conference of Govemmental Industrial Hygienists. ‘ADN: European Agr Waterways sment concerning the Intemational Carriage of Dangerous Goods by Inland ADR: European Agreement Concerning the International Cariage of Dangerous Goods by Road, ANTT: National Agency of Land Transpo. CAS: Chemical Abstract Service, DOT: Deparment of Transportation. GHS: Globally Harmonized System of Classification and Labeling of Chemicals. IARC: International Agancy for Research on Cancer IATA‘ International Air Transport Assocation, IBC Code: Intemational Code for the Construction and Equipment of Ships Carying Dangerous Chemicals in Bulk. ‘atari name: PERZIG -Perchoroalny 170 2 Galahat 9/10 References HMIS® ratings NFPA ratings NFPA ratings Disclaimer Revision information Iosue date: 04-10-2028, Revision dat: 09-11-2023 Supersedes date: 05-09-2023 Version number: 09 IMDG: international Martime Dangerous Goods, MARPOL: Inteenational Convention fr the Prevention of Pollution from Ships. NFPA National Fire Protection Assoccation, RID: Regulations concerning the International Carriage of Dangerous Goods by Rall ‘SCT: Secretariat of Communications and Transportation (NOM-002-SCT/2011}. 'STEL; Short term exposure limi. TWA: Time Weighted Average. NMOCR.019-SCFI-201 1 - Harmonized system of classification and communication of dangers of chemical products NOM.910-STPS.2014 (second revision) — Occupational Exposure Limits - becomes effective on April 28, 2016 NOM-018.STPS.2015 - Harmonized system forthe identication and communication of hazards {and risks for hazardous chemicals in the workplace NOM-026-STPS.2008 - Colors and signals of safety and hygiene, and risk identfication though {uids in pines NOM.028-STPS.2012— Work-Safely Management Systom for Processes and Critical Equipment Handling Hazardous Chemical Substances NOM-047-SSA1-201 1 — Workplace Biological Exposure Indies (BEIs) to Chemical Substances Workplace Threshold Quantities of Hazardous Chemicals Health 3° Flammabilty: 0 Physical hazard: 0 Health: 2 Flammabilty: 0 Instability: 0 Westlake Corporation cannot anticipate all conditions under which ths information and its product, or the products of other manufacturers in combination with ts product, may be used. Itis tho Users rosponsiailty to ensure safe conditions for handling, storage and disposal of tho product, land to assume lablity fr loss, injury, damage or expense due to improper use. The information in the sheet was writen based on the best knowledge and experience currently availabe. The technical information given herein is accurate to the best of our knowledge at the time of proparation, or prepared from saurces boleved to be reliable, Westlake cannot anticipate all Conditons under which this information and our product. or the produc of ether manufacturers in ‘combination with our product, may be used. Iis tho user's responsibilily to ensuro safe conditions for handling, storage and disposal of the product; comply with all laws and procedures; assume liabilty for loss, injury, damage or expense cue to improper use: and determine the Sultabilty of the product for your intended use, The infarmation in hs sheet is vai for cited regulations published as ofthe date this document was prepared. Updates may be prepared as the egulations are amended or pending revised information about the product. tis the customer's, responsibilty to seek updated regulatory information on any specific Westlake product. All products supplied by Westlake are subject to Westlake's terms and conditions of sale WESTLAKE MAKES NO WARRANTY, EXPRESSED OR IMPLIED, CONCERNING TH PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE OR CONCERNING THE ACCURACY OF ANY INFORMATION PROVIDED BY Westlake, except that ‘he product shall conform to Westlake's spectications. Product and Company Identification: Product Codes Composition / Information on Ingredients: Disclosure Overrides SECTION 4, Firs-aid measures: General information SECTION §, Fire-fighting measures: Suitable extinguishing media ‘SECTION 6, Measures that must be taken inthe event of accidental spillage or an accidental leak: Methods and materials for containing and cleaning up spills or releases ‘Transport Information: Material Transportation Infarmaton SECTION 16, Other Inclided information relevant to the preparation and updating of safety data sheets: Dielaimer ‘atari name: PERZIG -Perchoroalny 170 2 Galahat weno 10/10

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