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Additional Questions -II based on Chapter-1 Solution

The document contains a series of chemistry questions related to solutions, colligative properties, and Raoult's law, including assertions and reasons for various phenomena. It also includes calculations for freezing point depression, osmotic pressure, and molar mass determination. Additionally, it discusses ideal and non-ideal solutions, azeotropes, and the effects of temperature on solution properties.

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5 views

Additional Questions -II based on Chapter-1 Solution

The document contains a series of chemistry questions related to solutions, colligative properties, and Raoult's law, including assertions and reasons for various phenomena. It also includes calculations for freezing point depression, osmotic pressure, and molar mass determination. Additionally, it discusses ideal and non-ideal solutions, azeotropes, and the effects of temperature on solution properties.

Uploaded by

rayihanrazakhan
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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Additional Questions-II Based on Chapter-1 Solution

Given below are two statements labelled as Assertion (A) and Reason (R). Select the most
appropriate answer from the options given below:
(a) Both A and R are true and R is the correct explanation of A
(b) Both A and R are true but R is not the correct explanation of A
(c) A is true but R is false
(d) A is false but R is true

1. Assertion (A): When NaCl is added to water a depression in freezing point is observed.
Reason (R): The lowering of vapour pressure of a solution causes depression in the freezing point.
2. Assertion (A): Azeotropic mixtures are formed only by non-ideal solutions and they may have boiling
points either greater than both the components or less than both the components.
Reason (R): The composition of the vapour phase is same as that of the liquid phase of an azeotropic
mixture.
3. Assertion (A): Molarity of a solution in liquid state changes with temperature.
Reason (R): The volume of a solution changes with change in temperature.
4. Assertion (A): Molecular mass of benzoic acid when determined by colligative properties is found
high.
Reason (R): Dimerization of benzoic acid.
5. Equimolal solutions of NaCl and BaCl2 are prepared in water. Freezing point of NaCl is found to be –
20C, what freezing point do you expect for BaCl2 solution?
6. Write down four important points of differences between an ideal and a non ideal solution.
7. What do you mean by Raoult’slaw ? What are the limitations of Raoult’s law ?
8. How many types of azeotropes are there? Define them along with one example of each.
9. Plot a graph between vapour pressure and mole fraction of a solution obeying Raoult’s Law at constant
temperature?
10. A solution containing 18 g of non-volatile solute in 200g of water freezes at 272.07 K. calculate the
molecular mass of solute (given Kf = 1.86 K/m)
11. Calculate the osmotic pressure at 270C of a solution formed by mixing equal volumes of two
solutions, one containing 0.05 mole of glucose in 250 ml of solution and the other containing 3.42 g of
C12H22O11 in 250 ml of solution. [R = 0.082 L atm mol-1K-1]
12. An aqueous solution freezes at 272.4 K while pure water freezes at 273 K. Determine (i) Molality of
solution. (ii) Boiling point of solution (iii) Lowering of vapour pressure of water at 298 K.
Given: Kf = 1.86 K Kg mol-1. Kb = 0.512 K Kg mol-1, V.P.of pure water at 298 K = 23.756 mm Hg.
13. An aqueous solution of 2% non-volatile solute exerts a pressure of 1.004 bar at the normal boiling
point of the solvent. What is the molar mass of the solute? (Vapour pressure of pure water at the boiling
point (P0) = 1 atm = 1.013 bar)
14. Explain the following colligative properties in brief under the following head: (Definition, Graphical
representation and related mathematical expression)
1. Elevation of boiling point 2. Depression of freezing point
15. (a) Which colligative property is most suitable to measure molecular mass of proteins and why?
(b) 200 cm3 of an aqueous solution of a protein contains 1.26 g of the protein. The osmotic pressure of
such a solution at 300 K is found to be 2.57 × 10-3 bar. Calculate the molar mass of the protein.
16. (i) Two liquids A and B on mixing form an ideal solution. At 300C vapour pressure of solution
containing 3 mol of A and 1 mol of B is 550 mmHg. But when 4 mol of A and 1 mol of B are mixed. The
vapour pressure of solution thus formed is 560 mm Hg. What would be the V.P of pure A and B?
(ii) Explain the fact that Raoult’s Law is a special case of Henry’s Law
17. (a) What is meant by abnormal molar mass of solute? Discuss the factors which bring abnormality in
the experimentally determined molecular masses of solutes using colligative properties.
(b) Why is glycol and water mixture used in car radiators in cold countries?
(c) Give reason When 30 ml of ethyl alcohol and 30ml of water are mixed, the volume of resulting
solution is more than 60ml.
(d) What is de-icing agent? How does it work?

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