Corbory| Commpeuibds > Those anganfc Compeunds, hav'ing rr per rr Te C we =0), as 4 fureffooa 2 feoSly yombers of Cabony| compounds.» 9 gy RL =H pp Aldehyde- by R- P —R akepore 9 g-b—ot + carboxy fe 4ed o 0 a R-E—X > ais ne > gf, oad ree 0 fy abo 9 eT © e r ell uel > aed Ah aside. @ Scanned with OKEN ScannerSfruclure € Nafure of Conbon' L pep % Corbon | sep has t ie om soe foun. Nt = } [op if has Bond “Angle =)20° vA > Corbon | oy of o> So gofure “es! Cobbooy| Compounds, have (arse a a of Dipole wyoment , ushfeh Ge explsined, Qo the Baste of Resoqane®’ 4a — = —oO Cc=0 <> Aldehyde , ketone € Conbax Se Acka 9 UI > Alachyde > Pg, —cHO / vey > kore + pa P r cable 2 Bg, —cooy [Eat @ Scanned with OKEN Scannerof Aldchyde. onencla Sphesantalton Ae chong (rou -p |b eto & HoH eS hyde qt fannladhy ce aeefoly AN = apetbana| t= ethanol & aah Ho fy By os cas properalaehye. fa Bufy>al dehy . as prepaal An bufanol I 3 ae yt He pat CHO | jas pons se ome Pepe an 2 Hedyppropor4 ‘ ee 5 /\, a= 2-gefobuly fhex--endl fey one 4-Arekgheeos| (& Scanned with OKEN Scanner @ Scanned with OKEN Scannered cy ty= ay He Ip buf -a-en-t-al & x dy f cH si fale eS 4 - preor0-- ipl ty 3-8r0m0-2—methy|bulana| * ay a i 2 3 4 ‘He — AH | 0 igo go 4 fH UN= pen ne ~1,5-dea l= 4-chlonoh +, 4-dal >cHo "Sy =G-Yo | Be 4-4 LCHO (n= 4eholeln N= qlyexal -2-ena| AN = ethane-1,2—4fal I Mr @ Scanned with OKEN ScannerNar CHO boup 4. crit counlfag tothe a) L i ante i aad & tL cy — ty. cho 9 ene, 23° vlad ayo ox an= eyelo poepane Cobeachfe clo ; sae glohyane4- Meade tho HO. = a-nd¥ly| eyelohe Lolaehyd A tortion @ Scanned with OKEN Scanner= i CH cHO a= 2-¢4¢lopenty |ethona| ey cy [N= phenylocefaldehyde- 1N= 2-phenyfehana cy= ey CHO ete fooamaldehyde O [N= s-phenyphep-2—enal & scanne d with OKEN ScannerHHO ens 0 -gnorobenze]aehye- Oy TIN= 3- gnomobenxalaehy de CHO = phthaldehyae- cor I[N= Qenzené “1,2 afconbalaety de. cHO HO m salty aehy ae ft 201 1 In : 2-hydnonybenzeoe Coney iS} @ Scanned with OKEN ScannerPreperation of Heelys Ateyere Ae feo leche sunee ops py Oe 07) OF Aleck a) oF ? atic, > Reagent = prb-e (ppptdiore pi peeve [npteiofen claro chromae] N20 1° Alechof 2uild_o- 4 dehyde | 'ppeps oni 7 2° Aleohef 4 keane e> gaa Beh 5 he Hg H -O Ss CH He CHO [1°Aleo] tH 4) [ Aldehyde) SD 4 6 + 56 q cH, kefone (2 Alco] ( hee oe] @ Scanned with OKEN ScannerSy Besproperelon € Mele [Rowe 4] > In Ys proces, Alek! oa ode passe ove, oy ol SS Be sf ue 3000 rarek Wee)” ke ne &'1) CH cH, H- OY —_— he CHO [1° let] (4 (aek.ye] &] hey oy ts Nee £5 hy ( alcoho cH [esd N sam h as Wek Sts ee JH oAtaafion @ Scanned with OKEN ScannerPerce racoutt! Sayer —> Tee) es HO +04, +H- fl a ateay a —> 10 2 fn} A + i Sy oo} +0, RoooR *eccooy—y Kenn — 1 A [Kefone] aS A ell R-CooH + Rcoay ats 110 +09, + te & Nefe. ee Aldshyae, Rest Ai sued kefone S)From Hyde0 Conben ? ne capes oF Aloe URE ee pute fa oa hares ° &x: YN + WBHe fegttory! -H = He C= hg ane, he (en) @ Scanned with OKEN ScannerB\ by tydnahton of F Alkyne > > Addthon Only Ethyne } auf - 1 eee (ee ee ‘alah rg a t QE G > -HSa_ 2 ae He 5 es ay. Es (oa ig nt ry pea fares Ga, Sa Ce aa - Py OxzonolyPs op al Leal] > “ES method, Alkeoe Aa a Oz resence SF Zme aie & Ko fot Poot agg Tene er NG v z =a-e ONT > reo tte #0 th, cho. Ch he @ Scanned with OKEN Scannerprfror vipat es [‘sfephen Rao | > dp his process, Reduce ron SF afpal]eo, ‘okes place, bo the phesence of sfemyous chfortde 4 hua ; Iefne fs obfofned 6 Fobne, Oo {oNhe», Ny Dro hfs . Gives Conneaponding Hebe Re. H 0 J 0 I RCEN DE, py arty DO. GH nd Pod Nt OP by 4 (— NM ] & a y-¢ =N a Hy cH = NH _ ape Gi Sfhem Ae | Adal Halide [Rosen wyund Reo] 2 Hydragfn oho» / care oF acy] halrde foken place Over Va 6 7 Z 4 aly [uP§,03, 0090 & plus, per R- Efe He, g—bey + He ian Pe best ; da. ! “H cor HH — cor 6 éx im ts ay Ly os CH - 7 4 ol @ Scanned with OKEN Scanner~Reducffon of nphflex ¢ SS ARIGAL =H = S Sfso-Buly)4ludrheey H dide e[srerreeps ¢ Nee es > DIBAL-H bs a s}mone, bul 3h > tt Con heduc “e, les € at de i te sce. 7 1 > Nips miles, Qo Redlueffon Ah PlbAL- 4 ves Tene, whkeh dn forthe prey (ves (yh de. SR CEN EE Gy Fe Hy 7 ‘e me [alae] > DIBAL-H Con heduce Alkyres fo Alkenes af Conotf peduce, Ethyleofe Double Je bonds. x to tn y- we esas el @ Scanned with OKEN Scanner5.sfroton| / es are gleo goduced f aldehydes, J by ee euis Gent: J O 0 | ppleal- ee RoR Se T= Las kK © scanned with OKEN Scanner6) Eford RED » Sa ollapide $n CS, s, [ech econ lune fy freofed IS 6, ly ts 4 “fhe penned F e es, ee ) eloniettean Com 4X fs obfofneds which, 6 pe Addie Hy eae i oe > pertrol Criddfton of Jolune fakes plow. CH on cHO ? (o) os Oy} +a [6g 444] SIT veal | i AS oy (Jolene) EdQaternon - Koch xo bxo pt RO, Benzene “Benzene & rested Oth CO gy he fae F Akdre_ wedheny , ysth, ‘oy. Ale, hae Senzofdahyale. Elo Compl) oO oe CHO » CO FHC] Ip tehall [ee Cy + Hel [oem] [ Sorel @ Scanned with OKEN Scannerby de -chosn chlorsna 0p of Polune, Pe henzal chloride, ushteh Oo Hyanalys ‘f ve ae CH, I cH (oH a 9° bed dt shel = £He| @ Scanned with OKEN ScannerID. onohron of kefone c from fren 4 cfd olfee asf ik DeAly| Cader , ace Regent peacha Ly usSth cdef, peed Malky] Cadnbfeara « ThE pha | Gdnfurs, fe for! heacled et 4ad a ie kefooe aA ole HX) + cit “7 ne tele) ae : [ot ~Alky |Gaten] : E 0 O45 RON PP 5 gd -k + ecde| s 7 (hefoos] Pde apie, usken Goh nord ceage P Pe -preafed wth nip>Flea iF qi I nesfurrn soll. cf Emine, oleh, On fete tes By Kefone: ted Ete Filly 19 OER eb Pe pane A [tye f Orhrg] ox Gor OE oe ap Behe Bonzooifrt [ Benzophenone] [ es Pld [mph Ve @ Scanned with OKEN Scanner8.) Prom | from fc. =: Aeyleffon > 3 Reagent = rh Ale}, I ef a et= ge i, bo > ) Yee IEE Co t)4ah. 4leh, Ne tw @ Scanned with OKEN ScannerLheebeat prope Ip “en OF Chafee. °F is phe , ee Cia es hae 2 70 #7 ack af fe, anit ie wets. ported ,ee of HCN 1 NaHsd, Ul] - oH DP on 4 nit & fo pobloprres- 2 by 0 wih REO with Hon > a Vt | ica \7% JR RY / ew ( SN oe Vl \; ° =o + Nats =~ / gt ate Ss Alde sk Kefone >} | RRS & Coban + shag ois (Beneldahjae oe a Comp] @ Scanned with OKEN ScannerDEEN Heh (R-oy] > Mo i oH 62) ew Se \oe > J “Nor, [Hent-Aceya ay J (acct) J Gy Rad with Ghee fe oy \ 1S my \,7o7 9% 4 40 / (4 Om CH, A \oe ct, [ket] S> RAO wre RKO uth brane (NKJ> oH) \. ao! +N-H— Deen + 0 a H (Ime ] me peta é oie [aro] pate ts wt) [Anne] +} \=0 > schiffe Bane 1 .@ly al) +, + X20 OXme- ">see #22 = Hee @ Scanned with OKEN Scannerp— Cabeoy| pd prea sea + =O —> pheny| Hyaaxone pao ozo hy / Hydnazgne : 4&,4-diifro phen} Hychazene VY \ Deco + sofort doSv- daa) C=N- ap Sy j4-dinipeo 4 | [ete] (RE @ Scanned with OKEN Scannerla Aldo} Condleorsaf on RA Qe Se, sey [ ep, keeper] safToth a ane faker 2 Too Tdenfite} > Doro oar ff it pas [4/%« a rng OH hen, Wire if é oa daly joe | pln Sabo ee pe Macy - 0 & ‘y CHO To 4 by a Oy “fle & " Qs. Baar a“ He ec A” i “bd Pela Fe ped eh Cf —cH0 = a coo + 40 Cy at (to>benfon] aA AS se tee fee] He HO + of Bt = cy Paar Sue x ‘yo io he of HO aaa oh CH CHO + ae a Car) & scanne d with OKEN S canneryechants > Sort [fe . Onn OF Cpbedlo) 2 Ox, a OX ~ o=c— Hy + oH 1G \ 2 it é [ corbonfon) she 2 (ate oF phen ket kefoné e}> a NT Oy oy ey a -b &, Oo. & PA SEAN I poy “en GN eb cH, Lo 0 6 = (49) Set ik ue ¢— SAS Ye co 2S 2 fay st gts -cy—C-H a ws L oO iINa -t- CH / io 7 “CepD ay oh a et ee @ Scanned with OKEN ScannerCh. ee 4ldo] Condensapien Axa 2 PO Non Taenfr Compas ann akg mas ae oboe one ed hehe « ee oy ee 4 cy & Yo nase fal f P rat iD Tord aS ato i 4 Ly 6 reed pred (omens i, + et as OO ~~, Pea ty =o cH —c-H cH —<¢-H 1 @ Scanned with OKEN ScannerCanfzzoro!A RO > onh Aldch dea, having No W- 1, Pes his RxD: > ae bask. oe be Cyne key ode wed + hos Dispropentonefien REO! duchod rer fh HCHO a ise + cit-oH a 00) ie [ tested] yechadiony o7 > Cy, a |] a 47 uy a oS a) GP HG THN ™ YN yo p #- a “OK } 4 OH ey Jer-en0 ile ht pod, eke hale WH " coh- cHo don! tyr h hin xo hie 4 ifhave 10 X-. @ Scanned with OKEN ScannerPrllenta & Se sepet fot quale Sth Fe Neal | DPeffenin Dee kao 5 Hh room nhu cof ten nifofe — > fore nul > [a] NG yet oe ( (wt), | tor Awe ow nifel Qutdlesh i aa Gn oe in Ae as prompt idea es > a uksh b/w eon & a fy 7 Keto +8 lf [pers “te C00 age PHN, [0° fe (By tt pos N ole itt nye - a4 ape fe OR [on sap aye abo “Iese cooH nH t, [2! “K ] p ford oe pron “diet + ne ai & scanne d with OKEN Scannerfealtng 1 B Re jent Deol Heol fedls ent > Ns ital Couol wfinpiot (olin dion (180 re a Ea pil i " os 0 oc- ¢- ¢- COONa re (x80 one + f i a C8 ene > “Lit 2 Regt ae aut fi grou era a oe | + Cut! ne st a . é f No €xo & scanne d with OKEN Scanner<_ Hobofoar sedofooa, Lodofomy Qual ° Thre Comps, which Confols dey] & La 4} pep, a Lodoforry (jaf. > eee by 7 ne dasha sone at veh b ytlaa pp < CHL, whth : pert lke bf > Py +d, + ¢ NaH > cH? + HOON ayo. Hae] ( ye prey | beg po CHL + ey-coonld +3N0L 430° aay-l og iy Gator $ ee Q P Smell : Ne “ : COON Ls Ht + Nat +30 co Diop 3 y+ : & scanne d with OKEN Scanner2 some se Resperlt fb [Pke Naol d Cooel, ore also used éx4 0 ol -coo Not Sh Diag MO, cs, + a e08 ky AOL. cnt, + HeoBNa 8x3) ae ny 00g + gh Sc, 4g =. -¢ oR, 20 slohels > “etal : alte ltt oe neds "Thus, 20dofo>m af Pe, tho wae de “is fon iT &> ret wtich one aly” ‘# eel F Oy ethano| / ‘ of y separ 0 i 2- 2 ference deine uf tHeotNo FS HOF Ro 7a PENDOH CHA TH Nal pty "ya ge ae SHO+SNal 9 EE oh _ bi en eel + : Caoela cre, + (HC00) Co si @ Scanned with OKEN Scanner0 Jerk | usbich of hs indy wal er 3 sae pest 7 » ydiy x ° ae oaita~ por “he fay Lp Uy 2 ome a a }p cl, “ye i or x Bla » od, rey sf. “4 = Wy at any * D%4 1-4- ie e De on -<6 Fey on xX ) ‘ b. wé- ha pus do sfoon \olote - @ Scanned with OKEN ScannerCo boxy| [Pe cfd > Those. re Com J. hich Con fos, Conbory| or ae aa enka 4 4c /' Fp eT pep +H pr pr Coben] pep [ Se=e] + [oat] > —d-aH ithex Get of ° halve Corbexyle seein ° re, > 1% Ge] seat > its fF eae a) 4 liphafe Cobowlie 4 Ih gaa. fe [ Lo] Ppt ip Bao ° oils. Gobel 48> , > estanl-2 * by Amide ar > 44 yall 7 fae mae c("* bel @ Scanned with OKEN Scannereer wethods of Corbenyllt i jj from pP [eoto/s > oe Pee 1 cafe wtth & peg oy (” Chie ‘ Als a Pow oO oe Ve ’ TG aed) cO 20 oye C8) EC af eet - 0H Lote g-eh-eh-C00H [oufarnel | [pufanote qe J] Rom Aldelyde & Kepne . es ifr a Cy pen, bbe pie ete oth pels £4 eof se z OT ee "y fal i cat of te He) \) ie “ket y % | from 4 Aldehyde > pou k,¢20 7 Gos pas tah R- coo ex: cr, - CHO AK: Kens, Che Ch Cooy (Aide (1644 J @ Scanned with OKEN Scannerb from from kefonees > With Iodoform Rxn, O- uel On eal ron , Wes ee f ft D Ay JNaoH os te (oy kof) f yell prt] [pe & hy bs rot mod | CY (odofo%e4] cre ay fren | All [benzgne > ah Can bonplie 422 te an a io a > cele 2d fo Hees | > Ge ot of i ie ied tet Ky he or " y (0) otafe f oe x © sae © Or cus cH cool No pop Hts + cooH No - X-H B ote) A), @ Scanned with OKEN Scanner4, Lion G ronord Re pert te 7 PP a Re te pods wet Cg, pene Ff Corbowlfc 4d, ~ a Oo pe oslo} pyar a bo gh 4éa ne Ch a of Rmx + woes pu ae Y waif \ (44) ist co = a ser ) fre. n Te. nfees Cpe Pe g tua, eSale (Comp, ommPde fo formed, uxtsek e om as five ~ cH cooH peyvier| “3 8 2 CF — oe os : yO - oie fo ys @ Scanned with OKEN Scanner6 Posey 40h hebile 49 poy > ydrolysts gcid hobide qed ahah, fi ha uo, ios bre 4c: i Do, * i Les a le yi GH _ Lt +H [qe yl jhe « 6 wi mee / + —c-OH 6 6 | € gtofla pat tt i oy a) ) Ps Ackde Hydrolysis oF Exfos ive Uh, sed Este 4 i (, fer r gy eo off - ley Ss Rg 46 ~feoy ae 4 Q egy fe at eT we @ Scanned with OKEN Scanner_ Chemfeof Chamfeol preporien of £ conbonrl 4. Bla Nopre etn + ny fs wgost (in vy fe Com ie ve is »> dfsso Co fo 4 fo "Af na Co» 2 yee di cA & he, fP ms ot eae _ — coo] ot TL R-coo J f H ‘y ts Kym [Keo] Hoe: # ( (07) erp, Yok ‘fhen K Kf P| «Pe ghee hee Reo ares ae & form, pe R= Cony + Ga — Sie +f > aloo deod's ‘aloo acs pears with Bove lo Le 8.2 R-CooH wh te Sc fe < cooH + a => ee +O cent scanned with OKEN Scanner“ak ah ) Ea “4 NO, Ten, ¥) focnensen aa a "ED 4 a Ry oR ] Decreasen the Safe speogth. &% lich one FS yobe qefdPe 7 Ps Che OH paza-dcy Hy oH ce ey its > BD M1 [en st sp>sF*> sp] 4%) a y coo} i = [e aoe Nofurc. of ¢ 1s | Coot oO o ry NO,, ‘ei : 0.4) ye ai fey c ¢ Pe DT (pe a piefence errect ] Oo Uy Wp ot, ot Eon @ Scanned with OKEN Scannerff} é: Pe ro) 3 > when Corbsaylic 4c Resets with Alcohol pheno Gy he preclne ra a SQ + it “one q LO 4 such xa tA keen a cofrifefion 0 fer gE for tok ai cclied + 0 (eet De dpsofio Ren: s In hs RxO, 4éd Pe "OH g Alebhel gives ' > _smal]os the Alk | gf 4dd & Alcohols, fas} us'l| be “€afoxPfraton > E10 Snereasen she pale of efeitere? 6 COO cooH C00 te Loo A> erg > Ws bxn Ps also koeeon as @ Scanned with OKEN ScannerBY Re wth NHg > Po te on 4 bec foxd- » Conbomylte 4efd prracls with Mi, to give Amomontiem Self, uslich On further heating, of t tp, qe amt] hes oy ? -+ 4 t elo t Ni loi > : ae LO (An 2Jo coy f) oo ay Lent, &x: > 1 A + , 5 © pha Cm @ ¥} aa] [Eee] ewe ZO, t I} -+ & A/oOH () C-ONH i ° oA TAN, OK = eB Oe . nod i an 0 uN - A elie, CLI mah _| @ Scanned with OKEN Scannerp> Leetio & Epes, “> usher Corbory le qc & heofe 3, On yhe Ae oF =o, for be oe. onhy da} nhde ~ elf aol “PI ah o-<- s gh@aaply lela & > Cone SO ¢ Op 4¢ {= as pehydoaping eye «A se Pek 1 Pek € 606 Soc a | 3 + Apes pa‘ hes ar ey. pe] - 4 : 1 ale epee c] Po o€c] 0 y ‘ t et Seg dhe +eof ref @ Scanned with OKEN Scanner6) Reduechon + 7 Coabonslte qed Con be Reduced 40 {omleohof ustth ke hs or sf RA ke (Al Hy dt aoe, wk chp Rept Beg diey Ut , gaged (49) [1c aketel] Also - fen AaptHl v CH alkene} @ Scanned with OKEN Scannerb pecorborylofiog or cob 4_ > Remove} oF CO, _ pkes ple P > tko-l® m J pelle Carter) bre eee, 2 pools oad eodaline L lO +20] Comvlarfed fofo gikene, Kase a a poe [por RED Sy ge oyna hi + HO p4edj (Sor) [sey | 6 .. AV" Na C0, + af jap” 23 eo & scanne d with OKEN Scanner8) gelpfoofon ot conbengite 410 , > Also koeon oalic aie ue > fr this RED, Carboxylic add maf > Corbosylte 4etd, Con} ink X-H “rot a} wy. nfo! wth chinsine 4 & Gn the phesence ef Red p d +hus,—- O-H oberg ac fe formed: x Re ~ qt coor} + HX he R- pico en R H &'!) H —CooH 4 No x9 [woo-H oF cooq a gti conn + He] ‘ > fowl eee ns ed] Phews Epes “R like 3 coe ie Le 0 peace fo 9 pep thus Ps, we obey 60, oper Veal foomed lexe- a I 4 > p ue Lrec, on? cay lic AU Pts Chena! VA Ge (sto peacfs 5 cooH = !)HNOg & oy Los Be, oY pian, @ Scanned with OKEN Scannerua mepapien oF (oben lt F (be be fe > ete ‘Js omfg 43 Gobo] ot- Sphabe_ ny 4 fo 9 Cobo a ‘ sc Igo, ut ahe- 2 4b a ‘de, hoviag spoke son Cobo f°? Ci " lodles, sony em avn bon ar® Ape 6d " Tet pop f por mfecubyr. i be inet onto] oe welubs Wydrophobfe “ Fncresaen + | 3 > FD wher, hi &P dus fo pote | is F fen tr Borda G ae Sra aif have one Bp thon A Aleatsfs of Com onobla u ge enlors ae r o==H-0L fo Deo phe o- poets @ Scanned with OKEN ScannerCon Vobs for)s Verret oe “fdebyde othe cob Aleoho| —___ yee ——_— eA aan 8 od Reducf Teg Reducf (at. Reduce}? ] [ sf RA J ; ries fe Genny) tlehel ned &4 oer o tame , 9 See IE aloe! Sot, yyhano| boa. af LHO Cr re oY % [est] | (ney eee ne 4eid + Ales ho| ee + 1,0 - Oo Scanned with OKEN Scannerdjde > Dose te to sost Benzste pohy dies | gore \ ponte 4 J Y tetes fe Pee cH pee fis y= hy (oly opd cei 2) | (1 (‘sts | et IS te perf a pleat ac OF 500 agai ¢| rey i — cN cay cool as ae [4h] “oN pau A Nao) No 1 geo Aceve cued cope anite Qe wax _N ve @ ¢ SN 50h \Fudoy ton) OH [armel] cH [oF] my (0K it \ A af Soy [3.| & scanne d with OKEN Scanner1) Gooloston publ chante fe feet 7 ct f a [fe + Ng leg prot {et chee] ee | | [aeefor4) Cod msu wD ; ‘ i aplfo-eed a, Het, [O°] [ geefore] [ caleton gee J & scanne d with OKEN Scannerco fe Ackd cofamsde. » ee Le thc a ef Coo — > of coOnt = OEM + HS (seageic"] [ee > Aesforide to ef $e, cy cO-NH, E0./4 eyo of Bae [ stands J at | seehe 4° | 8 @ Scanned with OKEN ScannerDEBI Held to teete 424, soe te ch COOH 4) chert Ya of ery tak ed - ay Cone 50, 6) Cie COOH ) R= dw oy wlith with Cone. HS0y > C,H — OH Come re fps Na ria es + 10 Leg a (ike by oh were CH COOH coo = iy cyH—orf, + eyCoay —> GIL OE FO [tlcc) [404] “ef | Bet. Regen? -4+ oe -H-OH + Komgbs —> R-H + CH-CH-O- "On SoM ne oO / @ Scanned with OKEN Scanner