Safety Data Sheet Acetic Acid Food Grade
Safety Data Sheet Acetic Acid Food Grade
Section 1. Identification
Product name Acetic Acid Chemically Pure, Food Grade
Other means of Acetic acid. Ethanoic acid; Ethylic acid; Methanecarboxylic acid; Eisessig; Acetic acid,
identification glacial
SDS # 0000000787
Code 0000000787
Chemical formula C2-H4-O2
Relevant identified uses of the substance or mixture and uses advised against
Product use Industrial applications
For specific application advice see appropriate Technical Data Sheet or consult our
company representative.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
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Section 2. Hazards identification
Storage Not applicable.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label Not applicable.
elements
Hazards not otherwise Corrosive to respiratory tract
classified
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Section 5. Fire-fighting measures
Extinguishing media
Suitable extinguishing Use dry chemical, CO₂, alcohol-resistant foam or water spray (fog).
media
Unsuitable extinguishing Do not use water jet. The use of a water jet may cause the fire to spread by splashing
media the burning product.
Specific hazards arising Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the
from the chemical container may burst, with the risk of a subsequent explosion. Runoff to sewer may
create fire or explosion hazard. Vapors can form explosive mixtures with air. Vapors are
heavier than air and can spread along the ground or float on water surfaces to remote
ignition sources. Vapors may accumulate in low or confined areas or travel a
considerable distance to a source of ignition and flash back.
Hazardous combustion Combustion products may include the following:
products carbon oxides (CO, CO2) (carbon monoxide, carbon dioxide)
Special protective actions DO NOT FIGHT FIRE WHEN IT REACHES MATERIAL. Withdraw from area and allow
for fire-fighters the fire to burn. No action shall be taken involving any personal risk or without suitable
training. Promptly isolate the scene by removing all persons from the vicinity of the
incident if there is a fire. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Special protective Fire-fighters should wear positive pressure self-contained breathing apparatus (SCBA)
equipment for fire-fighters and full turnout gear.
Special remarks on May form explosive mixtures with air.
explosion hazards
Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
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Section 7. Handling and storage
Precautions for safe handling
Protective measures Put on appropriate personal protective equipment. Do not get in eyes or on skin or
clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate
ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or any
other ignition source. Use explosion-proof electrical (ventilating, lighting and material
handling) equipment. Use only non-sparking tools. Take precautionary measures
against electrostatic discharges. Do not reuse container. Empty containers retain
product residue and can be hazardous.
Advice on general Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Wash thoroughly after handling. Remove contaminated
clothing and protective equipment before entering eating areas. See also Section 8 for
additional information on hygiene measures.
Conditions for safe storage, Store in accordance with local regulations. Store in a segregated and approved area.
including any Store in original container protected from direct sunlight in a dry, cool and well-ventilated
incompatibilities area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Store and use only in equipment/
containers designed for use with this product. Containers that have been opened must
be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled
containers. Use appropriate containment to avoid environmental contamination. Protect
from freezing.
While specific OELs for certain components may be shown in this section, other components may be present in any mist,
vapor or dust produced. Therefore, the specific OELs may not be applicable to the product as a whole and are provided
for guidance only.
Appropriate engineering All activities involving chemicals should be assessed for their risks to health, to ensure
controls exposures are adequately controlled. Personal protective equipment should only be
considered after other forms of control measures (e.g. engineering controls) have been
suitably evaluated. Personal protective equipment should conform to appropriate
standards, be suitable for use, be kept in good condition and properly maintained.
Your supplier of personal protective equipment should be consulted for advice on
selection and appropriate standards. For further information contact your national
organisation for standards.
Provide exhaust ventilation or other engineering controls to keep the relevant airborne
concentrations below their respective occupational exposure limits.
The final choice of protective equipment will depend upon a risk assessment. It is
important to ensure that all items of personal protective equipment are compatible.
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Section 8. Exposure controls/personal protection
Environmental exposure Emissions from ventilation or work process equipment should be checked to ensure they
controls comply with the requirements of environmental protection legislation. In some cases,
fume scrubbers, filters or engineering modifications to the process equipment will be
necessary to reduce emissions to acceptable levels.
Do not re-use gloves. Protective gloves must give suitable protection against
mechanical risks (i.e. abrasion, blade cut and puncture). Protective gloves will
deteriorate over time due to physical and chemical damage. Inspect and replace gloves
on a regular basis. The frequency of replacement will depend upon the circumstances of
use.
Body protection Use of protective clothing is good industrial practice.
Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before handling
this product.
Cotton or polyester/cotton overalls will only provide protection against light superficial
contamination that will not soak through to the skin. Overalls should be laundered on a
regular basis. When the risk of skin exposure is high (e.g. when cleaning up spillages or
if there is a risk of splashing) then chemical resistant aprons and/or impervious chemical
suits and boots will be required.
Wear suitable protective clothing.
Footwear highly resistant to chemicals.
When there is a risk of ignition wear inherently fire resistant protective clothes and
gloves.
When there is a risk of ignition from static electricity, wear anti-static protective clothing.
For greatest effectiveness against static electricity, overalls, boots and gloves should all
be anti-static.
When the risk of skin exposure is high (from experience this could apply to the following
tasks: cleaning work, maintenance and service, filling and transfer, taking samples and
cleaning up spillages) then a chemical protective suit and boots will be required.
Work clothing / overalls should be laundered on a regular basis. Laundering of
contaminated work clothing should only be done by professional cleaners who have
been told about the hazards of the contamination. Always keep contaminated work
clothing away from uncontaminated work clothing and uncontaminated personal clothes.
Recommended:
Hard hat.
Chemical resistant boots.
Chemical resistant apron
Full chemical protective suit with a hood.
Chemical protective suit consisting of a jacket and trousers. The jacket should be
buttoned up to the neck, sleeves sealed at the gloves, and trouser legs worn outside the
boots. These precautions are required to prevent the clothing from accidentally trapping
product against the skin.
Other skin protection Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection Use only with adequate ventilation. Do not breathe vapor or mist. If ventilation is
inadequate, use NIOSH-certified respirator which will protect against organic vapor. If
operating conditions cause high vapor concentrations or the TLV is exceeded, use
supplied-air respirator.
If there is a requirement for the use of a respiratory protective device, but the use of
breathing apparatus (independent of ambient atmosphere) is not required, then a
suitable filtering device must be worn.
The filter class must be suitable for the maximum contaminant concentration (gas/vapor/
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Section 8. Exposure controls/personal protection
aerosol/particulates) that may arise when handling the product.
Possibility of hazardous Under normal conditions of storage and use, hazardous reactions will not occur.
reactions Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to avoid Keep away from heat, sparks and flame. This product should be stored away from
oxidizing materials and strong bases.
Incompatible materials Reactive with metals, oxidizing materials, reducing agents, alkalis and alcohols
Hazardous decomposition Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.
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Section 11. Toxicological information
Information on toxicological effects
Acute toxicity
Product/ingredient Test Species Result Exposure Remarks
name
acetic acid LC50 Inhalation Mouse 5620 ppm 1 hours -
Vapor
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Section 11. Toxicological information
Product/ingredient name Maternal Fertility Development Species Result Exposure
toxicity toxin
acetic acid - - Negative Rabbit Oral 13 days
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate Not available.
effects
Potential delayed effects Not available.
Long term exposure
Potential immediate Not available.
effects
Potential delayed effects Not available.
Potential chronic health effects
General No known significant effects or critical hazards.
Carcinogenicity No known significant effects or critical hazards.
Mutagenicity No known significant effects or critical hazards.
Teratogenicity No known significant effects or critical hazards.
Developmental effects No known significant effects or critical hazards.
Fertility effects No known significant effects or critical hazards.
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Section 11. Toxicological information
Route ATE value
Oral 3530 mg/kg
Other information Acetic Acid: Humans unacclimatized to acetic acid vapors experience extreme eye and
nasal irritation at concentrations above 25 ppm. Air concentrations of 50 ppm are
considered intolerable, causing intense lacrymation (eye weeping), nose, and throat
irritation. Repeated exposures to high concentrations in man can cause eye conjunctival
lesions, blackening of the hands, hyperkeratosis (thickening) of the skin, teeth erosion,
congestion and edema of the pharynx, bronchial constriction, and respiratory tract
irritation.
Bioaccumulative potential
This product is not expected to bioaccumulate through food chains in the environment.
Mobility in soil
Soil/water partition Not available.
coefficient (KOC)
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Section 12. Ecological information
Mobility This product may move with surface or groundwater flows because its water solubility is:
100% Miscible in water.
Other ecological information expected to be slightly toxic to aquatic species because of acidity
UN proper ACETIC ACID, ACETIC ACID, ACETIC ACID, Acetic acid, glacial
shipping name GLACIAL RQ GLACIAL GLACIAL
Packing group II II II II
Environmental No. No. No. No.
hazards
Additional Reportable quantity Product classified as Emergency Quantity limitation
information 5000 lbs / 2270 kg per the following schedules Passenger and Cargo
[571.66 gal / 2164 L]. sections of the F-E, S-C Aircraft: 1 L.
Package sizes Transportation of Packaging
shipped in quantities Dangerous Goods instructions: 851.
less than the product Regulations: Cargo Aircraft Only:
reportable quantity 2.40-2.42 (Class 8), 30 L. Packaging
are not subject to the 2.18-2.19 (Class 3). instructions: 855.
RQ (reportable Explosive Limit and Limited Quantities -
quantity) Limited Quantity Passenger Aircraft:
transportation Index 0.5 0.5 L. Packaging
requirements. ERAP Index 3000 instructions: Y840.
Limited quantity Yes. Passenger Carrying
Packaging Road or Rail Index 1
instruction
Exceptions: 154.
Non-bulk: 202. Bulk:
243.
Quantity limitation
Passenger aircraft/rail:
1 L. Cargo aircraft:
30 L.
Special provisions
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Section 14. Transport information
A3, A6, A7, A10, B2,
IB2, T7, TP2
SARA 311/312
Classification FLAMMABLE LIQUIDS - Category 3
SKIN CORROSION - Category 1A
SERIOUS EYE DAMAGE - Category 1
HNOC - Corrosive to digestive tract
SARA 313
Form R - Reporting This product does not contain any hazardous ingredients at or above regulated
requirements thresholds.
Supplier notification This product does not contain any hazardous ingredients at or above regulated
thresholds.
State regulations
Massachusetts The following components are listed: ACETIC ACID; ACETIC ACID GLACIAL
New Jersey The following components are listed: ACETIC ACID; ETHANOIC ACID
Pennsylvania The following components are listed: ACETIC ACID; ACETIC ACID, WATER
SOLUTIONS
California Prop. 65
This product does not require a Safe Harbor warning under California Prop. 65.
Other regulations
Australia inventory (AICS) All components are listed or exempted.
Canada inventory All components are listed or exempted.
China inventory (IECSC) All components are listed or exempted.
Japan inventory (ENCS) All components are listed or exempted.
Korea inventory (KECI) All components are listed or exempted.
Philippines inventory All components are listed or exempted.
(PICCS)
Taiwan Chemical All components are listed or exempted.
Substances Inventory
(TCSI)
REACH Status The company, as identified in Section 1, sells this product in the EU in compliance with
the current requirements of REACH.
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Section 16. Other information
National Fire Protection Association (U.S.A.)
2 Flammability
Health 3 0 Instability/Reactivity
Special
History
Date of issue/Date of 01/17/2020.
revision
Date of previous issue 07/08/2014.
Prepared by Product Stewardship
Key to abbreviations ACGIH = American Conference of Industrial Hygienists
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
CAS Number = Chemical Abstracts Service Registry Number
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as
modified by the Protocol of 1978. ("Marpol" = marine pollution)
OEL = Occupational Exposure Limit
SDS = Safety Data Sheet
STEL = Short term exposure limit
TWA = Time weighted average
UN = United Nations
UN Number = United Nations Number, a four digit number assigned by the United
Nations Committee of Experts on the Transport of Dangerous Goods.
Varies = may contain one or more of the following 64741-88-4, 64741-89-5, 64741-95-3,
64741-96-4, 64742-01-4, 64742-44-5, 64742-45-6, 64742-52-5, 64742-53-6, 64742-54-7,
64742-55-8, 64742-56-9, 64742-57-0, 64742-58-1, 64742-62-7, 64742-63-8, 64742-65-0,
64742-70-7, 72623-85-9, 72623-86-0, 72623-87-1
Indicates information that has changed from previously issued version.
Notice to reader
All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental
information contained in it is accurate as of the date specified below. No warranty or representation, express or implied is
made as to the accuracy or completeness of the data and information in this data sheet.
The data and advice given apply when the product is sold for the stated application or applications. You should not use the
product other than for the stated application or applications without seeking advice from BP Group.
It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. The
BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the
material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material.
Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that
any person handling or using the product is provided with the information in this sheet. Employers have a duty to tell
employees and others who may be affected of any hazards described in this sheet and of any precautions that should be
taken. You can contact the BP Group to ensure that this document is the most current available. Alteration of this
document is strictly prohibited.
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