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Bottino - Henry Low

Henrijev yakon

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Vesna Radin
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2 views1 page

Bottino - Henry Low

Henrijev yakon

Uploaded by

Vesna Radin
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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235

The relationship between fi and Lo,is

Lf = /3(
7’/K)/273.15 (8)
There are two assumptions in this equation. The first is that Henry’s law
holds between 1 atm. and the pressure of the measurement (really the partial
pressure of the gas), and the second is that the gas behaves ideally between
the temperature T and 273.15 K. Where sufficient data are available, these
assumptions may be checked. Generally, the assumptions are good for
measurements near atmospheric pressure, for temperatures not more than 50
K from 273.15 K, for mole-fraction solubilities (at 1 atm.) less than 0.01, and
for precisions of 1% or poorer.
By using the ideal-gas equation, it is possible to express Vs(STP) as

Vs(STP) = %[273.15/(T/K)][(P/atm.)/l] (9)


Substitution of eqn. (9) into eqn. (7) gives
6 = (T/K)/273.15( P/atm.) L, - l/p (10)
which yields for 8,
/I?= 273.15 L,/(T/K - 273.15 SL,) 01)
Recalling eqn. (8) finally gives

Lt = (T/K) L,/(T/K - 273.15 6L,) (12)


or, in terms of gas partial molar volumes,

L: = (T/K)L,?(sTP)/[ ( T/K) ~(STP) - L,v,] (13)


where rs’(STP) is the molar volume of the pure gas at STP.
Utilizing eqn. (13), and selecting reasonable values of rz = 50 cm3 mol-‘,
T= 298.15 K and v*‘(STP) = 22.414 1 mol-‘, yields the results given in
Table 1 for several values of Lt.For these values the difference between L,

TABLE 1
Lg calculated according t9 eqn. (13) for several values of L, at 298.15 KP

=, Lo, Percentage difference


0.001 0.001OOOOO2 2x10-’
0.01 0.01ooOO2 2x10-3
0.1 0.1oooO204 0.020
1 1.00205 0.21
10 10.209 2.09
100 125.69 25.7

a Vz = 50 cm3 mol-‘; T(STP) = 22.414 1 mol-‘.

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