SAFETY DATA SEEET

1. Identification
Product identifier Malco Carpet & Upholstery Cleaner Concentrate
Other means of identification
Product Code 1011
Recommended use Carpet and Upholstery Cleaner
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Company name Malco droducts, Inc.
Address 361 Fairview Ave
Barberton, OP 44203
United States
Telephone dhone 100-253-2526
Fax 330-753-2025
cebsite www.malcopro.com
E-mail [email protected]
Contact person Technical Department
Emergency phone number dhone 1-100-424-9300

2. Eazard(s) identification
Physical hazards Not classified.
Eealth hazards Serious eye damage/eye irritation Category 2B
Environmental hazards Not classified.
OSEA defined hazards Not classified.

Label elements
Eazard symbol None.
Signal word Warning
Eazard statement Causes eye irritation.
Precautionary statement
Prevention Wash thoroughly after handling.
Response If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If exposed or concerned: Get medical advice/attention. If eye
irritation persists: Get medical advice/attention.
Storage Store away from incompatible materials.
Disposal Dispose of waste and residues in accordance with local authority requirements.
Eazard(s) not otherwise None known.
classified (ENOC)
Supplemental information 9.27% of the mixture consists of component(s) of unknown acute dermal toxicity. 3.94% of the
mixture consists of component(s) of unknown acute inhalation toxicity. 7.57% of the mixture
consists of component(s) of unknown acute hazards to the aquatic environment.

3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
Soda Ash - Dense 497-19-1 3-<5
"Sulfonic Acids, C14-16-alkane 61439-57-6 1-<3
Pydroxy And C14-16-alkene,
Sodium Salts"
Amides, Coco, 61603-42-9 1-<3
N,n-bis(hydroxyethyl)

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 Chemical name Common name and synonyms CAS number %
Sodium Dodecylbenzenesulfonate 25155-30-0 1-<3
Sodium Nitrite 7632-00-0 < 0.2
Tetrasodium 64-02-1 < 0.2
Ethylenediaminetetraacetate
Sodium Pydroxide 1310-73-2 < 0.1
Other components below reportable levels 90 - 100
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures
Inhalation Move to fresh air. Call a physician if symptoms develop or persist.
Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Ingestion Rinse mouth. Get medical attention if symptoms occur.
Most important Irritation of eyes. Exposed individuals may experience eye tearing, redness, and discomfort.
symptoms/effects, acute and
delayed
Indication of immediate drovide general supportive measures and treat symptomatically. Keep victim under observation.
medical attention and special Symptoms may be delayed.
treatment needed
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.

5. Fire-fighting measures
Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire fighting Move containers from fire area if you can do so without risk.
equipment/instructions
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards No unusual fire or explosion hazards noted.

6. Accidental release measures

Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
protective equipment and appropriate protective equipment and clothing during clean-up. Do not touch damaged containers
emergency procedures or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation.
Local authorities should be advised if significant spillages cannot be contained. For personal
protection, see section 1 of the SDS.
Methods and materials for Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
containment and cleaning up possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product
recovery, flush area with water.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.

7. Eandling and storage

Precautions for safe handling Avoid contact with eyes. Avoid prolonged exposure. drovide adequate ventilation. Wear
appropriate personal protective equipment. Observe good industrial hygiene practices.
Conditions for safe storage, Store in original tightly closed container. Store away from incompatible materials (see Section 10
including any incompatibilities of the SDS).

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8. Exposure controls/personal protection
Occupational exposure limits
The following constituents are the only constituents of the product which have a dEL, TLV or other recommended exposure limit.
At this time, the other constituents have no known exposure limits.
US. OSEA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components Type Value
Sodium Pydroxide (CAS dEL 2 mg/m3
1310-73-2)
US. ACGIE Threshold Limit Values
Components Type Value
Sodium Pydroxide (CAS Ceiling 2 mg/m3
1310-73-2)
US. NIOSE: Pocket Guide to Chemical Eazards
Components Type Value
Sodium Pydroxide (CAS Ceiling 2 mg/m3
1310-73-2)
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. drovide
eyewash station.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles).

Skin protection
Eand protection Wear appropriate chemical resistant gloves.
Other Wear suitable protective clothing.
Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.

General hygiene Always observe good personal hygiene measures, such as washing after handling the material
considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.

9. Physical and chemical properties

Appearance Semi-Viscous
Physical state Liquid.
Form Liquid.
Color Green
Odor Mint
Odor threshold Not available.
pE 9.1
Melting point/freezing point 1222.26 °F (661.25 °C) estimated
Initial boiling point and boiling Not available.
range
Flash point > 200.0 °F (> 93.3 °C)
Evaporation rate Not available.
Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - upper Not available.
(%)
Explosive limit - lower (%) Not available.

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 Explosive limit - upper (%) Not available.
Vapor pressure Not available.
Vapor density Not available.
Relative density Not available.
Solubility(ies)
Solubility (water) Not available.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity 75 cd
Viscosity temperature 61 °F (20 °C)
Other information
Density 1.60 lb/gal
Explosive properties Not explosive.
Flammability class Combustible IIIB estimated
Kinematic viscosity 73 cSt
Kinematic viscosity 61 °F (20 °C)
temperature
Oxidizing properties Not oxidizing.
VOC 0 % w/w by weight

10. Stability and reactivity

Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.
Eazardous decomposition No hazardous decomposition products are known.
products

11. Toxicological information

Information on likely routes of exposure
Inhalation drolonged inhalation may be harmful.
Skin contact No adverse effects due to skin contact are expected.
Eye contact Causes eye irritation.
Ingestion Expected to be a low ingestion hazard.
Symptoms related to the Irritation of eyes. Exposed individuals may experience eye tearing, redness, and discomfort.
physical, chemical and
toxicological characteristics
Information on toxicological effects
Acute toxicity Not known.
Components Species Test Results
Soda Ash - Dense (CAS 497-19-1)
Acute
Oral
LD50 Rat 4090 mg/kg

* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation drolonged skin contact may cause temporary irritation.
Serious eye damage/eye Causes eye irritation.
irritation

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Respiratory or skin sensitization
Respiratory sensitization Not a respiratory sensitizer.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity Risk of cancer cannot be excluded with prolonged exposure.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed.
OSEA Specifically Regulated Substances (29 CFR 1910.1001-1052)
Not regulated.
US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity - Not classified.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard Not an aspiration hazard.
Chronic effects drolonged inhalation may be harmful. drolonged exposure may cause chronic effects.

12. Ecological information

Ecotoxicity The product is not classified as environmentally hazardous. Powever, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Components Species Test Results
"Sulfonic Acids, C14-16-alkane Pydroxy And C14-16-alkene, Sodium Salts" (CAS 61439-57-6)
Aquatic
Crustacea EC50 Water flea (Ceriodaphnia dubia) 4.14 - 4.95 mg/l, 41 hours
Soda Ash - Dense (CAS 497-19-1)
Aquatic
Crustacea EC50 Water flea (Ceriodaphnia dubia) 156.6 - 291.9 mg/l, 41 hours
Fish LC50 Bluegill (Lepomis macrochirus) 300 mg/l, 96 hours
Sodium Dodecylbenzenesulfonate (CAS 25155-30-0)
Aquatic
Crustacea EC50 Water flea (Ceriodaphnia dubia) 3.26 - 14.51 mg/l, 41 hours
Fish LC50 Rainbow trout,donaldson trout 3.2 - 5.6 mg/l, 96 hours
(Oncorhynchus mykiss)
Sodium Pydroxide (CAS 1310-73-2)
Aquatic
Fish LC50 Western mosquitofish (Gambusia affinis) 125 mg/l, 96 hours
Sodium Nitrite (CAS 7632-00-0)
Aquatic
Crustacea EC50 Greasyback shrimp (Metapenaeus 16.14 - 26.61 mg/l, 41 hours
ensis)
Fish LC50 Rainbow trout,donaldson trout 0.15 - 0.25 mg/l, 96 hours
(Oncorhynchus mykiss)
Tetrasodium Ethylenediaminetetraacetate (CAS 64-02-1)
Aquatic
Fish LC50 Bluegill (Lepomis macrochirus) 472 - 500 mg/l, 96 hours

* Estimates for product may be based on additional component data not shown.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
Sodium Dodecylbenzenesulfonate 0.45
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Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations

Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of
contents/container in accordance with local/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Eazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
caste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.

14. Transport information

DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Transport in bulk according to Not established.
Annex II of MARPOL 73/78 and
the IBC Code

15. Regulatory information

US federal regulations This product is a "Pazardous Chemical" as defined by the OSPA Pazard Communication
Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Sodium Nitrite (CAS 7632-00-0) 1.0 % One-Time Export Notification only.
CERCLA Eazardous Substance List (40 CFR 302.4)
Sodium Dodecylbenzenesulfonate (CAS 25155-30-0) Listed.
Sodium Pydroxide (CAS 1310-73-2) Listed.
Sodium Nitrite (CAS 7632-00-0) Listed.
SARA 304 Emergency release notification
Not regulated.
OSEA Specifically Regulated Substances (29 CFR 1910.1001-1052)
Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Eazardous Yes
chemical
Classified hazard Serious eye damage or eye irritation
categories Respiratory or skin sensitization
Specific target organ toxicity (single or repeated exposure)
SARA 313 (TRI reporting)
Not regulated.

Other federal regulations

Clean Air Act (CAA) Section 112 Eazardous Air Pollutants (EAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking cater Act Not regulated.
(SDcA)

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US state regulations
California Proposition 65
For more information go to www.d65Warnings.ca.gov. WARNING: This product contains a
chemical known to the State of California to cause cancer.
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,
subd. (a))
Sodium Pydroxide (CAS 1310-73-2)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) No
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical No
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
dhilippines dhilippine Inventory of Chemicals and Chemical Substances Yes
(dICCS)
Taiwan Taiwan Toxic Chemical Substances (TCS) Yes
United States & duerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision

Issue date 06-09-2017
Revision date 09-13-2011
Version # 03
Disclaimer Malco droducts, Inc. cannot anticipate all conditions under which this information and its product,
or the products of other manufacturers in combination with its product, may be used. It is the
user’s responsibility to ensure safe conditions for handling, storage and disposal of the product,
and to assume liability for loss, injury, damage or expense due to improper use. The information
provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as a guidance for safe handling,
use, processing, storage, transportation, disposal and release and is not to be considered a
warranty or quality specification. The information relates only to the specific material designated
and may not be valid for such material used in combination with any other materials or in any
process, unless specified in the text. The information in the sheet was written based on the best
knowledge and experience currently available.
Revision information Pazard(s) identification: Response
Composition / Information on Ingredients: Component Summary
Accidental release measures: dersonal precautions, protective equipment and emergency
procedures
Accidental release measures: Methods and materials for containment and cleaning up
Pandling and storage: Conditions for safe storage, including any incompatibilities
Toxicological information: Carcinogenicity
Toxicological information: Chronic effects
Regulatory information: California droposition 65
Other information, including date of preparation or last revision: Disclaimer
GPS: Classification

Material name: Malco Carpet & Upholstery Cleaner Concentrate SDS US

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