1 Consider the following statements: A;

P : I have fever P → (∼ Q ∧ R)
Q : I will not take medicine ∼ P ∨ (∼ Q ∧ R)
R : I will take rest (∼ P ∨∼ Q) ∧ (∼ P ∨ R)
The statement "If I have fever, then I
will take medicine and I will take rest"
is equivalent to:
((∼ P) ∨∼ Q) ∧ ((∼ P) ∨ R)
((∼ P) ∨∼ Q) ∧ ((∼ P) ∨∼ R)
(P ∨ Q) ∧ ((∼ P) ∨ R)
(P ∨∼ Q) ∧ (P ∨∼ R)
2 Let A be a point on the x-axis. Common D;
tangents are drawn from 𝐴 to the 4
curves 𝑥 2 + 𝑦 2 = 8 and 𝑦 2 = 16𝑥. If y = mx +
m
one of these tangents touches the two 4
curves at Q and R, then (QR)2 is equal
m
to =2 2
1 + m2
m =  1
y =  x  4 . Point of contact on
parabola
 a 2a 
Let m = 1,  2 , 
m m 
R ( 4, 8 )
Point of contact on circle Q ( − 2, 2)
(QR ) = 36 + 36 = 72
2

64
76
81
72
3 Let 𝑞 be the maximum integral value of A;
𝑝 in [0,10] for which the roots of the 5𝑝
5 𝑥 2 − 𝑝𝑥 + =0
equation 𝑥 2 − 𝑝𝑥 + 4 𝑝 = 0 are rational. 4
𝐷 = 𝑝 2 − 5𝑝 = 𝑝(𝑝 − 5)
Then the area of the region {(𝑥, 𝑦): 0 ≤
∴𝑞=9
𝑦 ≤ (x − q)2 , 0 ≤ x ≤ q} is
0 ≤ 𝑦 ≤ (𝑥 − 9)2

9
Area =  ( x − 9 ) dx = 243
2

243
25
125
3
164
4 x3 ax 2 D;
If the functions f ( x ) = + 2bx + 𝑓 ′ (𝑥) = 𝑥 2 + 2 𝑏 + 𝑎𝑥
3 2
x3 𝑔′ (𝑥) = 𝑥 2 + 𝑎 + 2𝑏𝑥
and g ( x ) = + ax + bx 2 , a  2b have a (2𝑏 − 𝑎) − 𝑥(2𝑏 − 𝑎) = 0
3 ∴ 𝑥 = 1 is the common root
common extreme point, then 𝑎 + 2𝑏 + Put 𝑥 = 1 in 𝑓 ′ (𝑥) = 0 or 𝑔′ (𝑥) = 0
7 is equal to 1 + 2𝑏 + 𝑎 = 0
7 + 2𝑏 + 𝑎 = 6

4
3
2
3
6
5 The range of the function 𝑓(𝑥) = A;
√3 − 𝑥 + √2 + 𝑥 is 𝑦2 = 3 − 𝑥 + 2 + 𝑥
+ 2√(3 − 𝑥)(2 + 𝑥)
= 5 + 2√6 + 𝑥 − 𝑥 2
25 1 2
y2 = 5 + 2√ − (x − )
4 2
ymax = √5 + 5 = √10
ymin = √5
[√5, √10]
[2√2, √11]
[√5, √13]
[√2, √7]
6 The solution of the differential equation C;
𝑑𝑦
=
𝑥 2+3𝑦2
− (3𝑥2+𝑦2 ) , 𝑦(1) = 0 is Put 𝑦 = 𝑣𝑥
𝑑𝑥 𝑑𝑣 1 + 3𝑣 2
𝑣+𝑥 = −( )
𝑑𝑥 3 + 𝑣2
𝑑𝑣 (𝑣 + 1)3
𝑥 =−
𝑑𝑥 3 + 𝑣2
2
(3 + 𝑣 )𝑑𝑣 𝑑𝑥
+ =0
(𝑣 + 1)3 𝑥
4𝑑𝑣 𝑑𝑣 2𝑑𝑣
∫ 3 +∫ −∫
(𝑣 + 1) 𝑣+1 (𝑣 + 1)2
𝑑𝑥
+∫ =0
𝑥
−2 2
2 + ln (v + 1) + + ln 𝑥
(𝑣 + 1) v+1
=𝑐
2
−2𝑥 𝑥+𝑦 2𝑥
2 + ln ( )+ + ln 𝑥
(𝑥 + 𝑦) 𝑥 𝑥+𝑦
=𝑐
2𝑥𝑦
+ ln (𝑥 + 𝑦) = 𝑐
(𝑥 + 𝑦)2
∴ 𝑐 = 0, as 𝑥 = 1, 𝑦 = 0
2𝑥𝑦
∴ + ln (𝑥 + 𝑦) = 0
(𝑥 + 𝑦)2
 𝑥𝑦
log 𝑒 |𝑥 + 𝑦| − =0
(𝑥 + 𝑦)2
𝑥𝑦
log e |𝑥 + 𝑦| + =0
(𝑥 + 𝑦)2
2𝑥𝑦
log e |𝑥 + 𝑦| + =0
(𝑥 + 𝑦)2
2𝑥𝑦
log e |𝑥 + 𝑦| − =0
(𝑥 + 𝑦)2
7 Let x = (8√3 + 13)13 and y = (7√2 + A;
9)9 . If [t] denotes the greatest integer ≤ 𝑥 = (8√3 + 13)
t, then = 13 C0 ⋅ (8√3)13
+ 13 C1 (8√3)12 (13)1
+⋯
x = (8√3 − 13)13
′

= 13 C0 (8√3)13
− 13 C1 (8√3)12 (13)1
+⋯
𝑥 − 𝑥 = 2[ 𝐶1 ⋅ (8√3)12 (13)1
′ 13

+ 13 𝐶3 (8√3)10
⋅ (13)3 … . ]
therefore, 𝑥 − 𝑥 ′ is even integer,
hence [𝑥] is even
Now, y = (7√2 + 9)9 = 9 C0 (7√2)9 +
9 C (7√2)8 (9)1 + 9 C (7√2)7 (9)2 … …
1 2
y ′ = (7√2 − 9)9
= 9 C0 (7√2)9
− 9 C1 (7√2)8 (9)1
+ C2 (7√2) (9)2 … …
9 7

𝑦 − 𝑦 ′ = 2[ 9 C1 (7√2)8 (9)1
+ 9 C3 (7√2)6 (9)3
+ ⋯]
y − y = Even integer, hence [y] is
′

even
[𝑥] + [𝑦] is even
[𝑥] is odd but [𝑦] is even
[𝑥] is even but [𝑦] is odd
[𝑥] and [𝑦] are both odd
8 A vector v⃗ in the first octant is inclined C;
to the x − axis at 60∘ , to the 𝑦-axis at v̂ = cos 60∘ î + cos 45∘ ĵ + cos 𝛾k̂
45∘ and to the z-axis at an acute angle. 1 1
If a plane passing through the points ⇒ + + cos2 𝛾 = 1 (𝛾 → Acute )
4 2
(√2, −1,1) and (𝑎, 𝑏, 𝑐), is normal to v ⃗, 1
⇒ cos 𝛾 =
then 2
⇒ 𝛾 = 60∘
Equation of plane is
1 1 1
(𝑥 − √2) + (𝑦 + 1) + (𝑧 − 1)
2 √2 2
=0
⇒ x + √2y + z = 1
(a, b, c) lies on it.
 ⇒ 𝑎 + √2𝑏 + 𝑐 = 1
√2𝑎 + 𝑏 + 𝑐 = 1
a + b + √2c = 1
𝑎 + √2𝑏 + 𝑐 = 1
√2𝑎 − 𝑏 + 𝑐 = 1
9 Let 𝑓, 𝑔 and ℎ be the real valued A;
functions defined on ℝ as LHL = lim g ( h( − k ) ) , k  0
k →0
 x
 , x 0 = lim g ( − 2 + 1 ) f (x) = −1 x  0
f (x) =  x , k →0
1, x =0 = g ( − 1) = 1

 sin ( x + 1) RHL = lim g ( h( k ) ) , k  0
 , x  −1 k →0
g ( x ) =  ( x + 1) and = lim g ( − 1) , f ( x ) = 1,  x  0
 k →0
1, x = −1
=1
h ( x ) = 2 x  − f ( x ) , where [𝑥] is the
greatest integer ≤ 𝑥.
Then the value of lim g ( h( x − 1) ) is
x →1

1
sin (1)
−1
0
10 The number of ways of selecting two C;
numbers 𝑎 and 𝑏, a ∈ {2,4,6, … . ,100} a ∈ {2,4,6,8,10, … . ,100}
and b ∈ {1,3,5, … . ,99} such that 2 is the b ∈ {1,3,5,7,9, … . ,99}
remainder when 𝑎 + 𝑏 is divided by 23 Now, 𝑎 + 𝑏 ∈ {25,71,117,163}
is (i) 𝑎 + 𝑏 = 25, no. of ordered pairs
(𝑎, 𝑏) is 12
(ii) 𝑎 + 𝑏 = 71, no. of ordered pairs
(𝑎, 𝑏) is 35
(iii) a + b = 117, no. of ordered pairs
(a, b) is 42
(iv) a + b = 163, no. of ordered pairs
(a, b) is 19 ∴ total = 108 pairs
186
54
108
268
11 If P is a 3 × 3 real matrix such that PT = D;
aP + (a − 1)I, where a > 1, then PT = aP + (a − 1)I
⇒ P = aPT + (a − 1)I
⇒ PT − P = a(P − PT )
⇒ P = PT , as a ≠ −1
Now, P = aP + (a − 1)I
⇒ P = −I ⇒ |P| = 1
⇒∣ Adj P ∣= 1
P is a singular matrix
|Adj 𝑃| > 1
1
|Adj 𝑃| =
2
|Adj 𝑃| = 1
12 Let 𝜆 ∈ ℝ, 𝑎 = 𝜆î + 2ĵ − 3k̂, ⃗b = î − 𝜆ĵ + A;
2k̂. a⃗ = 𝜆î + 2ĵ − 3k̂
If ((𝑎 + 𝑏⃗) × (𝑎 × 𝑏⃗)) × (𝑎 − 𝑏⃗) = 8𝑖ˆ − ⃗b = î − 𝜆ĵ + 2k̂
40𝑗ˆ − 24𝑘ˆ , then |𝜆(𝑎 + 𝑏⃗) × (𝑎 − 𝑏⃗)|2 is ⇒ (b ⃗ − a⃗) × ((a⃗ + b ⃗ ) × (a⃗ × b ⃗ ))
equal to = 8î − 40ĵ − 24k̂
⇒ ((a⃗ − b) ⋅ (a⃗ + ⃗b))(a⃗ × ⃗b)
⃗
= 8î − 40j − 24k̂
⃗
⇒ 8(a⃗ × b) = 8î − 40ĵ − 24k̂
Now, a⃗ × b ⃗ = |𝜆 2 −3|
1 −𝜆 2
= (4 − 3𝜆)î − (2𝜆 + 3)ĵ + (−𝜆2 − 2)k̂
⇒𝜆=1
∴ a⃗ = î + 2ĵ − 3k̂
⃗b = î − ĵ + 2k̂
⇒ a⃗ + ⃗b = 2î + ĵ − k̂, a⃗ − ⃗b = 3ĵ − 5k̂
î ĵ k̂
⇒ (a⃗ + ⃗b) × (a⃗ − ⃗b) = |2 1 −1|
0 3 −5
= 2î + 10ĵ + 6k̂
∴ required answer = 4 + 100 + 36
= 140
140
132
144
136
13 Let 𝑎 and 𝑏⃗ be two vectors. Let |𝑎 | = B;
1, |𝑏⃗| = 4 and a⃗ ⋅ b
⃗ = 2. If c = (2a⃗ × c = (2a⃗ × ⃗b) − 3b ⃗
⃗b) − 3b⃗ , then the value of ⃗b ⋅ c is ⃗ ⋅c =b
b ⃗ ⋅ (2a⃗ × b
⃗ ) − 3b
⃗ ⋅b
⃗
2
= −3| b|
= −48
− 24
− 48
− 84
− 60
14 Let a1 = 1, a2 , a3 , a4 , ….. be consecutive C;
natural numbers. Then a2 − a1 = a3 − a2 = ⋯ . . = a2022 −
1 1 a2021 = 1.
tan−1 (1+a a ) + tan−1 (1+a a )
1 2 2 3 a2 − a1
1 ∴ tan−1 ( )
+ ⋯ . +tan−1 (1+a ) is equal to 1 + a1 a2
2021 a2022
a3 − a2
+ tan−1 ( )
1 + a2 a3
a2022 − a2021
+ ⋯ . . +tan−1 ( )
1 + a2021 a2022
= [(tan−1 a2 ) − tan−1 a1 ]
+ [tan−1 a3
− tan−1 a2 ] + ⋯ ..
+[tan a2022 − tan−1 a2021 ]
−1

= tan−1 a2022 − tan−1 a1

= tan−1 (2022) − tan−1 1 =
𝜋
tan−1 2022 − 4 (option 3)
 𝜋 𝜋
= ( − cot −1 (2022)) −
2 4
𝜋
= 4 − cot −1 (2022) (option 1)
𝜋
− cot −1 (2022)
4
𝜋
cot −1 (2022) −
4
−1
𝜋
tan (2022) −
4
𝜋 −1
− tan (2022)
4
15 The parabolas: ax 2 + 2bx + cy = 0 and C;
dx 2 + 2ex + fy = 0 intersect on the line ax 2 + 2bx + c = 0
𝑦 = 1. If a, b, c, d, e, f are positive real ⇒ ax 2 + 2√ac𝑥 + c = 0(∵ b2 = ac)
numbers and a, b, c are in G.P., then ⇒ (x√a + √c)2 = 0
√c
x2 −
√a
Now, dx 2 + 2ex + f = 0
𝑐 √𝑐
⇒ 𝑑 ( ) + 2𝑒 [− ] + 𝑓 = 0
𝑎 √𝑎
𝑑𝑐 𝑐
⇒ + 𝑓 = 2𝑒√
𝑎 𝑎
d f 1
⇒ + = 2e√
a c ac
d f 2e
⇒ + = [ as b = √ae]
a c b
d e f
∴ , , are in A.P.
a b c
d, e, f are in A.P.
d e f
, , are in G.P.
a b c
d e f
, , are in A.P.
a b c
d, e, f are in G.P.
16 If a plane passes through the points D;
(−1, k, 0), (2, k, −1), (1,1,2) and is x − 1 2y + 1 z + 1
x−1 2y+1 z+1 = =
parallel to the line 1 = 2 = −1 , 1 2
1
−1
k2 +1 𝑥−1 𝑦 + 𝑧+1
then the value of is = 2
=
(k−1)(k−2) 1 1 −1
Points: A
(−1, k, 0), B(2, k, −1), C(1,1,2)
⃗⃗⃗⃗⃗ = −2î + (k − 1)ĵ − 2k̂
CA
⃗⃗⃗⃗⃗ = î + (k − 1)ĵ − 3k̂
CB
î ĵ k̂
⃗⃗⃗⃗⃗ × CB
CA ⃗⃗⃗⃗⃗ = |−2 k − 1 −2|
1 k − 1 −3
î(−3k + 3 + 2k − 2) − ĵ(6 + 2)
+ k̂(−2k + 2 − k + 1)
= (1 − k)î − 8ĵ + (3 − 3k)k̂
1
𝑥−1 𝑦+ 𝑧+1
The line 1 = 1 2 = −1 is
perpendicular to normal vector.
 ∴ 1 ⋅ (1 − k) + 1(−8) + (−1)(3 − 3k)
=0
⇒ 1 − k − 8 − 3 + 3k = 0
⇒ 2k = 10 ⇒ k = 5
k2 + 1 26 13
∴ = =
(k − 1)(k − 2) 4 ⋅ 3 6
17
5
5
17
6
13
13
6
17 Let a, b, c > 1, a3 , b3 and c 3 be in A.P., B;
and log a b, log 𝑐 𝑎 and log 𝑏 𝑐 be in G.P. As 𝑎 3 , 𝑏3 , 𝑐 3 be in A.P. → 𝑎 3 + 𝑐 3 =
c
If the sum of first 20 terms of an A.P., 2𝑏 log a , log c , log b are in G.P. . . . (1)
3 b a

whose first term is

𝑎+4𝑏+𝑐
and the log 𝑏 log 𝑐 log 𝑎 2
3 ∴ ⋅ = ( )
𝑎−8𝑏+𝑐 log 𝑎 log 𝑏 log 𝑐
common difference is is -444, ∴ (log 𝑎)3 = (log 𝑐)3 ⇒ 𝑎 = 𝑐 . . . (2)
10
then 𝑎𝑏𝑐 is equal to: From (1) and (2)
a=b=c
a+4b+c
T1 = = 2a; d
3
a − 8 b + c −6a
= =
10 10
−3
= a
5
20 3
∴ 𝑆20 = [4𝑎 + 19 (− a)]
2 5
20a − 57a
= 10 [ ]
5
= −74a
∴ −74a = −444 ⇒ a = 6
∴ abc = 63 = 216
343
216
343
8
125
8
18 Let 𝑆 be the set of all values of 𝑎1 for C;
which the mean deviation about the let a1 be any natural number
mean of 100 consecutive positive 𝑎1 , 𝑎1 + 1, 𝑎1 + 2, … . , 𝑎1
integers a1 , a2 , a3 , … . , a100 is 25. Then S + 99 are values of 𝑎𝑖′ 𝑆
is 𝑥‾
𝑎1 + (𝑎1 + 1) + (𝑎1 + 2) + ⋯ . . +𝑎1 + 99
=
100
100𝑎1 + (1 + 2 + ⋯ . +99)
=
100
99 × 100
= 𝑎1 +
2 × 100
 99
= 𝑎1 +
2
Mean deviation about mean =
100


i =1
xi − x

100
99 97 95 1
2( + + +⋯.+ )
2 2 2 2
=
100
1 + 3 + ⋯ . +99
=
100
50
[1 + 99]
= 2
100
= 25
So, it is true for every natural no. '
a1 1
𝜙
{99}
ℕ
{9}
19 3  1 
2
2
2
 1  D;
2


lim 4 +  2 +  +  2 +  + . . . +  3 −   𝑛−1
n→ n
 n   n   n  3 𝑟 2

 

lim ∑ (2 + )
𝑛→∞ 𝑛 𝑛
is equal to 𝑟=0
1
= 3 ∫ (2 + 𝑥)2 𝑑𝑥 = 27 − 8 = 19
0
12
19
3
0
19
20 For 𝛼, 𝛽 ∈ ℝ, suppose the system of C;
linear equations 1 −1 1
𝑥−𝑦+𝑧 = 5 |2 2 𝛼 | = 0; 8 + 𝛼 − 2(−4 + 1)
2𝑥 + 2𝑦 + 𝛼𝑧 = 8 3 −1 4
3𝑥 − 𝑦 + 4𝑧 = 𝛽 + 3(−𝛼 − 2) = 0
has infinitely many solutions. Then 𝛼 8 + 𝛼 + 6 − 3𝛼 − 6 = 0
and 𝛽 are the roots of 𝛼=4
𝑥 2 − 10𝑥 + 16 = 0
𝑥 2 + 18𝑥 + 56 = 0
𝑥 2 − 18𝑥 + 56 = 0
𝑥 2 + 14𝑥 + 24 = 0
#1,2,3,4,5, SINGLE ANSWER CORRECT TYPE
6,7,8,9,10,
11,12,13,
14,15,16,
17,18,19,
20
21 50th root of a number x is 12 and 50th 23;
root of another number 𝑦 is 18. Then 𝑥 + 𝑦 = 1250 + 1850 = (150 −
the remainder obtained on dividing 6)25 + (325 − 1)25 = 25 K − (625 +
(𝑥 + 𝑦) by 25 is ______
 1) = 25 K − ((5 + 1)25 + 1) =
25 K 1 − 2 Remainder = 23
22 Let A = {1,2,3,5,8,9}. Then the number 432;
of possible functions f: A → A such that 𝑓(1) = 1; 𝑓(9) = 𝑓(3) × 𝑓(3)
𝑓(𝑚 ⋅ 𝑛) = 𝑓(𝑚) ⋅ 𝑓(𝑛) for every 𝑚, 𝑛 ∈ i.e., 𝑓(3) = 1 or 3
𝐴 with m ⋅ n ∈ A is equal to ______ Total function = 1 × 6 × 2 × 6 × 6 ×
1 = 432
23 Let P(a1 , b1 ) and Q(a2 , b2 ) be two 24;
distinct points on a circle with center 1 √35
C(√2, √3). Let O be the origin and OC be × PC × √5 = ; PC = √7
2 2
perpendicular to both CP and CQ. If the
√35
area of the triangle OCP is 2 , then
𝑎12 + 𝑎22 + 𝑏12 + 𝑏22 is equal to ______

a21 + b12 + a22 + b22 = OP2 + OQ2

= 2(5 + 7) = 24
24 The 8th common term of the series 151;
S1 = 3 + 7 + 11 + 15 + 19 + ⋯ T8 = 11 + (8 − 1) × 20
S2 = 1 + 6 + 11 + 16 + 21 + ⋯ = 11 + 140 = 151
is _____
25 Let a line L pass through the point 158;
P(2,3,1) and be parallel to the line 𝑥 + 𝑖ˆ ĵ k̂
3𝑦 − 2𝑧 − 2 = 0 = 𝑥 − 𝑦 + 2𝑧. If the |1 3 −2| = 4î − 4ĵ − 4k̂
distance of L from the point (5,3,8) is 𝛼, 1 −1 2
x−2 y−3 z−1
then 3𝛼 2 is equal to _____ ∴ Equation of line is 1 = −1 = −1
Let Q be (5,3,8) and foot of ⊥ from Q
on this line be R.
Now, R ≡ (k + 2, −k + 3, −k + 1)
DR of 𝑄𝑅 are (k − 3, −k, −k − 7)
∴ (1)(k − 3) + (−1)(−k) + (−1)(−k
− 7) = 0
4
⇒k=−
3
2
13 4 2 17 2 474
∴ 𝛼2 = ( ) + ( ) + ( ) =
3 3 3 9
∴ 3𝛼 2 = 158
26 If ∫ √sec 2𝑥 − 1𝑑𝑥 = 𝛼log 𝑒 |cos 2𝑥 + 1;

1
∫ √sec 2𝑥 − 1𝑑𝑥
𝛽 + √cos 2𝑥 (1 + cos 𝑥)| + constant,
𝛽
then 𝛽 − 𝛼 is equal to __. 1 − cos 2𝑥
=∫ √ 𝑑𝑥
cos 2𝑥
sin 𝑥
= √2 ∫ 𝑑𝑥
√2cos2 𝑥 − 1
put cos 𝑥 = 𝑡 ⇒ −sin 𝑥𝑑𝑥 = 𝑑𝑡
𝑑𝑡
= −√2 ∫
√2𝑡 2 − 1
= − ln|√2 cos 𝑥 + √cos 2𝑥| + 𝑐
 1
= − ln |2cos 2𝑥 + cos 2𝑥
2
+ 2√cos 2𝑥
⋅ √2cos 𝑥| + 𝑐
1 1
= − ln |cos 2𝑥 + + √cos 2𝑥
2 2
⋅ √1 + cos 2𝑥| + 𝑐
1 1
∵ 𝛽 = ,𝛼 = − ⇒ 𝛽 −𝛼 = 1
2 2
27 If the value of real number 𝑎 > 0 for 13;
which 𝑥 2 − 5𝑎𝑥 +1 = 0 and 𝑥 2 − 𝑎𝑥 − Two equations have common root
3
5 = 0 have a common real roots is ∴ (4𝑎)(26𝑎) = (−6)2 = 36
√2𝛽 9 3
then 𝛽 is equal to _____ ⇒ 𝑎2 = ∴𝑎= ⇒ 𝛽 = 13
26 √26
28 The number of seven digits odd 240;
numbers, that can be formed using all Digits are 1, 2, 2, 2, 3,3,5
the seven digits 1, 2, 2, 2, 3, 3, 5 is _______ If unit digit 5, then total numbers =
6!
3!2!
6!
If unit digit 3, then total numbers = 3!
If unit digit 1, then total numbers =
6!
3!2!
∴ total numbers = 60 + 60 + 120 =
240
29 A bag contains six balls of different 14;
colours. Two balls are drawn in 6
C1 1
succession with replacement. The p= =
66 6
probability that both the balls are of the
same colour is 𝑝. Next four balls are C1  5C1  4 5
6
q= =
drawn in succession with replacement 6  6  6  6 54
and the probability that exactly three p : q = 9:5  m + n = 14
balls are of the same colours is 𝑞. If 𝑝 ∶
𝑞 = 𝑚 ∶ 𝑛, where 𝑚 and 𝑛 are coprime,
then 𝑚 + 𝑛 is equal to ____
30 Let 𝐴 be the area of the region 25;
( x , y ) : y  x , y  (1 − x ) , y  2x (1 − x )
2 2

Then 540 A is equal to ______

( )
2
A =  2x − 2x 2 − (1 − x ) dx
2

1
3
12
= 2 2x 2 − x 3 − x 
13
 5 5
A =  540 A =  540 = 25
108 108
#21,22,23, NUMERICAL TYPE
24,25,
26,27,28,2
9,30
31 A block of √3 kg is attached to a string A;
whose other end is attached to the wall.
An unknown force 𝐹 is applied so that
the string makes an angle of 30∘ with
the wall. The tension T is:
(Given g = 10 ms−2 )

𝜃 = 30∘
√3 g
cos 𝜃 =
T
√3 √3 g
⇒ =
2 T
⇒ T = 20 N
20 N
25 N
10 N
15 N
32 A flask contains hydrogen and oxygen B;
in the ratio of 2: 1 by mass at 5
𝐾𝑎𝑣 = 𝑘𝑇
temperature 27∘ C. The ratio of average 2
kinetic energy per molecule of Ratio = 1: 1
hydrogen and oxygen respectively is:
2:1
1:1
1:4
4:1
33 The equivalent resistance between A A;
and B is . . . .

1 1 1 1 1 1
= + + + +
R eq 2 12 4 6 2
6 + 1 + 3 + 2 + 6 18 3
= = =
12 12 2
2
⇒ 𝑅eq = Ω
3
2

3
1

2
 3

2
1

3
34 Given below are two statements: one is B;
labelled as Assertion 𝐀 and the other is Nuclear density is independent of A.
labelled as Reason 𝐑. Assertion A : The
nuclear density of nuclides
10
5 B, 3 Li, 26 Fe, 10 Ne and 83 Bi can be
6 56 20 209

arranged as
N N N
𝜌Bi > 𝜌Fe > 𝜌Ne > 𝜌BN > 𝜌Li
N
.
Reason 𝑹: The radius 𝑅 of nucleus is
related to its mass number 𝐴 as 𝑅 =
𝑅0 𝐴1/3 , where 𝑅0 is a constant.
In the light of the above statement,
choose the correct answer from the
options given below :
Both A and R are true and R is the
correct explanation of A
A is false but 𝑅 is true
𝐴 is true but 𝑅 is false
Both A and 𝑅 are true but 𝑅 is NOT the
correct explanation of A
35 A thin prism P1 with an angle 6∘ and D;
made of glass of refractive index 1.54 is 𝛿1 = 𝛿2 [for no average deviation]
combined with another prism P2 made ⇒ 6∘ (1.54 − 1) = A(1.72 − 1)
from glass of refractive index 1.72 to 6∘ × 0.54
⇒A=
produce dispersion without average 0.72
deviation. The angle of prism 𝑃2 is: 18∘
= = 4.5∘
4
6∘
1.3∘
7.8∘
4.5∘
36 The output Y for the inputs A and B of D;
circuit is given by Given circuit represent XOR.

Truth table of the shown circuit is:

37 A vehicle travels 4 km with speed of D;
3 km/h and another 4 km with speed of 2 1 1 8
= + =
5 km/h, then its average speed is: Vav 3 5 15
15
⇒ Vav = = 3.75 km/h
4
4.25 km/h
3.50 km/h
4.00 km/h
3.75 km/h
38 As shown in the figure, a point charge 𝑄 B;
is placed at the centre of conducting Electric field inside material of
spherical shell of inner radius 𝑎 and conductor is zero.
outer radius 𝑏. The electric field due to
charge 𝑄 in three different regions 𝐼, 𝐼𝐼
and III is given by: (I: r < a, II : a < r <
b, III : r > b)

EI = 0, EII = 0, EIII ≠ 0
EI ≠ 0, EII = 0, EIII ≠ 0
EI ≠ 0, EII = 0, EII = 0
𝐸𝐼 = 0, 𝐸𝐼𝐼 = 0, 𝐸𝐼𝐼 = 0
39 As shown in the figure, a current of 2 A D;
flowing in an equilateral triangle of side d tan 60∘ = 2√3
4√3 cm. The magnetic field at the d = 2 cm
centroid O of the triangle is: 𝜇0 i
𝐵=3× sin 60∘
(Neglect the effect of earth's magnetic 2𝜋d
field.) 2 × 10−7 × 2 √3
=3× ×
2 × 10−2 2
= 3√3 × 10−5
 4√3 × 10−4 T
4√3 × 10−5 T
√3 × 10−4 T
3√3 × 10−5 T
40 In the given circuit, rms value of A;
current (𝐼nms ) through the resistor R is: 𝑧 = √1002 + (200 − 100)2
= 100√2Ω
Vrms 200√2
irms = =
z 100√2
=2A

2A
1
A
2
20 A
2√2 A
41 A machine gun of mass 10 kg fires 20 g D;
bullets at the rate of 180 bullets per 180
20 × 10−3 × × 100 = 10 V
minute with a speed of 100 m s−1 each. 60
The recoil velocity of the gun is: ⇒ v = 0.6 m/s
0.02 m/s
2.5 m/s
1.5 m/s
0.6 m/s
42 Given below are two statements: one is D;
labelled as Assertion 𝐀 and the other is Both A and R are true and R is the
labelled as Reason 𝐑. Assertion A: correct explanation of A
Efficiency of a reversible heat engine
will be highest at −273∘ C temperature
of cold reservoir.
Reason 𝐑 : The efficiency of Carnot's
engine depends not only on
temperature of cold reservoir but it
depends on the temperature of hot
reservoir too and is given as 𝜂 = (1 −
T2
).
T1
In the light of the above statements,
choose the correct answer from the
options given below:
𝐀 is true but 𝐑 is false
Both 𝐀 and 𝐑 are true but 𝐑 is NOT the
correct explanation of 𝐀
𝐀 is false but 𝐑 is true
 Both 𝐀 and 𝐑 are true and 𝐑 is the
correct explanation of 𝐀
43 Match List-I with List-II. D
List – I List – II
(A) Torque (I) kg
𝑚− 1 𝑠 − 2
(B) Energy (II) kg 𝑚𝑠 − 1
density
(C) Pressure (III) kg
gradient 𝑚− 2 𝑠 − 2
(D) Impulse (IV) kg 𝑚2 𝑠 − 2
Choose the correct answer from the
options given below.
A-IV, B-III, C-I, D-II
A-I, B-IV, C-III, D-II
A-IV, B-I, C-II, D-III
A-IV, B-I, C-III, D-II
44 For a simple harmonic motion in a mass B;
spring system shown, the surface is k
frictionless. When the mass of the block =
m
is 1 kg, the angular frequency is 𝜔1 .
When the mass block is 2 kg the 2 m1 1
= =
angular frequency is 𝜔2 . The ratio 1 m2 2
𝜔2 /𝜔1 is:

√2
1
√2
2
1
2
45 An electron accelerated through a B;
potential difference 𝑉1 has a de-Broglie P2 h
wavelength of 𝜆. When the potential is KE = , P=
2m 𝜆
changed to V2 , its de-Broglie h 2
( )
wavelength increases by 50%. The eV1 = 𝜆
V
value of ( V1 ) is equal to: 2m
h 2
2
(1.5𝜆)
eV2 =
2m
V1 9
= (1.5)2 =
V2 4
3
9
4
3
2
4
46 Match List-I with List-II. D;
 List–I List–II
(A Attenuation (I) Combinati
) on of a
receiver
and
transmitte
r
(B Transducer (II) Process of
) retrieval of
informatio
n from the
carrier
wave at
received
(C Demodulati (III Converts
) on ) one form
of energy
into
another
(D Repeater (IV Loss of
) ) strength of
a signal
while
propagatin
g through a
medium
Choose the correct answer from the
options given below.
A-I, B-II, C-III, D-IV
A-II, B-III, C-IV, D-I
A-IV, B-III, C-I, D-II
A-IV, B-III, C-II, D-I
47 A current carrying rectangular loop B;
PQRS is made of uniform wire. The 𝐹 ∝ 𝐼1 𝐼2
length 𝑃𝑅 = 𝑄𝑆 = 5 cm and PQ = RS = 𝐹𝐼 : 𝐹2𝐼 = 1: 4
100 cm. If ammeter current reading
changes from I to 2I, the ratio of
magnetic forces per unit length on the
wire PQ due to wire RS in the two cases
I 2I
respectively 𝑓PQ : 𝑓PQ is:
1: 2
1: 4
1: 5
1: 3
48 A force is applied to a steel wire ' 𝐴 ', D;
rigidly clamped at one end. As a result, F/A
Y=
elongation in the wire is 0.2 mm. If Δℓ
same force is applied to another steel ℓ
YA
wire ' B ' of double the length and a ⇒F= Δℓ
diameter 2.4 times that of the wire ' 𝐴 ', ℓ
AΔℓ AΔℓ
the elongation in the wire ‘B’ will be ( ) =( )
(wires having uniform circular cross- ℓ 1 ℓ 2
sections)
 Δℓ2 A1 ℓ2
⇒ = ×
Δℓ1 A2 ℓ1
Δℓ2 1 2
⇒ = ×
0.2 2.4 × 2.4 1
⇒ ℓ2 = 6.9 × 10−2 mm
6.06 × 10−2 mm
2.77 × 10−2 mm
3.0 × 10−2 mm
6.9 × 10−2 mm
49 An object is allowed to fall from a B;
height 𝑅 above the earth, where 𝑅 is the Loss in PE = Gain in KE
radius of earth. Its velocity when it 𝐺𝑀𝑚 𝐺𝑀𝑚 1
(− ) − (− ) = 𝑚𝑣 2
strikes the earth's surface, ignoring air 2𝑅 𝑅 2
resistance, will be: 𝐺𝑀
⇒ 𝑣2 = = 𝑔𝑅
𝑅
⇒ 𝑣 = √𝑔𝑅
2√gR
√𝑔𝑅
𝑔𝑅
√
2
√2𝑔𝑅
50 A point source of 100 W emits light B;
with 5% efficiency. At a distance of 5 m 1 5
IEF = ×
from the source, the intensity produced 2 4𝜋 × 52
by the electric field component is: 1
= W/m2
40𝜋
1 W
2𝜋 m2
1 𝑊
40𝜋 m2
1 W
10𝜋 m2
1 𝑊
20𝜋 m2
#31,32,33,
34,35,
36,37,38,3
9,40,
41,42,43,4
4,45,
46,47,48,4
9,50
51 A faulty thermometer reads 5∘ C in 313;
melting ice and 95∘ C in steam. The 41∘ − 5∘ C − 0∘
=
correct temperature on absolute scale 95∘ − 5∘ 100∘ − 0∘
will be......... K when the faulty 36
⇒C= × 100 = 40∘ C = 313 K
thermometer reads 41∘ C. 90
52 If the potential difference between B 2;
𝑥
1 2 𝑥+1
and D is zero, the value of x is  . The =
n 3 𝑥
value of 𝑛 is _____.
 2 1
⇒ =
3 x+1
1
⇒ 𝑥 = 0.5 =
2
𝑛=2

53 The velocity of a particle executing SHM 88;

varies with displacement (x) as 4𝑣 2 = 4𝑣 2 = 50 − 𝑥 2
50 − 𝑥 2 . The time period of oscillations 1
𝑥 ⇒ 𝑣 = √50 − 𝑥 2
is 7 s. The value of 𝑥 is ______. 2
1
22 𝜔=
( Take 𝜋 = ) 2
7 2𝜋 88
𝑇= = 4𝜋 =
𝜔 7
𝑥 = 88
54 In a Young's double slit experiment, the 3;
intensities at two points, for the path Δ𝜙
𝜆 𝜆 I = 4I0 cos2 ( )
difference 4 and 3 ( 𝜆 being the 2
𝜋
wavelength of light used) are 𝐼1 and 𝐼2 I1 = 4I0 cos2 ( ) = 2I0
4
respectively. If 𝐼0 denotes the intensity 2𝜋
produced by each one of the individual I2 = 4I0 cos2 ( ) = I0
3
I +I
slits, then 1 2 = ________ I1 + I2
I0 ⇒ =3
I0
55 A radioactive nucleus decays by two 300;
different process. The half life of the dN
= −(λ1 + λ2 )N
first process is 5 minutes and that of dt
the second process is 30 s. The effective ⇒ λeq = λ1 + λ2
half-life of the nucleus is calculated to 1 1 1 11
𝛼 ⇒ = + =
be 11 s. The value of 𝛼 is _____ t1/2 300 30 300
300
 t1 2 =
11
56 A body of mass 2 kg is initially at rest. It 4;
starts moving unidirectionally under 1
mV 2 = Pt
the influence of a source of constant 2
power P. Its displacement in 4 s is
1 2 2𝑃𝑡
𝛼 √Pm. The value of 𝛼 will be ..... 𝑉=√
3 𝑚

𝑑𝑥 2𝑃𝑡
=√
𝑑𝑡 𝑚

2𝑃 2 3/2 4
𝑥=√ [𝑡 ]0
𝑚3
16√𝑃 1
𝑥= = × 16√𝑃
3 3
𝛼=4
57 As shown in figure, a cuboid lies in a 12;
region with electric field 𝐸 = 2𝑥 2 𝑖ˆ − 𝐸⃗ = 2𝑥 2 î − 4𝑦ĵ + 6k̂
4𝑦𝑗ˆ + 6𝑘ˆ 𝑁/𝐶. The magnitude of charge
within the cuboid is n𝜖0 C. The value of
 n is ______ (if dimension of cuboid is
1 × 2 × 3 m3 )

𝜙net = −8 × 3 + 2 × 6 = −12
𝑞
−12 =
𝜖0
|𝑞| = 12𝜖0
58 In an ac generator, a rectangular coil of 1584;
100 turns each having area 14 × 𝜉max = NAB𝜔
10−2 m2 is rotated at 360rev/min 360 × 2𝜋
= 100 × 14 × 10−2 × 3 ×
about an axis perpendicular to a 60
uniform magnetic field of magnitude = 1584 V
3.0 T. The maximum value of the emf
22
produced will be V. ( Take 𝜋 = 7 )
59 A stone tied to 180 cm long string at its 125;
end is making 28 revolutions in 28 × 2𝜋 2
horizontal circle in every minute. The 𝑎= 𝜔2 𝑅 =( ) × 1.8
60
magnitude of acceleration of stone is 56 22 2
1936 = ( × ) × 1.8
ms−2 . The value of x ______ 60 7
x
( Take 𝜋 =
22
) (44)2
7 = × 1.8
225
1936 × 1.8
=
225
𝑥 = 125
60 A uniform disc of mass 0.5 kg and 54;
radius r is projected with velocity a = −𝜇k g = −3
18 m/s at t = 0 s on a rough horizontal 𝑉 = 18 − 3 × 2
surface. It starts off with a purely 𝑉 = 12 𝑚/𝑠
sliding motion at 𝑡 = 0 s. After 2 s it 1 2
1 𝑚𝑟 2 𝑣 2
acquires a purely rolling motion (see 𝐾𝐸 = 𝑚𝑣 +
2 2 2 𝑟2
figure). The total kinetic energy of the 3 2
disc after 2𝑠 will be ______ J K .E = mv
4
(given, coefficient of friction is 0.3 and K .E = 3  18 = 54 J
g = 10 m/s2 ).

#51,52,53, NUMERICAL TYPE

54,55,
56,57,58,5
9,60

61 Which of the following reaction is C;

correct? Δ
4LiNO3 ⟶ 2Li2 O + 4NO2 + O2
Δ
2LiNO3 ⟶ 2LiNO2 + O2
 Δ
4LiNO3 ⟶ 2Li2 O + 2 N2 O4 + O2
Δ
4LiNO3 ⟶ 2Li2 O + 4NO2 + O2
Δ
2LiNO3 ⟶ 2Li + 2NO2 + O2
62 The most stable carbocation for the A;
following is:

The +M effect of NH2 is stabilizing the

carbocation.

c
d
b
a
63 The correct order of pKa values for the B;
following compounds is: Due to – M effect of − NO2 group, it
increases acidity +M effect of
N ( CH3 )2 decreases acidity.
Hyperconjugation of isopropyl
decrease acidity
∴ order of acidic strength
(c) > (a) > (d) > (b)
C>a>d>b
b>d>a>c
b>a>d>c
a>b>c>d
64 Decreasing order towards S N 1 reaction C;
for the following compounds is: The rate of S N 1 reaction depends
upon stability of carbocation which
follows the order

∴ Reactivity order b > d > c > a

a>c>d>b
a>b>c>d
b>d>c>a
d>b>c>a
65 D;
 In the above conversion of compound
(X) to product (Y), the sequence of
reagents to be used will be:

(i) Br2 , Fe (ii) Fe, H + (iii) LiAlH4

(i) Br2 (aq) (ii) LiAlH4 (iii) H3 O+
(i) Fe, H + (ii) Br2 (aq) (iii) HNO2 (iv)
CuBr
(i) Fe, H + (ii) Br2 (aq) (iii) HNO2 (iv)
H3 PO2
66 Maximum number of electrons that can B;
be accommodated in shell with 𝑛 = 4 The number of electrons in the
are: orbitals of sub-shell of 𝑛 = 4 are
4s 2
4p 6
4d 10
4f 14
Total 32
16
32
50
72
67 Match List-I with List-II. Bonus
List–I List–II +2
For Fe ( NH3 )6  , 0  P , hence the
(Complexes) (Hybridization
) pairing of electrons does not occur in
(A Ni (CO)4  (I) sp3 t 2 g . Therefore, complex is outer
) orbital and its hybridization is sp3d2
(B Cu ( NH3 ) 4 
2+
(II) dsp2 List–I List–II
) (Complexes) (Hybridizatio
(C)  2+ (III) sp3d2
 Fe ( NH 3 ) 
6
n)
(A Ni (CO)  (I) sp3
(D  2+ (IV) d2sp3  4

)  Fe ( H2O )6
 )
(B Cu ( NH ) 4  2+ (II) dsp2
Choose the correct answer from the  3 
)
options given below.
(C Fe NH 2+ (III sp3d2
)  ( 3 )6  )
(D  2+ (IV sp3d2
)  Fe ( H2O ) 
6 )
A-II, B-I, C-III, D-IV
A-I, B-II, C-III, D-IV
A-II, B-I, C-IV, D-IV
A-I, B-II, C-IV, D-III
68 The Cl – Co – Cl bond angle values in a B;
fac- Co ( NH3 )3 Cl3  complex is/are:

The Cl – Co – Cl bond angle in above

octahedral complex is 90°.
90° and 180°
90°
180°
90° and 120°
69 Given below are two statements: One is A;
labelled as Assertion A and the other is
labelled as Reason R.
The acid sensitive alcohol group
Assertion A: can be easily reacts with HCl, hence Clemmenson
reduced using Zn − Hg/HCl to reduction is not suitable for the
above conversion.

Reason 𝐑: Zn − Hg/HCl is used to

reduce carbonyl group to −CH2 −
group.
In the light of the above statements,
choose the correct answer from the
options given below:
A is false but 𝑅 is true
A is true but 𝑅 is false
Both A and R are true but R is not the
correct explanation of A
Both A and R are true and R is the
correct explanation of A
70 Chlorides of which metal are soluble in D;
organic solvents: BeCl2 having covalent nature is
soluble in organic solvent.
Ca
Mg
K
Be
71 Given below are two statements: One is B;
labelled as Assertion 𝐀 and the other Antiallergic and antacid drugs work
labelled as Reason R. Assertion A: on different receptors
Antihistamines do not affect the NCERT(XII) vol. 2 page no. 451 − 452
secretion of acid in stomach.
Reason R: Antiallergic and antacid
drugs work on different receptors.
In the light of the above statements,
choose the correct answer from the
options given below:
A is false but 𝑅 is true
 Both A and R are true and R is the
correct explanation of A
A is true but 𝑅 is false
Both A and R are true but R is not the
correct explanation of A
72 The wave function (Ψ) of 2𝑠 is given by D;
1 1 1/2 𝑟 At node 2s = 0
Ψ2𝑠 = ( ) (2 − ) e−r/2a0
2√2𝜋 𝑎0 𝑎0 r0
At r = r0 , radial node is formed. Thus, 2 − =0
a0
r0 in terms of a0
r0 = 2a0
𝑟0 = 𝑎0
r0 = 4a0
a
r0 = 0
2
r0 = 2a0
73 KMnO4 oxidises I − in acidic and A;
neutral/faintly alkaline solution, In acidic medium,
respectively to 2MnO− −
4 + 10I + 16H
+

→ 2Mn2+ + 5I2
+ 8H2 O
In neutral/faintly alkaline solution,
2MnO− −
4 + I + H2 O
→ 2MnO2 + 2OH−
+ IO−3
I2 &IO−3
IO−3 &I2
IO−3 &IO3
−

I2 &I2
74 Bond dissociation energy of E − H bond A;
of the " H2 E " hydrides of group 16 Bond dissociation energy of E − H
elements (given below), follows order. bond in hydrides of group 16 follows
(A) O the order.
(B) S H2 O > H2 S > H2 Se > H2 Te
(C) Se
(D) Te
A>B>C>D
A>B>D>C
B>A>C>D
D>C>B>A
75 The water quality of a pond was C;
analysed and its BOD was found to be 4. Clean water as BOD value of < 5
The pond has while polluted water has BOD of 15
or more.
Highly polluted water
Water has high amount of fluoride
compounds
Very clean water
Slightly polluted water
76 Match List-I with List-II. B;
 List – I (Mixture) List – II List – I (Mixture) List – II
(Separation (Separation
technique) technique)
(A CHCl3 + C6H5NH2 (I) Steam CHCl3 + C6H5NH2 Distillation
) distillatio Fractional
C6H14 + C5H12
n distillation
(B C6H14 + C5H12 (II) Differenti
C6H5NH2 + H2O Steam
) al distillation
extractio Organic Differential
n extraction
compound in H2O
(C C6H5NH2 + H2O (III Distillati
) ) on
(D Organic (IV Fractiona
) compound in ) l
H2O distillatio
n
A-IV, B-I, C-III, D-II
A-III, B-IV, C-I, D-II
A-II, B-I, C-III, D-IV
A-III, B-I, C-IV, D-II
77 Boric acid in solid, whereas BF3 is gas at C;
room temperature because of Boric acid has strong hydrogen
bonding while BF3 does not.
Therefore, boric acid is solid.
Strong ionic bond in Boric acid
Strong van der Waal’s interaction in
Boric acid
Strong hydrogen bond in Boric acid
Strong covalent bond in BF3
78 Given below are two statements. A;
Statement I: During Electrolytic In Electrolytic refining, the pure
refining, the pure metal is made to act metal is used as cathode and impure
as anode and its impure metallic form is metal is used as anode.
used as cathode. Na3 AlF6 is added during electrolysis
Statement II: During the Hall-Heroult of Al2 O3 to lower the melting point
electrolysis process, purified Al2 O3 is and increase conductivity.
mixed with Na3 AlF6 to lower the
melting point of the mixture.
In the light of the above statements,
choose the most appropriate answer
from the options given below:
Statement I is incorrect but Statement
II is correct
Both Statement I and Statement 𝐼 are
incorrect
Statement I is correct but Statement II
is incorrect
Both Statement I and Statement I are
correct
79 Formulae for Nessler's reagent is: C;
Nessler’s reagent is K 2 HgI4
KHg 2 I2
KHgI3
 K 2 HgI4
HgI2
80 1 L, 0.02M solution of [Co(NH3 )5 SO4 ]Br B;
is mixed with 1 L, 0.02M solution of [Co(NH3 )5 SO4 ]Br + AgNO3 → AgBr ↓
[Co(NH3 )5 Br]SO4. The resulting 0.01 mol excess 0.01Mol
solution is divided into two equal parts [Co(NH3 )5 Br]SO4 + BaCl2 → BaSO4 ↓
(X) and treated with excess AgNO3 0.01 mol excess 0.01Mol
solution and BaCl2 solution respectively
as shown below:
1 L Solution (X) + AgNO3 solution
(excess) → Y
1 L Solution (X) + BaCl2 solution
(excess) → 𝑍
The number of moles of Y and Z
respectively are
0.02,0.02
0.01,0.01
0.02,0.01
0.01,0.02
#61,62,63, SINGLE ANSWER CORRECT TYPE
64,65,
66,67,68,6
9,70,
71,72,73,7
4,75,
76,77,78,7
9,80
81 1 mole of ideal gas is allowed to expand 150;
reversibly and adiabatically from a q=0
temperature of 27∘ C. The work done is ΔU = w
3 kJ mol−1 . The final temperature of the 1 × 20 × [T2 − 300] = −3000
gas is _______ K(Nearest integer). T2 − 300 = −150
Given Cv = 20 J mol−1 K −1. T2 = 150 K
82 Iron oxide FeO, crystallises in a cubic 4;
lattice with a unit cell edge length of Z×M
d=
5.0Å. If density of the FeO in the crystal N0 × a3
is 4.0 g cm−3 , then the number of FeO 𝑍 × 72
4=
units present per unit cell is _____ 6 × 1023 × 125 × 10−24
(Nearest integer) 𝑍 = 4.166 ≃ 4
Given: Molar mass of Fe and O is 56 and
16 g mol−1 respectively.
NA = 6.0 × 1023 mol−1
83 An organic compound undergoes first 1350;
order decomposition. If the time taken 1 𝑎0
𝑡1 𝐾 ln 0.4𝑎0
for the 60% decomposition is 540 s, =
then the time required for 90% 𝑡2 1 ln 𝑎0
𝐾 0.1𝑎0
decomposition will be is ________ s. 10
540 ln 4
(Nearest integer). Given: ln 10 = =
2.3; log 2 = 0.3 𝑡2 ln 10
540 log 10 − log 4
=
𝑡2 log 10
540 1 − 0.6
=
t2 1
 540
⇒ = 0.4
𝑡2
540
⇒ 𝑡2 = = 1350 sec
0.4
84 Lead storage battery contains 38% by 243;
weight solution of H2 SO4. The van't ΔTf = 𝑖 K f m
Hoff factor is 2.67 at this concentration. 38 1000
⇒ ΔTf = 2.67 × 1.8 × ×
The temperature in Kelvin at which the 98 62
solution in the battery will freeze is ⇒ ΔTf = 30.05
_____ ∴ F.P. = 243 K
(Nearest integer).
Given K f = 1.8 K kg mol−1
85 Consider the following equation: 3;
2SO2 ( g) + O2 ( g) ⇌ 2SO3 ( g), ΔH The yield of SO3 at equilibrium will
= −190 kJ be due to:
The number of factors which will B. Increasing pressure
increase the yield of SO3 at equilibrium C. Adding more SO2
from the following is D. Adding more O2
A. Increasing temperature
B. Increasing pressure
C. Adding more SO2
D. Adding more O2
E. Addition of catalyst
x
86 The graph of log m vs log p for an 16;
𝑥 1
adsorption process is a straight line log = log k + log P
inclined at an angle of 45∘ with m n
1
intercept equal to 0.6020. The mass of ∘
= tan 45 = 1
gas adsorbed per unit mass of n
log k = 0.6020 = log 4
adsorbent at the pressure of 0.4 atm is
⇒K=4
× 10−1 (Nearest integer) x
Given : log 2 = 0.3010 ∴ = K ⋅ P1/n
m
x
= 4(0.4) = 1.6
m
x
= 1.6 = 16  10− 1
m
87 Number of compounds from the 3;
following which will not dissolve in Compound 2, 3, 7
cold NaHCO3 and NaOH solutions but
will dissolve in hot NaOH solution is
_____
88 A short peptide on complete hydrolysis 6;
produces 3 moles of glycine (G), two Number of peptide linkage = ( amino
moles of leucine (L) and two moles of acid -1) = 7 − 1 = 6
valine (V) per mole of peptide. The
number of peptide linkages in it are
_____
89 The strength of 50 volume solution of 150;
hydrogen peroxide is g/L (Nearest 50
Molarity = 11.35
integer). 50
Given: ∴ Strength in gm/L = 11.35 × 34
Molar mass of H2 O2 is 34 g mol−1
Molar volume of gas at STP = 22.7 L.
90 The electrode potential of the following 275;
half cell at 298 K. X + Y 2+ → Y + X 2+
X|X 2+ (0.001M) ∥ Y 2+ (0.01M)|Y 0
ECell = 0.36 − (−2.36) = 2.72 V
is _________ × 10−2 V (Nearest integer). 0.06 0.001
ECell = 2.72 − log
Given: Ex02+∣x = −2.36 V 2 0.01
EY0 2+ = +0.36 V = 2.72 + 0.03 = 2.75 V
2.303RT = 275 × 10−2 V
= 0.06 V
F
#81,82,83, NUMERICAL TYPE
84,85,
86,87,88,8
9,90