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Time : 125 Mins CHEMISTRY TEST 24 ORGANIC CHEMISTRY SOME Marks : 497
BASIC PRINCIPLES AND TECHNIQUES 1

1. How many stereoisomers does this molecule have?

CH3CH = CHCH2CHBrCH3
a) 4 b) 6 c) 8 d) 2
2. What is the minimum number of carbon atoms of an alkane must have to form an isomer?
a) 4 b) 3 c) 2 d) 1
3. In Carius method of estimation of halogen, 0.15 g of an organic compound gave 0.12 g of AgBr.What is the
percentage of bromine in the compound?
a) 68.08% b) 34.04% c) 42.1% d) 50%
63 PP
4. The stability of carbanions in the following:
20 A
08
56 TS

a) (a) > (b) > (c) < (d) b) (b) > (c) > (d) < (a) c) (d) > (b) > (c) < (a) d) (a) > (c) > (b) < (d)

5.
80 HA

a) Resonating structure b) Tautomers c) Geometrical isomers d) Optical isomers

6. Which of the following carbanion expected to be most stable?
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− − − −
a) p − NO 2C 6H 4CH 2 b) o − NO 2C 6H 4CH 2 c) o − CHOC 6H 4CH 2 d) p − CHOC 6H 4CH 2
7. Which of the following statements is not true about the stability of carbanions?
a) Stability of carbanions increases with increase in s-character of orbital
b) The electron withdrawing groups like - NO2, - CN, >C=O increases the stability of carbanions.
c) Order of stability of carbanions is 3° > 2° > 1°.
d) The negatively charged carbon is sp3 hybridised and pyramidal.

8. Which of the following orders correctly depicts the decreasing order of stability of carbanion?

a)

_
| _ || _ || _
b) OHC − CCHO − CHO > OHC − CH − CHO > H 3C − C O − CH − C O − CH 3 > CH 2 − CHO

_ _ _ _
c) CH 2NO 2 < CH 2CN < CH 2Cl < CH 2CH 3 d)
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 W
80 HA
56 TS
20 A
63 PP
08
 9. The order of decreasing stability of the following carbanions is
(i) (CH3)C-
(ii) (CH3)CH-
−
(iii) CH 3CH 2
−
(iv) C 6H 5CH 2
a) (i) > (ii) > (iii) > (iv) b) (iv) > (iii)> (ii)> (i) c) (iv) > (i) > (Ii) > (iii) d) (iii)> (ii)> (i)> (iv)
10. The correct order of acidic strength for the following compounds will be

a) III>I>II b) I>III>II c) II>III>I d) I>II>III

11. The presence of carbon in an organic compound can be shown by
a) heating the compound with sodium b) heating the compound with cupric oxide
c) heating the compound on buns en flame d) heating the compound with magnesium

12. The correct order of increasing bond length of CㅡH, CㅡO, CㅡC and C = C is:
a) CㅡC < C = C < CㅡO < CㅡH b) CㅡO < CㅡH < CㅡC < C = C c) CㅡH < CㅡO < CㅡC < C = C
d) CㅡH < C = C < CㅡO < CㅡC
63 PP
13. How many primary, secondary, tertiary and quaternary carbon atoms are present in the following compound?
CH 3 |
| |
20 A
CH 3 − CCH 3H − CH 2 − C − CH 3CH 3
08
a) One primary, two secondary and one tertiary b) Five primary, three secondary
56 TS

c) Five primary, one secondary, one tertiary and one quaternary

d) Four primary, two secondary and two quaternary
80 HA

14. Kjeldahl's method is used in the estimation of :

a) nitrogen b) halogens c) sulphur d) oxygen
15. Consider the following compounds.
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(i) C6H5COCI

The correct decreasing order of their reactivity towards hydrolysis is

a) (i) > (ii)> (iii)> (iv) b) (iv) > (ii) > (i)> (iii) c) (ii) > (iv) > (i)> (iii) d) (ii)> (iv) > (iii) > (i)
16. In compound 'X' all the bound angles are exactly 1090 28' 'X' is.
a) Chloromethane b) Iodoform c) Carbon tetrachloride d) Chloroform
17. Inductive effect involves
a) displacement of a-electrons resulting in polarisation
b) displacement of 1t-electrons resulting in polarisation c) delocalisation of a-electrons
d) delocalisation of π-electrons
18. In Duma's method of estimation of nitrogen 0.35 of an organic compound gave 55 mL of nitrogen collected at 300
K temperature and 715 mm pressure. The percentage composition of nitrogen in the compound would be:
(Aqueous tension at 300 K = 15 mm)
a) 15.45 b) 16.45 c) 17.45 d) 14.45
19. Which of the following techniques is most suitable for purification of cyclohexanone from a mixture containing
benzoic acid, isoamyl alcohol, cyclohexane and cyclohexanone?
a) Crystallisation b) IR spectroscopy c) Sublimation d) Evaporation
20. The correct IUPAC name of the following compound is

a) 2-ethyl-1-chlorocyclohexanol b) 4-carboxy-2-oxocyclohexanal c) 4-hydroxy-2-ethyl-1-chlorocyclohexane

d) 4-chloro-3-ethylcyclohexanol.
21. The IUPAC name of

a) 1, 3 isoproyl-3-rnethyl propane b) 2, 3, 6-trirnethyl heptane c) 2, 5, 6-trirnethyl heptane

d) 2, 6, 3-trimethyl heptane
22. Which one of the following is most reactive towards electrophilic reagent?

a) b) c) d)

23. In the following question, a statement of assertion is followed by a statement of reason. Mark the correct choice
as :
Assertion: Rotation about C=C is restricted.
63 PP
Reason : Electron charge cloud of the π bond is located above and below the plane of bonding atoms.
a) If both assertion and reason are true and reason is the correct explanation of assertion
b) If both assertion and reason are true but reason is not the correct explanation of assertion
20 A
08
c) If assertion is true but reason is false d) If both assertion and reason are false
56 TS

24.
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are :
a) resonating structures b) geometrical isomers c) tautomers d) optical isomers
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25. Which of the following is a false statement?

a) Free radicals, carbonium ions or carbanions are reaction intermediates
b) Reaction between methane and chlorine in presence of sunlight proceeds via free radical
c) The electronegative atom in the carbon chain produces +I effect.
d) Homolytic fission of C - C bonds gives free radicals

26. The correct statement regarding the comparision of staggered and eclipsed conformation of ethane, is
a)
The staggered conformation of ethane is less stable than eclipsed conformation, because staggered
conformation has torsional strain
b)
The eclipsed conformation of ethane is more stable than staggered conformation, because
eclipised conformation has no torsional strain
c)
The eclipsed conformation of ethane is more stable than staggered conformation, even through the eclipsed
conformation has torsional strain
d)
The staggered conformation of ethane is not.- stable then eclipsed conformation, because staggered
conformation has no torsional strain.
27. A is a lighter phenol and B is an aromatic carboxylic acid. Separation of a mixture of A and B can be carried out
easily by using a solution of:
a) sodium hydroxide b) sodium sulphate c) calcium chloride d) sodium bicarbonate
28. In the following question, a statement of assertion is followed by a statement of reason. Mark the correct choice
as :
Assertion: Hybridisation influences the bond length and bond enthalpy in organic compounds.
Reason : More the s character of hybrid orbital, shorter and stronger will be the bond
a) If both assertion and reason are true and reason is the correct explanation of assertion
b) If both assertion and reason are true but reason is not the correct explanation of assertion
c) If assertion is true but reason is false d) If both assertion and reason are false

29. Which of the following will not show cis-loans-isomerism?

a) CH 3 − CH = CH − CH 3 b) CH 3 − CH 2 − CH = CH − CH 2 − CH 3 c)

d)

30. Which of the following acids does not exhibit optical isomerism?
a) Maleic acid b) α-amino acids c) Lactic acid d) Tartaic acid.
31. Two possible stero-structure of CH3CHOH.COOH, which are optically active, are called
a) Diastereomers b) Astropisorners c) Enantiomers d) Mesomers
32. Which one of the following acids would you expect to be the strongest?
a) I - CH2COOH b) CI- CH2COOH c) Br - CH2COOH d) F - CH2COOH
63 PP
33. If on adding FeCl3 solution to acidified Lassaigne solution, a blood red colouration is produced, it indicates the
presence of
20 A
a) S b) N c) N and S d) S and Cl
08
34. Which of the following statements is not correct for a nucleophile?
56 TS

a) Nucleophile is a Lewis acid b) Ammonia is a nucleophile c) Nucleophiles are electron seeking.

d) Nucleophiles are not electron seeking.
80 HA

35. During hearing of a court case, the judge suspected that some changes in the documents had been carried out.
He asked the forensic department to check the ink used at two different places. According to you which technique
can give the best results?
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a) Column chromatography b) Solvent extraction c) Distillation d) Thin layer chromatography

36. Free radicals can undergo

a) rearrangement to a more stable free radical b) decomposition to give another free radical
c) combination with other free radical d) all are correct

37. Which one of the following compounds will be most easily attacked by an electrophile

a) b) c) d)

38. Homolyic fission of the following alkanes form free radicals CH3 - CH3, CH3 - CH2 - CH3, (CH3)2CH - CH3, CH3-
CH2-CH(CH3)2.

( )3Ċ < (CH3 )2Ċ − CH2CH3 < CH3 − ĊH − CH3 < ĊH3 − CH2
a) CH 3

b) (CH 3 ) Ċ < CH 2CH 3 < CH 3 − ĊH − CH 3 < ĊH 2 < (CH 3 ) Ċ

2 3

c) CH 3 − ĊH 2 < CH 3 − ĊH − CH 3 < (CH 3 ) Ċ − CH 2 − CH 3 < (CH 3 ) Ċ

2 3

d) CH 3 − ĊH 2 < CH 3 − ĊH − CH 3 < (CH 3 ) Ċ < (CH 3 ) Ċ − CH 2CH 3

3 2
39. Which of the following is correct with respect to -I effect of the substituents? (R = alkyl)
a) -NH2 > -OR > -F b) -NR2 < -OR < -F c) -NH2 < -OR < -F d) -NR2 > -OR > -F
40. In which of the following, functional group isomerism is not possible?
a) Alcohols b) Aldehydes c) Alkyl halides d) Cyanides
41. Which of the following is the most correct electron displacement for a nucleophilic reaction to take place?

a) b) c) d)

42. Which one of the following compounds is most acidic?

a) Cl-CH2-CH2-OH b) c) d)

43. The process of separation of a racemic modification into d and l-enantiomers is called
a) resolution b) dehydration c) revolution d) dehydrohalogenation
44. The correct IUPAC name of the compound

a) 3-ethyl 4-ethenylheptane b) 3-ethyl 4-propylhex-5-ene c) 3-(l-ethyl propyl) hex l-ene

d) 4-ethyl -3-propyl hex -1-ene
45. Which of the following compounds is not chiral?
a) DCH2CH2CH2C b) CH3CH2CHOCl c) CH3CHDCH2Cl d) CH3CHCTCH2D
46. The IUPAC name of the following compound is
63 PP
20 A
a) trans-2-chloro-3 -iodo-2-pentene
08 b) cis-3-iodo-4-chloro-3-pentene c) trans-3-iodo-4-chloro-3-pentene
56 TS

d) cis-2-chloro-3-iodo-2-pentene
47. The Lassaigne's extract is boiled with concentrated HNO3 while testing for halogens. By doing so, it
a) helps in the precipitation of AgCl b) increases the solubility product of AgCl
80 HA

c) increases the concentration of NO3- ions d) decomposes Na2S and NaCN, formed
48. Distillation under reduced pressure is generally used to purify those liquids which
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a) have very low boiling points b) are volatile

c) have high boiling points and which decompose below their boiling points
d) have a large difference in their boiling points

49. The IUPAC name of is

a) 1-chloro-1-oxo-2, 3-dimethyl pentane b) 2-ethyl-3-methylbutanoyl chloride

c) 2, 3-dimethylpentanoyl chloride d) 3, 4-dimethylpentanoyl chloride
50. Which of the following orders is correct regarding the -I effect of the substituents?
a) --NR2 < ㅡOR > ㅡF b) NR2 > ㅡOR > ㅡF c) --NR2 < ㅡOR < ㅡF d) -- NR2 > ㅡOR < ㅡF
51. Which of the following is the correct order of acidity of carboxylic acids?
(i) CI3CCOOH > Cl2CHCOOH > CICH2COOH
(ii) CH3CH2COOH > (CH3)2CHCOOH > (CH3)3CCOOH
(iii) F2CHCOOH > FCH2COOH > CICH2COOH
a) (i) and (ii) b) (ii) and (iii) c) (i) and (iii) d) (i), (ii) and (iii)

52. 2.18 g of an organic compound containing sulphur produces 1.02 g of BaSO4. The percentage of sulphur in the
compound is:
a) 7.26% b) 8.98% c) 10% d) 6.42%
53. The state of hybridisation of C2, C3, C5 and C6 of the hydrocarbon,

a) sp, sp3, sp2 and sp3 b) sp3, sp2, sp2 and sp c) sp, sp2, sp2 and sp3 d) sp, sp2, sp3 and sp2
54. Which of the foilorving biphenyls is optically active?

a) b) c) d)

55. The correct representation of 4-hydroxy-2-methylpent-2-en-l-al is

| | | |
a) CH 3 − CHOH − CH = CHCH 3 − CHO b) CH 3 − CHCH 3 − CH = COH − CHO
CH 3 |
| | | |
c) CH 3 − C OH − CH = CCH 3 − CHO d) CH 3 − CHOH − CH 2 − CHCH 3 − CHO
56. Geometrical isomers differ in
a) position of functional group b) position of atoms c) spatial arrangement of atoms
d) length of carbon chain
57. Hyperconjugation is 63 PP
a) σ−π conjugation b) noticed due to delocalisation of σ and π bonds c) no bond resonance
d) all the above.
20 A

58. Glycerine can be purified by

08
56 TS

a) vacuum distillation b) simple distillation c) steam distillation d) fractional distillation

59. Some meta-directing substituents in aromatic substitution are given. Which one is most deactivating?
80 HA

a) -SO3H b) -COOH c) -NO2 d) − C ≡ N

60. Number of chiral carbons in β − D − ( + ) − glucose is
a) five b) six c) three d) four
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61. In the following question, a statement of assertion is followed by a statement of reason. Mark the correct choice
as :
Assertion: Glycerol is purified by distillation under reduced pressure.
Reason : Method of distillation under reduced pressure is used to purify liquids having very high boiling points
and those, which decompose at or below their boiling points.
a) If both assertion and reason are true and reason is the correct explanation of assertion
b) If both assertion and reason are true but reason is not the correct explanation of assertion
c) If assertion is true but reason is false d) If both assertion and reason are false

62. Given

I and II are
a) A pair of optical isomers b) Identical c) A pair of conformers d) A pair of geometrical isomers
63. Which method can be applied to separate a mixture of camphor and benzoic acid?
a) Sublimation b) Chemical methods c) Crystallisation d) Extraction with solvent

64. The masses of carbon, hydrogen and oxygen in an organic compound are in the ratio 6: 1: 8 respectively. Which
of the following pairs of formulae correspond to above information?
a) CH2O and CH3CHO b) CH2O and C3H6O c) C3H6O and C2H6O2 d) C3H6O3 and HCHO

65. IUPAC names of the given structures are

(i) E (ii)F
 a) (i) hexane, (ii) 3-methylbutane b) (i) isopentane, (ii) 2,2-dimethylbutane
c) (i) 3-ethylbutane, (ii) isopentane d) (i) 3-methylpentane, (ii) 2-methylbutane.
66. In the following the most stable conformation of n-butane is:

a) b) c) d)

67. The IUPAC name of

is

a) 1, 3 -isopropyl-3 -methyl propane b) 2, 3, 6-trimethyl heptane c) 2, 5, 6-trimethyl heptane

d) 2, 6, 3 -trimethyl heptane
68. For the compound

which of the following IUPAC names is correct?

a) 2-methy-3-ethyl pentane b) 3-ethyl-2-methyl pentane c) 2-ethyl-3-methyl pentane
d) 3-methyl-2-ethyl pentane
69. The IUPAC name of 63 PP
20 A
08
56 TS

is
a) 1-chloro-1-oxo-2,3-dimethylpentane b) 2-ethyl-3-methylbutanoyl chloride
80 HA

c) 2,3-dimethylpentanoyl chloride d) 3,4-dimethylpentanoyl chloride

70. Which among the given molecules can exhibit tautomerism?
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a) III only b) Both I and III c) Both I and II d) Both II and III
71. Arrange the following in increasing order of stability

a) E<D<C<B <A b) E<D<C<A<B c) D<E<C<A<B d) A<E<D<C<B

72. Which of the following is the correct IUPAC name?
a) 3-Ethyl-4, 4-dimethylheptane b) 4, 4-Dimethyl- 3-ethylheptane c) 5-Ethyl-4, 4-dimethylheptane
d) 4, 4-Bis(methyl)-3-ethylheptane

73. 0.92 g of an organic compound was analysed by combustion method. The mass of the U-tube increased by 1.08
g. What is the percentage of hydrogen in the compound?
a) 13.04% b) 52.17% c) 65.21% d) 11.30%

74. Which of the following compounds is isomeric with 2, 2, 4, 4-tetramethylhexane?

a) 3-ethyl- 2, 2-dimethylpentane b) 4- isopropylheptane c) 4-ethyl-3-methyl-4-n-propyloctane
d) 4, 4-diethyl-3-methylheptane
75. Given below are the structures of few compounds with molecular formula C4HIOO. Select metamers from these
structures.
(i) CH3 - O - CH2CH2CH3
(ii) CH3CH2CH2CH2OH
(iii) CH3 - CH2 - O - CH2 - CH3
|
(iv) CH 3 − CHOH − CH 2 − CH 3
a) (i) and (ii) b) (ii) and (iii) c) (i) and (iii) d) (ii) and (iv)
76. The IUPAC name of

a) 3, 4 dimethylpentanoyl chloride b) 1-chloro-1-oxo 2, 3 dimethyl pentane

c) 2-ethyl-3-methyl butanoyl chloride d) 2, 3 dimethyl pentanoyl chloride
77. Which of the following represents 3-methylpenta-1,3-diene?
a) CH2= CH(CH2)2CH3 b) CH2= CHCH(CH3)CH2CH3 c) CH3CH = C(CH3)CH = CH2
d) CH3CH = C(CH3)2

78. Consider the following reactions,

△
I. CH2=CHCOOH ⟶ CH2=CH2 63 PP
II.
20 A
08
56 TS

△
III. CH3CH(COOH)2 ⟶ CH3CH2COOH
80 HA

In which cases, parent compound loses its functional group in preference?

a) I,II b) I,II,III c) II,III d) I,III

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79. Lassaignes test for the detection of nitrogen fails in

a) NH2CONHNH2·HCl b) NH2NH2 ·HCl c) NH2 CONH2 d) C6H5NHNH2.HCl

80. The correct order regarding the electronegativity of hybrid orbitals of carbon is:
a) sp > sp2 < sp3 b) sp > sp2 > sp3 c) sp < sp2 > sp3 d) sp < sp2 < sp3
81. Name of the compound given below is

a) 5- ethyl- 6 -methyloctane b) 4- ethyl- 3 -methylo ctane c) 3- ethyl- 4 -methyloctane

d) 2, 3-diethylheptane
82. In the following question, a statement of assertion is followed by a statement of reason. Mark the correct choice
as :
Assertion: When inductive and electromeric effects operate in opposite directions, the inductive effect
predominates.
Reason: Inductive effect is the complete transfer of shared pair of ππ electrons to one of the atoms
a) If both assertion and reason are true and reason is the correct explanation of assertion
b) If both assertion and reason are true but reason is not the correct explanation of assertion
c) If assertion is true but reason is false d) If both assertion and reason are false

83. In Kjeldahl's method of estimation of nitrogen, nitrogen is quantitatively converted to ammonium sulphate. It is
then treated with standard solution of alkali. The nitrogen which is present is estimated as
a) N2 gas b) NO2 gas c) NH3 gas d) (NH4)SO4 ppt.
84. Heterolysis of a carbon-chlorine bond produces
a) two free radicals b) two carbo cations c) one cation and one anion d) two carbanions.

85. CH3-CHCI-CH2-CH3 has a chiral centre. Which one of the following represents its R-configuration

a) b) c) d)

86. Few pairs of molecules are given below. Which bond of the molecule of the pairs is more polar?
(i) H3C - H, H3C - Br
(ii) H3C - NH2, H3C - OH
(iii) H3C - OH, H3C - SH
(iv) H3C - Cl, H3C - Br
a) C - Br, C - N, C - O, C - Br b) C - Br, C - O, C - O, C - Cl c) C - Br, C - O, C - O, C - CI
d) C - Br, C - O, C - S, C - Br

87. Inductive effect of which atom is taken as zero to compare inductive effect of other atoms?
a) Hydrogen b) Chlorine c) Carbon d) Oxygen
88. The molecular formula of diphenyl methane

63 PP
How many structural isomers are possible when one of the hydrogen is replaced by a chlorine atom?
a) 6 b) 4 c) 8 d) 7
20 A
08
89. Which of the following statement is not correct for a nucleophile?
56 TS

a) Nucleophile is a lewis acid b) Ammonia is a nucleophile c) Nucleophiles attack low electron density sites
d) Nucleophiles are not electron seeking
80 HA

90. Which of the following is an isomer of ethanol?

a) Methanol b) Acetone c) Diethylether d) Dimethylether
91. I-Butene and cyclobutane show
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a) position isomerism b) ring-chain isomerism c) functional isomerism d) metamerism

92. The correct order of increasing reactivity of C - X bond towards nucleophile in the following compounds is:

(CH3 )3C − X, (CH3 ) 2CH − X

a) I>II>IV>III b) II>III>I>IV c) IV>III>I>II d) III>II>I>IV
93. ln the hydrocarbon

The state of hybridization of carbons 1, 3 and 5 are in the following sequence

a) sp2, sp, sp3 b) sp, sp3, sp2 c) sp, sp2, sp3 d) sp3, sp2, sp
94. In steam distillation of toluene, the pressure for toluene in vapour is
a) Less than pressure of barometer b) Equal to vapour pressure of toluene in simple distillation
c) More than vapour pressure of toluene in simple distillation d) Equal to pressure of barometer
95. The number of structural isomers possible from the molecular formula C3H9N is :
a) 4 b) 5 c) 2 d) 3
96. Which one is a nucleophilic substitution reaction among the following?

a) b) c) d)
 97. In the following question, a statement of assertion is followed by a statement of reason. Mark the correct choice
as :
Assertion: Nitroalkanes and alkyl nitrites exhibit functional isomerism.
Reason : Compounds having same molecular formula but different functional groups are called functional
isomers
a) If both assertion and reason are true and reason is the correct explanation of assertion
b) If both assertion and reason are true but reason is not the correct explanation of assertion
c) If assertion is true but reason is false d) If both assertion and reason are false

98. Ionic species are stabilised by the dispersal of charge. Which of the following carboxylate ion is the most stable?

O| | O| | O| |
a) CH 3 − C − O − b) Cl − CH 2 − C − O − c) F − CH 2 − C − O − d)

99. Which type of hybridisation of each carbon is there in the compound?

CH3- CH=CH- CN
a) sp3,sp2,sp2,sp b) sp3,sp2,sp2,sp3 c) sp3,sp2,sp3,sp3 d) sp3,sp2,sp,sp3

100. In the hydrocarbon

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The state of hybridization of carbons 1, 3 and 5 are in the following sequence :
a) sp2, sp, sp3 b) sp, sp3, sp2 c) sp, sp2, sp3 d) sp3, sp2, sp
20 A
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101. Which of the following compounds will not undergo Friedal-Craft's reaction easily?
a) Xylene b) Nitrobenzene c) Toluene d) Cumene
56 TS

102. A sample of 0.50 g of an organic compound was treated according to Kjeldahl's method. The ammonia evolved
was absorbed in 50 mL of 0.5 M H2SO4. The residual acid required 60 mL of 0.5 M solution of NaOH for
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neutralisation. What would be the percentage composition of nitrogen in the compound?

a) 50 b) 60 c) 56 d) 44

103. Name of some compounds are given, which one is not correct in IUPAC system?
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a) b) c) d)

104. The IUPAC name of the compound having formula

a) 3,3,3-trimethylprop-l-ene b) 1,1,1- trimethylprop- 2-ene c) 3,3-dimethylpent -1-ene

d) 2,2-dimethylbut-3-ene.
105. Which one of the following is a free-radical substitution reaction?

a) CH 3CHO + HCN ⟶ CH 3CH(OH)CN b) c)

d)

106. Which of the following species is not electrophilic in nature?

⊕ ⊕ ⊕
a)
NO 2
b) c) BH3 d) H O
Cl 3

107. In the following question, a statement of assertion is followed by a statement of reason. Mark the correct choice
as :
Assertion: The name of the hydrocarbon (CH3)2CHCH2CH2CH( CH3)CH2CH3 is 2,5-dimethylheptane and not
 3,6-dimethylheptane.
Reason: Numbering should be done in such a way that sum of the locants on the parent chain is lowest possible
number.
a) If both assertion and reason are true and reason is the correct explanation of assertion.
b) If both assertion and reason are true but reason is not the correct explanation of assertion
c) If assertion is true but reason is false d) If both assertion and reason are false

108. The correct IUPAC name of the compound

a) 4-Ethyl-3-propyl hex-l-ene b) 3-Ethyl-4-ethenyl heptane c) 3-Ethyl-4-propyl hex-1-ene

d) 3*(1-ethylpropyl) hex-l-ene
109. Given below is a column of adsorbent in which the mixture of compounds A + B + C is placed. When the solvent
is poured through the column, the components are separated depending upon the degree of adsorption. Which of
the given statements is correct?

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20 A
08
56 TS

a) A is the most weakly adsorbed component hence remains near the top
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b) A is the most strongly adsorbed component hence remains near the top.
c) C is the most strongly adsorbed component hence is found near the bottom.
d) B is the most strongly adsorbed component hence is found in the centre of the column.
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110. The process of separation of an organic compound from its aqueous solution by shaking with a suitable solvent is
termed solvent extraction or differential extraction.

The organic compound present in the aqueous layer moves to the organic solvent because
a) the organic substance is more soluble in the organic solvent
b) organic compound being lighter moves in the upper layer
c) organic solvent is insoluble in water hence organic compound moves up
d) from the supersaturated aqueous solution the solute starts diffusing.
111. Structure of the compound whose IUPAC name is 3--ethyl-2-hydroxy-4-methylhex-3-en-5-ynoic acid is :

a) b) c) d)

112. Maximum -I effect is exerted by the group

a) -C6H5 b) -OCH3 c) -CI d) -NO2
113. The most important chemical method to resolve a racemic mixture makes use of the formation of
a) ameso-compound b) enantiorners c) diastereomers d) racemates
114. In the following question, a statement of assertion is followed by a statement of reason. Mark the correct choice
as
Assertion: The order of stability of carbocations is 3° > 2° > 1°.
Reason: Carbon atom in carbocation is in sp3 state of hybridisation.
a) If both assertion and reason are true and reason is the correct explanation of assertion.
b) If both assertion and reason are true but reason is not the correct explanation of assertion
c) If assertion is true but reason is false d) If both assertion and reason are false.

115. Which one of the following compounds is resistant to nucleophilic attack by hydroxyl ions?
a) Methyl acetate b) Acetonitrile c) Dimethyl ether d) Acetamide
116. The correct order of reactivity towards the electrophilic substitution of the compounds aniline (I), benzene (II) and
nitrobenzene (III) is
a) I>II>III b) III>lI>I c) II>III>I d) IIII
117. 0.2 g of an organic compound contains C, H and O. On combustion, it yields 0.15 g CO2 and 0.12 g H2O. The
percentage of C, H and O respectively is:
a) C = 15%,, H = 20%, 0 = 65% b) C = 10%, H = 8.2%, 0 = 81.8% c) C = 12.2%, H = 8.8%, 0 = 79%
d) C = 20%, H = 6.66%, 0 = 73.34%
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118. Which of the following ions is the most resonance stabilised?
a) Ethoxide b) Phenoxide c) Butoxide d) Isopropoxide
20 A
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119. For (i) I-, (ii) Cl- , (iii) Br- , the increasing order of nucleophilicity would be
a) Cl − < Br − < I − b) 1 − < Cl − < Br − c) Br − < Cl − < I − d) l − < Br − < Cl −
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120. Which of the following is a characteristic feature of a free radical?

a) It has a positive charge b) It has a negative charge c) It has all paired electrons
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d) It has an unpaired electron

121. What are the hybridization and shapes of the following molecules?
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(i) CH3F (ii) HC = N

a) (i) sp2, trigonal planar; (ii) sp3, tetrahedral b) (i) sp3, tetrahedral; (ii) sp, linear
c) (i) sp, linear; (ii) sp2, trigonal planar d) (i) sp2, trigonal planar, (ii) sp2, trigonal planar

122. Which of the following is an electrophilic reagent?

+
a) H2O b) NH3 c) OH- d) NO 2

123. Which of the following intermediates contains three pairs of electrons in its valence shell?
a) Carbocations b) Carbanions c) Free radicals d) Both (a) and (b)

124. The correct IUPAC name of the compound

a) 2,3-dimethylheptane b) 5,6-diethyl-3-methyldec-4-ene c) 5-butyl-3-methyloct-4-ene

d) 8-methyl-3-propylhex-3-ene
125. Which of the following possesses a sp-carbon in its structure?
a) CH2==CClㅡCH==CH2 b) CH2==C==CH2 c) CCl2==CCl2 d) CH2==CHㅡCH==CH2