SPHS011 Thermodynamics 2025 Wednesday 14 May PDF
SPHS011 Thermodynamics 2025 Wednesday 14 May PDF
Change in Length:
L = Li T
… coefficient of linear expansion
Li … initial length
L … change in length
T …change in temperature (in centigrade or Kelvin)
Thermal Expansion
Change in Volume:
V = Vi T
… coefficient of volume expansion
Vi … initial volume
V … change in volume,
T …change in temperature (in centigrade or Kelvin)
Thermal Expansion
The change in volume of a solid is also derived
from the linear expansion:
80ºC 80ºC
A B
400 mL
200 mL
Thermal Energy
• Which beaker of water has more
thermal energy?
– B - same temperature, more mass
80ºC 80ºC
A B
400 mL
200 mL
Heat Transfer Methods
Conduction is heat transfer through stationary
matter by physical contact.
(The matter is stationary on a macroscopic scale—we know that
thermal motion of the atoms and molecules occurs at any
temperature above absolute zero.)
Heat transferred from the burner of a stove
through the bottom of a pan to food in the pan is
transferred by conduction.
Conduction
When you heat a metal strip at one end, the heat
travels to the other end.
Cools at the
surface
RADIATION
?
L
Also T = P = PR
A
where R is the thermal resistance.
SUPER-CONDUCTOR??
Q=Pt =(13.3W)(86.400s)=1.15×106 J.
We set this equal to the heat transferred to melt the ice, Q=mLf,
and solve for the mass (m):
Heat Transfer
⚫ How much heat is required to warm 230 g
of ice at -9°C to 70°C of water?
GIVEN: WORK:
m = 230 g = 0.23 kg Q = m·T·Cp
Ti = -9°C m = 230 g = 0.23 kg
Tf = 70°C T = 70°C - 0°C = 70°C
Q total= ? Q = (0.23kg)(70°C)(4190 J/kg·K)
Cwater= 4190 J/kg·K Q = 67 459 J
Cice= 2100 J/kg·K T = 0°C – (-9°C) = 9°C
Lf=3.34 x 105 J/kg Q=(0.23kg)(3.34x105J/kg)
Q=76 820 J
Q=(0.23 kg)(9°C)(2100 J/kg·K)
Q=4347 J
Q total= 67459 J + 76820 J + 4347 J
= 148626 J
Example
solution
Example 2
A metal rod with a diameter of 2.30 cm and a length of 1.10 m has
one end immersed in ice at 0 C and the other end in boiling water
at 100 C. If the ice melts at a rate of 1.32 grams every 175 s, what
is the thermal conductivity of the metal?(Lf = 333 x 103 J/kg)
Assume no heat loss to the surrounding air.
Heat is conducted to the ice at a rate of
T Qc
H = P = A = .
L t
Qc is the heat necessary to melt the ice
T
Qc = A t.
L
The heat needed to melt a given mass of ice is
Q = mice Lf .
Since all the heat conducted by the rod is absorbed by the ice:
T
A t = mice Lf
L