two similar cars A and

circular
AParallel plate capacitor made of surface The kinetic energies of respectively. On
plates is being chareed such that the B are 100 J and 225 J after 1000 m and
applying breaks, car A
stops
charge density on its plates is increasing at a IfF,and are the
constant rate with time. The magnetic field car B stops after 1500 n.
on cars A and B.
forces applied by the breaks
ar1s1ng due to displacement current is : the ratio F/Fy is
respectively, then
() non-zero everywhere with maximum at
the imaginary cylindrical surface ()) (2)
connecting peripheries of the plates 3
(2) zero between the plates and non-zero 3
outside (3) (4)
2
(3) zero at all places
(4) constant between the plates and zero
outside the plates The current passing through the battery in the
given circuit, is:
1.592
2 An electric dipole with dipole moment
5x 106 Cm is aligned with thedirection of a 52
A
uniform electric field of magnitude
2.592
4 x!05 N/C. The dipole is then rotated through 5.52
an angle of 60° with respect to the electric
field. The change in the potential energy of the
1.52
dipole is: 32
(1) 1.2 J (2) 1.5 J
5V
(3) 0.8 J (4) 1.0 J 3
() 2.5 A (2) 1.5 A
3 A ballof mass 0.5 kg is dropped from a height (3) 2.0A (4) 0.5 A
of 40 m. The ballhits the ground and rises
to a height of 10 m. The impulse imparted to Three identical heat conducting rods are
the ball during its collision with the ground is connected in series as shown in the figure. The
(Take g =9.8 m/s2) rods on the sides have thermal conductivity 2K
(1) 0 (2) 84 NS while that in the middle has thermal
(3) 21 NS (4) 7 NS conductivity K. The left end of the
combination is maintained at temperature 37
and the right end at T. The rods are thermally
4 The intensity of transmitted light when a insulated from outside. In steady state,
polaroid sheet, placed between two crossed temperature at the left junction is T, and that
polaroids at 22.50 from the polarization axis at the right junction is T,. The ratio T,/T, is
of one of the polaroid, is (, is the intensity of
polarised light after passing through the first 3T 2K K 2K
polaroid):
lo T
() 8 (2)
16
() (2) 4
(3) (4) 4
2 4
(3) (4)
48 English | 2
| Contd..
 In an oscillating spring mass system, a spring AB 0s a part of an elecrical circuit (see fieure).
is connected tO abox Mlled with sand. As the The potential difterence * - V, at the
box oscillates, sand leaks slowly out of the box instant when current i =2A and is increasing
/second is:
at a rate of I amp
vertically so that the average frequency o(1)
B
and average amplitude A() of the system 1H 202
SV
(2) 10 volt
change with time1. Which one of the following (|) 9 volt
options schematically depicts these changes (3) 5 volt (4) 6 volt
correctly?
10 Aparticle of mass m is moving around the
origin with a constant force F pulling it
towards the origin. If Bohr model is used to
orbit
describe its motion, the radius r of the nlh
depend
and the particle's speed v in the orbit
on n as
()
A(1) vc nl/3
) r c n2/3:
(2) roc n/3: vcn-l/3
(3) r nl/3: cnl/3
o(1) (4) ra nl/3: vc n2/3
11 In some appropriate units, time () and position
(2) A(1) (x) relation of a moving particle is given by
I=x+x. The acceleration of the particle is
2 2
() (2) +
(x+1)³ 2x+1
2 2
o() (3) (4)
(x+2)° (2r+1)
(3)
A()
12 A model for quantized motion of an electron
in a uniform magnetic field B states that the
flux passing through the orbit of the electron
is n(hle) where n is an integer, h is Planck's
constant and e is the magnitude of electron's
charge. According to the model, the magnetic
moment of an electron in its lowest energy
o()
state will be (m is the mass of the electron)
heB heB
(1) Tm
(2) 2Tm
(4) A(I)
he he
(3) (4) 2Tm
TM
48_English | 3 | Contd...
 mass 20kg and lenyh
s
objective of focal length 16 A uniform rod of vertical wallmakino
13 Amicroscope has an leans against asmooth
of focal length 4 cm
and the The other end rests on
Z Cm, eyepiece angle of 60° with it.
If the distance of
distinct The friction force th
tube length of 40 cm, rough horizontal floor.
the magnification in the the floor exerts
on the rod is
VIsIon of eye is 25 cm,
(take g = 10m/s²)
microscope is
(1) 150 (2) 250 (1) 200 N (2) 200 3 N
(3) 100 (4) 125
(3) 100 N (4) 100 3 N
14 There are two inclined surfaces of equal length
(L) and same angle of inclination 45°
with the 17 Two identical charged conducting spheres
horizontal. One of them is rough and the other Aand B have their centres separated by a
times certain distance. Charge on each sphere is a
isperfectly smooth. A given body takes 2 them is E
and the force of repulsion between
as much time to slide dowD on rough surface
than on the smooth surface.The coefficient of
Athird identical uncharged conducting sphere
and
is brought in contact with sphere A first
kinetic friction (H)betwèen the object and then with B and finally removed from both
the rough surface is close to Newforce of repulsion between spheres A and
B(Radii of A and B are negligible compared
(1) 0.5 (2) 0.75
to the distance of separation so that for
(3) 0.25 (4) 0.40 calculating force between them they can be
consideredas point charges) is best given as :
15 A full wave rectifier circuit with diodes (D,) 3F
(1) (2)
and (D) is shown in the figure. If input supply 8
voltage Vin = 220sin (100T) volt, then at
t= 15 msec 3F 2F
(3) (4)
5 3
18 Two cities X and Y are connected by a regular
bus service with a bus leaving in either
direction every T min. A girl is driving scooty
with a speed of 60 km/h in the direction X to
R. Y notices that a bus goes past her
every
30 minutes in the direction of her motion. and
every T0 minutes in the opposite direction.
() D, and D, both are forward biased Choose the correct option for the period T of
the bus service and the speed (assumed
(2) D, and D, both are reverse biased constant) of the buses.
(3) D, is forward biased, D, is reverse () 10 min, 90 km/h
biased
(2) 15 min, 120 km/h
(4) D, is reverse biased, D, is forward
(3) 9 min, 40 km/h
biased
(4) 25 min, 100 km/h
48 English |
| Cont...
 Container has two chambers of volumes 22 Which of the following options represent the
Photcleri curent
19
variation of photoelectric current with property
=2 litres and l = 3 litres separated by a of light shown on the x-axis?
partition made of athermal insulator. The
chambers contains n, = 5 and n, 4 moles of
ideal gas at pressures P =T atm and
P2 2 atm, respectively. When
the partition is
A.
Photelcri curent
removed. the mixture attains an equilibrium
Intensity of light
pressure of:
() 1.4 atm
(2) 1.8 atm
(3) 1.3 atm B.
20

(4) I.6 atm

De-Broglie wavelength of an electron orbiting
Photelcri Curent 609 Intensity of light
in the n 2state of hydrogen atom is close to
C
(Given Bohr radius = 0.052 nm)
(1) 1.67 nm
(2) 2.67 nm
(3) 0.067 nm

Photelcri Curent Frequency of light

68
(4) 0.67 nm D.
0
Frequency of light
21 lo an ac power supply of 220 V at 50Hz, a () A and D (2) Band D
resistor of 20 2. a capacitor of reactance 2552 (3) A only (4) Aand C
and an inductor of reactance 45 2 are
23 A pipe open at both ends has a fundamental
connected in series. The corresponding current
frequency fin air. The pipe is now dipped
in the cireuit and the phase angle between the vertically in awater drum to half of its length.
current and the voltage is, respectively The fundamental frequency of the air column
is now equal to :
() 15.6 A and 300
3f
(2) 15.6 A and 450 () (2) 2/
(3) 7.8 A and 300
(4) 7.8 A and 45° (3)
2
(4) f
48 English | |Contd...
 combination
camera, a of our
27 In a certain
Pand Q. suspended similar thin convex lenses are arranged axially
24 Two identical point mnasses
springs of spring the power ofthe combination
from two separate massless in contact. Thenmagnification in
respectively,
oscillate
and the total comparison
constants k, and kT, magnification (m) for
speeds are the each
vertically.If their maximum the power (P) and
same, the ratio (4 Ap) of
the amplitude A lens will be, respectively
is: (2) pand m4
of mass Q to the amplitude Ap of mass P () 4p and +
4p and 4m (4) p and 4m
(3)
(2) Two gases A and B are filled at the same
28
with movabla
pressure in separate cylinders
k2 pistons of radius ; and rB, respectively. On
(3) (4) k2 both the
k supplying an equal amount of heat to
systems reversibly under constant pressure,
the
pistons of gas A and B are displaced by 16 cm
25 The output (Y) of the given logic and 9 cn, respectively. If the change in their
implementation is similar to the output of internal energy is the same, then the ratio
(an/a gate.
is equal to
AO 2
(1) J3 (2)
BO 4 3
(3) 3
(4) 4
Ao
29 A balloon is made of a material of surface
l) OR (2) NOR
tension S and its inflation outlet (from where
(3) AND (4) NAND gas is filled in it) has small area A. It is filled
with a gas of density p and takes a spherical
26
shape of radius R. When the gas is allowed to
An oxygen cylinder of volume 30 litre has flow freely out of it, its radius r
18.20 moles of oxygen. Afier some oxygen is changes from
Rto 0(zero) in time T. If the speed vr) of
withdrawn from the cylinder, its gauge gas
coming out of the balloon depends on r as
pressure drops to ll atmospheric pressure at t and To Sa AB pY RÒ then
temperature 27°C. The mass of the oxygen
Cwithdrawn from the cylinder is nearly equal to: () a= -B=-1,y=.O= 7
100
Given, R= J motK-!, and
12
(2) a= 7
molecular mass of O, = 32,
atm pressure = 1.01 x 10 N/ml (3) a= 3
) 0.116 kg
2B=-l,y= +1, 8=2
(2) 0.156 kg
(3) 0.125 kg (4) 0.144 kg (4) a =
48 English ]
5a=-B=-1,y=-8=7
6
| Contd...
30 Abob of heavy mass n issuspended by a light 32 The Sun rotates around its centre once in
string of length /. The bob is given a horizontal 27 days. What willbe the period of revolution
if the Sun were to expand to twice its present
velocity vo as shown in figure. If the string gets radius without any external influence? Assume
slack at some point Pmaking an angle from the Sun to be a sphere of uniform density.
the horizontal, the ratio of the speed v of the () 115 days (2) 108 days
bob at point P to its initial speed v is:
(3) 100 days (4) 105 days
33 The radius of Martian orbit around the Sun is
about 4 times the radius of the orbit of
Mercury. The Martian year is 687 Earth days.
Then which of the following is the length of
I year on Mercury ?
m
(1) 172 earth days
(2) 124 earth days
(3) 88 earth days
cos (4) 225 earth days
()
|2+3 sin
34 A wire of resistance R is cut into 8 equal
pieces. From these pieces two equivalent
sin
(2) resistances are made by adding four of these
2+3 sin 0 together in parallel. Then these two sets are
added in series.The net effective resistance of
the combination is:
(3) (sin 9) R R
() 16
(2)
(4) R R
2+3sin (3) (4)
64 32
31 A physical quantity P is related to four 35 A photon and an electron (mass m) have
observations a, b, c and d as follows: the same energy E. The ratio
P= a'b2 lcvd (photon /^electron ) of their de Broglie
The percentage errors of measurement in a, b,
wavelengths is: (c is the speed of light)
cand d are 1%,3%, 2%, and 4% respectively. 2m
The percentage error in the quantity P is
() (2) N2m
(1) 13% (2) 15%
(3) 10% (4) 2% (3) (4) cy2mE
48_ English | bu'telefa | Contd...
 planc clCtroHan.
solid 38 The electric field in a
cut from a larger
36 A sphere of radius Ris wave is given by
shown in the figure. The
Sphere of radius 2R as the smaller 10')V/m
ratio of the moment of inertia of E, =60cos (5x
+1.5×
sphere to that of the rest
part of the sphere
about the Y-axis is : Then expression for the correspondiny
subscripts denote the
magnetic field is (here
direction of the field) :
+1.5x1007
() B, =60cos (5x
.5x 1001
k-2R (2) B, = 60sin (5x + 1
10 )T
(3) B, = 2x10-cos (5x +I.5 z
+1.5x10)
(4) B, =2x107'cos (5x
7 7
() (2)
57 64
7 7
39 Abody weighs 48 N on the surface of the
(3) (4) earth. The gravitational force experienced by
40 the body due to the earth at a height equal to
one-third the radius of the earth from its
37 An electron (mass 9x1031 kg and surface is :
charge 1.6x10-1C) moving with speed c/100 (1) 32 N
(c= speed of light) is injected into a magnetic (2) 36 N
field B of magnitude 9x104Tperpendicular (3) 16 N
to its direction of motion. We wish to apply an
(4) 27 N
uniform electric field E together with the
magnetic field so that the electron does not
40 An unpolarized light beam travelling in air is
deflect from its path. Then (speed of light
c=3x10 ms) incident on amedium of refractive index L.73
at Brewster's angle. Then
(1) E is parallel to B and () both reflected and transmitted light
its magnitude is 27x 102 V m! are
perfectly polarized with angles of
’ reflection and refraction close to 60° and
(2) E is parallel to B and 30°, respectively.
its magnitude is 27x104 VmI
(2) transmitted light is completely
(3) E is perpendicular to B and with angle of refraction close topolarized
30
its magnitude is 27x 104 Vml (3) rellected light is completely
polarized and
the angle of reflection is close
(4) E is perpendicular to B and to 60°
its magnitude is 27x102 Vm-! reflected light is partially polarized and
the angle of reflection is close
to 30"
48 English |
|Contd..
 A2 amp current is flowing through two
41 A constant voltage of 50 V is maintained 44
between the points A and B of the circuit different small circular copper coils having
shown in the figure. The current through the radii ratio I:2. The ratio of their respective
branch CD of the circuit is : magnetic moments wil| be
() 2:1
(2) 4:1
12 22
B (3) I:4
A
(4) I:2
32 D 4Q
W 45 Consider a water tank shown in the figure.
It has one wall at x= L and can be taken
to be very wide in the z direction.
When filled with aliquid of surface tension S
50V and density p, the liquid surface makes angle
(1) 2.5 A (2) 3.0 A ,(0, << l) with the x-axis at x = L. If y(r) is
(3) 1.5 A (4) 2.0A the height of the surface then the equation for
Yx) is :
42 The plates of a parallel plate capacitor are
separated by d. Two slabs of different dielectric
3
constant K, and K, with thickness d and
2
respectively are inserted in the capacitor. Due
to this, the capacitance becomes two times
larger than when there is nothing between the
plates.
If K, =1.25 K,, the value of K, is : x=L
(1) 1.60 (2) 1.33
(3) 2.66 (4) 2.33
(take (x) =sin(x) = tan x)= , g is the
dx
43 Consider the diameter of a spherical object
acceleration due to gravity)
being measured with the help of a Vernier
callipers. Suppose its 10 Vernier Scale
Divisions (V.S.D.) are equal to its 9 Main Scale ()
Divisions (M.S.D.). The least division in the
M.S. is 0.1 cm and the zero of V.S. is at
x=0.l cm when the jaws of Vernier callipers (2)
dx
are closed.
If the main scale reading for the diameter is
M= Scm and the number of coinciding (3) d'y_PE x
vernier division is 8, the measured diameter
after zero error correction, is
() 4.98 cm (2) 5.00 cm (4)
d'y
(3) 5.18 cm (4) 5.08 cm dx
48 English ) 9 | Contd..
 two statemnents :
following 50 Given below are
for the
46 Identify the suitable reagent
diatomi
conversion. Statement I : A hypothetical
stable
molecule with bond order zero is quite
increases, tha
CHO Statement II : As bond order
OCH,’ bond length increases.
choose the
(1) (i) NaBH, (i) HH,0 In the light of the above statements,
most appropriate answer from the options
(2) H/Pd-BaSO4
given below :
(3) (i) LiAlIH,, (i) H/H,0
(1) StatementI is true but Statement II
(4) (i) AlHGBu), (ii) H,0
is false
47 The correct order of decreasing acidity of the (2) Statement Iis false but Statement II
following aliphatic acids is : is true
(1) HCOOH >CH,COOH > (3) Both Statement Iand Statement II
(CH,),CHcOOH> (CH,),CCOOH are true
(2) HCOOH> (CH,),CCOOH > (4) Both Statement Iand Statement II
(CH),CHCOOH > CH,COOH are false
(3) (CH,);CCOOH > (CH,),CHCOOH >
CH,COOH > HCOOH
(4) CH,COOH > (CH),CHCOOH > 51 Out of the following complex compounds,
(CH,),CCOOH > HCOOH which of the compound will be having the
minimum conductance in solution?
48 Which one of the following reactions does
NOT belong to "Lassaigne's test"? (1) [Co(NH3),Jcl;
(1) Na + X + NaX
(2) 2CuO + C
2) [Co(NH;),ci<c1
’ 2Cu+ CO,
(3) Na +C+ N ’ NaCN (3) Co(NH;)}, Cl3)
(4) 2Na + S Na,S (49 Co(NH,), Cl;]
49 If the rate constant of a reaction is 0.03 s 52 Which of the following aqueous
how much time does it take for 7.2 mol
L-I
concentration of the reaçtant to get reduced to exhibit highest boiling point? solution will
0.9 mol L-l9 () 0.01M Na,SO4
(Given: log 2 = 0.301) (2) 0.015M CH,O%
(1) 210s (2) 21.0 s (3) 0.0IM Urea
(3) 69.3 s (4) 23.l s (4) 0.01M KNO,
48 English )
10
| Contd...
 Given below are twO statements :
53 Given below are two statements : one is 56
labelled asAssertion (A) and the other is Statement I: Like nitrogen that can form
labelled as Reason (R).
ammonia, arsenic can form arsine.
Assertion (A) : Iundergoes SE2
reaction faster than CI. Statement II: AntÉmony cannot form
Reason (R) : lodine is a better leaving group antimony pentoxide.
because of its large size. In the light of theabove statements, choose the
Inthe light of the above statements, choose the most appropriate answer from the options
correct answer from the options given below given below :
(1) A is true but R is false (1) Statement I is correct but Statement II
is incorrect
(2) A is false but R is true
(3) Both A and R are true and R is the correct (2) Statement I is incorrect but Statement II
explanation of A is correct
(4) Both A and R are true but R is not the (3) Both Statement I and Statement II
correct explanation of A
are correct
(4) Both Statement Iand Statement II
54 Consider the following compounds :
are incorrect
KO,, H,O, and H,SO,.
The oxidation states of the underlined elements
in them are, respectively. 57 Given below are two statements :
(|) +1, -2, and +4
Statement I : Ferromagnetism is considered
(2) +4, -4, and t6
as an extreme form of paramagnetism.
(3) +1, -1, and t6
(4) +2, -2, and +6 Statement Il : The number of unpaired
electrons in a Cr ion (Z=24) is the same
as that of a Ndt ion (Z = 60).
55 Match List - Iwith List - II
List-I List-II In the light of the above statements, choose
A. Haber process Fe catalyst the correct answer from the options given
below :
B. Wacker oxidation II. PdCl,
C. Wilkinson catalyst II. (PPh;),RhCI| () Statementis true but Statement II
IV. TiCI, with is false
D. Ziegler catalyst
AlCH;), (2) Statement | is false but Statement ||
Choose the correct answer from the optiOns is true
given below :
() A-I, B-II, C-IlI, D-IV (3) Both Statement I and Statement Il
are true
(2) A-I, B-IV, C-I|I, D-||
(3) A-I, B-II, C-1V, D-|| (4) Both Statement Iand Statenent II
(4) A-I, B-IlI, C-1, D-IV are false
48 English ) |Contd...
2 + 2
 statements are true)
following
does 61 Which of the
58 Which one of the following
reactions
Unlike Ga that
has a very high melting
a very low melting point.
A.
NOT give benzene as the product ? point, Cs has electronegativity
scale. the
red hot Iron Tube B. On Pauling are not the same
() values of N and Cl
H-C=C-H at 873 K
Caz, and S2- are all
C. Ar, K+, CE,
H,0 isoelectronic species.
(2) warim
order of the
first
ionization
D. The correct
enthalpies of Na,
Mg. Al, and
Na.
(3) sodalime Si is Si> Al> Mg >
is greater than
E. The atomic radius of Cs
Mo,0, that of Liand Rb.
(4) n-hexane 773K, 10 - 20atm. Choose the correct answer from
the options
given below :
(1) Cand D only
59 Match List - I with List - II (2) A, C, and E only
List-I List-II (3) A,B, and E only
A. XeO; sp'd: linear (4) Cand E only
B. Xef, II. sp; pyramidal
62 The standard heat of formation, in
C. XeOF4 III. sp'd; distorted kcal/mol of Ba² is :
octahedral
[Given : standard heat of formation of so
D. XeF% IV. sp°d: square ion (aq) =-216 kcal/mol, standard heat of
Pyramidal crystallisation of
Choose the correct answer from the options BaSO,(s) = -4.5 kcal/mol, standard heat of
given below : forniation of BaSO,(s) =-349 kcal/mol]
() A-IV, B-II, C-III, D-I () + 133.0 (2) + 220.5
(3) - I28.5 (4) - 133.0
(2) A-IV, B-I, C-l, D-III
(3) A-II, B-I, C-IV, D-III 63 Match List - Iwith List - II
(4) A-I, B-I, C-III, D-IV List-I List-II
(Example) (Type of Solution)
60 How many products (including stereoisomers) A. Humidity Solid in solid
are expected from monochlorination of the B. Alloys I|. Liquid in gas
following compound? C. Amalgams |I. Solid in gas
D. Smoke
HC. IV. Liquid in solid
CH- CH, -CH; Choose the correct answer from the options
given below :
H,C
() A-III, B-1, C-IV, D-I|
(1) 5 (2) 6 (2) A-IlI, B-II, C-I, D-|V
(3) 2 (4) 3
(3) A-II, B-IV, C-I, D-I||
(4) A-II, B-I, C-IV, D-|||
48_Engiish |
12
|Contd..
 We
C(s) +2H,(g)’CH,(g): AH=-74.8 kJ mol-! 66 Total number of possible isomers (both
64
structural as well as stereoisomers) of cyclic
Which of the following diagrams gives an
accurate representation of the above reaction? ethers of molecular formula C,H,O is :
[R ’ eactants; P ’ products] (|) 10 (2) |
(3) 6 (4) 8
Energy
(kJ mol 74.8
R
(1)
P 67 For the reaction A(g) 2B(g). the
backward reaction rate constant is higher than
Reaction progress the forward reaction rate constant by a factor
of 2500, at 1000K.
Energy
(kJ mol)
P [Given : R=0.0831 L atm mol-! K
R 74.8 Kp for the reaction at 1000 K is
(2) (1) 0.033 (2) 0.021
Reaction progress (3) 83.I (4) 2.077 x105
Energy
(kJ mol| R 68 The ratio of the wave lengths of the light
absorbed by a Hydrogen atom when it
74.8T| P undergoes n =2 ’n=3andn=4 n=6
(3)
transitions, respectively. is
SReaction progress
1
() 7 (2) 4
Energy
(kJ mol
R
(3) (4)
(4) 36 16
Reaction progress
69 If the molar conductivity (Am) of a
65 Sugar X 0.050 mol L- solution of amonobasic weak
acid is 90 S cm² mol-, its extent (degree) of
A. is found in honey.
dissociation will be
B. is a keto sugar.
C. |Assume A =349.6 S cm² mol-! and
exists in a and B - anomeric forms.
D. is laevorotatory. A = 50.4S cm² mol-!.]
X* is :
(1) 0.225 (2) 0.215
(1) Maltose (2) Sucrose
(3) 0.115 (4) 0.125
(3) D-Glucose (4) D-Fructose
48 English | 13
IConts
 moles of liquidY|74 Energy and radius of first Bohr orbit of
70 S moles of liquid X and J0 pressure of Het and Li2 are
make a solution having a vapoUr
Xand Y [Given Ry -2.18 x 10-18 J, a, =52.9 pm)
70 torr. The vapour pressures of pure
Which of
are 63 torr and 78 torr respectively. () E,(L0?) = -19.62x10-l6 J;
regarding the described
the tollowing is true r(Li?)= 17.6 pm
solution?
(1) The solution is ideal.
E,(He)= -8.72x 10-l6 J:
than the
(2) The solution has volume greater r,(He*) =26.4 pm
sum of individual volumes. (2) E,(Li?t) = -8.72× 10-l6 J;
(3) The solution shows positive deviation. r,(Li?)= 17.6 pm
deviation.
(4) The solution shows negative E,(He) = -19.62x l0-l6J;
71 Among the following, choose the ones with r,(He) = 17.6 pm
equal number of atoms. (3) E,(Li?)=-19.62x 10-18 J;
A. 212 gof Na,CO, (s) [molar mass = 106 g] r,(Li?)= 17.6 pm
B. 248 g of Na,O (s) [molar mass = 62 gl E,(He*) =-8.72x10-18 J;
C. 240 g of NaOH (s) [molar mass 40 g|
D. 12 gof H, (g)[molar mass =2 gl r(He)= 26.4 pm
E. 220 g of CO,(g) [molar mass = 44 g] (4) E,(Li?) =-8.72x 10-18 J:
Choose the correct answer from the options r,(L²) 26.4 pm
given below :
E,(He*) =-19.62x10-18 J;
(1) B, C, and D only
(2) B, D, and E only r,(He) = 17.6 pm
(3) A, B, and C only
(4) A, B, and D only 75 Among the given compounds I-III, the correct
order of bond dissociation energy of C-H bond
72 Which of the following are paramagnetic? marked with * is :
A. [NiCI4 ] B. Ni(CO),
H
H
C.
[Ni(CN), D. Ni(,0), " H
E. Ni(PPh3)4 H
Choose the correct answer from the options
given below:
() Aand Donly () |>||>T (2) I| >|||>I
(2) A, D and E only (3) I>|> || (4) |> I| > I||
(3) A and C only
(4) Band E only 76 Dalton's Atomic theory could not explain
73 If the half-life (t,)for a first order reaction which of the following?
is I minute, then the time required for 99,9% () Law of multiple proportion
completion of the reaction is closest to : (2) Law of gaseous volume
() 5minutes (2) 10 minutes (3) Law of conservation of mass
(3) 2 minutes (4) 4 minutes
(4) Law of constant proportion
48 _English| 14 |Contd...
77 ldentify the correct orders against the property 81 Which one of the following compounds does
mentioned
not decolourize bromine water?
A. H,O> NH, > CHCI, - dipole moment
B. XeF > XeO > XeF, number of lone () o-CH-CH,
pairs on central atom
C. 0-H> C-H> N-0 bond length (2) (o)-NH,
D. N, > O, > H, - bond enthalpy (3)
Choose the correct answer from the options
given below :
() A, Conly (2) B, Conly (4) (o-OH
(3) A, D only (4) B, D only
82 Predict the major product P' in the following
78 Match List Iwith List II. sequence of reactions
List I List II (i) HBr, benzoyl peroxidc
CH,
(Name of (Deficiency (ii) KCN P
Vitamin) disease) (ii) Na (Hg)/C,H,OH (Major)
A. Vitamin B Cheilosis
B. Vitamin D II. Convulsions NC
-CH,
C. Vitamin B, III.Rickets (2) CH,
D. Vitamin B, IV. Pernicious anaemia ()
NC
Choose the correct answer from the options
given below : -CH, CH,
(|) A-II, B-II, C-I, D-|V (4)
(2) A-IV, B-|II, C-lI, D-I (3)
CH,NH,
(3) A-I, B-||I, C-II, D-IV
(4) A-IV, B-|II, C-l, D-|
83 Match List Iwith List II
79 The correct order of decreasing basic strength List I List II
of the given amines is : (Mixture) (Method of
(1) N-ethylethanamine > ethanamine > Separation)
N-methylaniline > benzenamine A. CHCI, + 1. Distillation
(2) benzenamine > ethanamine > CH,NH, under reduced
N-methylaniline > N-ethylethanamine
pressure
(3) N-methylaniline > benzenamine > B. Crude oil in |I. Steam
ethanamine > N-ethylethanamine
petroleum distillation
(4) N-ethylethanamine > ethanamine
benzenamine > N-methylaniline industry
C. Glycerol from I|I. Fractional
80 The correct order of the wavelength of light spent-lye distillation
absorbed by the following complexes is, D. Aniline - water IV. Simple
3+ distillation
A. [Co(NH3), B. [cofCN),I Choose the correct answer from the options
given below :
c [Cu(H;0),]j" D. (i(H,0),"
Choose the correct answer from the options
() A-IlI, B-V, C-I, D-||
(2) A-I, B-IV, C-I1, D-I
given below:
(3) A-V, B-II, C-I, D-l|
(1) C
<D<A <B (2) C<A <D <B (4) A-1V, B-III,C-lI, D-I
(3) B<D<A<C (4) B<A<D <C
48 English | 15 | Contd...
 electronic
87 Match List I with List II
following
84 Which among the elements?
configurations belong to main group List I List II
B. [Ar]3d'482
A. [Ne]3s' (on) (Group Number
D. (Ar3ql°4s!
C. [Krl4d°ss?sp5 in Cation Analysis)
E. [Rn]5r°6d7s A. Co2+ Group-I
option
answer from the
Choose the correct B. Mg2t II. Group-lli
given below :
() D and E only C. Pb2+ III. Group-IV
(2) A, C and D only D AJ3+
IV. Group-VI
(3) Band E only
(4) A and C only Choose the correct answer from the options
given below :
85 Which one of the following compounds can
exist as cis-trans isomers? (1) A-III, B-II, C-IV, D-I
(1) 1,1-Dimethylcyclopropane (2) A-III, B-II, C-I, D-IV
(2) 1.2-Dimethylcyclohexane
(3) Pent-1-ene (3) A-III, B-IV, C-II, D-I
(4) 2-Methylhex-2-ene (4) A-III, B-IV, C-1, D-1I
86 Phosphoric acid ionizes in three steps with
their ionization constant values 88 Higher yield of NO in
and
Ka Kay Ka,: respectively, Ng(g)+0,(g)2NO(g) can be
while K is the overall ionization constant. obtained at
Which of the following statements are true?
A. log K= log K + log K,+ log K,. [ AH of the reaction = + 180.7 kJ mol-!]
a
ag
A. higher temperature
B. HPO4 is a stronger acid than H,POz B. lower temperature
and
HPO C. higher concentration of N,
C. K,a >K
a3 D. higher concentration of O,
+ ha Choose the correct answer from the options
D. Ka 2 given below:
Choose the correct answer from the
given below: options (1) B, C, D only
(1) B, Cand D only (2) A, C, D only
(2) A, B and C only
(3) A and B only (3) A, D only
(4) A and C only
(4) B, Conly
48_English |
16 [ Cont...
 89
Given below are two statements :
Statement I:
Benzenediazonium
by the reaction of aniline with salt is
prepared
acid at 273 -278 K. It nitrous
the dry state.
decomposes casily in
Statement lI : Insertion of iodine into the
benzene ring is difficult and hence
iodobenzene is prepared through the reaction
of benzenediazonium salt with KI.
In the light of the above statements, choose the
most appropriate answer from the options
given below
I) Statement Iis correct but Statement I
is incorrect
(2) Statement I is incorrect but Statement I
is correct
(3) Both Statement Iand Statement I|
are correct
(4) Both Statement Iand Statement II
are incorrect
90 The major product of the following reaction is:
(i) CH,MgBr
(excess)
(ii) H,0*
H,C OH OH
(1) CH,
CH,
(2)
Chhs OH
(3) CN
CH, OH
(4) CHs
1
48_English