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2monthly Test Paper Class 12 (April)

This document is a monthly assessment test for 12th-grade chemistry students, consisting of multiple sections including multiple-choice questions, short answer questions, and problem-solving tasks. It covers various topics such as colligative properties, Raoult's law, osmotic pressure, and the behavior of solutions. The test is designed to evaluate students' understanding and application of key chemistry concepts within a time limit of 1.5 hours.

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7 views

2monthly Test Paper Class 12 (April)

This document is a monthly assessment test for 12th-grade chemistry students, consisting of multiple sections including multiple-choice questions, short answer questions, and problem-solving tasks. It covers various topics such as colligative properties, Raoult's law, osmotic pressure, and the behavior of solutions. The test is designed to evaluate students' understanding and application of key chemistry concepts within a time limit of 1.5 hours.

Uploaded by

deepak839910
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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Monthly Assessment test

CLASS: 12TH MAX.MARKS: 35M


SUB: CHEMISTRY TIME: 1 ½ h
SECTION-A (8x1= 8M)
1.Which of the following is temperature dependent?

A) Molality B) Molarity C) Molefraction D) ppm

2. Calculate the molarity of the following solution: 30 mL of 0.5 M H2SO4 diluted to 500 mL.

A. 0.04 B. 0.03 C. 0.02 D.0.08

3.Which of the following is not a colligative property?

A. LVP B. RLVP C. ∆Tf D. VP of a liquid

4. The vapour pressure of pure liquids A and B are 450 and 700 mm Hg respectivelyat 350 K . Find
out the composition of the Vapour phase, if total vapour pressure is 600 mm Hg ?
A. 0.4, 0.6 B. 0.3, 0.7 C. 0.5 ,0.5 D. 0.2 ,0.8

5. A solution is obtained by mixing 300 g of 25% solution and 400 g of 40% solution by mass.
Calculate the mass percentage of the resulting solution?

A. 0.152 B.0.243 C. 0.876 D. 0.335

6. Which of the following aqueous solutions should have the highest boiling point?

(A) 1.0 M NaOH (B) 1.0 M Na2SO4 (C) 1.0 M NH4NO3 (D) 1.0 M KNO3

7. Assertion (A): The boiling point of 0.1M urea solution is less than that of 0.1M KCl solution.

Reason(R) : Elevation in boiling point is directly proportional to number of solute particles in the
solution.

A. Both A and R are true and R is the correct explanation of A


B. Both A and R are true but R is not the correct explanation of A.
C. A is true but R is false. D. A is false but R is true.

8. Assertion : Azeotropic mixtures are formed only by non-ideal solutions and they may have
boiling points either greater than both the components or less than both the components.

Reason: The composition of the vapour phase is same as that of the liquid phase of an azeotropic
mixture.

A. Both A and R are true and R is the correct explanation of A


B. Both A and R are true but R is not the correct explanation of A.
C.A is true but R is false. D.A is false but R is true.

SECTION-B (3x2=6M)
9. A) Why do gases always tend to be less soluble in liquids as the temperature is raised?

B) Gas(A) is more soluble in water than Gas(B) at the same temperature. Which one of the two
gases will have the higher value of KH and why?

10. The partial pressure of ethane over a solution containing 6.56 × 10 -3 g of ethane is 1 bar.
If the solution contains 5.00 × 10-2 g of ethane, then what shall be the partial pressure of the
gas? (2M)
11. How does sprinkling of salt help in clearing the snow-covered roads in hilly areas?
Explain the phenomenon involved in the process.
SECTION – C (4X3=12M)
12. A) State Raoults law of non-volatile solute in a liquid?
B) The vapour pressure of pure benzene at a certain temperature is 0.850 bar. A non-
volatile, non-electrolyte solid weighing 0.5 g when added to 39.0 g of benzene (molar mass
78 g mol-1). Vapour pressure of the solution, then, is 0.845 bar. What is the molar mass of
the solid substance?
13. A) Define the following terms: (i) Elevation in boiling point (ii) Depression in freezing point. (1M)
B) Will the elevation in boiling point be same if 0.1 mole of sodium chloride or 0.1 mole of cane
sugar is dissolved in 1L of water? Explain. (2M)

14. A) On mixing liquids X and Y , Volume of the resulting solution decreases. What type of
deviation from Raoults law is shown by the resulting solution? What change in temperature
would you observe after mixing liquids X and Y?
B) What is maximum bp and minimum bp azeotropes? Give examples.
15. What is Osmotic pressure? At 300 K, 36 g of glucose present in a litre of its solution has an
osmotic pressure of 4.98 bar. If the osmotic pressure of the solution is 1.52 bars at the same
temperature, what would be its concentration? (3M)
SECTION – D (1x4=4M)
16. The osmotic pressure associated with the fluid inside the blood cell is equivalent to that of 0.9%
(mass/volume) sodium chloride solution, called normal saline solution and it is safe to inject
intravenously. On the other hand, if we place the cells in a solution containing more than 0.9%
(mass/ volume) sodium chloride is called hypertonic. If the salt concentration is less than 0.9%
(mass/volume), the solution is said to be hypotonic.

A) What are isotonic solutions? Give example.

B) 200 cm3 of an aqueous solution of a protein contains 1.26 g of the protein. The osmotic pressure
of such a solution at 300 K is found to be 2.57 × 10-3 bar. Calculate the molar mass of the protein.

C) What will happen to RBC”s when placed in

a) 1.2 % (w/v) NaCl solution b) 0.4 % (w/v) NaCl solution.


SECTION- E (1x5= 5M)
17. A) The Vanthoff factor value when (1M)
a) CH3COOH is dissolved in water. b) CH3COOH is dissolved in benzene.
B) a) What is meant by positive and negative deviations from Raoult's law and how is the
sign of ∆H and ∆V related to positive and negative deviations from Raoult's law? (1M)
b) What role does the molecular interaction play in a solution of alcohol and water ? (1M)
C) A 5% solution (by mass) of cane sugar in water has boiling point of 393K. Calculate the
freezing point of 5% glucose in water if freezing point of pure water is 273 K. (2M)

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