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Charitha Dissanayake
B.Sc.Engineering (Hon's)

wOHhk fmdÿ iy;sl m;% ^Wiia fm<& úNd.h" 2023 ^2024 ckjdrs&
General Certificate of Education (Adv. Level) Examination, 2023 (January 2024)
nyqjrK W;a;r m;%h
MCQ Answer Sheet
Fast Track - 04 MARKING SCHEME

04.Cu(s) + 4HNO3(aq) Cu(NO3)2(aq) +2NO2(g) + 2H 2O(l)

01.

Zn(s) + 4HNO3(aq) Zn(NO3)2(aq) + 2NO2(g) + 2H2O(l)

2Cu(NO3)2(aq) + 4KI(aq) 2CuI(s) + I2(aq) + 4KNO3(aq)

I2(aq) + 2Na2SO3(aq) 2NaI (s) + Na2S4O6(aq)

P1= mdIka fY%AKsfha jeäu ixLHd;h iys; úlsrKhg wod<

ms;a;, kso¾Ylfha ;snQ Cu ujq, .Kk x hehs .ksuq'
bf,lafg%daK ixl%uKh
jehjQ Na2S2O3 ujq, .Kk= 0.2moldm-3 ´ 20 ´ 10-3dm3
P2= ndu¾ fY%aKsfha jeäu ixLhd;h iys; úlsrKhg wod,
x/10 = 4 ´ 10-3 mol
bf,lafg%daK ixl%uKh
x = 0.04 mol
B 0= ndu¾ fY% A K s f ha È.= u ;rx. wdhduh iys ; úls r Khg
Cu ialkaOh = 0.04mol ´ 63.5gmol-1
wod, bf,la fg%daK ixl%uKh
= 2.54 g
EB = EB - EP
0 1 1
Zn ialkaOh = 3.19g - 2.54g
E = hf
= 0.65 g
hf / =hf1 - hf2
\f /=f1 - f2 Zn ujq, .Kk =
c =fl = 0.01 mol

l = Cu mol : Zn mol
0.04 : 0.01
lBO = =
4:1
ms<s;=r - 1 ms<s;=r -5

02. fuys§ CO ys C u; mj;sk tlir hq.,h ¨úia wï,hla jk

05.Ca 2+, Cl-, S2- yd Ar iu bf,la fg%daksl m%fNao fõ' tuksid
BH3 g odhl úh hq;=h' CO ys O u; Ok wdfrdamKhla mj;sk
fïjdfha kHIaál wdfrda mKh ^mrudKql l%u dxlh& wvqjk
neúka tys tlir hq .,h ndysrg odhl fkdfõ'
ms< sfj,g wrh jeä ùu isÿ fõ'

ms<s;=r -3 ms<s;=r -2

06. ;%s;aj nkaOk < oaú;aj nkaO k È. < ;ks nkaOk È.

03.

(a) yd (d) j, ;%s;aj nkaOk ;snqKo a ys § C º C w;r ;%s;aj

4-cyano-6-oxo-3-phenylhexanoic acid nkaOkh d j, C º N j,g jvd È.ska jeä fõ' ukao C g jvd
ms<s;=r -2 N j, mrudKql wrh wvq ksidh'

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fnkaiSka j,§ nkaOk È. oaú;aj nkaOkhg jvd È.ska jeä fõ' 09. CH 4 + 2O 2 CO 2 + 2H 2O
fnkaiSkaj, mj;s kafka wdxYs l oa ú;aj nkaOkhla ùu fuhg CH 4 1mol ka
= 900kJ
fya;=jhs'
jdIamS lrKh jk c, ialkaOh m g f,i .ksuq '
d<a<c<e<b
ms<s;=r -5
wjfYdaIKh lrk ;dmh = +

07. ÿn, tal NdIañ l wï,h HA kï

250C 1000C olajd
HA (aq) + NaOH NaA (aq) + H2O(l)
r;aùug wjYH ;dmh (Q)= mcq
jeh jQ NaOH mol = 0.15moldm ´ -3
-1 -1
= kg ´ 4200 Jkg K ´ 75K
= 1.8375 ´ 10-3mol = 315m J
25cm ;=< ;snQ H mol= 1.8375 ´ 10 mol
3 + -3
jdIamùug wjYH ;dmh = mol ´ 44 kJmol-1

[H +] = = 0.0735moldm-3 = ´ 103 J

pH = -log10[H 3O+(aq)] msgjQ ;dmh = 315m + ´ 103

= -log10 (0.0735)
900 ´ 103 = 315m + ´ 103
= 1.134
m = 326g
ms<s;=r -5
ms<s;=r -5

08.(1) " (2) , (3) yd (5) hka;%K mshjr ksrjoH fõ' (4) hdka;%Kh
10. (1) m%ldYh i;H fõ' S4O2-6 ys ksjerÈ ¨úia jHQ yh my;
my; mßÈ fjkia úh hq;=h '
mßÈ jk w;r tys O iïnkaO S mrudKq foflysu
TZlrK wxlh +5 ne.ska fõ'

(2) m%ldYh i;H fõ' fuys S jgd nkaOk 4 la yd tlir

hq.,a 1la f,i úl¾IK tall 5la mj;S '
(3) ys fnkaiSka khsf g%da lrKfha § iEfok weÍks hï

whkfha fm%dafgdakhla bj;a ùu my; wdldr folgu ±laúh

yel' iïm%h qla; jHQyhla i,ld"

(3) m%ldYh i;H fõ' ir, WodyrK f,i SO3, H2SO4,
S2O2-3 ie,lsh yel' S mj;skafka ;=kajk wdj¾;fha
neúka S ys ixhqc;d ljpfha bf,lafg%daK 8 g jvd
;nd.; yel'
(4) m%ldYh wi;H fõ'
iïm%h qla ; uqyqu i,ld"

NH3 ys yevh msróvdldr jqj o" NH3 ys N jgd úl¾IK

tall 4 la mj;sk neúka N jgd bf,lafg%daK hq. ,
cHdñ;sh p;=ia;,Sh fõ'

ms<s;=r -4

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(5) m%ldYh i;H fõ' (2)

fuys§ B ys uqyqïlrKh sp2 isg sp3 olajd fjkia jqjo

N ys uqyqïlrKh fjkia fkdfõ'
ms<s;=r -4
(3)
11. (1) m%ldYh i;H fõ'
(2) m%ldYh i;H fõ'
f (A - A) > f (A - B) <f (B - B)
(3) m%ldYh i;H fõ' fuf,i A - A w;r wdl¾IK n, yd B
- B w;r wdl¾IK n, j,g jvd A - B w;r wdl¾IK n,
ÿn, ùu ksid mßmQ¾K ødjKhlg jvd jeä A yd B wKq
ixLHdjla jdIa m l,dmhg .uka lrhs'
túg jdIam l,dmh ;=< A yd B ys wdxYsl mSvk yd uq¿
jdIam mSvkh jeä fõ'
(4) fuu ødjH ñY% lsÍfï§ iM, wka;¾ wKqql wdl¾IK n, (4)
ì`o fy,S u la is ÿjk ks i d tka ;e,a ms úm¾hdih ;dm
wjfYdaIl fõ' i;H fõ'
(5) wi;Hhs ' jvd;a u jdIamYS ,S jkafka B fõ' PB0 > P0A
ùfuka th meyeÈ,s fõ'
ms<s;=r - 5

12. N2O3(g) NO(g) + NO2(g)

n n n

PV = nRT, V yd R ksh; neúka"

P µ nT (5)
1.25 x 105Pa µ n ´ 250K
P µ 2n ´ 300K
ka"

P = 3 ´ 105 Pa
ms<s;=r -1

13. (1)

tfukau fuys§ ,efnk ;D;shs l uOHidrh NaOH fyda

Na2CO 3 iu`. m%;sl%s hd fkdlrhs'
ms<s;=r - 5

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14. m<uq fm< m%;sl %s hdjloS" (2) m%ldYh i;H fõ' wefkdavfha § yd lef;davfha § isÿjk
t = m%;sls%hd my; mßÈ fõ'
- wefkda vfha § -
40s = –
2Cl (aq)
Cl2(g) + 2e
-2 -1
K1 = 1.7325 x 10 s - lef;davfha § -
–
Y+kH fm< m%;sl%sh djloS" 2e + 2H 2O(l) H2(g) + 2OH (aq)

(3) wi;H fõ' wefkda v l=àrfha isg lef;dav l= àrhg Na+

t =
–
.uka l< o lef;dav l= àrfha is g wefkdav l= àrhg OH
20s = whk nyqwjhúl mg,h yryd .uka fkdlrhs ' m%ldYh

K2 = 3.465 x 10-2moldm-3s-1 wi;H fõ'

(4) m%ldYh i;H fõ'
= = 0.5mol-1dm3 (5) m%ldYh i;H fõ' wefkdav m%;sls%hdfjka Cl
–
Cl2 njg

ms<s;=r - 1 m;a lrñka wdfrda mK bj;alrk w;r lef;davfha § H2O

_
OH njg m;a lrñka wdfrda mK ,ndfoa'

15. ixfhda.fha m ialkaOh ;=< ujq, .Kk x hehs .ksuq' ms<s;=r - 3

KHC2O4. H2C2O4. 2H 2O ys mj;sk H + ujq, = 3x

18. (1) m%ldYh wi;H fõ' Sc wdka;ßl uQ ,øjHhls '
25cm3 l mj;sk H+ ujq, = 3x / 10
(2) m%ldYh i;H fõ'
+ Na+(aq) + H2O(l)
Cr(OH)3(s) [Cr(OH)6]3-(aq)
fld< fld<
jeh jQ NaOH ujq, = 0.12moldm-3 H 24 H 10-3dm3
= 2.88 H 10-3mol (3) [Co(NH3)6]2+ ly ÿUqre meye;s fõ' m%ldYh i;Hhs'

x = 9.6 H 10-3mol (4) m%ldYh i;H fõ'

wjYH ialkaOh (m) = 9.6 H 10-3mol H 254gmol-1 Cu2+ c,Sh ødjK j,§ H2S iu`. CuS kï l¿ wjlafIamh
,nd fohs' kuq;a Co2+ yd Ni2+ NdIañl ødjK j,§ jeä S2-
= 2.438g » 2.44g
idkaøKhla hgf;a NiS yd CoS f,i wjlafIa m fõ'
ms<s;=r -4
(5) m%ldYh i;H fõ'
Fe3+ e4 ([Fe(CN)6])3 fyda KFe[Fe(CN)6]
Fe
16. H2(g) + Cl2(g) 2HCl(g)
fm%Yshka ks,a
DH q= 2DHqf (HCl(g))
ms<s;=r - 1
= 2 x -92 kJmol-1
= -184kJmol-1 19. R = K[X]a [Y]b

DS q = SqM, - Sqm%;sl%shl
´ ´
= 2x187 JK-1mol-1 -(131JK-1mol-1 +223JK-1mol-1)
= +20JK-1mol-1 ´ ´

DG q= DHq - TDSq ´ ´
-1 -1 -1
= -184kJmol - (300K ´ +0.02kJmol K )
= =
= -184kJmol-1 - 6kJmol-1
b=2 a=1
= -190kJmol-1
ka
ms<s;=r -1
K =

17.(1) m%ldYh i;H fõ' wefkda v yd lef;dav l=àr nyq wjhúl = 6.122 ´ 1010mol-2dm6s-1
mg,hlska fjkalr we;s w;r th yryd legdhk yqjudre ms<s;=r -2
úh yelsh'

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20. N2(g) + 3H2(g) 2NH3(g)
(1) KD =
wdrïNl n 3n
m%;s l%shd l< 0.5n 1.5n =
iu;=,s; 0.5n 1.5n n
= 9.64 m%ldYh wi;H fõ'
3n
(2) wi;H fõ'
=

PN = XN . PT (3) KD =
2(g) 2(g)

= ´P = =

PH
2(g)
= ´P = = 0.1 m%ldYh wi;H fõ'

PNH
3(g)
= ´P = (4) KD =

=
p
= 10 m%ldYh i;H fõ'
ms<s;=r 2
(5) KD =

=
21. [Fe(OH)2 (OH2)4]Cl
= 1.82 m%ldYh wi;H fõ'
tetraaquadihydroxidoiron(III) chloride
ms<s;=r - 4
ms<s;=r - 5

24. wKql iQ;%h g fkd.e,fmk neúka (5) ms< s;= re bj;a fõ' 1, 2,
22. = 3, 4 ixfhda . ish,a, Na iu`. m%; sl% sh d lr H2 jdhqj ,nd foa'

µT fgd,kaia m%;sldrlh iu`. m%;sl%shdlr ߧ levm; ,ndfokafka

V1 µ 300K we,aä yhs v u`. sks" 1 yd 4 ms<s ;=r e bj;a fõ'
V µ 400K 2 iy 3 w;ßka a - H mj;skafka 2 ixfhda.fha muKla neúka
2 muKla iajhx ix>Kkhg Ndckh fõ'
ka =
ms<s;=r - 2
V =

ms<s;=r -2 25. fuys § moaO;s h iu;=,s; ùug kï"

= ksh;hla úh hq ;=h '

23.c,h ;= < Wmßu lef*a aka idkaøKh =
(1) = 0.2 (2) = 0.2
=

CHCl3 ;=< Wmßu lef*aka idkaøKh= (3) = 0.2 (4) = 0.2

= (5) = 0.188
vhs t;s,a B;¾ ;=< Wmßu lef*a ka idkaøKh"
ms<s;=r -5
= =

fnkaiSka ;=< Wmßu lef*a ka idkaøKh"

26. idka ø HNO3 yuqfõ Br- Br2 njgo I- I 2 njgo
= TZlrKh fõ' túg HNO3 u`.ska NO2 msg fõ' fïjd ish,a, ;o

= meye jdhq fõ' túg (4) ms<s ;=r bj;a fõ'

;. H2SO4 yuqfõ wjla fIamhla ,ndÿka neúka A, ZnI 2 úh
fkdyel' ZnSO4 c, ødjH fõ' (3) ms<s;=r bj;a fõ'

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A, NaOH yuq fõ wjla f Ia mhla ÿka neúka A, BaBr2 úh CrO 2 ÿn, wdï,s l MnO2 WNh.=KS
fkdyel' Ba(OH)2 c, ødjH fõ' (1) ms<s;=r bj;a fõ' Sr(OH)2 CrO 3 wdï,sl MnO3 ÿn, wdï,s l
o uo jYfhka ødjH fõ'
Mn2O7 wdï,sl
flfia kuq; a ,enqKq wjlafIamh jeämq r NaOH yuqfõ Èh jQ ms<s;=r -2

neúka A, SrI2 úh fkdyel' (2) ms<s;r

= bj;a fõ' jeämqr laIdrh
30.(1) m%ldYh i;H fõ'
yuqfõ Èhjkafka Pb(OH)2 jeks WNh.=KS yhsfv%dlaihsv fõ' -Cl ÿn, úl%S hldÍ ldKavhla jk w;r -CH3 ldKavh
Pb2+(aq) PbSO4(s) ÿn, il%shldÍ ldKav hla fõ' fnkaiska j,hg wdfoaY ù
iqÿ
we;s ldKavfha il%sh iajNdjh jeä jk ;rug ixfhda .h"
Pb2+ Pb(OH)2(s) Na2[Pb(OH)4](aq)
iq ÿ NaOH bf,lafg%da*s,sl wdfoaY m% ;sl%shd isÿlrk fõ.h jeä fõ'

ms<s;=r - 5 (2) i;H fõ'

27. iS>%;djh (R) = K[A2B4(g)]x

6 ´ 10-4moldm-3s-1 = K[2.4 ´ 10-2moldm-3]x fuys (CH3)2CO ys ldnke,a ldnkag ne£ we;s we,als,a
-4 -3 -1 -3 -3 x
2 ´ 10 moldm s = K[8 ´ 10 moldm ] ldKav fol ksid ldnke,a ldnkays Ok O%eùlrKh H2CO
ka" 3 =3 x
ys ldnke,a ldnka ys Ok O%eùlrKhg jvd wvqfõ' \
x =1 CH 3COCH 3 ys kshqla,sfhda*s,sl wdl,kh ùfï yels hdj
6 10 moldm s wvq ù m%;sls% hd YS>%;dj wvq fõ'
ka" K =
2.4 10 moldm
= 2.5 ´ 10-2s-1 (3) wi;H fõ'

ms<s;=r - 3 (CH 3) 2CHOH ys úl¾Il ldKa v .Kk jeä neúka

(CH3)2CHOH ys –Od- – Hd+ O%eùlrKh" CH3CH2CH2OH
28. rjq,a kshufhka" ys –Od- – Hd+ O%eùlrKhg jvd ÿn,h' \(CH3)2CHOH ys
0 0
PA = P XA PB = P XB
A B
wdï,s l;djh wvq neúka Na iuÕ jvd wvq YS >%;djhlska
= 200 ´ PB = 400 ´
m%;sls%h d lrhs'
= 150mmHg = 100mmHg
(4) i;H fõ'
fvda,a gkaf.a wdxYsl mSv k ksh ufhka"
PA = YAP

A
YA = = = 0.6

jdIamfha A ixhq;sh = 0.6 x 100%

C6H5Cl j, Cl ys t1jeä fõ'
= 60%
ms<s;=r -5

29. (1) m%ldYh wi;H fõ' Al2O3, ZnO WNh.= KS Wjo CrO 3
wdï,s l yd Mn2O3 NdIañ l fõ'
(2) m%ldYh i;H fõ' fuys ±lafjk ish¿ Tlaihsv WNh.=KS fõ' (5) i;H fõ' (CH3CH 2)3CBr ys Br bj;a jQ miq ;D;s h s l
(3) m%ldYh wi;H fõ' fuys CrO 2 ÿn, wdï,sl fõ' ldfnda legdhkhla iEfok w;r (CH3CH 2)2CHBr ys Br
bj;a jQ miq oaú;Sh sl ldfndalegdhkhla iEfoa' oa ú;shsl
(4) m%ldYh wi;H fõ' fuys Fe2O3 wdï,s l jk w;r CrO
ldfnda legdhkhg jvd ;D;Sh sl ldfndalegdhkh ia:dhS
ÿn, NdIañl fõ'
neúka (CH3CH 2)3CBr" ;' HNO3 / AgNO3 iuÕ jvd jeä
(5) m%ldYh wi;H fõ' fuys CrO 2 ÿn, wdï,sl jk w;r YS>%;djhls ka m%;sls%hd lrhs'
MnO3 o ÿn, wdï,s l fõ' ms<s;=r -3
ie'hq' -( CrO ÿn, NdIañl MnO NdIañl

Cr2O3 WNh.=KS Mn2O3 ÿn, NdIañ l

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31. (a) m%ldYh wi;H fõ' (c) m%ldYh wi;H fõ' m%;sl%shdj jug keUqre fjñka mj;skafka
bf,lafg%dav úNj ^TZyrK úNj& wkqj wefkda vh úh kï bÈß m%;s l%shd iS>% ;djhg jvd miq m%;sl%sh d iS >%;djh
hq;af;a M+(aq) / M(s) fõ' ta wkqj by< fõ'
iajhxisoaOj isÿjk fldaI m%;sls%hdj my; mßÈ fõ' (d) m%ldYh wi;Hhs'
2M(s) + X 2+
(aq)
2M +
(aq)
+ X(s) (a) muKla i;H fõ'

(b) m%ldYh wi;H fõ' ms<s;=r -5

EqCell = Eqcathode – Eqanode

34. (a) m% ldYh wi;H fõ' -Cl ldKavh fnkaiSkag bf,lafg%daK
= 0.44V – 0.33V
odhl lrñka wdxYs l oaú;a j nkaOk ,laIK fmkajk
= 0.11V
neúka kshq la,sfhda*hs, yuq fõ fnkaiSka myiqfjka bj;a
(c) m%ldYh i;H fõ' WIaK;aj h jeä lrk úg ;dm odhl
fkdfõ' tuksid la f,dafrda fnkaiS ka kshqla ,sfhda *s,sl
jk fldaI m%;sls%hdfõ wdmiq m%;sls%hdj Èßu;a ù ECell wvqfõ'
wdfoaY m%;s l%shd is ÿ fkdlrhs '
(d) m%ldYh i;H fõ' X2+ idkaøKh jeäjk úg Tla isyrK
(b) m%ldYh wi;H fõ' fuys§ iEfok .%Skdâ m%;sldrlhg
m% ;sls%h dj Èßu;a fjñka fldaI m%;sls%h dj Èßu;a fõ'
-COOH ldKavfha H+ u`.ska myr fok neúka fuf,i
(c) yd (d) i;H fõ'
.%Skdâ m%;sldrlh ksmoúh fkdyel'
ms<s;=r -3
(c) m%ldYh i;H fõ'

32. (a) m%ldYh i;H fõ'

3CuO(s) + 2NH3(g) N2(g) + 3Cu(s) + 3H2O(g)

(b) NH3 hkq NdIañl jdhqjls' tuksid NH3 u`.ska r;= ,sÜgia
ks,a meye;s fõ' m% ldYh wi;H fõ'
(c) NH3 ys j, m%n, H nkaOk we;s ksid PH3 j, ;dmdxlhg
jvd NH3 j, ;dmdxlh by, fõ' m%ldYh i;Hhs '
(d) NH3 j,g Tlaisldrl yd Tlaisydrl .=K we;' m%ldYh
ixfhda . folu Br2 iu`. iqÿ wjlafIam idok neúka"
i;H fõ'
y`ÿkd .; fkdyel'
NH3 ys TZydrl .=K (d) m% ldYh i;H fõ' N u; we;s tlir bf,lafg%dak hq.,h
2NH3(g) + 3Cl2(g) N2(g) + 6HCl (g) m%odkhg we;s yelsh dj jeäjk úg NdIañl m%n,;djh

3CuO(s)+ 2NH3(g) N2(g) + 3Cu(s) + 3H2O(g) jeä fõ' CH 3CONH2 ys my; ±lafjk wdldrhg N u;
we;s tlir bf,lafg%da, hq. , úia :dk.; ùu iu`. tu
NH3 ys TZldrl .= K
bf,lafg%dak hq.,h m%odkh lsÍug we;s yelshdj wvq fõ'
2Na(s) + 2NH3(l) 2NaNH2(l) + H2(g) (CH3CONH2 < NH3 ^NdIañl;djh'&

(a), (c), (d) i;Hhs'

ms<s;=r -5
(c) yd (d) i;H fõ'
ms<;
s =r - 3
[0.4moldm ]
33. Q C = =
[0.2moldm ] [0.1moldm ]
= 40mol-1dm 3 35. (a) m%ldYh i;H fõ' PbSO3 iqÿ wjla fIamhla jk w;r
Q C > KC ;' H+ yuqfõ fuh SO2 jdhqj msg lrhs'
m%;sl%shdj iu;=,s; fkdfõ' iu;=,s; ùug QC = KC úh hq;=h' (b) m%ldYh i;H fõ'
ta i`oyd [SO2] yd [O 2] jeä úh hq;=h ' [SO3] wvq úh hq;=h'
3 2 2
2 2 3(aq) 2 3(s) (s) 2 4
tkï wdmiq m%;sl %shdj Èßu;a úh hq;=h '
(a) m%ldYh i;H fõ'
(b) m% ldYh wi;H fõ' iu;=,s; ùug m%;sl%shdj jug keUqre
úh hq ;=h '

pß; Èidkdhl B.Sc. Engineering (Hon's)

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(c) m%ldYh wi;H fõ' C, NaCl úh fkdyel' Cu2+(aq) idkaøKh jeäl< úg fldaI m%;sl%s hdfõ bÈß
m%;sl%shdj Èßu;a jk neúka ú'.d'n' jeä fõ' m%l dYh
i;H fõ'
(a), (d) i;H fõ'
ms<s;=r - 4

(d) m%ldYh wi;H fõ' PbSO3 iqÿ wjlafIa mhls ' 38. (a) m%ldYh wi;H fõ' N2 fyda CO 2 wï, jeis we;s

(a) yd (b) i;Hh' lsÍug odhl fkdfõ'

ms<s;=r - 1 (b) m% ldYh wi;H fõ' NO2 yd SO4 yß;d.dr jdhq

fkdfõ'
(c) m%ldYh i;H fõ' CFC m%N, yß;d.dr jdhqjla jk
36.(a) T2 yS§ iu;=,s;h ^m%ia:drfha wju ,laIfha § iu;=,;
s fõ'&
w;ru ´fida ka úhk ydhkhg o odhl fõ'
ol= Kg nrj mj;sk neúka T2 yS§ iu;=,s;;d ksh;h T1
(d) m%ldYh i;H fõ'
yS§g jvd jeäúh hq;=h ' m%ldYh i;H fõ'
(c) yd (d) i;H fõ'
(b) T2 > T1 neúka WIaK;aj h jeä lrk úg iu;=,s;h M,
ms<s;=r -3
foig keUqre jk nj fmfka ' tkï WIaK;a jh jeä lrk
úg bÈß m%; sls%h dj Èßu;a ù we;' tuksid f,a peÜ,sh ¾
39. BaSO4(s) Ba2+(aq) + SO42-(aq)
uQ,O¾uhg wkqj bÈß m%;sls%hdj ;dm wjfYdaIl fõ' m%ldYh
x x
i;H fõ'
SrSO4(s) Sr2+(aq) + SO42-(aq)
(c) DGq ys w.h (–) nj m% ia:drfhka fmfka'
y y
DGq = DHq – TDSq iïnkaOhg wkqj neúka DH(+) neúka
(a) Ksp = [Ba2+(aq)][SO42-(aq)]
DGq < 0 ùug DSq w.h Ok úh hq ;=h' m%ldYh wi;H fõ' (BaSO4(s))

(d) m%ldYh wi;H fõ' DG ys ixLHd;aul w.h jeä jkafka

[SO42-(aq)] =
T2 yS § nj m%ia:drfhka fmfka'
\ (a) ksjerÈ fõ'
(a) yd (b) m%ldY i;H fõ'
ms<s;=r -1 (b) uq¿ [SO42-(aq)] = [Ba2+(aq)] + [Sr2+(aq)]

\ (b) wi;H fõ'

37. (a) m%ldYh i;H fõ' Mg úoHq;a ridhksl fY%aKf

s ha Cu g jvd
(c) uq¿ [SO42-] = =
by<ska mj;sk neúka Mg wi, TZlrKh isÿfõ' tuksid
Mg wefkdavh f,i l%shd lrhs ' (c) wi;H fõ'
(b) m% l dYh wi;H fõ' fuys úoHq ; a .dul n,hg (d) [Ba2+(aq)] + [Sr2+(aq)] = x + y = [SO42-(aq)]
wekdhkfha n,mEula ke;' \ (d) i;H fõ'
(c) m%ldYh wi;H fõ' WIaK;ajh jeäl< úg úoHq;a .dul (a) yd (d) i;H fõ'
n,h wvq fõ' ish¿ fldaI m%;l
s h
s% d ;dmodhl ùu Bg fya;j
= hs' ms<s;=r -4
(d) fldaI m%;sl%shdj my; mßÈ fõ'
40. (a) m%ldYh i;H fõ' fvd,uhsÜ yd yqK.
q ,a ms<siaiu
S ksid;a"
úoHq;a úÉfþok fldaIh wdY%s ;j by< WIaK;ajhla ,nd
.ekSug fmfg%da,shï bkaOk oykh ksid;a jdhqf.da,hg
CO 2 tla fõ'
(b) m%ldYh wi;H fõ' NH3 ksIamdokhg wjYH H2 ,nd
.ekSug iajNdúl jdhqj fyda kema; d ì`§u Ndú;d lrk
úg jdhqf.da,hg CO 2 ksoyia fõ' tfia u by< WIaK;aj
,nd .ekSug isÿflfrk fmfg%d,
a shï bkaOk oykh ksid
o jdhqf.da,hg CO 2 tla fõ'

pß; Èidkdhl B.Sc. Engineering (Hon's)

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(c) m%ldYh wi;H fõ' mg, flda I l%u fha § jeh jkqfha 44. m<uq m%l dYh i;H fõ'
idfma CIj wvq úoHq; a m%u dKhls ' Tiaj,aâ ;kqlrK kshuhg wkqj"
(d) m%ldYh i;H fõ'
fõ'
TiO2(s) + C(s) + 2Cl2(g) TiCl4(g) + CO2(g)
fuys§ CO2(g) msg fõ' ta wkqj idkaøKh wvqjk úg ú>gk m%u dKh jeä fõ'
(a) yd (d) i;H fõ' fojk m%ldYh i;H fõ' idkaøKh jeäjk úg a w.h wvq
ms<s;r
= -4 jQjo [H +] jeä fõ' [H +] =
túg pH w.h wvq fõ'
41.m<uq m%l dYh i;H fõ' ms<s;=r - 2
O=C=O : º N:
uq' l sp sp
45.m<uq m%l dYh i;H fõ'
wdfrdamKh 0 -1
fojk m% ldYh wi;H fõ'
uqyqïlrKh iudk jk úg wdfrda mKh Okj jeä C ys úoHq;a
m%;sl%shdfõ hdka;%Kh my; mßÈ jqj fyd;a § we;s iS>%;d ksh;h
iDK;djh ­ fõ'
i;H fõ'
\CN- < CO2 f,i ldnkays úoHq;a iDK;djh jeä fõ'
A + B ® E fiñka
fojk m%ldYh i;H fõ'
E + A ® C fõ.fhka
kuq;a m<uq jekak myod fkdfoa'
ms<s;=r -3
ms<s;=r -2

46. m<uq m%l dYh i;H fõ'

42.
fojk m%l dYh wi;H fõ' HF jeks ÿn, wï,hla ie,l+ úg
Rf = Kf [AO(g)]2 [B2(g)]
tys ú>gkhg ;dmh jeh Wjo ú>gkfhka ,efnk F- ic,kh
Rr = Kr [AOB(g)]2
ùu ksid ;dmh msg fõ' tuksid iuia :hla f,i .;aúg HF ys
mSvk jeä l< úg idkaøK jeä ù Rf yd Rr hk folu jeä fõ'
WodiSkSlrK tka;e,amsh HCl g jvd jeä fõ'
m<uq m%ldYh i;Hhs' mßudj wvq ls Ífuka mSv kh jeäl< úg
ms<s;=r -3
f,apeÜ,sh¾ uQ,O¾uhg wkqj mSv kh wvq lr .ekSug jdhq
wKq .Kk wvqjk ÈYdjg m%;sl%shdj keUq re fõ'
47. m<uq m%ldYh wi;H fõ'
fojk m%ldYh i;Hhs' kuq;a tuÕska m<uq m%ldYh ksjerÈj
HNO3 mQ¾ Kj c, úÉfþokh ù whk idok neúka wka;¾
myod fkdfoa'
wKql n, m% N, ùula isÿ fõ' tuksid moaO;sh rjq,a kshufhka
ms<s;=r -2
iDK wm.uk olajk nj meyeÈ,s fõ'
m<uq m%l dYh i;H fõ'
43. m<uq m%l dYh i;H fõ'
wka;¾ wKql n, m%N, ùu fya;=fjka ñY% lsÍu ;dm odhl fõ'
ief*dakSlrKfhka miqj ,efnk moa O;sfha c,Sh l,dmh ;= <
tuksid tys§ WIaK;a jh by, hhs'
.a,siÍka iy inka hï m%udKhla Èh ù we;' c,Sh l,dmh
;=< we;s inka bj;a lsÍu i`oyd c,Sh l,dmhg n%hska ødjKh ms<s;=r -4

tla lrhs' túg c,Sh l,dmh ;=, inka ys ødjH;djh wvqjk

48. m<uq m%ldYh wi;H fõ' weuhsv 2,4-DNP iu`. m%;sl% shd
w;r inka kej; wjla fIam fõ' miqj c,Sh ødjKh bj;a
fkdlrhs'
lsÍu u.ska .a,iÍka moaO;sfhka bj;a lr .kS '
fojk m%ldYh i;H fõ' 2,4-DNP ys N u; we;s tlir hq.,h
fojk m% ldYh wi;H fõ'
ndysrg odhl lsÍfuka thg kshq la,sfhda*hs,hla f,i yeisß h
ms<s;=r -3
yel'
ms<s;=r -4

pß; Èidkdhl B.Sc. Engineering (Hon's)

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49. m<uq m%l dYh i;H fõ' fojk m%ldYh i;H fõ'

CH 3COOH ys fukau CH 3CH 2CH 2OH ys o O%eùh C - O yd

O - H ldKav we;s neúka tajdg wka;¾ wKql H nkaOk

iEÈh yel' ;jo CH 3COOH yg H nkaOk iE§u u.ska oaú

wjhúl iE§fï yelshdjla we;'

fï fya;= j ksid CH 3 COOH ys

;dmdxlh CH3CH 2CH 2OH ys ;dmdxlhg jvd jeä fõ'

fojk j.ka;s h u.ska m<uq jekak meyeÈ,s lrhs'

ms<s;=r -1

50. m<uq m%ldYh wi;H fõ'

H2O(g) yß;d.dr jdhqjla jqjo th f.da ,Sh WKqiqu jeä ùug
fya;= fkdfõ' thg fya;=j flá ld,Skj fyda N+f.da,Sh idOl
fya;=fjka jdhq f.da,fha c, jdIam ixhq;sh fjkia jqjo
iuia :hla f,i jdhq f.da ,S h c, jdIa m ixhq ;s h fjkia
fkdùuhs'
fojk m%ldYh i;H fõ' kuq;a tuÕska m<uq m%ldYh ksjerÈj
myod fkdfoa'
ms<s;=r -2

pß; Èidkdhl B.Sc. Engineering (Hon's)