According to REACH Regulation (EC) No 1907/2006, as retained and amended by SI 2019/758 and SI 2020/1577

SAFETY DATA SHEET

AGS 221 TUNN

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Trade name
AGS 221 TUNN
Product no.
3624
Unique formula identifier (UFI)
1V00-D0TQ-500R-7EJ5
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
Graffiti remover
Restricted to professional users.
Uses advised against
None known.
1.3. Details of the supplier of the safety data sheet
Company and address
TENSID DEUTSCHLAND GMBH
MAX-PLANCK-STR. 7
DE-63594 HASSELROTH-NEUENHASSLAU
Germany
+49 6055 906930
+49 6055 906950
www.tensid.org
Contact person
Wolfgang Röttger
E-mail
[email protected]
Revision
19/11/2024
SDS Version
4.0
Date of previous version
02/08/2024 (3.0)
1.4. Emergency telephone number
Healthcare professionals: Dial 0344 892 0111 to reach The National Poisons Information Service (NPIS) (24 hour
service)
General public:
England - Dial 111 to reach NHS 111 (24 hour service)
Scotland - Dial 112 to reach NHS 24 (24 hour service)
Wales - Dial 111 or 0845 4647 to reach NHS Direct (24 hour service)
See section 4 “First aid measures”.

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Not classified according to Regulation (EC) No. 1272/2008 (CLP) as retained and amended in UK law.
2.2. Label elements
Hazard pictogram(s)
Not applicable.
Signal word

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According to REACH Regulation (EC) No 1907/2006, as retained and amended by SI 2019/758 and SI 2020/1577

Not applicable.
Hazard statement(s)
Not applicable.
Precautionary statement(s)
General
-
Prevention
-
Response
-
Storage
-
Disposal
-
Hazardous substances
None known.
Additional labelling
EUH210, Safety data sheet available on request.

UFI: 1V00-D0TQ-500R-7EJ5
VOC
VOC content: 155 g/L
MAXIMUM VOC CONTENT (Phase II, category B/a1: 850 g/L)
2.3. Other hazards
▼Additional warnings
This mixture/product does not contain any substances known to fulfil the criteria for PBT and vPvB classification.
This product does not contain any substances considered to be endocrine disruptors in accordance with the
criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2023/707.

SECTION 3: Composition/information on ingredients

3.1. Substances
Not applicable. This product is a mixture.
3.2. ▼Mixtures
Product/substance Identifiers % w/w Classification Note

1-methoxy-2-propanol CAS No.: 107-98-2 5-10% Flam. Liq. 3, H226 [1]

monopropylene glycol methyl EC No.: 203-539-1 STOT SE 3, H336
ether UK-REACH:
Index No.: 603-064-00-3

See full text of H-phrases in section 16. Occupational exposure limits are listed in section 8, if these are available.

Other information
[1] European occupational exposure limit.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information
In the case of accident: Contact a doctor or casualty department – take the label or this safety data sheet.
Contact a doctor if in doubt about the injured person’s condition or if the symptoms persist. Never give an
unconscious person water or other drink.
Inhalation
Upon breathing difficulties or irritation of the respiratory tract: Bring the person into fresh air and stay with
him/her.
Skin contact
Upon irritation: rinse with water. In the event of continued irritation, seek medical assistance.

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According to REACH Regulation (EC) No 1907/2006, as retained and amended by SI 2019/758 and SI 2020/1577

Eye contact
If in eyes: Flush eyes with water or saline water (20-30 °C) for at least 5 minutes. Remove contact lenses. Seek
medical assistance and continue flushing during transport.
Ingestion
If the person is conscious, rinse the mouth with water and stay with the person. Never give the person anything to
drink.
In case of malaise, seek medical advice immediately and bring the safety data sheet or label from the product. Do
not induce vomiting, unless recommended by the doctor. Have the person lean forward with head down to avoid
inhalation of or choking on vomited material.
Burns
Not applicable.
4.2. Most important symptoms and effects, both acute and delayed
None known.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
Information to medics
Bring this safety data sheet or the label from this product.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media: Alcohol-resistant foam, carbon dioxide, powder, water mist.
Unsuitable extinguishing media: Waterjets should not be used, since they can spread the fire.
5.2. Special hazards arising from the substance or mixture
Fire will result in dense smoke. Exposure to combustion products may harm your health. Closed containers, which are
exposed to fire, should be cooled with water. Do not allow fire-extinguishing water to enter the sewage system and
nearby surface waters.
If the product is exposed to high temperatures, e.g. in the event of fire, dangerous decomposition compounds are
produced. These are:
Nitrogen oxides (NOₓ)
Carbon oxides (CO / CO2)
5.3. ▼Advice for firefighters
No specific requirements.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Ensure adequate ventilation, especially in confined areas.
Contaminated areas may be slippery.
6.2. Environmental precautions
Avoid discharge to lakes, streams, sewers, etc.
Keep unauthorized persons away from the spill
6.3. Methods and material for containment and cleaning up
Limit spillage and collect using granular absorbent or similar materials, and dispose of it in accordance with the
regulations on dangerous waste.
Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous
earth and place in container for disposal according to local regulations.
Wherever possible cleaning should be performed with normal cleaning agents. Avoid use of solvents.
6.4. Reference to other sections
See section 13 “Disposal considerations” on handling of waste.
See section 8 "Exposure controls/personal protection" for protective measures.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Avoid contact during pregnancy and while nursing.
Smoking, drinking and consumption of food is not allowed in the work area.
See section 8 "Exposure controls/personal protection" for information on personal protection.
7.2. Conditions for safe storage, including any incompatibilities
Containers that have been opened must be carefully resealed and kept upright to prevent leakage.

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According to REACH Regulation (EC) No 1907/2006, as retained and amended by SI 2019/758 and SI 2020/1577

Recommended storage material

Always store in containers of the same material as the original container.
Storage conditions
4 - 25 Celcius
Incompatible materials
Strong acids, strong bases, strong oxidizing agents, and strong reducing agents.
7.3. Specific end use(s)
This product should only be used for applications quoted in section 1.2.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

1-methoxy-2-propanol monopropylene glycol methyl ether
Long term exposure limit (8 hours) (ppm): 100
Long term exposure limit (8 hours) (mg/m³): 375
Short term exposure limit (15 minutes) (ppm): 150
Short term exposure limit (15 minutes) (mg/m³): 560
Annotations:
Sk = Can be absorbed through the skin and lead to systemic toxicity.

The Control of Substances Hazardous to Health Regulations 2002. SI 2002/2677 The Stationery Office 2002.
EH40/2005 Workplace exposure limits (Fourth Edition 2020).

DNEL
No data available.
PNEC
No data available.
8.2. Exposure controls
Compliance with the given occupational exposure limits values should be controlled on a regular basis.
General recommendations
Smoking, drinking and consumption of food is not allowed in the work area.
Exposure scenarios
There are no exposure scenarios implemented for this product.
Exposure limits
Professional users are subjected to the legally set maximum concentrations for occupational exposure. See
occupational hygiene limit values above.
Appropriate technical measures
The formation of vapours must be kept at a minimum and below current limit values (see above). Installation of a
local exhaust system if normal air flow in the work room is not sufficient is recommended. Ensure eyewash and
emergency showers are clearly marked.
Apply standard precautions during use of the product. Avoid inhalation of vapours.
Hygiene measures
In between use of the product and at the end of the working day all exposed areas of the body must be washed
thoroughly. Pay special attention to hands, forearms and face.
Measures to avoid environmental exposure
No specific requirements.
Individual protection measures, such as personal protective equipment
Generally
Use only UKCA marked protective equipment.
Respiratory Equipment
Type Class Colour Standards
Respiratory protection - - -
is not needed in the
event of adequate
ventilation
Skin protection

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According to REACH Regulation (EC) No 1907/2006, as retained and amended by SI 2019/758 and SI 2020/1577

Recommended Type/Category Standards

Dedicated work - -
clothing should be
worn.

Hand protection
Material Glove thickness (mm) Breakthrough time Standards
(min.)
Nitrile 0,4 >480 EN374-2

Eye protection
Type Standards
Wear safety glasses EN166
with side shields.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state
Liquid
Colour
Yellow
Odour / Odour threshold
Faint
pH
-
pH in solution
7 (10%)
Density (g/cm³)
1.05
▼Kinematic viscosity
No relevant or available data due to the nature of the product.
Particle characteristics
Not applicable - product is a liquid
Phase changes
Melting point/Freezing point (°C)
Not applicable - based on structure
Softening point/range (°C)
Does not apply to liquids.
Boiling point (°C)
120-150
▼Vapour pressure
No relevant or available data due to the nature of the product.
▼Relative vapour density
No relevant or available data due to the nature of the product.
Decomposition temperature (°C)
Not applicable - product is a liquid
Data on fire and explosion hazards
Flash point (°C)
61
Flammability (°C)
230
▼Auto-ignition temperature (°C)
No relevant or available data due to the nature of the product.

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According to REACH Regulation (EC) No 1907/2006, as retained and amended by SI 2019/758 and SI 2020/1577

Lower and upper explosion limit (% v/v)

1.1 - 10.6
Solubility
Solubility in water
Insoluble
▼n-octanol/water coefficient (LogKow)
No relevant or available data due to the nature of the product.
Solubility in fat (g/L)
1000
9.2. Other information
VOC (g/l)
155
▼Oxidizing properties
No relevant or available data due to the nature of the product.
Other physical and chemical parameters
No data available.

SECTION 10: Stability and reactivity

10.1. Reactivity
No data available.
10.2. Chemical stability
The product is stable under the conditions, noted in section 7 “Handling and storage”.
10.3. Possibility of hazardous reactions
None known.
10.4. Conditions to avoid
None known.
10.5. Incompatible materials
Strong acids, strong bases, strong oxidizing agents, and strong reducing agents.
10.6. ▼Hazardous decomposition products
Under normal conditions of storage and use, hazardous decomposition products should not be produced

SECTION 11: Toxicological information

11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008 as retained and amended in UK law
Acute toxicity
Product/substance 1-methoxy-2-propanol monopropylene glycol methyl ether
Species: Rat
Route of exposure: Oral
Test: LD50
Result: 7200 mg/kg

Product/substance 1-methoxy-2-propanol monopropylene glycol methyl ether

Species: Rabbit
Route of exposure: Dermal
Test: LD50
Result: 13000 mg/kg ·

Product/substance 1-methoxy-2-propanol monopropylene glycol methyl ether

Species: Rat
Route of exposure: Inhalation
Test: LC 50 (6 Hours)
Result: 7200 ppm

Skin corrosion/irritation
Based on available data, the classification criteria are not met.
Serious eye damage/irritation
Based on available data, the classification criteria are not met.
Respiratory sensitisation
Based on available data, the classification criteria are not met.
Skin sensitisation

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According to REACH Regulation (EC) No 1907/2006, as retained and amended by SI 2019/758 and SI 2020/1577

Based on available data, the classification criteria are not met.

Germ cell mutagenicity
Based on available data, the classification criteria are not met.
Carcinogenicity
Based on available data, the classification criteria are not met.
Reproductive toxicity
Based on available data, the classification criteria are not met.
STOT-single exposure
Based on available data, the classification criteria are not met.
STOT-repeated exposure
Based on available data, the classification criteria are not met.
Aspiration hazard
Based on available data, the classification criteria are not met.
11.2. Information on other hazards
Long term effects
None known.
Endocrine disrupting properties
This mixture/product does not contain any substances known to have hormone-disrupting properties in relation to
health.
Other information
None known.

SECTION 12: Ecological information

12.1. Toxicity
Product/substance 1-methoxy-2-propanol monopropylene glycol methyl ether
Species: Fish
Duration: 96 hours
Test: LC50
Result: 20800 mg/L

Product/substance 1-methoxy-2-propanol monopropylene glycol methyl ether

Species: Daphnia
Duration: 96 hours
Test: EC50
Result: 23300 mg/L

Product/substance 1-methoxy-2-propanol monopropylene glycol methyl ether

Species: Algae
Duration: 72 hours
Test: IC50
Result: >1000 mg/L

12.2. Persistence and degradability

Product/substance 1-methoxy-2-propanol monopropylene glycol methyl ether
Result: 96%
Conclusion: Readily biodegradable
Test: OECD 301 E

12.3. Bioaccumulative potential

Product/substance 1-methoxy-2-propanol monopropylene glycol methyl ether
LogKow: <3
Conclusion: No potential for bioaccumulation

12.4. Mobility in soil

1-methoxy-2-propanol monopropylene glycol methyl ether
LogKoc = 1.699, High mobility potential.
12.5. Results of PBT and vPvB assessment
This mixture/product does not contain any substances known to fulfil the criteria for PBT and vPvB classification.
12.6. Endocrine disrupting properties
This mixture/product does not contain any substances considered to have endocrine-disrupting properties in relation
to the environment.
12.7. Other adverse effects

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According to REACH Regulation (EC) No 1907/2006, as retained and amended by SI 2019/758 and SI 2020/1577

None known.

SECTION 13: Disposal considerations

Waste treatment methods

Product is covered by the regulations on hazardous waste. (*)
Regulation (EU) No 1357/2014 of 18 December 2014 on waste as retained and amended in UK law.
EWC code
20 01 13* Solvents
Specific labelling
Contaminated packing
Packaging containing residues of the product must be disposed of similarly to the product.

SECTION 14: Transport information

14.1 14.2 14.3 14.4 14.5 Other

UN / ID UN proper shipping name Hazard class(es) PG* Env** informatio
n:

ADR - - - - - -

IMDG - - - - - -

IATA - - - - - -

* Packing group
** Environmental hazards
Additional information
Not dangerous goods according to ADR, IATA and IMDG.
14.6. Special precautions for user
Not applicable.
14.7. Maritime transport in bulk according to IMO instruments
No data available.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Restrictions for application
Restricted to professional users.
Pregnant women and women breastfeeding must not be exposed to this product. The risk, and possible technical
precautions or design of the workplace needed to eliminate exposure, must be considered.
Demands for specific education
No specific requirements.
Control of Major Accident Hazards (COMAH) - Categories / dangerous substances
Not applicable.
UK-REACH, Annex XVII
1-methoxy-2-propanol monopropylene glycol methyl ether is subject to UK-REACH restrictions (entry 40).
Additional information
Not applicable.
Sources
The Health and Safety at Work etc. Act 1974 Regulations 2013.
2012 No. 1715 ENVIRONMENTAL PROTECTION: The Volatile Organic Compounds in Paints, Varnishes and Vehicle
Refinishing Products Regulations 2012.
Regulation (EU) No 1357/2014 of 18 December 2014 on waste as retained and amended in UK law.
Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures (CLP) as
retained and amended in UK law.
Regulation (EC) No 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals
(REACH) as retained and amended in UK law.
15.2. Chemical safety assessment
No

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According to REACH Regulation (EC) No 1907/2006, as retained and amended by SI 2019/758 and SI 2020/1577

SECTION 16: Other information

Full text of H-phrases as mentioned in section 3

H226, Flammable liquid and vapour.
H336, May cause drowsiness or dizziness.
Abbreviations and acronyms
ADN = European Provisions concerning the International Carriage of Dangerous Goods by Inland Waterway
ADR = The European Agreement concerning the International Carriage of Dangerous Goods by Road
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
CAS = Chemical Abstracts Service
CE = Conformité Européenne (European conformity)
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]
CSA = Chemical Safety Assessment
CSR = Chemical Safety Report
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
EINECS = European Inventory of Existing Commercial chemical Substances
ES = Exposure Scenario
EUH statement = CLP-specific Hazard statement
EuPCS = European Product Categorisation System
EWC = European Waste Catalogue
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
GWP = Global warming potential
IARC = International Agency for Research on Cancer (IARC)
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of
1978. ("Marpol" = marine pollution)
OECD = Organisation for Economic Co-operation and Development
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
RID = The Regulations concerning the International Carriage of Dangerous Goods by Rail
RRN = REACH Registration Number
SCL = A specific concentration limit
SVHC = Substances of Very High Concern
STOT-RE = Specific Target Organ Toxicity - Repeated Exposure
STOT-SE = Specific Target Organ Toxicity - Single Exposure
TWA = Time weighted average
UN = United Nations
UVBC = Unknown or variable composition, complex reaction products or of biological materials
VOC = Volatile Organic Compound
vPvB = Very Persistent and Very Bioaccumulative
Additional information
Not applicable.
The safety data sheet is validated by
RO
Other
A change (in proportion to the last essential change (first cipher in SDS version, see section 1)) is marked with a
triangle.
The information in this safety data sheet applies only to this specific product (mentioned in section 1) and is not
necessarily correct for use with other chemicals/products.
It is recommended to hand over this safety data sheet to the actual user of the product. Information in this safety
data sheet cannot be used as a product specification.
Country-language: GB-en

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