Student's Solution Copy [Code - 28600]

BRAHMASTRA_Full Syllabus Test-04_Advanced Paper -1

12th+13th JEE (M+A) - Phase 1
KOTA

Date: 12-May-2025 Duration: 3 Hours Max Marks: 180

Maths - Section A

1. Answer: A,B,C

Sol:

Let ⊥ distance from H to BC, BD and

CD be

p, 2p, 3p
1 1 2
× 12(p + 2p + 3p)= 12 sin 60°
2 2

p = √3

1 1
× 6 × 2√3+ × 12√3+
2 2
1
× h0 6√3
2

1 1 2
= ( × 12 sin 60°)
2 2

∴ h = 2. So ⊥ distance of A from CM
2 2
= √2 + 3 = √13
2. Answer: A,B,C Sol:

Given eq of line an which edge of c,

lies in

= = (say)
x−1 4−2 z−3
⇒ λ
1 2 3

Its general coordinates is

(λ + 1, 2λ + 2, 3x + 3)

Let C ≡ (λ1 + 1, 2λ1 + 2, 3λ1 + 3)

and D ≡ (λ2 + 1, 2λ2 + 2, 3λ2 + 3).

∵ CD = √14.

2
∴ CD = 14

2 2
⇒ (λ1 − λ2 ) + 4(λ1 − λ2 ) +

2
9(λ1 − λ2 ) = 14

2
⇒ 14(λ1 − λ2 ) = 14.

2
⇒ (λ1 − λ2 ) = 1 ⇒ λ1 − λ2 = ±1

Consider λ2 = 1 + λ2

Let centroid of tetrahedron Δ − ABC

is G(α, β, γ)

∴ 4α = 2 + 0 + λ1 + 1 + λ2 + 1

⇒ 4α = 4 + λ1 + 1 + λ1

⇒ 4α = 5 + 2x1

Similarly, 4β = 10 + 4λ1 and

4r = 9 + 6λ1

4α−5
⇒ = λ1 ,
2

4β−10
= λ1 ,
4

4r−9
= λ1
6

4y−10
Locus of
4x−5
∴ G.: =
2 4

(say)
4z−9
= = λ (i)
6

But given Locus of G eq passes

through ( 2 , y1 , z1 ).
3

∴ From (i)

3
⇒ 4 × = 2λ + 5
2

1
⇒ 2λ = 1 ⇒ λ =
2

∴ 4y1 = 4λ + 10 ⇒ y1 = 3

and 4z1 = 6λ + 9 ⇒ z1 = 3
∴ Required Locus of Centroid of 3. Answer: C,D
tetrahedron is
Sol:
3

y2 + 4y'y + (y')2 = 0
(x− )
2 y−3 z−3
= =
1 2 3

2 2
−4y±√16y −4y
∴a=2, b=3,g
1
= 3, z1 = 3. y' = 2

∴ a + b = 5, y1 + z1 = 6 and dy −4y±2√3y
=
a + b + y1 = 8. dx 2

dy
Therefore, the correct answer is = (− 2 ±√3 ) dx
y
(A, B, C)

lny = (−2 ±√3 ) x + lnC

( −2+√3 ) x
(+ve) y = Ce

( −2−√3 ) x
(−ve) y = Ce

Therefore, the correct answer is

(C,D)
 Maths - Section B

4. Answer: B 5. Answer: A

Sol: Sol:
K(K+1)
S K= 2 Let the matrix be A =[
a b
] , then
c d
n
Sr
Qn= π
Sr −1
A − 2 A + I = 0. Sum of root is 2
2

r=2
and product of root is 1 , which
n represent trace and determinant of
Qn=
1
π (1 +
Sr −1
) matrix respectively.
r=2

n Then pair of (a, d) can be (5, – 3), (–

Qn=1 +
1
π
Sr −1
3, 5), (4, –2), (–2, 4), (3, –1), (–1,
r=2
3), (2, 0) and (0, 2)
n
=
2
1 + π
2
r +r−2
(Because sum of a + d = 2)
r=2

n−2 n
Now
=
2 1 1
1 + ( ) π ( − )
3
r=2
r−1 r+2
(a, d) is (5, – 3) or (–3, 5)

= 1 + (
2
)
n−2
(
n
−
3!
)
Here |A| = ad – bc = 1⇒ bc = – 16
3 n! (n+2)!

⇒ (b, c) can be (4, –4) or (–4, 4)

lim Qn = lim
n→∞ n→∞
⇒ 4 possibilities of matrix A is
possible
n−2
2 n 3!
[1 + ( ) [ − ]]= 1
3 n! (n+2)!

Case – II
Therefore, the correct answer is (C)
(a, d) is (4, – 2) or (–2, 4)

Here |A| = ad – bc = 1⇒bc = – 9

⇒ (b, c) = (–3, 3) or (3, – 3)

⇒ 4 possibilities of matrix A is
possible

Case- III

(a, d) = (3, – 1) or (–1, 3)

Here |A| = ad – bc = 1⇒bc = –4

⇒ (b, c) = (2, – 2), (–2, 2), (1, –4),

(–4, 1)

⇒ 8 possibilities of matrix A is
possible

Case - IV

(a, d) = (2, 0) or (0, 2)

|A| = ad – bc = 1⇒bc = – 1

Here (b, c) = (1, – 1) or (–1, 1)

Total possible matrices = 4 + 4 + 8 +

4 = 20

⇒ 4 possibilities of matrix A is
possible
6. Answer: B 7. Answer: D

Sol:

c
2
= ab (given)

4 2 2
x (c −(2ab − 1)ab + a b )

2
+y (c + 2√ab − 2ab) − 10c = 0

4 2 2 4
⇒ x (c − (2c − 1) c + c )

2 2
+y (c + 2c − 2c ) − 10c = 0

2 2
⇒ c ⋅ x + y (2c − c ) − 10c = 0

2
⇒ c (x − y)+2c(y − 5)= 0

2
⇒ x − y + (y − 5)= 0
c

L1 + λL2 = 0 (Form)

L1 : x − y = 0, L2 : y = 5

∴ Variable line passes through (5, 5).

Maximum distance from the origin of
the variable line is

P| = √25 + 25 = 5√2
max
Sol: circles orthogonally whose
coordinates obtained by solving
The equation of circle taking AB as equations
diameter
i.e. solving x2 + y2 – 3x – y = 0 and
(x – 2)(x – 4) + (y – 1)(y – 3) = 0 x+y–5=0
....(1)
⇒ x2 – 6x + 10 = 0 (D < 0)
The equation of the line joining the
points A and B is x1 + x2 = 6; x1x2 = 10

x–y–1=0 ....(2) Similarly, y2 – 4y + 5 = 0

The equation of members of family of y1 + y2 = 4; y1y2 = 5

circle passing through A and B is
3 3 3 3
given by ∴ x
1
+ x
2
+ y
1
+ y
2

S (x – 2)(x – 4)+ (y – 1)(y – 3) +

≡ = (x1 + x2)3 – 3x1x2(x1 + x2)+ (y1 +
λ(x – y – 1) = 0 where λ∈ R is y2)3 – 3y1y2(y1 + y2)
parameter
= 216 – 30(6) + 64 – 60
∴ S ≡ x2 + y2 + (λ – 6)x + (– λ –
4)y +(11 – λ) = 0 ....(3) = 36 + 4 = 40 Ans.

Let the circle which cuts the

members of circle be

S1 = x2 + y2 + 2gx +2fy + c = 0
....(4)

Applying condition of orthogonality

for (3) and (4), we get
λ−6
2g( + 2f( = c + 11 –
−λ−4
) ) λ
2 2

i.e. (– 6g – 4f – c – 11)+ λ (g – f +
1) = 0

This will also hold for all λ ∈ R

∴ we have – 6g – 4f – c – 11 = 0

and g–f+1=0

solving these equations for g and f in

terms of c,

we get g= and f =
−c−15 −c−5

10 10

substituting the values of g and f in

terms of c in (4), we get the circles
cutting the circles of system (4)
orthogonally as

x2 + y 2 + 2 (
−c−15 −c−5

10
) x + 2( 10
) y+
c=0

or x2 + y2 – 3x – y– (x + y – 5)
c

=0

which represents the equation of

family of circles passing through two
fixed points and cutting the family of
 Maths - Section C

8. Answer: 4

Sol:

1+3+32+….+ 32021
n
( r −1 )

sum of GP = a × ( ( r−1 ) )

a = 1, r = 3

2022 2022
3 −1 3 −1
= =
3−1 2

1011
2
(3 ) −1

=
2

1011
[10−1] −1
n n n
n 0 n−1 1
= (p + q) = c p q + c p q
2 0 1

n n−r r n 0 n
+. . . . . . . . . . . + cr p q +. . . . . . . + cn p q

1011 1010
10 −(10 )⋅1011c +…
1
[ ]−1
+1011c (10)−1
1010
=
2

= 50( int )+(1011)(5)−1

divide by 50
5055−1 5054
⇒ =
50 50

⇒ Remainder = 4

9. Answer: 441

Sol:
4⋅1 4⋅2 4⋅3 m
+ + + … =
4 4 4 n
1+4⋅1 1+4⋅2 1+4⋅3

4k
Tk =
4
1+4⋅k

4k
=
4 2 2
1+4k +4k −4k

4k
=
2
2
2
( 2k +1 ) −(2k)

4k
=
2 2
( 2k +2k+1 ) ( 2k −2k+1 )

2 2
( 2k +2k+1 ) − ( 2k −2k+1 )
= 2 2
( 2k +2k+1 ) ( 2k −2k+1 )

1 1
⇒ Tk = −
2 2
2k −2k+1 2k +2k+1
1 1
T1 = −
1 5

1 1
T2 = −
5 13

⋮
1 1
T10 = −
181 221

1 220 m
S10 = 1 − = =
221 221 n

m + n = 441
10. Answer: 7 Sol:
3 2 2
f (x)= x − 2 kx − 4kx + k = 0

note that f (0)= k

2
> 0

f (1) > 0

2
⇒ 1 − 2k − 4k + k > 0

2
k − 6k + 1 > 0

[k − (3 + 2√2)]

[k − (3 − 2√2)] > 0

......(1)

Also f (4)< 0

2
⇒ 64 − 32k − 16k + k < 0

2
k − 48k + 64 < 0

2
(k − 24) < 512

(k − 24 + 16√2)

(k − 24 − 16√2) < 0

[k − 8(3 − 2√2)]

[k − 8(3 + 2√2)] < 0

......(2)

(1)∩(2) ⇒ 3 + 2√2

< k < 8(3 + 2√2)

3 + √8 < k < 8(3 + √8)

∴ a = 3; b = 8

3 2
(a + b) + (ab + 2)
3 2
⇒ (11) + (26)

= 1331 + 676 = 2007 Ans.

11. Answer: 13 12. Answer: 8

Sol: Sol:

As sin x cosy = 1. x
2

f (x)=[ ]−[√x], x ∈[0, 4]

2

Here two cases are possible;

[√x] D.C at x = {1, 4}
either sin x = 1 and cos y = 1
2

or sinx = – 1 and cos y = – 1 at

x
[ ] D.C
2

Case - I: When sin x = 1, cos y = 1 x ={√2, 2, √6, 2√2, √10, 2√3, √14, 4}

x= y = 2kπ,
π
⇒ 2nπ + , check at x = 4
2

−
where n, k ∈ I. f (4 )= 7 − 1 = 6

Now, x
2
+ y
2
≤ 9π
2
f (4) = 8 − 2 = 6

now Discontinuous at 8 points

2 2
⇒ (4n + 1) + (4k) ≤ 36

∴ When k = 0, 13. Answer: 3

n = –1, 0, 1 and Sol:

when k = ± 1, n = –1, 0 Given that,

Case – II: When sin x = – 1, y(2x

4
+ y)
dy
= (1 − 4 xy )x
2 2

dx

cos y = –1
4 2
⇒ 2x y dy + y dy
⇒ x = 2nπ – π
, 3
+4x y dx − x dx = 0
2 2
2

y = (2k + 1)π 2
⇒ 2x y(x dy + 2 xydx)
2

where n, k I
2 2
∈ +y dy − x dx = 0

Now, x2 + y2 ≤9π
2
⇒ 2x
2
yd(x y) + y
2 2 2
dy−x dx = 0

⇒ (4n – 1)2 + (4k + 2)2 ≤ 36 Integrating both side,

∴ When k = –1, n = – 1, 0, 1 and 2(x y)
2
2

y
3
3
x
⇒ + − + c = 0
when k = 0, n = – 1, 0, 1.
2 3 3

so,
So, total number of such pairs is 7
from case-I and 6 from case-II, 2
2
x
3 y
3

(x y) − + + c = 0
i.e., 13 pairs are possible. 3 3

2
2 3 3
3(x y) − x + y + c = 0

Therefore,

λ1 = 3 , λ2 = −1 , λ3 = 1

λ1 +λ2 +λ3 = 3 − 1 + 1 = 3
 Maths - Section D

14. Answer: C

Sol:
2

(P)
1 80 r
√∑
3 r=1 2
r −80r+3200

Let f(r) =
r
2
r −80r+3200

∵ f(r) + (80 – r) = 2

1 80
⇒ √∑ f (r) = 3
3 r=1

3 3 3
α tan α−α
e (e −1 )

(Q) lim
3 2
α→0 2 ln ( 1+α sin α)
3 3
tan α−α
= lim 5
2α
α→0

tanα−α
= lim ( )
3
2α
α→0
2 2
tan α+α +αtanα 1
( 2
)=
α 2

(R)
1 a
= ⇒ 2a = 1
2 1

(S) f(x) is non differentiable at 4

points x = 1, 4, 9, 16
15. Answer: A Sol:
π
θ1 + θ2 =
2

θ2 θ2
dθ tanθdθ
∴ I = ∫ = ∫
θ1 π θ1 1+tanθ
1+tan( −θ)
2

(Using King)
θ2
1002π
2I = ∫ dθ= θ2 − θ1 =
θ1 2008

(R)
501π
⇒ I = ⇒
2008

(B)
′ ′
1 {f ( x ) ⋅g ( x ) +f ( x ) ⋅g ( x ) }
2
I = ∫ [g (x)⋅
2
0 g (x)
′ ′
g ( x ) ⋅f ( x ) −f ( x ) ⋅g ( x )
+ 2
] dx
g (x)

1 f (x)
d d
= ∫ [{ f (x)⋅g(x)} + { ( )}] dx
0 dx dx g(x)

1
f (x)
= [f (x)⋅g(x)+ ]
g(x)
0

f (1)
= [f (1)⋅g(1)+ ]−
g(1)

f (0)
[f (0)⋅g(0)+ ]
g(0)

– [(0) – (0)] = 2009

2009 2009
= [ + ]
2 2

⇒ (S)

(C) Consider y = f(x) = (1 – xn+1)1/n

where n = 2007

⇒ x = f–1(y) = g(y) say

∴ yn = 1 – xn+1;

xn+1 = 1 – yn;
1
n
x = (1 − y ) n+1 ;

1
−1 n
f (y) = (1 − y ) n+1 ;

1
n
g (y) = (1 − y ) n+1 ;

1 1

n 2007 2008
g (x) = (1 − x ) n+1 = (1 − x )

Hence, the two functions appearing

as integra and are inverse of each
other.
1 1
∴ I = ∫ f (x)dx − ∫ g(y) dy
0 0

But y = f(x)

⇒ dy = f ’(x)dx
 and x = g(y) 17. Answer: A

I = ∫
1
f (x)dx − ∫
0
′
xf (x)dx
Sol:
0 1

1
Total number of mapping is 35
(A) No, one-one mapping is possible
1 ′
= ∫ (f (x)+ xf (x)) dx = xf(x)]
so probability is zero.
0
0

(B) Select any two from five to map

= f(1) – 0 = 0 ⇒ (P)
16. Answer: A with 3 is 5C2 and map remaining
things
Sol: (C) (2, 2, 1), (2,1,2), (1,2,2),
(1,1,3), (1,3,1) & (3,1,1)
(A) 2 2 2

∴Required number of onto function

2 sin θ + 4 sin θcos θ = 2

2 2 2 = 30 + 30 + 30 + 20 + 20 + 20 =
sin θ + 2 sin θ (1 − sin θ) = 1
150
So probability =
150
2 4
3 sin θ − 2 sin θ − 1 = 0 3
5

1
⇒ sinθ = ± , ±1
√2

π π
θ = ,
4 2
(D)
(B)
3x
Let y =
π

1 π
⇒ ≤ y ≤ 3∀x ∈ [ , π]
2 6
4

Probability =
3 1
=
Now f(y) = [2y] cos [y] 3
5
3

Critical points are y = 1

2
, y = 1,
3
y = ,y = 3
2

Point of discontinuity
π π π
{ , , , π}
6 3 2

∣1 1 0 ∣
∣ ∣
(C) Volume = 1 2 0
∣ ∣
∣1 1 π∣

→ → →
(D) a + b = −√3 c
→ 2
∣→ ∣
⇒ ∣ a + b ∣ = √3
∣ ∣

→ 2
∣→ ∣
∣ a + b ∣ = 3⇒ 1 + 1 + 2cosθ = 3
∣ ∣

1 π
cosθ = ⇒ θ =
2 3
Physics - Section A
1. Answer: C 2. Answer: B,C

Sol: Sol:

As we know velocity of object 1 & 2 Given that in the arrangement

after collision is given by, shown, the small spherical object of
mass m is at rest on a smooth floor
m1 − em2 ( 1+e ) m2 u2
at x = − 2 and it is connected to a
R
v1 = ( )u1 +
m1 + m2 m1 + m2

spring of force constant k.

( 1+e ) m1 u1 m2 − em1
v2 = + ( )u2
m1 + m2 m1 + m2

Mass of ball A and ball B is same

which is m & mass of ball C and ball
D is same which is 2m.

Velcotiy of ball A, ball B, ball C and

1 2 1 2 R
ball D before collision, 2
mv =
2
kA ⇒ A =
4

ua = 0
Period where is the
m m
T = 2π√
k k
ub = v

uc = 0
system parameter ratio.
ud = 0
Given
3π m 3T
t = √ =
4 k 8

For elastic collision, e = 1 x = A sin ωt ⇒ V = Aω cos ωt

So the velocity of ball B and ball C R

√
k 2π 3T
Vο = cos
after collision will be, 4 m T 8

m − 2m v R k 1
vb = ( )v = − Vο = √ ( )
m + 2m 3 4 m
√2

2 mv 2
vc = = v
Then object distanceVο
R k
m+ 2m 3 = √
4 2m

Now after 1st collision ball C travelled

Therefore, option (2) is correct and
with speed vc & colliode with ball D
(1) is incorrect.
and ball B travelled with velocity vb
& colliode with ball A. x = A sin ωt =
R
sin
2π 3T
=
R

4 T 8
4√ 2

As given that all collision are elastic

collision and we know if collision is Then object distance u =(
R
−
R
)
elastic b/w equal mass objects then 2
4√ 2

equal masses interchange their

From the lens makers formula:
velocities.

So when after when ball C colliode

1
=
1

v
+
1

u
where f is focal length, v
f

with ball D(2nd collision) ball D is image distance, u is object

travelled with same speed of ball C distance
and ball C comes at rest and same
happen when ball B colliode with ball v
=(
f
)= 2√2
A(3rd collision) ball A travelled with
u f −u

same speed of ball B and ball

Then speed of the image is
B comes at rest. v
2
V1 = ( ) Vο
u
So overall there are 3 no. of collision.
R k 2k
1st collision b/w B & C |V1 |= 8 ×
4
√
2m
= R√
m

2nd collision b/w C & D Therefore, option (3) is correct and

3rd collision b/w B & A (4) is incorrect.

Hence, options (2) and (3) are

correct.
3. Answer: B,D

Sol:
hc
Ea =
λ

1
1−
λa E4 −E1 16 1
= = 1 1
=
λe E4 −Em 5
−
2 16
m

m = 2

hc
(4 → 2)Ee =
λ

h
λ =
√2mKE

12400 12400
λe = = = 4509A°
Ee 2.75

= 450nm

(2)n = 2 → −3. 4

n = 1 → −13. 6

E2 3.4 1
∴ = =
E1 13.6 4
 Physics - Section B

4. Answer: A 5. Answer: A

Sol: Sol:

We first find the area in which the Equation of continuity,

cannon shell can reach. The equation
of trajectory for cannon shell is Rate= r =
A
VP+ (A −
A
)VQ
3 3

1 2
gx
2
...
2
3r 3×0.1
y = x tan θ − 2
sec θ ∴ VP + 2VQ = = = 30m/ sec
u A −2
10
(i)
2 2
As Vp = 20 m/ sec
sec θ = 1 + tan θ

Hence, VQ = 5 m/ sec
For maximum y for a given value of x
- Therefore, the correct answer is (A)
1 2
dy
= x −
2
gx
(2 tan θ) = 0
6. Answer: D
2
d(tanθ) u

2
Sol:
u
⇒ tan θ =
gx
From Stefan's law., the rate at which
energy is radiated by sun at its
putting in equation (1)
surface is p = σ × 4 π r2T4
1 2 1 2
2 gx 4 2 gx
[Sun is a perfectly black body as it
u 2 u u 2
ymax = x − 2
[1 + 2 2
] = − 2
gx u g x 2g u
emits radiations of all wavelengths
∴ The cannon shell can hit an area and so for it e = 1] The intensely of
given by this power at earth's surface (under
the assumption R >>r0) is
1 2
2 gx
u 2
y ≤ − 2
2g u

p
I= 2
4πR

2 4

= σ×4πr T
2
4πR

Given in the problem 2 4

=
σr T

y = 250m, u = 100m/s, g = 10 m/s. R

2

Putting these value we get,

2
σr (t+273)
= 2
R
2
x
≤ 250
2000 Therefore, the correct answer is (D)
⇒ −500√2 ≤ × ≤ 500√2

Plane is in danger for a period of

1000√2
= 2√2 sec
500
7. Answer: C

Sol:

Smooth 10- T = 1a1 = a + Rα

1 2
TR = × 2R a = Rα
2

T = 2a
T
⇒ 10 − T = + T
2

⇒ T = 4

2 1 2
a = 2m/s ⇒ ℓ = × 2t
2 1

t1 = √ℓ

Case (ii)

10 − T' = 1a'1 + Rα' = 2Rα'

3 2
T' × 2R = × 2 × R α'
2

2T'
Rα' =
3

2T'
10 − T' = 2 ×
3

7T' 30 20
10 = ⇒ T' = ⇒ a' =
3 7 7

1 20 2
ℓ = × × t
2 7 2

7ℓ
t2 = √
10
 Physics - Section C

8. Answer: 2 9. Answer: 4

Sol: Sol:

Let T1 and T2 be the temperatures The energy of photon emitted by

before and after heating hydrogen atom is
respectively.
1
13. 6(1 − )= 10. 2 eV
Since the internal energy of the
2
2

system remains constant, we have:

Let the electron to be removed from
ΔQ = ΔW lithium (Li) be in a state denoted by
quantum number n. Then,
Then, the internal energy as a result
of heating is given as: z
2
3
2

10. 2eV ≥ 13. 6( 2

)= 13. 6( 2
)
n n
3
ΔW1 = R(T2 − T1 )
2 2

or 2 13.6×3
n ≥ = √12
The potential energy of compressed
10.2

spring is given as: or n ≥ 2√3

ΔW2 =
k
(x2
2 2
− x1 ) Therefore, the minimum value of n is
2
4.

Equillibrium condition of piston gives

that:
F kx
P = =
S S

pS
⇒ x =
K

Thus, the potential energy becomes:

R
ΔW2 = (T2 − T1 )
2

So, the total change in energy is:

ΔW = ΔW1 + ΔW2

= 2R(T2 − T1 )

Then, the heat capacity of the system

is:
ΔQ ΔU
C = = = 2R.
ΔT T2 −T1
10. Answer: 27 12. Answer: 4

Sol: Sol:

Q value of the reaction is, The charge transferred will be

distributed between the capacitor
Q = (2 × 4 × 7. 06 − 7 × 5. 6) MeV

QC = CV
= 17. 28 MeV
dQ
C dV dC
iC = = C + V
dt dt dt

2 2
diC d V dV dC d C
= C 2
+ 2 + V 2
dt dt dt dt dt

Applying conservation of energy for = 6 ×

1

2
− 2 ×
1

2
× 2 +
1

2
× 0 = 1 mA / sec

collision,
dir
= 1 mA / sec
Kp + Q = 2 Kα .....(i) dt

dic

(Here, Kp and Kα are the kinetic dt

= 1mA/ sec

energies of proton and α - particle diℓ diC dir

respectively) dt
=
dt
+
dt
= 2 mA / sec

From the conservation of linear VL = L

diℓ
= 4 mV
momentum (As there is no external dt

force) ......(ii)

[Here P = √2 mk ]
2
⇒ Kp = 16Kα cos θ

2
1
=( 16 Kα )( ) ( as mα = 4mp )
4

∴ Kα = Kp .......(iii)

Solving eqs. (i) and (iii) with Q =

17.28

we get Kp = 17. 28 MeV

11. Answer: 7

Sol:
C

n1 C−Vs

Given that
3 1
= =
2 n2 C

C−Vs
2

3 C−Vs2 2C
⇒ = ⇒ ω =
2 C−Rω 5R

Beats when S1 is at A
C C 5n
Δn1 =[ − ]n =
C−Rω C−Vs2 9

Beats when S1 is at B
C C
Δn2 =[ − ]n
C+Rω C−Vs2

25n
Δn2 =
63

Δn1 7
∴ =
Δn2 5
13. Answer: 2

Sol:

charges +q are placed A+ A, C and

D. charge Q is place at B.

Now it's given net force on charge q

diagonally to Q that is D is O.
2
q
from figure, F1 = F3 = 2
4πε0 a

Resultant of F1 & F3 acting

perpendicular is along diagonal 'BD'
and is equal to
2
√2.q
√2 F1 =
2
4πε0 a

BD=√2. a

And force on + q at D due to Q,

qQ
F2 =
2
4πε0 (BD)

qQ
F2 = 2
along BD
8πε0 a

Net force √2 F1 + F2 = 0 along BD

2
√2q qQ

2
+ 2
= 0
4πε0 a 8πε0 a

Q = −2√2 q

In comparing x = 2.
 Physics - Section D

14. Answer: B 16. Answer: A

Sol: Sol:

T
y
A→Q;B → R,S ; C → S; D → P,
(A) = cont.
P
y−1
Q, R
y−1
TP
y
= const. ∴ R 17. Answer: A

Sol:

(A) If upper plate is initially -ve

charge (q1) then charge after time t

q = – q1 + q0 (1 – e–t/RC) ... (1)

where q0 is may charge
correct option is (P)
kQx
(B)
2
(x + R )
2
3/2
If initial charge across capacitor is
more then maximum charge, then
when switch is closed capacitor starts
discharge. so correct option is (Q)
too.

(B) diff. eq (1) w.r.t. t

–t/ RC –t
I = q0 (– e ) ×
RC

q0
–t/ RC –t/ RC
(C) I =
RC
e = I0 e

so correct option is (S)

(C) If q = q1 + q0 (1 – e–t/RC)
(D) Speed decreases as infinity does
–t/ RC

not exist. I =
dq
=
q0 e

dt RC

15. Answer: B
d0 q0 –q+q1
I = = [ ]
Sol: RC q0

q0 +q1 1
I = ( )–( )q
RC RC

This is straight line relation, & correct

option is (R)
2
q
1
U =
2 C

Put value of q from eq (1) and

correct option is (Q) ]

l
E2 = V ' = E1
1+R
 Chemistry - Section A

1. Answer: A,B,C 2. Answer: B,C,D

Sol: Sol:

(i)

(ii)

(iii)
M.O. is vacant in

ground state

(iv)

3. Answer: B,C,D
 Chemistry - Section B

4. Answer: C 6. Answer: D

Sol: Sol:

[CO32−] to just start ppt. of SrCO3

[CO32−] to just start ppt. of MgCO3

5. Answer: D =
Sol:
Now, for H2CO3 2H+ + CO32−
Polarity can be defined as
electronegativity difference: Ka =
Electronegativity order N > P⇒
Polarity order H – N > P – H ∴ [H+] Max [H+] to start ppt of SrCO3
Hence the correct order will be- P-H ​
< As-H < Sb-H < N–H = M

∴ Min pH to start ppt. of SrCO3 = 4.8

And, Max [H+] to start ppt of MgCO3

∴ min pH to start ppt. of MgCO3 =

5.6

Hence, in the pH range 4.8 to 5.6,

only ppt. of SrCO3 will occur.

Therefore, the correct answer is (D)

7. Answer: D

Sol:

Their electronic configurations are

given below :

Ce = [Xe] 4f1 5d1 6s2 ; Ce3+ = [Xe]

4f1

Eu = [Xe] 4f7 6s2 ; Eu3+ = [Xe] 4f6

Yb = [Xe] 4f14 6s2 ; Yb3+ = [Xe]

4f13

It is clear from the configuration

of Ce3+ , Eu3+ and Yb3+ are
paramagnetic ions.
 Chemistry - Section C

8. Answer: 4 9. Answer: 9

Sol: Sol:
Es
−
K = A0 e RT

(A)
Ea
lnK = lnA0 −
RT

(B) logK = log 1000 −

11488

8.314×300×2.30

= 3 − 2 = 1
(C)
−1
K = 10 hrr

A0

(D) Kt = ln(
At
)

( A0 )
2. 3 = 2. 3 log( )
( At )

(E) (
A0
)=
10
=
A0

At 1 A0 −x

( E.C )t
= 9
( B.C.C )t

(F)
10. Answer: 2

Sol:
(G)
XeO3 + NaOH→NaHXeO4

2NaHXeO4 + 2NaOH→Na4 XeO6 +

(H) 2H2O + Xe + O2

XeO64– ion of Na4XeO6 has octahedral

structure which contain two pπ dπ
bonds.
11. Answer: 7 13. Answer: 6

Sol: Sol:

The magnetic moment can be

calculated with the help of the
formula:

μ = √n(n + 2) ; Here n is the

number of unpaired electrons.

Higher is the number of unpaired

C products are (after ozonolysis) electrons higher will be the magnetic
moment.

(1) Compound A is MnO2

Mn+4 (3d3) ⇒ n = 3, µ = 3.87 = x

12. Answer: 25 (2) Compound B is K2MnO4

Sol: Mn+6 (3d1) ⇒ n = 1, µ = 1.73 = y

The value of H+ is maximum, e.m.f. (3) Compound C is KMnO4

will be minimum.
Mn+7 (3d0) ⇒ n = 0, µ = 0 = z
+
[H ]= Cα
So, (x+y+z) = 3.87 + 1.73 + 0
If α ↑, i ↑, ΔTf ↑, freezing point = 5.60
decreases so e.m.f decreases.

Hence acid HE have maximum [H

+
] ,
so x = 5
 Chemistry - Section D

14. Answer: C 16. Answer: D

Sol: Sol:

NaNO2 + dil. H2 SO4 →

Readily decompose

HN O2 −−−−−−−−−−−→ NO

+
H

(P) HNO2 + FeSO4 →

aq

+1 +1

[Fe (H2 O) (NO)] SO4

5

(Brown ring)

(Q) 2 HgCl
2
+ SnCl2 →

Hg Cl2 + SnCl4
2

(White ppt)

(R) Hg
2
Cl2 + NH4 OH →

Hg + Hg(NH2 )Cl
(Black ppt)

H2 S

(S) Ni
+2
−−−
− → NiS
NH4 OH (Black ppt)

17. Answer: A

Sol:
So. the correct answer is option 'C'. Theory based
15. Answer: B

Sol:
T1
η = 1 − = 1 − 0. 5 = 0. 5
T2

%η = 50%

ΔUtotal = qtotal + wtotal

qtotal = −wtotal

qtotal = (T2 ΔS) − (T1 ΔS)

heat taken from source heat rejected to sink

= 800 × 100 − 400 × 100

= 80000 − 40000

qtotal = 40, 000 = 40 kJ

|Wtotal |= | − 40 kJ | = 40 kJ

Heat rejected to sin k = −40 kJ

Number of cycles required to

illuminate 1000 bulbs of 200 watt
each (per second)
1000×200
= = 5
40,000