ipc part 2
ipc part 2
For general purposes, the higher powers assumed to be zero, leaving only
average coefficient of resistance.
Thereby a linear relationship between resistance and temperature is
assumed over a small temperature range.
This method is not sufficiently accurate for use in resistance
thermometry.
For platinum two constants are sufficient up to about 1200oF and even
higher.
Its equation is therefore quadratic and varies from a linear relationship
by about 7% at the upper limit.
Three constants are generally used for copper, although the relationship
is very nearly linear up to 250oF.
3 constants are required for nickel in the common temperature range,
and its relationship is nonlinear.
The coefficient of resistance may vary considerably with the purity
of the metal and with its heat treatment.
In fact temperature coefficient of resistance has been used as a test for
impurities.
This is considered as disadvantage in the use of the resistance
thermometer; namely that the primary element is sensitive to
contamination and oxidation and requires protection.
Resistance temperature measurements may be made below 32oF, but
although platinum has been used as low as -400oF, the industrial
resistance thermometer is not often used below -150oF.
The resistance vs temperature was radically altered at very low
temperatures by the phenomenon of superconductivity.
At a temperature of about 1 to 50o K, depending upon the metal, the
resistance drops suddenly to almost zero.
Naturally the resistance thermometer can not be used below this point.
In precision resistance thermometry a platinum resistance element is
used.
The resistance-temperature relation for platinum is given by
Callendar equation:
T = [(Rt – Ro)/(R100-Ro)]100 + δ[T/100 – 1]T/100
T = temperature at resistance element, oC
Rt = resistance at temp T, ohms
Ro= resistance at 0oC, ohms
R100=resistance at 100oC
δ = constant, characteristic of each element (about 1.49 to 1.50per deg.
centigrade)
The accuracy of the Callendar equation is excellent agreement with
the thermodynamic scale, and correction is not required in the
region 32 to 1832oF.
3 constants, R100, Ro, and δ are determined by calibration of
thermometer at 0,100 and 444.6oC.
Another form as indicated in right side figure, is made with the platinum
wire clamped between two mica plates.
This latter form makes the thermometer bulb more compact.
Improvement in heat transfer characteristics is obtained by using a
metal frame having spring qualities so as to insure physical contact
between all parts of the bulb.
The platinum bulb is used industrially between the limits of -300 to
1200oF.
The copper resistance bulb usually has 10 ohms resistance at 32oF, less
than other bulbs because of low resistivity of copper.
Since it is used only at moderate temperatures, the frame may be
composed of a plastic or of a glass instead of mica.
The copper bulb is used industrially between the limits of -40 and 250oF.
The nickel resistance bulb has a resistance at 32oF of 100 to 300 ohms,
depending on the circuit in which it is used.
A high resistance is employed because the resistivity of nickel is high, it
is a relatively inexpensive material, and high resistance makes
resistance measurements easier.
Since it is used in moderate temperature range, the wire may be wound
with plastic or glass insulation.
Temperature range: -300 and 600oF.
A resistance thermometer element is some times made of a very thin
nickel foil with a resistance of about 10 ohms. As a bolometer it is used
to receive radiant energy.
Another type of resistance thermometer element is made in the form
of a woven-wire mesh cloth. This type is particularly suitable for some
surface temperature measurements.
The measuring junction is formed in two different ways: twisted weld and
butt weld.
The twisted weld is made by twisting the two wires for several turns and
welding.
The shape of the junction after welding remains unchanged.
Twisted weld is made with wires of larger sizes and gives mechanical strength.
The butt weld is made by fusing the two wires into a round bead. This is used
for small size wires.
In order to prevent the forming of a second junction, the wires of a
thermocouple are insulated from each other by being threaded through
porcelain insulators.
These insulators will retain their shape up to 2800 F
o
The ends of the thermocouple wires are connected to a porcelain block having
screw terminals for connections.
Tube thermocouples are made of iron-Constantan with the iron in
the form of a tube, the constantan wire running down the center of
the tube as shown below:
The purpose of this construction is to improve speed of response by
avoiding the use of a thermal well.
The iron tube is generally 1/8 inch outside diameter, and the
junction is made by swaging and welding the iron tube around the
constantan wire.
The constantan wire is insulated from the iron tube with either
asbestos or ceramic.
•
The cost of long lengths of Chromel and Alumel wire is high, and the
cost platinum wire in even moderate lengths is prohibitive.
With Chromel-Alumel and platinum thermocouples less expensive
lead wire is used.
Iron and Copper-Nickel alloy lead wires which have temperature-
emf characteristics very close to that of Chromel-Alumel, are widely
used.
Copper and Constantan lead wire may be used for Chromel-Alumel
thermocouples only when high accuracy is not required, since temp-
emf characteristics of these pairs do not match beyond 125oF
For Platinum thermocouples, lead wires are made of copper and
copper-nickel alloy, the temperature-emf characteristics of which is
the same as for platinum thermocouple.
This is important since floats are usually spherical, and this is the
point of maximum area.
The float cage may be obtained in steel or cast iron and float in
copper, stainless steel, nickel or aluminum.
The rotation of the shaft may be converted into a change of
pneumatic pressure by the use of a pneumatic transmission system.
Indicating and recording instruments, remotely located, may be
operated from the float when pneumatic means of transmission are
used.
Often the motion of the float is used to operate directly a valve for
control of level or to operate directly a recording instrument.
The range of the instrument is restricted, and level changes greater
than 10 to 20 in. can not generally be measured.
Several different means are in use for transmitting the arm motion
o the float and shaft type unit to a remote point. One of these is
shown in fig.9.3.
The pressure gage may be installed up to about 1000 ft from the vessel and can
be placed either the above or below the vessel.
The rate of feed to the bubbler pipe should preferably be controlled with an
orifice and differential pressure regulator.
Often a small rotameter is used to indicate the flow of feed.
The diaphragm box system is shown in the fig. 9.5
It is very similar to diaphragm seal used for pressure gages, with the difference
that the diaphragm is very slack, thin and flexible and the system is filled
with air.
The diaphragm box is usually suspended in the vessel by a chain or if currents
exist in the vessel, by a fixed support.
The box is connected to the pressure receiver.
The calculations regarding pressure, head and density are the same as for the
bubbler system.
The instrument may be located up to about 500 ft from the vessel
and either above or below it.
Changes in level from about 20 in up to 250 ft may be measured.
This system is some what limited for use in corrosive liquids.
The diaphragm boxes are made of cast iron or bronze and
diaphragms are of neoprene fabric.
For liquids with suspended solids, a liquid flushing arrangement can
be made to clear the open end of the diaphragm box.
It is essential that the complete system be airtight since loss of air
would prevent operation.
The air trap system is shown in the Fig. 9.6
This system is similar to the diaphragm box system, except that no
diaphragm is used; the reason is that no suitable diaphragm material
can be found for some kind of corrosive liquids.
The pressure receiver operates from the pressure of the trapped air.
The main limitation of this type is the possibility of slow loss of air
trapped in the system.
For this reason, an auxiliary tap should be provided for filling the
system with air as frequently as necessary.
The pressure measurement of liquid level is theoretically as accurate
as the pressure gage itself.
Weight determinations are direct when the pressure measurements
are used.
Radiation pyrometers
The radiation pyrometer consisting of a radiation receiving element
and a potentiometer instrument has come into wide use because it is
able to measure directly temperature of work surfaces in a furnace.
It can measure the temperature of moving objects, and is less
effected by a corrosive atmosphere than a thermocouple, and it can
measure higher temperature than a thermocouple.
Most important in many applications is its fast speed of response.
The most common type of radiation receiving unit is shown in the
figure.
A lens is used to concentrate the radiant energy from the source on
the diaphragm and on the thermopile.
Sighting glasses are shown in the unit to enable the proper line of
sight and proper focus to be established.
The position of the lens or the diaphragm is usually made
adjustable for calibrating purposes.
The angle of the lens or mirror is usually selected so that the target
diameter is a given fraction of the distance from target to receiver.
The distance from target to receiver is 10 or 20 times the maximum
useful diameter of the target.
The lens type radiation receiver is arranged so that the image of the
target surface is focused on the diaphragm opening.
For this reason, an adjustment of the position of either the
diaphragm or the lens is provided.
The mirror type radiation receiver is arranged so that the image of
the front diaphragm is focused on the thermopile by the mirror.
Therefore the measured temperature is substantially independent
of target distance if the field of view is filled.
Absorbing media at ambient temperature between the target and
thermopile reduce the amount of radiation received by the thermopile.
Such substances as smoke, dirt and gases absorb radiation and cause
the instrument to read low.
On the other hand, hot gases, flame, and high temperature carbon
particles may add to the radiation and cause the instrument to read
high.
Gases such as CO2, SO2 and water vapor, ammonia have absorption and
radiation bands in the wavelengths useful to the radiation receiver.
If these media are prevalent, then one remedy is to use a target tube.
Some times an open tube which is purged with air will keep the line of
view free from absorbing media.
Hot gases and flame in the line of sight should be avoided.