305-34208J

Aug. 2020

Shimadzu Multitype ICP Emission Spectrometer

ICPE-9800 Series

Instruction Manual
Hardware
Read this manual thoroughly before you use the product.
Keep this manual for future reference.
This page is intentionally left blank.
Introduction
Read this manual thoroughly before using the product.
Thank you for purchasing this product. This manual describes the installation, operation,
hardware validation, usage cautions, accessories and options for this product. Read this
manual thoroughly before using the product and operate the product in accordance with
the instructions in this manual.
Also, keep this manual for future reference.

IMPORTANT
• If the user or usage location changes, ensure that this Instruction Manual is always
kept together with the product.
• If this manual or a product warning label is lost or damaged, immediately contact
your Shimadzu representative to request a replacement.。
• To ensure safe operation, read all Safety Instructions before using the product.
• To ensure safe operation, contact your Shimadzu representative if product
installation, adjustment, or re-installation (after the product is moved) is required.

Notice
• Information in this manual is subject to change without notice and does not represent
a commitment on the part of the vendor.
• Any errors or omissions which may have occurred in this manual despite the utmost
care taken in its production will be corrected as soon as possible, although not
necessarily immediately after detection.
• All rights are reserved, including those to reproduce this manual or parts thereof in
any form without permission in writing from Shimadzu Corporation.
• Microsoft and Windows are registered trademarks of Microsoft Corporation in the
United States and/or other countries. Other company names and product names
mentioned in this manual are trademarks or registered trademarks of their respective
companies. The TM and ® symbols are omitted in this manual.

ã 2014-2021 Shimadzu Corporation. All rights reserved.

ICPE-9800 Series Hardware i

 Introduction

Indications Used in This Manual

Dangers, Warnings, Cautions, and Notes are indicated using the following conventions:

Indication Meaning

Indicates a potentially hazardous situation which, if not

avoided, could result in death or serious injury.

Indicates a potentially hazardous situation which, if not

avoided, may result in minor or moderate injury, or equipment
damage.

Indicates information provided to improve efficiency or clarify

explanations.

The following symbols are used in this manual.

Indication Meaning

Indicates an action that must not be performed.

Indicates an action that must be performed.

Indicates information provided to improve product performance.

Indicates the location of related reference information.

ii ICPE-9800 Series Hardware

 Safety Instructions

Safety Instructions
To ensure safe product operation, read these important safety instructions carefully
before use and follow all, WARNING and CAUTION instructions given in this section.

n Caution Regarding the Installation Place

Do NOT use this product in hazardous environment such as when explosive

gas exists.
Explosion may occur.

Do NOT use fire in a room where inflammable solvent is used.

Avoid installing other devices that generate sparks in a same room with this
product.
Take appropriate measures against static electricity thoroughly.
Prepare a fire extinguisher for possible accidents.

Some of solvents that are used for the measurement are hazardous. Ventilate
the room thoroughly.
It may cause intoxication.

Install a cleaning facility near this product.

Install a cleaning facility near this product, so an operator can wash eyes,
hands, and other parts whenever the operator contacts the solvent or the
solvent gets into eyes.

ICPE-9800 Series Hardware iii

 Introduction

Do not install the equipment in places where corrosive gases and gases
containing organic solvents/dihalides/siloxanes, oil mists, wastes/dust are much
existing.
Performance may fail to maintain and the lifetime of the equipment may
become shortened.

Do not use the equipment in the environment where the equipment

condensates.
It may not be properly operated.

Do not install in places where liquids are poured on the equipment. Also, do
not place a vessel with liquids available on the equipment.
If liquids enter inside the equipment, it causes ignition, electric shock, failure.

Do not install the equipment in places where there are strong magnetic
sources.
In strong magnetic places, the equipment may not properly operate. Also, when
the power source lines have much noises, add the noise filters.

Install the power switch in an easy to operate place.

The power switch is located in the left side face of the equipment. It is
necessary to be ready to turn off the power source immediately in the event
of emergency.

Install in an indoor environment with the installation category (II), pollution

level (2), and the altitude of 2000 m or lower.
Environment with other conditions may prevent its normal operation.

Consider the weight of entire measurement system when installing this

product.
The desk or the table which this product is placed has to be able to bear the
entire weight of the measurement system and is flat and stable. If the product
is installed on a location not satisfying above conditions, an accident due to
falling or dropping may occur.

Do not install the equipment in places where corrosive gases and gases
containing halides, wastes/dust are heavily existing.
This may make it impossible to maintain the product's performance or shorten
the life of the product.

Confirm the sufficient ventilation at the installation location.

This product uses Argon gas; therefore, without good ventilation, an operator
may suffer from oxygen deficiency.

Prepare an independent grounding with the grounding resistance of 30 Ω or

lower (10 Ω or lower if possible).
During the operation, the product emits high frequency that is within the
range specified in the Radio law and such high frequency leaks outside from
the product.
Check that the surrounding devices do not get affected.

iv ICPE-9800 Series Hardware

 Safety Instructions

n Caution Regarding the Installation Work

Do not put heavy objects on the power cord, and do not get near heating
appliances.
Do not process, forcibly bend and pull the power cord.
Cords damage, and it causes ignition, electric shock, failure.
If the cords damaged, immediately contact your Shimadzu representative to
request a replacement.

To ensure safe operation, contact your Shimadzu representative if product

installation, adjustment, re-installation (after the product is moved), or repair
is required.
It may cause injury and failure. Also, it is also important to secure the safety
of the equipment operation.

Take measures for topple-over prevention due to an earthquake.

The equipment topples over due to vibrations, and may cause injury.

Check the power supply voltage displaying on a label of the equipment side,
and connect to the conforming power source.
If it is not conforming to it, and it causes ignition and electric shock. When
the power supply voltage is unstable and the power source capacity is short,
a satisfactory performance cannot be obtained. Also check the power source
capacity of the whole system, and after checking it, prepare for the conforming
power source.

Ground.
If not grounded, when the failure and current leakage occur, it may get an
electric shock. Also, it is also important to secure the safety of the equipment
operation.

Connect the power cord to the power receptacle located at easy to reach
position by a hand.
In the event of emergency, it is needed to disconnect the power cord from
the power receptacle.

ICPE-9800 Series Hardware v

 Introduction

When installing the equipment, be careful for gaps of the equipment.

It may cause injury by pinching fingers.

Caution should be taken so that you do not pinch your fingers whil
opening/closing the door.
It may cause injury.

Perform the earth for potential equalization with the PC and the optional
system.
Communication between systems breaks down, and the system fails.

vi ICPE-9800 Series Hardware

 Safety Instructions

n Caution Regarding the Work and Operation

In the event of unusual sounds and foreign odors generating from the main
body, and if nothing is displayed on the display of the data processing PC,
do not use the equipment.
It may lead to the important accidents and data loss.

Do not use a flammable spray (hair spray, spray type insecticides, etc.) near
the product.
It may cause fire by igniting.

Be sure to take appropriate measures against static electricity.

Static electricity may catch fire on the sample, etc., causing a large scale
accident such as fire and explosion.

When analyzing organic solvent, use the organic solvent system (option).
When organic solvent is analyzed without using the organic solvent system, it
may lead to a serious accident.

When handling a solvent or a sample, wear protective goggles and gloves.

If the solvent gets into an eye of an operator, the eye sight may be lost.
If the solvent gets into an eye, immediately rinse with clean water, and
getmedical attention.

Consult a doctor if you are wearing a pace maker.

During the operation, the product emits high frequency that is within the
range specified in the Radio law and such high frequency leaks outside from
the product.
If you are wearing a pace maker, consult a doctor in order to prevent any
accident.

Be sure to connect the equipment to a duct for exhaust, and always exhaust
during analyzing.
Poisonous gases may generate depending on the samples, and if the exhaust
is insufficient, it may lead to the important accident.

Use the power cord specified or provided by Shimadzu.

Failing to do so may result in electric shock or fire. Do NOT use the power
cord specified or provided by Shimadzu for other devices. This product
(including accessories) is manufactured for measuring and industrial purposes,
and not suitable for household usage.

ICPE-9800 Series Hardware vii

 Introduction

Do not wipe the equipment with alcohol and thinner-family solvents.

It may cause failure, rust and discoloration.

If chemical is attached on the product, immediately remove the chemical.

Due to the paint and resin material used on exterior of the product, some
chemical might be converted.

Be sure to take the backups for the contents in the hard disk of the PC.
The important data may be lost due to contingencies.

Turn off the power source, and when the power source is turned on once
again, be sure to space the interval of 30 sec. to the minimum.
Otherwise, it may cause failure.

When operating the vacuum pump from the standby status, fully ventilate the
measuring room.
Oil steam may discharge from the vacuum pump, and if the ventilation is
insufficient, it may lead to the accident.

When poisonous samples and waste liquids are handled, properly protect
yourself by wearing gloves and masks.
If mishandled, it may lead to the accident.

n Caution about a High-Frequency Use

Observe applicable regulations for the country where it is used.

The 27 MHz magnetic field leakage at 1 meter from the side of the instrument
is 1 V/m or less.

n Caution about a Waste Fluid Disposal

Waste fluids to be discharged after measuring a sample should be properly

disposed of in accordance with laws and municipal ordinances.
When the improper disposal is made, penalties may be fined.

n Caution Regarding the Handling of High Pressure Gas

In this product, a high pressure argon gas are being used. Be sure to check the following
contents, and caution should be taken for handling gases.

viii ICPE-9800 Series Hardware

 Safety Instructions

Pay attention to that there is no flame within 2 m in surroundings of the gas

cylinder, and make sure that the temperature does not become at 40°C max.
Be sure to secure the gas cylinder with ropes, etc., and never overturn.
When a high temperature and a strong impact are added, it may explode.

Install the gas cylinder outdoors where the direct sunlight is not applied with
good draft, and introduce the gas to indoors by a piping.
When the liquefied gas cylinder is used in particular, since this installation
method is obliged by law, be sure to observe it.
When a high temperature and a strong impact are added, it may explode.

Fully ventilate the measuring room, and after the use of gas is finished,
tighten the main cock of the cylinder immediately.
In case the gas leakage occurs, it may become devoid of oxygen.

When the stockpiles of the high pressure argon gas cylinder becomes 300 m3
max., take the legal authorization.
When this equipment is used without obtaining the authorization, penalties
may be fined. Refer to the law such as High-Pressure Gas Safety Law.

When this equipment is used without obtaining the authorization, penalties

may be fined. Refer to the law such as High-Pressure Gas Safety Law.

n Caution Regarding the Maintenance Inspection / Upgrading Services

In other than the operation described in this document, never remove the
main body cover.
It may cause injury and failure.
As for the repair necessary to remove the main body cover in other than the
operation described in this document, consult your Shimadzu representative.

When the inspection, the service and replacement of the parts are performed,
turn off the breaker of the switchboard.
It may cause electric shock and short circuit.

When the parts are replaced, use the parts being described in the instruction
manual.
If the other parts are used, the equipment may not normally enable to be used
due to breakage of the parts.

ICPE-9800 Series Hardware ix

 Introduction

n Danger of Repairs / Disassembling / Remodeling

Do not remodel / disassemble without permission.

It may cause electric shock and short circuit. Also, it may cause injury and
failure.

As for repairs, consult your Shimadzu representative.

It may cause ignition, electric shock and injury.

x ICPE-9800 Series Hardware

 Safety Instructions

In an Emergency

If abnormality such as scorching odor is discovered, immediately stop the equipment.

Furthermore, when the equipment is used again, inspect the equipment, and contact your
Shimadzu representative if necessary.

1 Turn off the power switch on the left side of the main body.

2 Turn off the main breaker of the power source line.

3 Close the main cock of gas being supplied to the equipment.

4 Close the main cock of water being supplied to the equipment.

(When the optional cooling water circulation system is used, stop the cooling water
circulation system, and turn off the power.)

5 Turn off the power source of the following equipment.

• PC
• Display

ICPE-9800 Series Hardware xi

 Introduction

During a Power Outage

If power outage occurs, immediately stop the equipment.

Furthermore, when the equipment is used again, inspect the equipment, and contact your
Shimadzu representative if necessary.

1 Turn off the main breaker of the power source line.

2 Turn off the power switch on the left side of the main body.

3 Close the main cock of gas being supplied to the equipment.

4 Close the main cock of water being supplied to the equipment.

(When the optional cooling water circulation system is used, stop the cooling water
circulation system, and turn off the power.)

5 Turn off the power source of the following equipment.

• PC
• Display

xii ICPE-9800 Series Hardware

 Safety Instructions

Warning Labels

In order to ensure safety, warning labels are attached in places requiring caution.
If a warning label is lost or damaged, obtain a new label through your Shimadzu
representative and attach it in the correct position.

Locations where warning labels are affixed

ICPE-9800 Series Hardware xiii

 Introduction

Num
Warning Labels Description
ber
Back face 037-70863-02 LABEL,WARN SB80-863P
1 「RISK OF ELECTRIC SHOCK」
Refer servicing to qualifed personnel.
Front of top face of plasma stand 037-72525-01 LABEL,
WARN SB60-525P
2
「HIGH TEMPERATURE」
Risk of burn.Avoid contact or looking into the duct.

Top front of plasma stand 037-70859-01 LABEL,

WARNING SB150-859P
3 「HOT SURFACE」
Risk of burn. Avoid contact within 3 min, after the
plasma-OFF.

xiv ICPE-9800 Series Hardware

 Warranty

Warranty
Shimadzu provides the following warranty for this product.

1. Period:
Please contact your Shimadzu representative for information about the period of this warranty.

2. Description:
If a product/part failure occurs for reasons attributable to Shimadzu during the warranty period,
Shimadzu will repair or replace the product/part free of charge. However, in the case of products
which are usually available on the market only for a short time, such as personal computers and
their peripherals/parts, Shimadzu may not be able to provide identical replacement products.

3. Limitation of Liability:
(1) In no event will Shimadzu be liable for any lost revenue, profit or data, or for special, indirect,
consequential, incidental or punitive damages, however caused regardless of the theory of
liability, arising out of or related to the use of or inability to use the product, even if Shimadzu
has been advised of the possibility of such damage.

(2) In no event will Shimadzu's liability to you, whether in contract, tort (including negligence), or
otherwise, exceed the amount you paid for the product.

4. Exceptions:
Failures caused by the following are excluded from the warranty, even if they occur during the
warranty period.

(1) Improper product handling

(2) Repairs or modifications performed by parties other than Shimadzu or Shimadzu designated
companies

(3) Product use in combination with hardware or software other than that designated by Shimadzu

(4) Computer viruses leading to device failures and damage to data and software, including the
product's basic software

(5) Power failures, including power outages and sudden voltage drops, leading to device failures
and damage to data and software, including the product's basic software

(6) Turning OFF the product without following the proper shutdown procedure leading to device
failures and damage to data and software, including the product's basic software

(7) Reasons unrelated to the product itself

(8) Product use in harsh environments, such as those subject to high temperatures or humidity levels,
corrosive gases, or strong vibrations

(9) Fires, earthquakes, or any other act of nature, contamination by radioactive or hazardous
substances, or any other force majeure event, including wars, riots, and crimes

(10) Product movement or transportation after installation

(11) Consumable items

Recording media such as CD-ROMs are considered consumable items.

* If there is a document such as a warranty provided with the product, or there is a separate contract
agreed upon that includes warranty conditions, the provisions of those documents shall apply.

ICPE-9800 Series Hardware xv

 Introduction

After-Sales Service and Availability of Replacement Parts

n After-Sales Service

If any problem occurs with this product, perform an inspection and take appropriate
corrective action as described in the troubleshooting section of this manual.
If the problem persists, or the symptoms are not covered in the troubleshooting section,
contact your Shimadzu representative.

n Replacement Parts Availability

Replacement parts for this product will be available for a period of seven (7) years after
the product is discontinued. Thereafter, such parts may cease to be available.
If Shimadzu receives notice of the discontinuation of units or parts, the necessary quantity
for the above period is immediately calculated and secured. However, such units or parts
may cease to be available within seven years after the discontinuation of the product,
depending on the conditions of individual manufacturers and on changes in the quantity
required.

Maintenance, Inspections, and Adjustment

In order to maintain the instrument's performance and obtain accurate measurement
data, daily inspection and periodic inspection/calibration are necessary.
• For daily maintenance, inspection, and replacement parts, see"7 Maintenance" P.38
of this manual.
• Periodic inspection/calibration should be requested to your Shimadzu representative.
• Replacement cycles described for periodic replacement parts are a rough estimate.
Replacement may be required earlier than the described replacement cycles depending
on usage environment and frequency.

Movement and Disposal of the Product

When the movement or disposal of this product is performed, consult your Shimadzu
representative.

xvi ICPE-9800 Series Hardware

 Action for Environment (WEEE)

Action for Environment (WEEE)

n To all users of Shimadzu equipment in the European Union:

Equipment marked with this symbol indicates that it was sold on or after
13th August 2005, which means it should not be disposed of with general
household waste. Note that our equipment is for industrial/professional use
only.

Contact your Shimadzu service representative when the equipment has

WEEE Mark reached the end of its life. They will advise you regarding the equipment
take-back.
With your co-operation we are aiming to reduce contamination from waste electronic and
electrical equipment and preserve natural resources through re-use and recycling.
Do not hesitate to ask Shimadzu service representative if you require further information.

ICPE-9800 Series Hardware xvii

 Introduction

Electromagnetic Compatibility
This product complies with following standard.
• IEC61326-1(EMI:Group2 ClassA, EMS:Iudustrial)
• FCC47 CFR Rert18 Subpart C
• KC(ISM device classification : Group2 Class A)

n Emissions (Electromagnetic Interference)

This is a class A product and is not designed for use in a residential environment.
When this product causes an electromagnetic disturbance to devices being used near this
product, create an appropriate distance between those devices and this product in order
to eliminate the disturbance.

n Electromagnetic Susceptibility (Immunity)

Test conditions are Table2(Iudustrial Lacation) .

Compliance with these standards does not ensure that the product can operate at a level
of electromagnetic interference that is stronger than the level tested. Interference
stronger than the values specified above may cause the product to malfunction.

When installing or using this product, especially in an industrial location:

Locate the product away from any device emitting strong levels of electromagnetic noise.
Use a power source that is separated from the power source of any device emitting
strong levels of electromagnetic noise.

To prevent static electricity:

Prior to touching the product, the operator should be sure to discharge the static
electricity stored in their body by first touching a grounded metallic structure.
Do not touch any terminals or connectors that are not connected to cables while the
product is turned ON.

xviii ICPE-9800 Series Hardware

Contents
Introduction Indications Used in This Manual ......................... ii
Safety Instructions ............................................. iii
Warranty ......................................................... xv
After-Sales Service and Availability of
Replacement Parts ........................................... xvi
Maintenance, Inspections, and Adjustment ........ xvi
Movement and Disposal of the Product ............ xvi
Action for Environment (WEEE) ....................... xvii
Electromagnetic Compatibility ........................ xviii

1 Overview

2 Parts

Preparation for 5
3 Installation
3.1 Installation Environment ......................................

3.2 Installing and Handling the Data Processing

Unit ................................................................... 5
3.2.1 Operating Environment and Storage ........................... 6
3.2.2 Maintenance ..................................................... 6

3.2.3 Other Points ..................................................... 6

Configuration and Operating 7

4 Principle of the ICPE-9800
4.1 Block Diagram ....................................................

4.2 Appearance and Configuration ............................. 8

4.3 Power Supply, and Argon Gas and Cooling
Water Piping ...................................................... 9
4.4 Connecting the Data Processing Unit to the
ICPE-9800 .......................................................... 10
4.5 Spectrometer and Light-Focusing System ............. 10
4.6 CCD Detector .................................................... 11
4.7 Shutter ............................................................. 12

ICPE-9800 Series Hardware xix

 Contents

4.8 Temperature Control ......................................... 12

4.9 Vacuum System ................................................. 12
4.10 Cooling System .................................................. 12
4.11 Argon Gas System ............................................. 13
4.12 Sample Introduction System (Including Plasma
Stand Interior) ................................................... 13
4.12.1 Standard Parts for the ICPE-9800 Series ..................... 17

4.12.2 Optional Torches .............................................. 17

4.12.3 Optional Nebulizer ............................................ 18
4.12.4 Chamber Kit for Organic Solvent Samples (Option) ......... 18
4.12.5 Hydrofluoric Acid Sample Injection System HFS-4 (P/N
S211-92881-41) (Option) ...................................... 19

4.13 Cooling Jacket ................................................... 19

4.14 Radial View Unit (ICPE-9820) .............................. 20
4.14.1 Selecting the View ............................................ 21
4.14.2 Selecting the Radial-view Observation Height ................ 21

4.15 RF Power Supply ............................................... 21

4.16 Purpose and Operating Principles of Safety
Devices ............................................................. 22
4.17 Connector Panel ................................................ 23
4.18 Peristaltic Pump (Option) ................................... 25
4.18.1 Mounting Position ............................................. 25

4.18.2 Pump Tube .................................................... 26

4.19 Optional Plasma Torch and Orifice Assembly S2

......................................................................... 26

5 Specifications 5.1 Plasma Light Source ........................................... 28

5.2 RF Power Supply ............................................... 28
5.3 Spectrometer ..................................................... 28
5.4 Measuring Unit ................................................. 29
5.5 Data Processing Unit Software:
ICPEsolution(Option P/N 211-44263-92) ................ 29
5.5.1 Measurement Samples ........................................ 29
5.5.2 Qualitative Analysis ............................................ 29
5.5.3 Quantitative Analysis: Calibration Curve Method /
Standard Addition Method ................................... 29
5.5.4 User Support .................................................. 30

xx ICPE-9800 Series Hardware

 Contents

5.5.5 Instrument Control ............................................ 30

5.6 Utilities ............................................................. 31
5.6.1 Power Supply Requirements .................................. 31
5.6.2 Ground ........................................................ 31
5.6.3 Argon Gas ..................................................... 31

5.6.4 Cooling Water ................................................. 31

5.6.5 Installation Conditions ......................................... 31

5.6.6 Dimensions and Weight ....................................... 31

5.6.7 Options ........................................................ 32

6 Operation 6.1 Starting the ICPE-9800 ....................................... 33

6.1.1 Starting the ICPE-9800 at Installation ........................ 33
6.1.2 Starting the ICPE-9800 in Daily Use ......................... 33
6.2 Stopping the ICPE-9800 in Daily Use ................... 34
6.2.1 Daily Shutdown ............................................... 34
6.2.2 Leak Valve Operation (After vacuum pump is stopped) ..... 35

6.3 Checking Operation of Safety Devices ................. 36

6.4 Response in Emergency ...................................... 36
6.4.1 Recovery after Emergency Stop ............................... 37

6.4.2 Response to Power Failure .................................... 37

7 Maintenance 7.1 Replacing and Inspecting Glassware .................... 38

7.1.1 Replacing the Torch ........................................... 38

7.1.2 Nebulizer ...................................................... 38

7.1.3 Replacing the Chamber ....................................... 38

7.1.4 Cleaning Glassware ........................................... 39

7.2 Removing Glassware .......................................... 39
7.2.1 Removing the Chamber and Extension Pipe ................. 39
7.2.2 Removing the Nebulizer ....................................... 40

7.2.3 Removing the Drain Trap ..................................... 41

7.2.4 Removing the Torch .......................................... 42

7.3 Attaching the Glassware .................................... 43

ICPE-9800 Series Hardware xxi

 Contents

7.3.1 Attaching the Torch ........................................... 43

7.3.2 Attaching the Drain Trap ..................................... 46

7.3.3 Attaching the Nebulizer to the Chamber .................... 47
7.3.4 Attaching the Chamber ....................................... 48

7.4 Replacing the Sample Introduction Tube ............. 49

7.5 Replacing the Helix Seal .................................... 50
7.5.1 Removing the Helix Seal ...................................... 50

7.5.2 Fitting the Helix Seal .......................................... 50

7.6 Replacing the Peristaltic Pump Tube ................... 51

7.7 Replacing the Drain Tube .................................. 52
7.8 Cleaning and Replacement of Reflect Mirror in
Cooling Jacket ................................................... 53
7.9 Cleaning the Axial-View Observation Orifice
Assembly .......................................................... 55
7.9.1 Remove the orifice assembly. ................................. 55

7.9.2 Clean the Orifice Assembly ................................... 56

7.9.3 Attach the orifice assembly ................................... 56

7.10 Attaching and Removing the Cooling Jacket ....... 57

7.10.1 Removing the Cooling Jacket ................................. 57

7.10.2 Attaching the Cooling Jacket ................................. 58

7.11 Cleaning the Entrance Window (ICPE-9810) ......... 59

7.11.1 Work Flow .................................................... 59
7.11.2 Removing the Cooling Jacket ................................. 60

7.11.3 Filling Argon Gas inside the Spectrometer ................... 60

7.11.4 Cleaning the Entrance Window .............................. 60

7.11.5 Attaching the Cooling Jacket ................................. 61

7.12 Cleaning the Entrance Windows and Mirrors

(ICPE-9820) ........................................................ 61
7.12.1 Work Flow .................................................... 62
7.12.2 Preparing ...................................................... 63
7.12.3 Filling the Spectrometer With Argon Gas .................... 63
7.12.4 Removing the Front Cover of the Radial-view
Observation Unit .............................................. 64
7.12.5 Removing the Entrance Window ............................. 65
7.12.6 Cleaning the Entrance Windows and Mirrors ................ 65

7.12.7 Mounting the Purge Tube and Entrance Windows .......... 66

xxii ICPE-9800 Series Hardware

 Contents

7.12.8 Mounting the Radial-view Observation Unit's Front

Panel ........................................................... 66

7.13 Cleaning/Replacing the Purge Tube (ICPE-9820)

......................................................................... 67
7.14 Replacing the Molecular Sieve (Oil Absorbent)
in the Vacuum Pump ......................................... 68
7.15 Replacing the Vacuum Pump Oil ........................ 69
7.16 Replacing FILTER ELEMENT of OIL MIST TRAP ...... 69
7.17 Cleaning the Fan Filters ..................................... 70
7.18 Waste Tank ....................................................... 71
7.19 Checking Operation of Safety Devices ................. 71
7.20 Inspecting the Argon Gas and Cooling Water
Piping ............................................................... 71
7.21 Cleaning the Filter for the Mains Water Supply
Connection Kit (Option) ..................................... 72
7.22 Cleaning the Main Unit ..................................... 73

Maintenance Parts 74
8 and Consumable Items
8.1 Maintenance Parts List .......................................

8.2 Consumable Items List ....................................... 74

9 Troubleshooting

ICPE-9800 Series Hardware xxiii

This page is intentionally left blank.
1 Overview
Shimadzu's ICPE-9800 series multitype ICP emission spectrometer is a compact,
high-performance, tabletop model. 1
The vacuum-type echelle spectrometer, the two-dimensional semiconductor detector, the
photometry system, the ICP RF power supply, and the analysis software were all
developed by Shimadzu.
The combination of an echelle spectrometer and a two-dimensional detector brings many
advantages. For example, the simultaneous analysis of multiple elements reduces analysis
time, the use of a mini torch reduces running costs, and axial-view plasma observation
increases sensitivity.
The software is Windows-compatible and easy to use. It has powerful support functions
that provide the user with the information required for analysis and includes a wide
variety of application software for ensuring a high level of reliability.
There are also many options that can be attached to this product, including an ultrasonic
nebulizer and a hydride generator.

ICPE-9800 Series Hardware 1

 2 Parts
The standard ICPE-9800 series package consists of the following parts. Check that they
are all included.

Box Part number Part name Q'ty Notes

ICPE-9810 main unit
１ 211-87700-58 ICPE-9810 ASSY １
(axial-view observation)
ICPE-9820 main unit
１ 211-92900-58 ICPE-9820 ASSY １ (axial-/radial-view
observation)
For connecting the torch
2 211-85118-91 PLASMA GAS TUBING ASSY 1
(plasma gas)
For connecting the torch
2 016-31404 PVC TUBE,LMT-55 1/8X1/4X1/16 2m (auxiliary gas) and
nebulizer
PVC TUBE,LMT-55 For connecting the drain
2 016-31429-10 2m
7/16X9/16X1/16 trap (glass)
2 016-43505 PP TUBE, 44-PP 5.5m Piping for argon gas
For connecting the argon
2 035-65503 HALF UNION, C1N1/4XPT1/4 1
gas inlet
2 035-69703-01 INSERT, B-405-170 2 Insert for swedgelock
2 210-14037 INLINE FILTER, B-4F-7 1 Filter for argon gas
038-03560-05
2 CASE, 1-4698-05 1 Molecular sieve dish
(038-03586-02)
Hardware Instruction
2 305-34207 IM, ICPE-9800H/W J 1
Manual (Japanese)
Hardware Instruction
2 305-34208 IM, ICPE-9800H/W E 1
Manual (English)
Hardware Instruction
2 305-34209 IM, ICPE-9800H/W C 1
Manual (Chinese)
CERTIFICATE OF COMPLIANCE,
2 206-84934-75 1 Accessory with ICPE-9810
9810
CERTIFICATE OF COMPLIANCE,
2 206-84934-76 1 Accessory with ICPE-9820
9820
2 228-30164 PROCEDURE,CC 1
2 465-06072 EXPLANATION DOC.,CC CHN 1
2 305-34175 SAFETY INFO 1
2 305-34333 INFORMATION SHEET 1
LABEL.ASSURANCE LABEL, Warranty form (affixed at
2 037-70238-01 1
53X34 installation)
BOLT,SST HEXSOCH SEMS P3 Torch height adjusting jig
2 022-27602 1
M3X6 securing screws
Voltage label (attached at
2 206-52224-03 LABEL, 200V 1
time of installation)

2 ICPE-9800 Series Hardware

Box Part number Part name Q'ty Notes
Voltage label (attached at
2 206-52224-04 LABEL, 230V 1
time of installation)
Voltage label (attached at
2 206-52224-05 LABEL, 240V 1
time of installation)
Voltage label (attached at
2 206-52224-06 LABEL, 220V 1
time of installation)
PVC TUBE, LMT-55 Exhaust tube for drain
2 016-31428 1.2m
3/16X5/16X1/16 trap 2
For connecting the
2 211-83697 CONNECTION TUBE 5
autosampler suction tube
2 239-07003-08 M.SIEVE,13X4X8M 1
2 017-30813-01 SILICONE GREASE, HIVAC-G 50G 1
2 211-90546 WINDOW COVER 1 Accessory with ICPE-9820
2 037-02829-66 KNOB,KNURL A-176-S-6 1 Accessory with ICPE-9820
2 086-03819 SPANNER,HEX 2.5 1 Accessory with ICPE-9820
DISK CTRL PARAMETERS Instrument information
2 211-49118-41 1
ICPE9800 disk
2 211-91422-41 TORCH POS-9800 1 Torch height adjusting jig
2 211-81444 TORCH ADAPTOR 1
Clip for torch and
2 210-15508-01 BALL JOINT CLIP12 2
extension pipe
For securing carrier gas
2 037-61113-01 CLAMP, SNP-1 1
tube
Drain trap, drain tube
2 037-61113-04 CLAMP, SNP-10 1
connecting clamp
Spray chamber, drain trap
2 046-00993-01 CLIP, TS-15 D-310-1 1
connecting clip
Vacuum pump, exhaust
2 035-06033-36 CLAMP, SNK1016 1
valve connecting clamp
2 037-61117-57 HOSE CLAMP,HI-GRIP STEEL 35 1 Clamp for vacuum hose
2 046-00092-20 NEBULIZER, 10UES 1 Made of glass
2 046-00093-02 CYCLONE CHAMBER, HE 1 Made of glass
2 046-00093-01 DRAIN TRAP, 8214 1 Made of glass
2 211-81448 MINI TORCH 1 Made of glass
2 211-86533 EXTENSION PIPE L 1 Made of glass
2 211-86083-92 EXHAUST VALVE ASSY 1 Attached to vacuum pump
Connector for torch gas
2 046-00092-25 CONNECTOR, GAZFIT04 2
connection
2 211-88859-41 LAN CABLE ASSY 1 5ｍ
2 211-86053-91 GR ASSY,ECHELLE 1 Echelle grating
Spectrometer's internal
2 211-84635 PLATE 1
light-intercepting plate

ICPE-9800 Series Hardware 3

 2 Parts

Box Part number Part name Q'ty Notes

Bolt for securing
BOLT,SST HEXSOCH SEMS P3
2 022-27617 1 spectrometer's internal
M4X8
light-intercepting plate
Centering ring for vacuum
2 035-06033-02 CENTERING RING,SNS7016 1
hose
2 211-88850-42 VACUUM-PUMP ASSY 1

4 ICPE-9800 Series Hardware

3 Preparation for Installation
3.1 Installation Environment
Before installing the ICPE-9800, the laboratory must be prepared as described in the
ICPE-9800 series installation guidelines provided separately. Check the following items
before installation.

1 The position of the plasma stand exhaust duct and the exhaust capacity must be
appropriate. A damper must also be provided.
An exhaust capacity of 1.7 m3/min is required for the plasma stand exhaust guide
(inner diameter: 118 mm).

2 Air-conditioning equipment that can maintain an ambient temperature in the

3
range 18ºC to 28ºC must be installed. The ambient temperature must not vary
more than 2ºC/hour. The humidity must be in the range 20% to 70%.

3 The equipment must not be directly exposed to the air discharged from the
air-conditioning equipment.

4 The equipment must not be directly exposed to sunlight.

5 The equipment must not be installed in a location subject to shocks or vibrations.

6 The respective distances between the equipment and the walls must satisfy the
following conditions.
Back of equipment: 140 mm min
Right side of equipment: 400 mm min. normally, 600 mm min. during maintenance
Left side of equipment: 200 mm min. normally, 600 mm min.during maintenance

7 There must be no high-capacity heat-generating sources near the equipment.

8 Voltage fluctuations of the power supply must not exceed ±10%.

9 There must be no devices incorporating CPUs (e.g., computers) less than 2 m from
the equipment.

10 The purity of the argon gas must be at least 99.95% and the gas pressure at the
inlet to the equipment must be in the range 450±10 kPa.

11 The main body's cooling water must not condense in the range of 5 to 30 °C,
1.5L/min or more. The pressure must be in the range of 150 to 300 kPa. If a
cooling water circulator is used, the temperature must be set to 20 °C or higher,
and the temperature accuracy must be controlled to ±0.5 °C.

3.2 Installing and Handling the Data Processing Unit

General points to note regarding the installation and handling of the data processing
unit are given below.

ICPE-9800 Series Hardware 5

 3 Preparation for Installation

3.2.1 Operating Environment and Storage

1 Do not install the unit in a location where the display screen will be directly
exposed to sunlight or light emitted by lighting fixtures in the ceiling.

2 Do not install the unit in a location where it will be exposed to direct sunlight
or near heating equipment, such as stoves.

3 Do not install the unit in a location subject to large amounts of moisture or dust.

4 Do not install the unit in a location subject to shocks or vibrations.

5 Do not install the unit on a slope.

3.2.2 Maintenance

1 If the main unit becomes dirty, wipe it with a soft, dry cloth. If the dirt is
particularly difficult to remove, dip a cloth in some diluted neutral detergent,
wring out the cloth, and use it to wipe off the dirt. Finally, wipe the unit with a
dry cloth. Do not use benzene or thinner as this may cause discoloration.

2 Wipe the display screen with a dry cloth.

3.2.3 Other Points

Be careful not to subject the computer to shocks when carrying it. Otherwise, faults may
occur. Also, disconnect the power plug and connecting cable before moving the
computer.

If nothing appears on the screen or if there is an unusual sound or smell, turn

OFF the power immediately. It is dangerous to continue operation in this state.

6 ICPE-9800 Series Hardware

4 Configuration and Operating Principle of the ICPE-9800
4.1 Block Diagram

Fig. 4-1 Block Diagram

ICPE-9800 Series Hardware 7

 4 Configuration and Operating Principle of the ICPE-9800

4.2 Appearance and Configuration

The ICPE-9800 basically consists of the spectrometer case, the plasma stand, the RF power
supply, thecontroller, and the vacuum system. Inside the spectrometer case, the echelle
spectrometer is contained in
a temperature-controlled bath. The controller incorporates the gas controller and the
control powersupply.

Fig. 4-2 Appearance of ICPE-9800 Series

Do NOT install the ICPE-9800 in a position where it is difficult to turn OFF the
power switch.

8 ICPE-9800 Series Hardware

 4.3 Power Supply, and Argon Gas and Cooling Water Piping

4.3 Power Supply, and Argon Gas and Cooling Water Piping
The ICPE-9800 requires a single-phase, 200/220/230/240-V, 50/60-Hz, 6 kVA power supply,
a ground, argon gas, and cooling water.

Fig. 4-3 External Connection of Power Supply

Fig. 4-4 Argon Gas and Cooling Water Connections

The cooling water cools the cooling jacket, RF power supply, RF coil, and CCD.
Argon gas is supplied, at a regulated flow, to the plasma torch, nebulizer, cooling jacket
(for purge gas) and CCD.

ICPE-9800 Series Hardware 9

 4 Configuration and Operating Principle of the ICPE-9800

The drain for water leakage serves to channel any water that leaks inside the instrument
into a collection container. Connect a tube with an inside diameter of 9 mm and put
the outlet end of this tube into the collection container.

Do not put the drain tube for water leakage into the waste tank.
Vapor from the waste liquid may enter the main body through the drain tube
for water leakage and corrode its interior.

4.4 Connecting the Data Processing Unit to the ICPE-9800

Connect the ICPE-9800 LAN terminal and the LAN card terminal on the data processing
unit with the LAN cable provided.
"4.3 Power Supply, and Argon Gas and Cooling Water Piping"

4.5 Spectrometer and Light-Focusing System

In axial-view observation, light from the ICP is bent 90° by the back-reflect mirror in the
cooling jacket, it passes through the glass window in the section joining the spectrometer
and the cooling jacket, and it
is reflected by the toroidal mirror and the plane mirror to form an image at the entrance
slit.
In the echelle mounting, the spectrometer mount uses an echelle diffraction grating with
79 grooves/mm and a blaze angle of 63.4°.
Light that passes through the pinhole (rectangular) entrance slit is converted to parallel
light by the collimator mirror (parabolic mirror), and is divided (in a vertical direction)
according to wavelength by the echelle diffraction grating. Then the light is divided (in
a horizontal direction) according to order by the prism, it is reflected off the Schmidt

10 ICPE-9800 Series Hardware

 4.6 CCD Detector

mirror in order to correction aberrations, and it is reflected off the telemeter mirror
(concave mirror) to form an image at the CCD detector.

Fig. 4-5 Optical System

4.6 CCD Detector

The CCD detector's light-receiving surface consists of 1,024 × 1,024 pixels and the size of
each individual pixel is 20 μm × 20 μm.
The dark current (output signal with no light input) decreases as the temperature of the
light-receiving surface decreases and so the detector is cooled with a peltier element.
Cooling water is required for this purpose. (Check the specifications.)
Also, in order to facilitate the detection of spectra in the vacuum ultraviolet region, gaps
in the spectrometer and CCD are purged with argon gas. The gas should be supplied at
a high flow rate when the plasma lighting is started, and then a low flow rate should
be used constantly. This gas also serves to prevent condensation on the detector.
It is controlled by the data processing unit.
• High flow rate 4.5 L/min
• Low flow rate 0.5 L/min

ICPE-9800 Series Hardware 11

 4 Configuration and Operating Principle of the ICPE-9800

4.7 Shutter
At the CCD detector, light in the entire spectral region is accumulated for the constant
time, and then the electric charge is read for each pixel. During reading, however, the
light from the plasma must be blocked. In order to facilitate blocking control, a shutter
is positioned in front of the entrance slit.
The shutter repeatedly opens and closes at a minimum interval of 0.1 sec. For example,
for 5 sec. of accumulation, the accumulated value for 0.1 s is measured 50 times, and
the values are added, and then the accumulated value for 1 sec. is measured 5 times,
and the values are added. This completes one analysis. This is controlled with signals
from the computer. The CCD dark current is measured with the shutter closed. This is
also controlled with signals from the computer.

4.8 Temperature Control

The spectrometer is housed in a thermally insulated case. The temperature of the
spectrometer is kept constant by circulating air at a constant temperature in the space
between the case and the spectrometer. The spectrometer temperature is set to 38°C and
is regulated by ON/OFF heater control. There is no cooling function and so proper control
may not be possible if the ambient temperature is high (e.g., higher than 28°C).
ICPE-9800 performance is greatly affected by the stability of the spectrometer
temperature. Therefore, do not turn OFF the power supply to the main unit under normal
circumstances as this will also turn OFF temperature control. Stability is maintained in
momentary power interruptions but approximately half a day is required for recovery if
the power supply to the main unit is turned OFF for a few hours or more.

4.9 Vacuum System

Spectra for short wavelengths of 190 nm or less are attenuated due to absorption by
oxygen and water vapor and so the air in the spectrometer is evacuated by a vacuum
pump.
The solenoid valve separates the spectrometer and the vacuum system and closes
automatically when pump operation stops. If the pump is restarted, the valve opens
automatically after approximately one minute.
If the vacuum level does not reach 20 Pa or less approximately 20 minutes after the
pump starts, there is a possibility of a leak and so the vacuum pump stops automatically.
Check the vacuum level reached by viewing the data processing software's [Instrument
Control] window.
Moreover, OIL MIST TRAP is installed in the pump. Oil mist exhausted to be in operation
of the vacuum pump is collected in it, and as a result, oil is recovered to the vacuum
pump.

4.10 Cooling System

The cooling system is shown below.

12 ICPE-9800 Series Hardware

 4.11 Argon Gas System

When the plasma is ignited, the valve opens automatically and cooling water flows. The
flow of cooling water is monitored with the flow switch. If it detects that cooling water
is not flowing, the plasma is not ignited. If the plasma is already ignited, it is
automatically extinguished.

4.11 Argon Gas System

4
The argon gas passes through an in-line filter before entering the ICPE-9800.
The gas pressure at the ICPE-9800 inlet (argon gas inlet shown in "Fig. 4-4") is set in the
range 450±10 kPa. If the pressure is less than 300 kPa, the pressure sensor detects this
and automatically extinguishes
the plasma.

While the carrier gas is flowing, do NOT perform any operation that will cause
the source pressure of the argon gas to drop below 100 kPa (such as replacing
the argon gas cylinder).

4.12 Sample Introduction System (Including Plasma Stand Interior)

The parts are shown in "Fig. 4-6" and "Fig. 4-7".

Risk of Burn Injury

There is a risk of burn injury. When checking the plasma stand,
do NOT touch the plasma stand interior for 3 minutes after the
plasma is extinguished.

1 Plasma Torch
The plasma torch is made of quartz and has a threefold structure in which plasma
gas (coolant gas), auxiliary gas, and carrier gas flow (from the outside).

2 Plasma gas
For the plasma gas (coolant gas), argon gas is delivered at a standard rate of 8
to 10 L/min.

ICPE-9800 Series Hardware 13

 4 Configuration and Operating Principle of the ICPE-9800

3 Auxiliary gas
The auxiliary gas is delivered at a standard rate of 0.6 L/min. The function of this
gas is to lift up the plasma slightly to protect the quartz tube in the middle.

4 Carrier gas
The carrier gas introduces nebulized sample solution particles into the center of
the plasma at a standard rate of 0.6 to 0.8 L/min.
The flow rate of carrier gas is not only related to the sample introduction rate.
If it is too high, the plasma is cooled excessively, the retention time of the sample
in the plasma is reduced, and the sensitivity is lowered. For this reason, precise
adjustment is required. (The maximum possible flow rate of the carrier gas depends
on the nebulizer.)

5 Purge gas
For the purge gas, argon gas is circulated in the area between the light-focusing
lens and the plasma to prevent dirt from the plasma or the sample adhering to
the lens or the mirror. In the plasma ignition sequence, after approx. 10 sec. of
purging at a high flow rate, purging is continued at a low flow rate. Approx.

6 Nebulizer and Chamber

The nebulizer has a coaxial structure. It nebulizes samples so that they can be
introduced into the plasma.
The chamber sorts the nebulized sample particles and introduces them into the
plasma. Large particles adhere to the internal wall and are drained away. Only
small particles are introduced into the torch.

7 Drain Trap
Keeps the chamber's internal capacity at a constant level and prevents the carrier
gas escaping to the drain side.

8 Sample Introduction Tube

Introduces the sample into the nebulizer.

14 ICPE-9800 Series Hardware

 4.12 Sample Introduction System (Including Plasma Stand Interior)

9 Orifice ASSY L
This reduces the argon background light intensity, improves the effectiveness of
the emission spectrum from the measurement elements, and guides it into the
spectrometer.

Fig. 4-6 Sample Introduction System, Argon Gas System, and Cooling Jacket
(Plasma Stand Interior)

10 RF Coil
A 27-MHz RF current is applied to the RF coil, the argon gas is heated and ionized
by the induced current generated between the coil and the plasma, and the
plasma is thereby maintained. The plasma is ignited by the igniter.
The RF coil is tubular and cooling water flows through the interior.

11 Optical Fiber for Photoelectric Switch

Guides the light from the plasma to the photoelectric switch, which detects
whether or not the plasma is ignited.

12 Drain Tube
Drains the waste from the drain trap to the waste tank.

ICPE-9800 Series Hardware 15

 4 Configuration and Operating Principle of the ICPE-9800

13 Exhaust Tube
Draws the gas given off by the sample in the drain trap to the exhaust duct.

Fig. 4-7 Sample Introduction and Waste System (Plasma Stand Exterior)

16 ICPE-9800 Series Hardware

 4.12 Sample Introduction System (Including Plasma Stand Interior)

4.12.1 Standard Parts for the ICPE-9800 Series

1 Mini Torch (P/N S211-81448)

This is a mini-sized torch with an external diameter of 16 mm. It allows the argon
gas flow rate to be reduced as compared to the standard torch. The inner tube
size of the mini torch is the same as that of the standard torch, so the efficiency
of sample introduction is equivalent but high output plasma cannot be used.
(Plasma output up to 1.2 kW)
It is used in combination with the cyclone chamber. It is not possible to remove
the cooling jacket and use the torch exclusively for radial-view observation.

2 Nebulizer, 10UES (P/N S046-00092-20)

This is the standard nebulizer made of glass. It is used for a variety of applications.

3 Cyclone Chamber (P/N S046-00093-02)

This is used for analyzing aqueous samples. It has good sample introduction
efficiency and is ideal for highly sensitive measurements of aqueous samples. The
chamber can be effectively washed and has a low memory.
It is not suitable for organic solvent samples, as the sample introduction efficiency
is too good and the plasma easily becomes unstable.
4
4 Drain trap (P/N S046-00093-01)
This is a drain trap for cyclone chambers.

4.12.2 Optional Torches

1 High TDS Analysis

• High TDS Torch (P/N S204-74323)

This is used for high matrix samples, such as highly concentrated salt samples like
sea water, which, with a mini torch or standard torch, might cause salt deposition
inside. The exterior of the high TDS torch is the same as that of the standard
torch, but its inner tube is wider, making the sample introduction efficiency poorer.
Also, the plasma easily becomes unstable under non-standard conditions, and if
the RF output is lowered below 1.2 kW or volatile samples are introduced, the
plasma can go out. If possible, use the standard torch for samples that cause no
salt deposition.

ICPE-9800 Series Hardware 17

 4 Configuration and Operating Principle of the ICPE-9800

2 Organic Solvent Analysis

• Torch（P/N S211-92878-41）
This is the standard-size torch with an external diameter of 20 mm. The maximum
output is 1.6 kW. It is used in analyzing organic solvent samples that require high
output plasma. However, for samples containing volatile organic solvents the
organic solvent torch is used.
It can also be used for radial-view observation when analyzing high matrix samples
or high concentration samples.
For aqueous samples, it is used in combination with the cyclone chamber. For
organic solvent samples, it should be used in combination with the double-tube
chamber.

• Organic Solvent Torch (P/N S211-92876-41)

This is used for highly volatile organic solvent samples that would be difficult to
introduce into a standard torch, as they would cause the plasma to go out. The
inner tube is narrower than that of the standard torch, so it reduces volatilization
of the sample, allowing highly volatile organic solvent samples to be introduced
efficiently. Conversely, the drain pressure is increased, which requires the flow rate
of the carrier gas to be reduced. For this reason, the amount of sample introduced
into the plasma is reduced.
It is used in combination with the optional chamber kit for organic solvent
samples. For some particularly high-volatility samples, the water-cooled chamber
should be used.

4.12.3 Optional Nebulizer

1 Nebulizer 07UES (P/N S046-00092-21)

This is a nebulizer made of glass, for use with small samples. The capillary
is thinner than in nebulizer 10UES, allowing a spray to be produced very
efficiently. Care must be taken, as insoluble components in the sample
solution can easily become clogged in the capillary. Also, it is not suitable
for analyzing organic solvent samples, as the spray efficiency is very good.

4.12.4 Chamber Kit for Organic Solvent Samples (Option)

This comprises a double-tube chamber suitable for analyzing organic solvent samples,
with its drain trap and drain tube. The nebulizer used is the standard 10UES. The kit
should be used in combination with the torch option that is appropriate for the solvent
being analyzed: the standard torch or the torch for organic solvents.

1 Chamber kit for organic solvents (P/N S211-92879-41)

This uses the double-tube chamber, which gives a high level of separation
of atomized samples. The amount of sample introduced can be reduced,
suiting it to the analysis of volatile organic solvent samples.

18 ICPE-9800 Series Hardware

 4.13 Cooling Jacket

2 Water-cooled Chamber Kit for organic solvents (P/N S211-92880-41)

The chamber is cooled, allowing it to be used to analyze highly volatile
organic solvent samples, which would be difficult to analyze with the
chamber kit for organic solvents. Cooling water with minimal temperature
variation (cooling water circulator) is required for high-precision analysis.

4.12.5 Hydrofluoric Acid Sample Injection System HFS-4 (P/N S211-92881-41) (Option)

This sample injection system is a set comprising a torch suitable for analyzing hydrofluoric
acid samples along with a nebulizer, chamber, drain trap and drain tube that are made
of resin. For details, see the instruction manual that is provided with the HFS-4
hydrofluoric acid sample injection system.

4.13 Cooling Jacket

In axial-view observation, the plasma makes contact with the cooling jacket. The cooling
jacket is cooled with water and prevents damage to the orifice and the emission of light
by the metal elements that make up the orifice. The purge gas flows through the cooling 4
jacket towards the plasma and prevents sample particles contaminating the optical
system. Also, in order to facilitate analysis of the vacuum ultraviolet region, the area
between the plasma and the spectrometer septum is purged.
Light passes through the center of the orifice, it is reflected off the back-surface mirror,
it passes throughthe entrance window, and it is focused by the dual light-focusing mirrors
to form an image at the entrance slit.
If no cooling water is flowing, the safety switch operates and the ICP is not ignited.
"Fig. 4-8" shows the optical system inside the cooling jacket.

ICPE-9800 Series Hardware 19

 4 Configuration and Operating Principle of the ICPE-9800

Fig. 4-8 Optical System inside Cooling Jacket

Use a radial view unit of the option without the cooling jacket when you
measure the organic solvents sample and the HF sample. If you measure these
samples with the cooling jacket installed, the orifice assembly will deteriorate
rapidly and the cooling jacket will be damaged.

4.14 Radial View Unit (ICPE-9820)

The radial-view observation unit of the ICPE-9820 is installed in the plasma stand and
switches between axial-view observation and radial-view observation. For radial-view
observation, one of two observation heights can be selected with the software (for the
optional plasma torch). These observation heights are set at 9 mm and 15 mm above
the RF coil.
When analyzing organic solvent samples and highly concentrated hydrofluoric acid
samples, use it set to radial-view observation only, with the cooling jacket removed.
Risk of Burn Injury
There is a risk of burn injury.
Do NOT start work inside the plasma stand for 3 minutes after
the plasma is extinguished.

Fig. 4-9 Radial-View Observation Unit (ICPE-9820)

20 ICPE-9800 Series Hardware

 4.15 RF Power Supply

4.14.1 Selecting the View

The axial or radial view is selected by setting a method in ICPEsolution. The selection
can be made manually on the [Instrument Control] window in ICPEsolution Fig. 4-9). The
correspondence between the view status and the color of the indicator is as follows.
• Axial view status (AXIAL) ：●
• Radial view status (RADIAL) ：○

4.14.2 Selecting the Radial-view Observation Height

The observation height is shown by the radial-view observation height indicator (Fig. 4-9).
It shows the observation height (H or L) during radial-view observation. Observation
height H is used when an optional torch is fitted, and observation height L when the
mini torch is fitted.

When using a mini torch, set the observation height to "L".

Normal analysis will not be possible if the setting is "H".
4

4.15 RF Power Supply

This is a water-cooled, RF power supply that incorporates a self-oscillating switching
circuit and automatically follows up on the plasma.

Fig. 4-10 Names of RF Power Supply Parts

ICPE-9800 Series Hardware 21

 4 Configuration and Operating Principle of the ICPE-9800

1 RFG-CONT PCB
Controls each part of this power supply. It has the following two functions.

• Exchange of signals with the CPU

• Safety checks

2 RF Unit
Produces a maximum output of 1.6 kW at a frequency of 27 MHz.

4.16 Purpose and Operating Principles of Safety Devices

The ICPE-9800 incorporates the following safety devices: a temperature fuse in the plasma
stand, a plasma stand door switch, a cooling water flow switch, a temperature fuse in
the RF power supply, an argon gas pressure switch, a photoelectric switch, and a CCD
condensation sensor. See "7.19 Checking Operation of Safety Devices" for details on the
procedures used to check the operation of safety devices.

Risk of Electric Shock or Burn Injury

Do NOT use the equipment with the safety devices disabled.
Doing so may result in electric shock or burn injury.

1 Argon Gas Pressure Sensor

Monitors the argon gas pressure. If the pressure drops to 300 kPa or less, a safety
circuit operates and interrupts RF output.

2 Plasma Stand Door Switch

Ensures that RF output is not applied to the coil when performing maintenance
checks inside the plasma stand. If the plasma stand door is opened, a safety circuit
operates and interrupts RF output.

3 Cooling water Flow Switch

Monitors the cooling water. If no cooling water is flowing, a safety circuit operates
and interrupts RF output to prevent burning of the RF coil and overheating of
the cooling jacket.

4 Temperature Fuse in RF Power Supply

Monitors the temperature in the RF power supply. If the radiator temperature of
any part increases to 60°C or higher, a safety circuit operates and interrupts RF
output.

5 Temperature Fuse in Plasma Stand

Monitors the temperature inside the plasma stand. If the temperature inside the
plasma stand increases to 60°C or higher, a safety circuit operates and interrupts
RF output.

6 Photoelectric Switch
Detects whether or not the plasma is ignited. If the plasma is extinguished, a safety
circuit operates and interrupts RF output.

22 ICPE-9800 Series Hardware

 4.17 Connector Panel

7 Spectrometer Temperature Switch

Monitors the temperature of the spectrometer's temperature-controlled bath. If
the temperature of the temperature-controlled bath reaches 60°C, a buzzer sounds
and the power supply to the heater turns OFF.

8 CCD Condensation Sensor

Monitors condensation inside the CCD detector. The CCD detector is cooled to -15
°C, so if the humidity level at the installation location is too high, condensation
may occur inside it and this could damage the CCD.
When the condensation sensor is actuated, the CCD power supply automatically
goes OFF and the plasma is extinguished.

4.17 Connector Panel

The connector panel is used to connect to optional units.

1 PUMP
Terminal used to connect to the peristaltic pump (option) of the UAG-1 ultrasonic
nebulizer.
4

ICPE-9800 Series Hardware 23

 4 Configuration and Operating Principle of the ICPE-9800

2 ASC
Terminal used to connect to the autosampler (option).

Fig. 4-11 Connector Panel

24 ICPE-9800 Series Hardware

 4.18 Peristaltic Pump (Option)

4.18 Peristaltic Pump (Option)

4.18.1 Mounting Position

The optional peristaltic pump is mounted on the lower part of the plasma stand of the
ICP main body.

Fig. 4-12 Mounting Position of the Peristaltic Pump

Fig. 4-13 Peristaltic Pump

For details on fitting the pump tube, see、"7.6 Replacing the Peristaltic Pump Tube"

ICPE-9800 Series Hardware 25

 4 Configuration and Operating Principle of the ICPE-9800

4.18.2 Pump Tube

The following pump tubes for peristaltic pumps are available; select the tube to be used
according to the application. Also check its durability, e.g. through an immersion test
with the actual sample, before using it.

Part number Part name Material Application Tag Colours

General-use product for
S018-31558-01 Tube,0.25-OB-F PVC orange/blue
general applications
General-use product for
S018-31558-02 Tube,0.76-BLK-F PVC black/black
general applications
General-use product for
S018-31558-03 Tube,0.89-ORG-F PVC orange/orange
general applications
Specialized for
Tube,
S018-31558-11 Solva hydrocarbons, petroleum black/black
0.76-BLK-SF-F
products and distillates
Specialized for highly
Tube,VS0.76-BLK
S018-31558-21 Viton concentrated acids and black/black
-F
corrosive solvents
For MIBK
Tube,,
S018-31558-31 Tygon MH Special environmentally white/white
1.02-WHT-MH-F
friendly design

4.19 Optional Plasma Torch and Orifice Assembly S2

If axial view observations are performed using the optional plasma torch (P/N
S211-92878-41) or high TDS torch (P/N S204-74323), the optional orifice assembly S2 (P/N
S211-88571-42) is required. Replace the orifice assembly L2 (P/N S211-87758-42) attached
to the cooling jacket with the orifice assembly S2.
Cleaning of the orifice assembly S2 is the same as for cleaning of the axial-view
observation orifice assembly in section"7.9 Cleaning the Axial-View Observation Orifice
Assembly"

26 ICPE-9800 Series Hardware

 4.19 Optional Plasma Torch and Orifice Assembly S2

Fig. 4-14 Orifice ASSY S2 and Orifice ASSY L2

The orifice assembly L2 will deteriorate rapidly if the plasma is ignited using the
plasma torch (P/N S211-92878-41) or high TDS torch (P/N S204-74323) with the
orifice assembly L2 installed.

ICPE-9800 Series Hardware 27

 5 Specifications
5.1 Plasma Light Source

1 ICP observation

• ICPE-9810 ：Axial-view with argon gas purge function

• ICPE-9820 ：Axial / radial view with argon gas purge function

2 Spray chamber ：Cyclone chamber made of Borosilicate glass

3 Plasma torch ：Mini-torch made of quartz

4 Nebulizer ：Coaxial type made of Borosilicate glass

5 Gas controller ：Automatic control of gas flow rate from CPU Three flow lines for
plasma
Flow rate setting ranges

• Plasma gas (coolant gas) : 0 to 20 L/min

• Auxiliary gas : 0 to 1.5L/min
• Carrier gas : 0 to 1.5 L/min
• Purge gas for cooling jacket : about 0.5L/min
• Purge gas for CCD : about 0.5L/min

5.2 RF Power Supply

1 Oscillation method：Free running

2 Frequency ：27 MHz

3 RF output ：1.6 kW max. (When the mini torch is used: 1.2 kW)

4 Output stability ：Within ±0.3%

5 RF circuit element ：Transistor

5.3 Spectrometer

1 Optical system ：Echelle mounting

2 Wavelength range ：167nm to 800nm

3 Dispersive elements
：Echelle diffraction grating with 79 grooves/mm
：Prism

28 ICPE-9800 Series Hardware

 5.4 Measuring Unit

4 Reciprocal linear dispersion

：0.21nm/mm （200nm）
：0.68nm/mm （600nm）

5 Spectrometer temperature :Equipped with temperature control

6 Vacuum system ：Rotary pump with leak valve control

Pressure: 10 Pa max.

5.4 Measuring Unit

CCD semiconductor detector
• Effective number of pixels ：1024×1024pixels
• Pixel size ：20μｍ×20μｍ
• Equipped with peltier cooling device
• Equipped with condensation sensor

5.5 Data Processing Unit Software: ICPEsolution(Option P/N 211-44263-92)

5.5.1 Measurement Samples

• 1 data file, 300 samples max.

5
• Pasting of sample information
Possible to paste sample information from the clipboard into the sample table

5.5.2 Qualitative Analysis

• Analysis using internal database

• Automatic selection of qualitative-analysis wavelength for each sample
• Database calibration function
• Profile subtraction function

5.5.3 Quantitative Analysis: Calibration Curve Method / Standard Addition Method

• Multi-method analysis:
Possible to analyze using multiple methods in succession
• Measurement wavelength:
Possible to set multiple measurement wavelengths for each element
Automatic selection of quantitative-analysis wavelength for each sample
Possible to additionally register any required wavelengths

ICPE-9800 Series Hardware 29

 5 Specifications

• Correction methods:
Background correction, inter-element correction, internal standard correction, drift
correction, weight/dilution correction
• Calibration curve:
1st to 3rd order expressions Determination limit indication
• Printing:
Setting of printing items
Automatic printing of analysis results after measurement
Batch printing (analysis conditions, calibration curves, analysis results, etc.)
• Copying of displayed screens:
Possible to copy analysis values, profiles, calibration curves, etc., to other applications
using the Windows clipboard function
• Saving data:
Echelle mode (all data saved)
Analysis wavelength save mode (only data for selected wavelengths saved)
• Exporting data:
Possible to output analysis results to files in CSV format or tab delimited text format
Automatic export at analysis
Batch export
• Recalculation functions:
Addition and recalculation for analysis elements and wavelengths
Recalculation of intensity after changing intensity calculation information, such as the
accumulation interval, the background point, or the internal standard element Changing
of calibration curve conditions, such as the calibration curve order
• QA/QC functions (optional):
Evaluation and recorrection of calibration curve and inter-element correction coefficients
Evaluation, recorrection, and remeasurement of drift during measurement
Recovery test, dilution test, remeasurement test
• Support for 21 CFR Part 11 (option):
21 CFR Part 11 is supported through the combination of "ICPEsolution" and the analysis
data management tool "CLASS-Agent".
The Agent connection kit, the CLASS-Public Agent, and Microsoft SQL Server are
required.

5.5.4 User Support

• Development assistant
• Diagnosis assistant
• Automatic wavelength selection

5.5.5 Instrument Control

• Monitor display of instrument status

• Control of vacuum pump

30 ICPE-9800 Series Hardware

 5.6 Utilities

• Automatic igniting/extinguishing of plasma

• Automatic extinguish function that operates when analysis completed
• Automatic control of autosampler

5.6 Utilities

5.6.1 Power Supply Requirements

Single phase ：200/220/230/240V±10% 50/60Hz 6kVA

5.6.2 Ground

30 Ω max., independent ground

5.6.3 Argon Gas

Purity ：99.95%min.
Pressure ：450±10ｋPa

5.6.4 Cooling Water 5

Pressure ：150 to 300kPa

Flow rate ：1.5L/minor greater While the plasma is extinguished, cooling water feed by
the valves in the main body stops.
Water temperature ：5 ～ 30℃(no condensation) When a cooling water circulator is used,
the temperature setting should be 20 °C, and the fluctuation range within 0.5 °C.

5.6.5 Installation Conditions

Temperature ：18 to 28℃ (temperature must not fluctuate more than 2°C/hour)
Humidity ：20 to 70% (with no condensation)

5.6.6 Dimensions and Weight

Dimensions ：1,300 mm (width) × 660 mm (depth) × 720 mm (height)

(not including plasma stand exhaust guide)
Weight ：210㎏

ICPE-9800 Series Hardware 31

 5 Specifications

5.6.7 Options

Autosampler ：AS-10, ASX-560, ASX-280

Ultrasonic nebulizer：UAG-1
Peristaltic pump：Built into the main unit
Hydride generator : HVG-1

The computer and the software for data processing are not included in ICPE-9800.
Please purchase a computer and software separately.

Please reffer to specifications of ICPE-9800 series SPPD-0051.

Software PKG ICPE-9800(E) P/N 211-44263-92

32 ICPE-9800 Series Hardware

6 Operation
This section describes the procedures used to start and stop the ICPE-9800.
Refer to the software instruction manual for details on the analysis operations.

6.1 Starting the ICPE-9800

6.1.1 Starting the ICPE-9800 at Installation

1 Connect the main unit and the PC with the LAN cable.

2 Connect the power cable, the argon gas piping, and the cooling water piping.

3 Supply power to the ICPE-9800.

Turn ON the power switch. (Raise the lever.)
Switch Indication
Ｉ ：ON
○ ：OFF

4 Turn ON the CRT power switch

5 Turn ON the printer (option) power switch.

6
6 Turn ON the computer power switch.

7 Perform the operations described below under "6.1.2 Starting the ICPE-9800 in
Daily Use".

6.1.2 Starting the ICPE-9800 in Daily Use

1 Supply cooling water to the ICPE-9800.

If mains water is used, open the main valve of the mains water supply.
If a cooling water circulation system is used, start the system.

2 Supply argon gas to the ICPE-9800.

Open the main valve of the argon gas supply. The pressure of the argon gas supplied
to the ICPE-9800 is in the range 450±10 kPa.

ICPE-9800 Series Hardware 33

 6 Operation

3 Turn ON the exhaust duct that you attached above the plasma stand exhaust
guide.
Risk of Oxygen Deficiency
There is a risk of oxygen deficiency. Be sure to operate the
exhaust duct.

4 Open the plasma stand and check that the cooling jacket, glassware, and other
items are set properly.
"7.10 Attaching and Removing the Cooling Jacket"

Check that the cooling water tube and argon gas purge tube are connected to
the cooling jacket.
If they are not connected, the cooling jacket may be damaged when the plasma
is ignited.

5 Start the software and perform the necessary operations.

If an irregularity is observed during the startup procedure, turn OFF the power
switch and other power supply equipment, stop the supply of cooling water and
argon gas, and contact your Shimadzu representative.
During vacuum pump operation, oil might ooze from the oil seal part. Put the
pump on the tray etc. to prevent this oil making the floor dirty. When you set
up the pump, set it up so that the edge of the tray should not touch the body
part of the pump.
Use the following tray or equal goods separately.
P/N038-00309-26 VAT NR-374-06. W345x D246x H19(mm). Made of stainless steel
If a vacuum error occurs after the vacuum pump has been operating for 20
minutes,turn ON the vacuum pump again. (Select [ON] in the "Vacuum Pump
ON/OFF"
window on the [Instrument] menu, and click [OK].)
If the same error re-appears, replace the molecular sieve.
(See 7.14 Replacing the Molecular Sieve (Oil Absorbent) in the Vacuum Pump)
If the error continues to occur, please contact your Shimadzu representative.

6.2 Stopping the ICPE-9800 in Daily Use

6.2.1 Daily Shutdown

1 Turn off the plasma.

2 Clean the inside of the stand and the glassware.

3 Waste liquid is treated.

34 ICPE-9800 Series Hardware

 6.2 Stopping the ICPE-9800 in Daily Use

4 After stopping the vacuum pump, open the leak valve.

Vacuum pump is not normally turned off on a daily basis.

"6.2.2 Leak Valve Operation (After vacuum pump is stopped)"

5 Quit the software.

6 Stop the supply of cooling water.

7 Turn OFF the display power switch.

8 Turn OFF the computer power switch.

Turn OFF the printer (option) switch.

9 Turn OFF the exhaust duct.

If the power switch is turned OFF, the spectrometer temperature-control circuit

stops operating.
The time required for the spectrometer to stabilize varies with the external
temperature but, if it has been OFF for 24 hours, 6 hours is required. It soon
recovers, however, after a momentary power interruption.
In consideration of this point, then, leave the power switch ON if continuous
temperature control is required. Turn OFF the power switch only when stopping
the equipment for a long time.
6
Do NOT turn OFF the power switch before exiting the software. Otherwise, an
error will occur.
If the cooling water circulation system is not going to be used for a long time,
remove the water from the tank.
Also, replace the water in the tank at least once a month.

6.2.2 Leak Valve Operation (After vacuum pump is stopped)

When stopping the vacuum pump, release the molecular sieve case to
atmospheereic pressure.

1 After stopping the vacuum pump, open the leak valve.

(Viewed from above, turn the valve counter-clockwise 2 complete turns.)

ICPE-9800 Series Hardware 35

 6 Operation

2 After the air-leak sound disappears, close the leak valve.

Fig. 6-1 Molecular Sieve Case

6.3 Checking Operation of Safety Devices

The ICPE-9800 is equipped with safety devices. The plasma cannot be ignited if the safety
devices are not operating properly.
Check the operation of the safety devices on a regular basis (every one month).
"6.3 Checking Operation of Safety Devices"

6.4 Response in Emergency

In the event of an emergency situation, such as a fire or an earthquake, if there is not
enough time to stop the ICPE-9800 in the usual way, turn OFF the ICPE-9800's power
switch. The power supplied to the ICPE-9800 is interrupted.
Stop the supply of argon gas to the ICPE-9800 by closing the main valve of the argon
gas supply.

36 ICPE-9800 Series Hardware

 6.4 Response in Emergency

Stop the supply of cooling water to the ICPE-9800.

If there is enough time, stop the ICPE-9800 as described in"6.2.1 Daily

Shutdown".

6.4.1 Recovery after Emergency Stop

After stopping the ICPE-9800 by turning OFF the power switch, perform the following
recovery procedure.

1 Turn OFF the computer power switch.

2 Turn ON the power switch.

3 Start the ICPE-9800 as described in "6.1 Starting the ICPE-9800".

6.4.2 Response to Power Failure

In the event of a power failure, perform the following procedure.

1 Turn OFF the ICPE-9800's power switch and the computer power switch.

2 When power is restored, start the ICPE-9800 as described in"6.1 Starting the
ICPE-9800".
6

ICPE-9800 Series Hardware 37

 7 Maintenance
Extinguish the plasma at least once a day to perform, for example, maintenance
of the glassware and to check that there is no condensation on the parts.

7.1 Replacing and Inspecting Glassware

The glassware inside the ICP stand must sometimes be cleaned or replaced.
The approximate replacement period and the replacement procedure are given below.
Risk of Burn Injury
There is a risk of burn injury. Do NOT touch the plasma stand
interior for 3 minutes after the plasma is extinguished.

The glassware is fragile. Handle it with care.

7.1.1 Replacing the Torch

Replace the torch in the following cases.。

• If the torch melts (periphery)
• If samples adhere to the torch's center orifice
• If, after analyzing high-concentration boron (B), a trace amount of another element is
to be analyzed
• If the torch's center orifice melts or is damaged in some other way

Even if the internal diameter of the tip of the torch's center orifice becomes
smaller, this cannot be checked with the torch installed. If the spectra for an
element do NOT appear or if the intensity weakens, it is possible that the tip
of the torch's center orifice has melted or the internal diameter has changed.
Remove the torch and check the tip of the torch's center orifice.

7.1.2 Nebulizer

Deposits adhere to the tip of the nebulizer when analyzing alkali solvents. Be sure to
use a water bubbler (option) when analyzing this kind of sample. If there is clogging in
the tip of the nebulizer, the sample suction speed may reduce significantly and sample
suction may even stop. In this case, the nebulizer must be replaced or cleaned.

7.1.3 Replacing the Chamber

Replace the chamber in the following cases.

38 ICPE-9800 Series Hardware

 7.2 Removing Glassware

• If a conspicuous amount of dirt accumulates

• If there is a crack or some other damage that causes gas to leak and adversely affect
operation

7.1.4 Cleaning Glassware

Clean the glassware with hydrochloric acid (HCl) 2 standard solution.

Do NOT perform ultrasonic cleaning on the glassware.

7.2 Removing Glassware

Risk of Burn Injury
There is a risk of burn injury. Do NOT touch the plasma stand
interior for 3 minutes after the plasma is extinguished.

Glass parts break easily and may cause injury if they are
damaged. Handle them with care.

Fig. 7-1 Removing Glassware

7.2.1 Removing the Chamber and Extension Pipe

1 Remove the ball joint clip that connects the chamber and the extension pipe and
remove the chamber.

ICPE-9800 Series Hardware 39

 7 Maintenance

2 Remove the ball joint clip that connects the extension pipe and the torch and
remove the extension pipe.

Fig. 7-2 Removing the Chamber

7.2.2 Removing the Nebulizer

1 To remove the nebulizer, first loosen the fitting of the Helix by turning the
knurled knob counter-clockwise 1/2 turn(Diagram B), then slide the nebulizer
straight out.

Fig. 7-3 Removing the Nebulizer

Take care that no force is applied to the nebulizer’s carrier gas connection pipe.

2 Remove the sample introduction tube.

40 ICPE-9800 Series Hardware

 7.2 Removing Glassware

3 Remove the gas connector from the nebulizer, while depressing the stopper on
the gas connector.

Fig. 7-4 Removing the Nebulizer

Do not forcibly remove the gas connector from the nebulizer while the stopper
is still in place.

7.2.3 Removing the Drain Trap

1 Remove the clip for TS-15.

2 Remove the drain trap.

Hold the part connecting the chamber and the drain trap with one hand and, with the
other hand, pull the clip for TS-15 to remove it.

3 Remove the part connecting to the exhaust tube.

Hold the chamber with one hand and, hold the drain trap with the other hand, and pull
and turn the chamber to remove the drain trap.

4 Remove the liquid in the drain trap.

Slide the clamp's hook up and down to remove it. 7

ICPE-9800 Series Hardware 41

 7 Maintenance

5 Cut the drain tube away from the drain trap.

Be careful about the handling of a cutting tool in cutting off the
drain tube.

Fig. 7-5 Removing the Drain Trap

7.2.4 Removing the Torch

1 Remove the torch from the torch mount.

Loosen the torch clamp's knurled screw and remove the torch. (If the chamber is set,
remove the chamber first.)
"7.2.1 Removing the Chamber and Extension Pipe"

2 Remove the plasma gas tube assembly and the auxiliary gas tube.

42 ICPE-9800 Series Hardware

 7.3 Attaching the Glassware

3 Remove the igniter cable from the torch.

Fig. 7-6 Removing the Torch

7.3 Attaching the Glassware

Glassware breakes easily and may cause injury if they are

damaged. Handle them with care.

7.3.1 Attaching the Torch

1 Fit gas connectors to the plasma gas tube assembly and auxiliary gas tube.

7
2 Slide the plasma gas tube assembly onto the torch's plasma gas inlet.
Slide it until the inlet reaches the end of its travel inside the connector.

3 Connect the igniter cable to the torch's auxiliary gas inlet.

4 Slide the auxiliary gas tube onto the torch's auxiliary gas inlet. Slide it until the
inlet reaches the end of its travel inside the connector.

Check that the igniter cable is securely connected to the auxiliary gas inlet of
the torch.

ICPE-9800 Series Hardware 43

 7 Maintenance

5 Fit the PTFE ring at a position about 46 mm from the end of the torch.

This PTFE ring is not required with the optional plasma torch.

Fig. 7-7 Fitting the Gas Tube, Igniter Cable and PTFE Ring

When replacing the auxiliary gas tube, make it by cutting vinyl tubing with an internal
diameter of 1/8 inch and external diameter of 1/4 inch (P/N S016 31404) to a length of 130
mm.

6 Secure the torch to the torch mount.

Insert the torch into the torch mount and turn the knurled screw of the torch clamp to
lightly secure it.

44 ICPE-9800 Series Hardware

 7.3 Attaching the Glassware

7 Adjust the torch position.

1 Stand the torch position adjustment jig on the torch mount.

2 Move the torch to the position where the protruding section of the torch position
adjustment jig makes contact with the end of the torch and, in this position, turn
the torch clamp to secure the torch.

Fig. 7-8 Attaching the Torch

Do NOT tighten the clamp with a driver or some other
tool. Tightening the clamp forcefully with a tool may 7
cause the torch to break.

3 Remove the torch position adjustment jig and return it to the original position.
At this time, pull the chain protruding from the torch position adjustment jig
outside the plasma stand door.

Be sure to remove the torch position adjustment jig before igniting

the plasma.
Igniting the plasma with the torch position adjustment jig standing
on the torch mount may cause damage to the torch, RF coil, or torch
position adjustment jig.

ICPE-9800 Series Hardware 45

 7 Maintenance

4 Check the position of the coil. If it has shifted out of position relative to the
torch, return it to the original position while referring to "Fig. 7-8 Attaching the
Torch".

7.3.2 Attaching the Drain Trap

1 Attach the drain tube.

• Slide approx. 20mm of drain tube onto the bottom end of the drain trap.
• Secure the drain tube with the clamp.

2 Connect the exhaust tube.

3 Attach the drain trap to the chamber.

• Slide the drain trap onto the bottom end of the chamber.
• Attach the clip for TS-15.

Fig. 7-9 Attaching the Drain Trap

46 ICPE-9800 Series Hardware

 7.3 Attaching the Glassware

7.3.3 Attaching the Nebulizer to the Chamber

1 Attach the argon gas supply tube to the nebulizer.

Fig. 7-10 Attaching the Argon Gas Supply Tube

2 Attach the sample introduction tube to the nebulizer.

Insert the nebulizer to the end of its travel inside the sample introduction tube's
connector.

Fig. 7-11 Attaching the Sample Introduction Tube

3 Before inserting the nebulizer, turn the lock nut clockwise until it rests lightly
against the Helix seal. 7
"7.5.1 Removing the Helix Seal"

4 Insert the nebulizer straight in until its carrier gas connection tube makes contact
with the lock nut's entry point.

ICPE-9800 Series Hardware 47

 7 Maintenance

5 Tighten the nebulizer in place and seal the spray chamber by turning the knurled
knob of the lock nut clockwise (approx. 1/4 to 3/4 turn) by hand (Diagram A)
until it is snug.
Please touch it with a soft touch to check if it is sealed.

Fig. 7-12 Attaching the Nebulizer

DO NOT OVERTIGHTEN (approx. 1/4 to 3/4 turn).

7.3.4 Attaching the Chamber

1 Join the ball joint of the torch and the extension pipe, and secure the connection
with the ball joint clip.

2 Join the ball joint of the extension pipe and the chamber, and secure the
connection with the ball joint clip.
Set the torch, extension pipe, and chamber so that they form a straight line.

48 ICPE-9800 Series Hardware

 7.4 Replacing the Sample Introduction Tube

3 Fill the drain trap with water.

Fig. 7-13 Attaching the Chamber

7.4 Replacing the Sample Introduction Tube

The sample introduction tube, sample introduction tube connector and drain tube
deteriorate due to the effects of sample solvents. This may cause instability in sample 7
suction or liquid leakage. In this case,
replace the sample introduction tube. Attach a new sample introduction tube to the
nebulizer. Insert the nebulizer until it touches the bottom of the sample introduction
tube connector.

Fig. 7-14 Replacing the Sample Introduction Tube

ICPE-9800 Series Hardware 49

 7 Maintenance

7.5 Replacing the Helix Seal

If the Helix seal becomes deformed and fails, it must be replaced. Follow the instructions
below.

Fig. 7-15 Replacing the Helix Seal

7.5.1 Removing the Helix Seal

1 Loosen the lock nut and remove the Helix seal from the spray chamber.

2 If the Helix seal remains in the spray chamber, insert the Helix plug and use it
to remove the seal.
(See Fig. 7-16-A.)

7.5.2 Fitting the Helix Seal

1 Loosen the lock nut and remove it from the spray chamber.

2 Attach the lock nut and Helix seal to the Helix plug as shown in Fig. 7-16-A.

Fig. 7-16 Helix Plug

Ensure that the white face of the seal is facing the chamber, as shown in Fig.
7-16-A.

50 ICPE-9800 Series Hardware

 7.6 Replacing the Peristaltic Pump Tube

3 Insert the whole thing into the nebulizer connector of the spray chamber.

4 Gently turn the lock nut clockwise until light resistance is felt.

5 Remove the Helix plug.

If the lock nut is tightened without the nebulizer or Helix plug inserted, the
Helix seal may deform and fail.

7.6 Replacing the Peristaltic Pump Tube

Since the sample pressure feed tube is constrained by the rotor and guide, it is subject
to plastic deformation and eventually samples will no longer feed through it. For this
reason it has to be replaced with a new tube at regular intervals.

Fig. 7-17 Peristaltic Pump 7

1 Loosen the guide retainer's screw and remove the retainer from the guide.

2 Remove the old pump tube from the rotor and pull off the sample introduction
tubes connected at both ends.

3 Insert a new pump tube into the tube hanger.

4 While winding the tube onto the rotor, catch the tube stoppers in the tube
hangers.

ICPE-9800 Series Hardware 51

 7 Maintenance

5 Attach the guide retainer on the guide, and adjust the screw.

6 Connect the nebulizer sample suction tube and the autosampler suction tube to
the pump tube.
Cut and connect the nebulizer sample suction tube or the autosampler suction tube to
the appropriate length.

7 Start the pump from the [Instrument Control] window in ICPEsolution, and adjust
the guide retainer so that samples flow smoothly.

7.7 Replacing the Drain Tube

1 Remove the drain tube as described in"7.2.3 Removing the Drain Trap".
If there is any solution remaining in the drain tube, release all of it into the waste tank.

2 Connect the new drain tube to the drain trap as described in "7.3.2 Attaching
the Drain Trap".
Ensure that the drain tube doesn't sag.

3 Insert the drain tube into the waste tank.

Ensure that the end of the drain tube is not immersed in waste.

52 ICPE-9800 Series Hardware

 7.8 Cleaning and Replacement of Reflect Mirror in Cooling Jacket

4 Fill the drain trap with water.

Fig. 7-18 Tube Arrangement on Right Side

Check that there is no solution in the exhaust tube for the drain trap.
If there is any it will make the liquid level height in the drain trap unstable,
adversely affecting the accuracy of analysis.

7.8 Cleaning and Replacement of Reflect Mirror in Cooling Jacket

Risk of Burn Injury
There is a risk of burn injury. Do NOT touch the plasma stand
interior for 3 minutes after the plasma is extinguished.

7
1 Loosen the mirror holder's set screws and remove the mirror holder from the
jacket.

ICPE-9800 Series Hardware 53

 7 Maintenance

2 When cleaning the mirror, leave it on the mirror holder and clean it with gauze
moistened with alcohol.

Fig. 7-19 Removing the Mirror Holder

Do NOT remove the mirror from the mirror holder when cleaning it.

3 If the dirt cannot be removed, replace the mirror with a new one.

Position the mirror so that the reflecting side is facing downward.

Fig. 7-20 Replacing Back-Reflect Mirror

When replacing the mirror, mount the new one with the reflecting surface facing
down.
Take care not to scratch the mirror.

4 After cleaning or replacing the mirror, insert the mirror holder into the jacket.

5 Ensure that the front and side surfaces of the mirror holder are in contact with
the jacket.

54 ICPE-9800 Series Hardware

 7.9 Cleaning the Axial-View Observation Orifice Assembly

6 Tighten the set screw to fix the mirror holder.

Fig. 7-21 Attaching Mirror Holder

7.9 Cleaning the Axial-View Observation Orifice Assembly

There are two types of orifice assembly: the orifice L2 assembly for the standard mini
torch for ICPE9800, and the orifice S2 assembly for standard size torches such as the high
TDS torch. The figures show the L2 assembly as an example, but the procedure is the
same for the S2 assembly.
Risk of Burn Injury
There is a risk of burn injury. Do NOT touch the plasma stand
interior for 3 minutes after the plasma is extinguished. 7

Cleaning the orifice assembly helps prevent sample contamination and abnormal
electric discharge. If such phenomena are observed, clean the orifice assembly.
The frequency of cleaning will differ depending on the samples being analyzed
and the period of use.

7.9.1 Remove the orifice assembly.

1 Turn the orifice with a spanner.（13mm）

ICPE-9800 Series Hardware 55

 7 Maintenance

2 After the orifice becomes looser, turn it manually to remove it.

Fig. 7-22 shows the orifice L2 assembly as an example.

Fig. 7-22 Removing the Orifice Assembly L2

7.9.2 Clean the Orifice Assembly

1 Prepare hydrochloric acid (HCl) 2 standard solution as the cleaning fluid.

2 Immerse the orifice assembly in the cleaning fluid for 2 minutes.

3 Remove the orifice assembly from the cleaning fluid and wash it with purified
water.

4 Wipe the surface of the orifice assembly (particularly the interior and the surface
of the tungsten tip) with gauze to remove all moisture.

Do NOT perform ultrasonic cleaning on the orifice assembly.

7.9.3 Attach the orifice assembly

1 Attach the orifice assembly to the cooling jacket by turning it manually.

56 ICPE-9800 Series Hardware

 7.10 Attaching and Removing the Cooling Jacket

2 Tighten the assembly with a spanner.

Be careful not to tighten with excessive force.

Fig. 7-23 Orifice Assembly L2 Attachment

The contact surface with the cooling jacket will become rough due to wear of
the orifice assembly. This will decrease the orifice assembly cooling efficiency,
leading to significant deterioration of the orifice assembly surface. In this case,
replace with a new orifice assembly.

Make sure to turn on the purge gas while nebulizing the sample
to check the suction speed. The orifice assembly will deteriorate
rapidly and the cooling jacket will be damaged.

7.10 Attaching and Removing the Cooling Jacket

There is a possibility that the mirror inside the cooling jacket may be contaminated when
analyzing organic solvents or hydrofluoric acid samples. In this case, then, remove the
cooling jacket.
Risk of Burn Injury
There is a risk of burn injury. Do NOT touch the plasma stand
interior for 3 minutes after the plasma is extinguished.

7.10.1 Removing the Cooling Jacket

Remove the cooling jacket using the following procedure. 7

1 Remove the two cooling water tubes. (Fig. 7-24)

2 Remove the argon gas purge tube. (Fig. 7-25)

3 Remove the two attachment screws. (Fig. 7-26)

When the cooling water tubes are removed, the small amount of cooling water
that remains in the connection adapter will spill out: wipe this up with a cloth.

ICPE-9800 Series Hardware 57

 7 Maintenance

7.10.2 Attaching the Cooling Jacket

Attach the cooling jacket using the following procedure.

1 Insert the upper positioning pin in the cooling jacket's pin hole and turn the
jacket slightly in a counter clockwise direction until the lower positioning pin
makes contact with the bottom of the cooling jacket.

2 Secure the cooling jacket in this position using the two attachment screws. Check
that the two screws are tightened. (Fig. 7-26)

3 Connect the two cooling water tubes. (Fig. 7-24)

4 Connect the argon gas purge tube. (Fig. 7-25)

Fig. 7-24 Removing the Cooling Water Tubes

Fig. 7-25 Removing the Argon Gas Purge Tube

Fig. 7-26 Removing and Attaching the Cooling Jacket

58 ICPE-9800 Series Hardware

 7.11 Cleaning the Entrance Window (ICPE-9810)

7.11 Cleaning the Entrance Window (ICPE-9810)

If the ICPE-9800 is used for a long time, the surface of the entrance windows mirror
becomes dirty and the spectral intensity dropped. Because the significant spectral intensity
affects the reproducibility of analytical values adversely, cleaning is required on a regular
basis.
Cleaning of the entrance window using the following procedure.
Note that the cleaning procedure for the ICPE-9820 is different. Refer to"7.12 Cleaning
the Entrance Windows and Mirrors (ICPE-9820)"for the procedure.
Risk of Burn Injury
There is a risk of burn injury.
Do NOT start work inside the plasma stand for 3 minutes after
the plasma is extinguished.

7.11.1 Work Flow

If it takes much time to cleaning operation or the humidity of the laboratory is

high, it takes much time that the vacuum level reaches the required level.
Prepare tools or alcohol before cleaning operation to finish operation within
almost ten minutes.

ICPE-9800 Series Hardware 59

 7 Maintenance

7.11.2 Removing the Cooling Jacket

Remove the cooling jacket. See"7.10.1 Removing the Cooling Jacket".

7.11.3 Filling Argon Gas inside the Spectrometer

The spectrometer is maintained a vacuum state. After filling argon gas, remove the
entrance window. Clean the entrance window.

1 Check that argon gas is supplied to the ICPE-9800.

2 Open the [Vacuum Pump ON/OFF] window from the [Instrument] menu in
ICPEsolution, and purge the spectrometer.
After the vacuum pump has stopped, open its leak valve immediately.
See "6.2.2 Leak Valve Operation (After vacuum pump is stopped)".

3 Check that the spectrometer purge has been completed.

Before purging the spectrometer, check that argon gas is being supplied.
Also check that the argon gas piping is connected to the gas cylinder.

7.11.4 Cleaning the Entrance Window

1 Remove the entrance window after loosening the flat head screw with the
Phillips-head screwdriver.

2 Clean the both side of the window with cotton swab (applicator) dipped in
alcohol.

60 ICPE-9800 Series Hardware

 7.12 Cleaning the Entrance Windows and Mirrors (ICPE-9820)

3 After cleaning windows, attach the windows.

Fig. 7-27 Remove the Entrance Window

Do NOT remove the entrance window with the spectrometer held vacuum.
Otherwise, spectrometer is filled with air and the optical parts in the
spectrometer become dirty.

7.11.5 Attaching the Cooling Jacket

1 Replace the absorbent.

"7.14 Replacing the Molecular Sieve (Oil Absorbent) in the Vacuum Pump"

2 Open the [Vacuum Pump ON/OFF] window from the [Instrument] menu in
ICPEsolution, and start the vacuum pump.

3 Attach the cooling jacket.

7
"7.10.2 Attaching the Cooling Jacket"

7.12 Cleaning the Entrance Windows and Mirrors (ICPE-9820)

When the instrument is used over a long period the surfaces of the entrance window
and the mirror in the radial-view observation unit become dirty and the spectral intensity
drops. A significant drop in spectral intensity adversely affects the reproducibility of
analytical values, so clean the entrance window and mirror if any impediment to analysis
is confirmed. Carry out the cleaning by following the procedure below. Note that the

ICPE-9800 Series Hardware 61

 7 Maintenance

cleaning procedure for the ICPE-9810 is different. Refer to、"7.11 Cleaning the Entrance
Window (ICPE-9810)"for the procedure.

Risk of Burn Injury

There is a risk of burn injury.
Do NOT start work inside the plasma stand for 3 minutes after
the plasma is extinguished.

7.12.1 Work Flow

Filling the spectrometer with argon gas before cleaning allows the vacuum to
reach the required level in a short time.
However, if the cleaning work takes a long time or the humidity in the
laboratory is high, it will take a longer time for the vacuum to reach the
required level.
Prepare the tools, alcohol, etc. before starting cleaning in order to ensure that
the cleaning operation can be completed within about 10 minutes.

62 ICPE-9800 Series Hardware

 7.12 Cleaning the Entrance Windows and Mirrors (ICPE-9820)

7.12.2 Preparing

Fig. 7-28 Removing the Cooling Jacket and Front Panel

1 Remove the cooling jacket.

For details on the removal procedure, see"7.10.1 Removing the Cooling Jacket".

2 Loosen the two front panel fixing screws a little.

Loosen the front panel fixing screws before purging the spectrometer.
If the spectrometer is purged without loosening these screws they will become
difficult to remove.

7.12.3 Filling the Spectrometer With Argon Gas

The inside of the radial-view observation unit is held in a vacuum along with the
spectrometer. 7
Therefore, after filling the interior of the spectrometer with argon gas, remove the
radial-view observation unit's front panel and clean the radial-view observation unit's
entrance window and mirrors.

1 Check that argon gas is being supplied to the main unit.

2 Open the [Vacuum Pump ON/OFF] window from the [Instrument] menu in
ICPEsolution, and purge the spectrometer.
After the vacuum pump has stopped, open its leak valve immediately.
For details on the operating procedure after the vacuum pump stops, see"6.2.2 Leak Valve
Operation (After vacuum pump is stopped)".

ICPE-9800 Series Hardware 63

 7 Maintenance

3 Check that purging of the spectrometer is completed.

(When filling with argon gas is completed, the level of vacuum indicated in the
Instrument Monitor bar in ICPEsolution will be several hundred Pascals.)

Before purging the spectrometer, check that argon gas is being supplied.
Also check that the argon gas piping is connected to the gas cylinder.

7.12.4 Removing the Front Cover of the Radial-view Observation Unit

First remove the argon gas purge tube from the front panel of the radial-view
observation unit, and then remove the front panel.

Fig. 7-29 Front Panel of the Radial-View Observation Unit

(Attaching/Removing the Entrance Window)

1 Remove the argon gas purge tube from the radial-view observation unit.

2 Remove the two front panel fixing screws and remove the front panel.
Do NOT remove the front panel of the radial-view
observation unit while a vacuum is maintained inside the
radial-view observation unit.
Otherwise the spectrometer will fill with air and the optical
parts inside it will become dirty.

3 Remove the purge tube cover.

4 Using the dedicated tool for attaching/removing the purge tube (a hex wrench),
loosen the hexagonal socket head bolts securing the purge tube and remove the
purge tube.

64 ICPE-9800 Series Hardware

 7.12 Cleaning the Entrance Windows and Mirrors (ICPE-9820)

7.12.5 Removing the Entrance Window

Fig. 7-30 Front Panel of the Radial-View Observation Unit

(Attaching/Removing the Entrance Window)

1 Remove the entrance window for radial view observation from the front panel
of the radial-view observation unit.
Use the dedicated tool for attaching/removing the purge tube (a hex wrench) to remove
the entrance window for radial view observation.

Do NOT remove the positioning plate for the entrance window for radial view
observation.
Changing the position where it is set will adversely affect the reproducibility of
the analytical values and make normal analysis no longer possible.

7.12.6 Cleaning the Entrance Windows and Mirrors

1 Wipe dirt off both sides of both of the removed entrance windows with cotton
swabs (applicators) dipped in alcohol.

ICPE-9800 Series Hardware 65

 7 Maintenance

2 Wipe dirt off the two internal mirrors with cotton swabs (applicators) dipped in
alcohol.

If the top mirror is facing inward, set [Axial] for [View Direction] on the
[Instrument Control] window of ICPEsolution.

Fig. 7-31 Cleaning the Mirrors

7.12.7 Mounting the Purge Tube and Entrance Windows

1 Using the same tool as in"7.12.5 Removing the Entrance Window"Window",

mount the entrance windows for axial view observation and radial view
observation on the front panel of the radial view observation unit.

2 Using the dedicated tool for attaching/removing the purge tube (a hex wrench),
secure the purge tube.

3 Fit the purge tube cover.

7.12.8 Mounting the Radial-view Observation Unit's Front Panel

1 Mount the front panel of the radial-view observation unit and secure it with the
two screws.

66 ICPE-9800 Series Hardware

 7.13 Cleaning/Replacing the Purge Tube (ICPE-9820)

2 Connect the argon gas purge tube.

Be sure to connect the argon gas purge tube without fail.

3 Replace the vacuum pump's molecular sieve.

"7.14 Replacing the Molecular Sieve (Oil Absorbent) in the Vacuum Pump"

4 Open the [Vacuum Pump ON/OFF] window from the [Instrument] menu in
ICPEsolution, and start the vacuum pump.

5 The two screws of the radial-view observation unit's front panel will loosen, so
retighten them.

6 Attach the cooling jacket.

"7.10.2 Attaching the Cooling Jacket"

Turn the vacuum pump ON, and stand by until the instrument stabilizes.
It takes about 3 to 4 hours for the instrument to stabilize after this cleaning
work.

7.13 Cleaning/Replacing the Purge Tube (ICPE-9820)

When a high concentration sample is analyzed, some of the sample may adhere to the
purge tube. If the tube becomes heavily contaminated, remove the purge tube and clean
off the contamination using alcohol. If the tube is chipped or cracked, replace it with a
new one.
Risk of Burn Injury
There is a risk of burn injury.
Do NOT start work inside the plasma stand for 3 minutes after
the plasma is extinguished.
7
1 Remove the purge tube by referring to "7.12 Cleaning the Entrance Windows
and Mirrors (ICPE-9820)".
"7.12 Cleaning the Entrance Windows and Mirrors (ICPE-9820)"

Do NOT remove the positioning plate.

Changing the position where it is set will adversely affect the reproducibility of
the analytical values and make normal analysis no longer possible.

2 Clean or replace the purge tube.

ICPE-9800 Series Hardware 67

 7 Maintenance

3 Connect the purge tube by referring to "7.12.7 Mounting the Purge Tube and
Entrance Windows".

7.14 Replacing the Molecular Sieve (Oil Absorbent) in the Vacuum Pump
The molecular sieve in the vacuum pump at the back of the ICPE-9800 can be replaced
while maintaining a vacuum state in the spectrometer.
Replace the molecular sieve using the following procedure.

1 Open the [Vacuum Pump ON/OFF] window from the [Instrument] menu in
ICPEsolution, and stop the vacuum pump.

2 Loosen the leak valve (d) to allow leakage.

3 Remove the filter lid (c) and take out the absorbent container (b).

4 Replace the absorbent.

5 Reattach the absorbent container (b) and the filter lid (c).

6 Close the leak valve (d).

Fig. 7-32 Replacing the Molecular Sieve

68 ICPE-9800 Series Hardware

 7.15 Replacing the Vacuum Pump Oil

7.15 Replacing the Vacuum Pump Oil

Replace the pump oil once every six months.

Before taking out the oil, warm it up by running the pump for a short while.

1 Open the [Vacuum Pump ON/OFF] window from the [Instrument] menu in
ICPEsolution, and stop the vacuum pump.

2 Remove the drain plug and drain the oil.

Please put oil in a container that can contain more than 1L. If the removed oil
is muddy or dirty, flush thoroughly with clean oil before pouring the oil.

3 Close the drain plug and add oil via the oil inlet.

Normally, add oil until the surface is in the center of the oil gauge.。

7
Fig. 7-33 Replacing the Vacuum Pump Oil

The rotary pump weighs approx. 9.5kg. Do NOT perform

maintenance work with an inappropriate posture.

7.16 Replacing FILTER ELEMENT of OIL MIST TRAP

Replace FILTER ELEMENT once every 2000 hours from 1500 hours (pump operation time).
"7.15 Replacing the Vacuum Pump Oil"

ICPE-9800 Series Hardware 69

 7 Maintenance

7.17 Cleaning the Fan Filters

The fan filter on the left side of the main unit must be cleaned on a regular basis.
Clean this filter once every three months.

1 Turn OFF the computer power supply and the power switch.

2 Pull the front end of the side filter cover to the left and then forward to remove
it.

3 Remove the filter.

4 Remove dust from the filter with a vacuum cleaner.

5 Clean the filter cover in the same way.

6 Attach the filter onto the filter cover, engage the catches at the back end of the
cover onto the ICPE-9800, and close the front end of the cover.

7 Turn ON the power switch.

Fig. 7-34 Cleaning the Filter on the Left Side of the Main Unit

If the power switch is turned OFF, the spectrometer temperature-control circuit

stops operating. The time required for the spectrometer to stabilize varies with
the external temperature but, if it has been OFF for 1 to 2 hours, 6 hours is
required. It soon recovers, however, after a momentary power interruption.

70 ICPE-9800 Series Hardware

 7.18 Waste Tank

7.18 Waste Tank

Be sure to use a chemically resistant waste tank because approx. 1 mL/min of sample is
discharged from the sample introduction system of the plasma stand after plasma is
ignited. Alternatively, use the optional " DRAIN TANK, PLASTIC 10LT (P/N S210-15534)"
waste tank.
Place the waste tank as close to the plasma stand as possible. Ensure that waste liquid
flows smoothly through the drain tube and that the end of the drain tube is put in the
waste tank but not immersed in the waste liquid. Be sure to check the amount of waste
liquid in the waste tank before use to prevent an overflow during use.
After use, close the cover of the waste tank or dispose of waste liquid promptly. If waste
liquid is left in the waste tank with the cover open for a long time, out-gassing may
cause corrosion around the waste tank.

Dispose of waste in accordance with your country's laws and regulations.

7.19 Checking Operation of Safety Devices

The operation of the safety devices used with the ICPE-9800 can be checked as described
below. Check the operation of the safety devices on a regular basis (every one month).

1 Argon gas pressure sensor:

1)Ignite the plasma.
2)Stop the supply of argon gas and check that the plasma is extinguished.

2 Plasma stand door switch:

1) Ignite the plasma.
2) Open the plasma stand door and check that the plasma is extinguished.

3 Cooling water flow switch for RF coil, RF power supply, and orifice assembly:
1) Ignite the plasma.
2) Stop the supply of cooling water and check that the plasma is extinguished

7.20 Inspecting the Argon Gas and Cooling Water Piping 7

Inspect the argon gas and cooling water piping on a regular basis to ensure that there
are no leaks.

ICPE-9800 Series Hardware 71

 7 Maintenance

7.21 Cleaning the Filter for the Mains Water Supply Connection Kit (Option)

Fig. 7-35 Cleaning the Filter for the Mains Water Supply Connection Kit

If the filter's integrated coupling (one-touch joint) is opened while the mains
water supply valve is open, the mains water will gush out, so be sure to turn
shut off the mains water supply valve before starting the work.
The water in the hose will flow out when the filter case is opened, so this should
be done in a sink, for example.

1 Close the main valve for the mains water supply.

2 Open the [Instrument Control] window in ICPEsolution, and set the [Coolant
Water Valve] to [ON].
This will release the residual pressure in the piping.

3 Open the filter's integrated coupling and loosen the filter to remove it, then
clean it with a brush or similar implement.

4 Return the filter to the coupling integrated with the filter and reconnect it.

Check that the filter case is securely connected.

5 Open the main valve for the mains water supply.

6 In the [Instrument Control] window, set the [Coolant Water Valve] to [OFF], and
click [Apply].

7 Check that there are no water leaks.

8 Close the main valve for the mains water supply.

72 ICPE-9800 Series Hardware

 7.22 Cleaning the Main Unit

7.22 Cleaning the Main Unit

If the main unit cover or interior of the plasma stand is dirty, wipe it clean with a soft
dry cloth.
If they are significantly dirty, dip a soft cloth in some diluted neutral detergent,
thoroughly wring out the cloth and use it to wipe off the dirt. Then dip a soft cloth in
some water, thoroughly wring it out and use it to wipe away all the detergent.

ICPE-9800 Series Hardware 73

 8 Maintenance Parts and Consumable Items
8.1 Maintenance Parts List

P/N Part name Unit Notes

S211-81444 TORCH ADAPTOR Accessory Made of Teflon
S211-91422-41 TORCH ADJUST JIG,ASSY Accessory To adjust torch point
S035-60903-01 COUPLER,MC-04PH Gas piping part Plug (one-touch type)
S211-88275-91 PACKING MIRROR Plasma stand Mirror in cooling jacket
Window between vacuum
PARTITION WINDOW
S211-86114-95 Plasma stand spectrometer and
HOLDER
light-guide
Radial-view observation
S211-87873-41 PURGE HOLDER ASSY Plasma stand
unit
Radial-view observation
S211-87889 PURGE PIPE COVER Plasma stand
unit
Vacuum system Oil mist trap for vacuum
S042-00125-25 OIL MIST TRAP,OMT-050A
part pump
S305-34207 IM, ICPE-9800H/W J Instruction Manual
S305-34208 IM, ICPE-9800H/W E Instruction Manual
S305-34209 IM, ICPE-9800H/W C Instruction Manual

8.2 Consumable Items List

Approximate
P/N Part name replacement Notes
period
S211-88556 FILTER 1 year (*1) Main unit
S211-81448 MINI TORCH 3 months (*2) Plasma stand
Plasma stand (optional
S211-92878-41 PLASMA TORCH 3 months (*2) plasma torch, standard
size)
Plasma stand (optional
S204-74323 PLASMA TORCH,SILICON 3 months (*2) plasma torch for high-TDS
samples)
Plasma stand (optional
S211-92876-41 TORCH FOR SOLVENT 3 months (*2) plasma torch for organic
solvents)
Connector for torch gas
S046-00092-25 CONNECTOR,GAZFIT04 1 year (*2)
connection
S211-86533 EXTENSION PIPE L 1 year (*2) Plasma stand
S210-15508-01 BALL JOINT CLIP,12 1 year (*2) Plasma stand

74 ICPE-9800 Series Hardware

 8.2 Consumable Items List

Approximate
P/N Part name replacement Notes
period
S046-00092-20 NEBULIZER,10UES 2 months (*2) Plasma stand
Optional nebulizer for
S046-00092-21 NEBULIZER,07UES 2 months (*2)
small samples
S046-00092-09 CONNECTOR,QSM 2 months (*2) Accessories for nebulizer
S046-00092-10 TUBE ADAPTOR,0735 2 months (*2) Accessories for nebulizer
For securing carrier gas
S037-61113-01 CLAMP,SNP-1 1 year (*2)
tube
PLASMA GAS TUBING Plasma stand (plasma gas
S211-85118-91 1 month
ASSY tube)
Plasma stand (*3)
PVC TUBE, LMT-55
S016-31404 1 month (Auxiliary gas and carrier
1/8X1/4X1/16
gas tubes)
S046-00093-02 CYCLONE CHAMBER,HE 1 year (*2) Plasma stand
Accessory for the cyclone
S046-00093-92 LOCKING SCREW,0152 6 months (*2)
chamber
Accessory for the cyclone
S046-00093-93 SEAL,0237 6 months (*2)
chamber
For the optional chamber
S211-90552 CHAMBER FOR SOLVENT 1 year (*2)
for organic solvents
For the optional chamber
CHAMBER WATER COOL
S211-90551 1 year (*2) for organic solvents
FOR SOLVENT
(water cooling type)
Nebulizer holder for
S202-43797 NEBULIZER HOLDER 1 year (*2)
optional chambers
O-ring for optional
S210-12566-01 O-RING,SMOKE 6X2 1 year (*2)
chambers
O-ring for optional
S210-12566-02 O-RING,SMOKE 34.5X3 1 year (*2)
chambers
Plasma stand (for
S046-00993-01 CLIP,TS15 D-310-1 6 months (*2)
connecting the drain trap)
S046-00093-01 DRAIN TRAP,8214 1 year (*2) Plasma stand
Drain trap for optional
S211-90553 DRAIN 1 year (*2)
chambers
PVC TUBE, LMT-55 Plasma stand (exhaust
S016-31428 3 months (*2)
3/16X5/16X1/16 tube for drain trap) (*3)
PVC TUBE,LMT-55 Plasma stand (drain tube
S016-31429-10
7/16X9/16X1/16
3 months (*2)
for drainage) (*3)
8
Plasma stand (for securing
S037-61113-04 CLAMP,SNP-10 1 year (*2)
the drain tube)
Plasma stand (orifice for
S211-87758-42 ORIFICE L2 ASSY 1 month (*2)
mini torch)
Orifice for optional
S211-88571-42 ORIFICE S2 ASSY 1 month (*2)
plasma torches

ICPE-9800 Series Hardware 75

 8 Maintenance Parts and Consumable Items

Approximate
P/N Part name replacement Notes
period
SUCTION TUBE ASSY, Plasma stand (sample
S046-00092-18 2 months (*2)
NFTS-075 introduction tube)
S211-87874-41 PURGE PIPE ASSY 1 year (*2) Plasma stand (purge tube)
S042-00125-92 FILTER ELEMENT,02056 1500 hours For vacuum pump
S017-30166-01 PUMP OIL,R-2 1L 6 months For vacuum pump
S239-07003-08 M.SIEVE,13X4X8M 6 months Vacuum system
SILICONE GREASE,HIVAC-G Vacuum grease (for
S017-30813-01 -
50G vacuum pump) 50 g
For connecting the
S211-83697 CONNECTION TUBE 1 month (*2)
autosampler suction tube
Pump tube for peristaltic
S018-31558-01 TUBE,0.25-OB-F 1 week (*2)
pumps
Pump tube for peristaltic
S018-31558-02 TUBE,0.76-BLK-F 1 week (*2)
pumps
Pump tube for peristaltic
S018-31558-03 TUBE,0.89-ORG-F 1 week (*2)
pumps
Pump tube for peristaltic
S018-31558-11 TUBE,0.76-BLK-SF-F 1 week (*2)
pumps
Pump tube for peristaltic
S018-31558-21 TUBE,VS0.76-BLK-F 1 week (*2)
pumps
Pump tube for peristaltic
S018-31558-31 TUBE,1.02-WHT-MH-F 1 week (*2)
pumps
For connecting the torch
PVC TUBE,LMT-55
S016-31404 Accessories (auxiliary gas) and
1/8X1/4X1/16
nebulizer (*1)
PVC TUBE,LMT-55 Exhaust tube for drain
S016-31428 Accessories
3/16X5/16X1/16 trap (*1)
PVC TUBE,LMT-55 For connecting the drain
S016-31429-10 Accessories
7/16X9/16X1/16 trap (glass) (*1)

＊1：Varies with the ICPE-9800 installation environment.

＊2：Varies with the analysis samples.
＊3：Please order it by a meter unit.

76 ICPE-9800 Series Hardware

9 Troubleshooting
No Problem Possible cause and solution 9
Possible causes are given below. Identify and remove the
cause of the problem.
• Deposits adhered to the tip of the nebulizer.
• Deterioration of nebulizer
• Deterioration of sample introduction tube
• Bubbles entered the sample introduction tube and the
sample suction volume decreased.
• The sample introduction tube is not properly inserted in
the nebulizer.
• The tip of the torch's center orifice is dirty.
The spectral intensity • The tip of the torch's center orifice melted.
1
dropped significantly.
• The internal diameter of the torch's center orifice
changed.
• The reflective mirror inside the cooling jacket is dirty (in
axial-view observation).
• The entrance window is dirty.
• Foreign matter adhered to the center of the orifice
assembly (in axial-view observation).
• The entrance window of the radial-view observation kit
is dirty (in radial-view observation).
• The drain trap was damaged and drain liquid does not
accumulate.
• The ICPE-9800 installation location does not meet
requirements related to installation location or facilities.
The spectral intensity
2 • One of the causes listed for problem 1
is unstable.
• A large amount of exhaust is discharged from the
exhaust duct.

Condensation occurs • Wipe off the water droplets with gauze or some other
3 on the RF coil or the appropriate material and ignite the plasma.
cooling jacket. • Increase the coolant temperature.
• The blank liquid is dirty.
The spectral intensity • The torch is dirty.
4 for elements is high
even with a blank. • The chamber is dirty.
• The rinse time is short.

If the problem is not resolved by performing the appropriate countermeasures, make a note
of the problem and contact your Shimadzu representative.

ICPE-9800 Series Hardware 77

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