Safety data sheet

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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

SECTION 1: Identification of the substance/mixture and of the

company/undertaking
1.1. Product identifier

ETHYLBENZENE
Chemical name: Benzene, ethyl-
CAS Number: 100-41-4

REACH registration number: 01-2119489370-35-0009, 01-2119489370-35-0002, 01-2119489370-

35-0004, 01-2119489370-35-0005, 01-2119489370-35-0037, 01-2119489370-35-0006

1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended use: Monomer for manufacturing of polymers

For the detailed identified uses of the product see appendix of the safety data sheet.

1.3. Details of the supplier of the safety data sheet

Company: Contact address:

BASF SE BASF plc
67056 Ludwigshafen 4th and 5th Floors, 2 Stockport Exchange
GERMANY Railway Road, Stockport, SK1 3GG
UNITED KINGDOM

___________________________________________________________________________
Telephone: +44 161 475 3000
E-mail address: [email protected]

1.4. Emergency telephone number

International emergency number:

Telephone: +49 180 2273-112
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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

SECTION 2: Hazards Identification

2.1. Classification of the substance or mixture

According to GB-CLP Regulations UK SI 2019/720 and UK SI 2020/1567

Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.

Flam. Liq. 2 H225 Highly flammable liquid and vapour.
Acute Tox. 4 (Inhalation - H332 Harmful if inhaled.
vapour)
STOT RE 2 H373 May cause damage to organs (Auditory organ) through
prolonged or repeated exposure.
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.

For the classifications not written out in full in this section the full text can be found in section 16.

2.2. Label elements

According to GB-CLP Regulations UK SI 2019/720 and UK SI 2020/1567

Pictogram:

Signal Word:
Danger

Hazard Statement:
H225 Highly flammable liquid and vapour.
H332 Harmful if inhaled.
H304 May be fatal if swallowed and enters airways.
H373 May cause damage to organs (Auditory organ) through prolonged or
repeated exposure.
H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements (Prevention):

P271 Use only outdoors or in a well-ventilated area.
P210 Keep away from heat, hot surfaces, sparks, open flames and other
ignition sources. No smoking.
P280 Wear protective gloves and eye protection or face protection.
P243 Take action to prevent static discharges.
P260 Do not breathe dust/gas/mist/vapours.
P273 Avoid release to the environment.
P241 Use explosion-proof electrical, ventilating and lighting equipment.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P242 Use non-sparking tools.

Precautionary Statements (Response):

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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

P312 Call a POISON CENTER or physician if you feel unwell.

P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for
breathing.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water or shower.
P314 Get medical advice/attention if you feel unwell.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or physician.
P331 Do NOT induce vomiting.
P370 + P378 In case of fire: Use water spray, dry powder, foam or carbon dioxide for
extinction.

Precautionary Statements (Storage):

P405 Store locked up.
P403 + P235 Store in a well-ventilated place. Keep cool.

Precautionary Statements (Disposal):

P501 Dispose of contents and container to hazardous or special waste
collection point.

Hazard determining component(s) for labelling: ethylbenzene, toluene, benzene

2.3. Other hazards

According to GB-CLP Regulations UK SI 2019/720 and UK SI 2020/1567

See section 12 - Results of PBT and vPvB assessment.

Product does not contain a substance above legal limits included in the list established in
accordance with Article 59(1) of Regulation (EC) No 1907/2006 for having endocrine disrupting
properties or is identified to have endocrine disrupting properties in accordance with the criteria set
out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605.

SECTION 3: Composition/Information on Ingredients

3.1. Substances

Chemical nature

ethylbenzene (Content (W/W): 100 %)

CAS Number: 100-41-4
EC-Number: 202-849-4
INDEX-Number: 601-023-00-4

Hazardous ingredients (GHS)

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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

ethylbenzene
Content (W/W): > 0 % - <= 100 % Asp. Tox. 1
CAS Number: 100-41-4 Flam. Liq. 2
EC-Number: 202-849-4 Acute Tox. 4 (Inhalation - vapour)
INDEX-Number: 601-023-00-4 STOT RE (Auditory organ) 2
Aquatic Chronic 3
H225, H332, H304, H373, H412

toluene
Content (W/W): > 0 % - < 1 % Asp. Tox. 1
CAS Number: 108-88-3 Flam. Liq. 2
EC-Number: 203-625-9 Skin Corr./Irrit. 2
INDEX-Number: 601-021-00-3 Repr. 2 (unborn child)
STOT SE 3 (drowsiness and dizziness)
STOT RE (Central nervous system) 2
Aquatic Chronic 3
H225, H315, H304, H336, H361d, H373, H412

benzene
Content (W/W): > 0 % - < 0.2 % Asp. Tox. 1
CAS Number: 71-43-2 Flam. Liq. 2
EC-Number: 200-753-7 Skin Corr./Irrit. 2
INDEX-Number: 601-020-00-8 Eye Dam./Irrit. 2
Muta. 1B
Carc. 1A
STOT RE (Blood) 1
Aquatic Chronic 3
H225, H319, H315, H304, H350, H340, H372,
H412

For the classifications not written out in full in this section, including the hazard classes and the
hazard statements, the full text is listed in section 16.

3.2. Mixtures

Not applicable

SECTION 4: First-Aid Measures

4.1. Description of first aid measures
First aid personnel should pay attention to their own safety. If the patient is likely to become
unconscious, place and transport in stable sideways position (recovery position). Immediately
remove contaminated clothing.
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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.

On skin contact:
Immediately wash thoroughly with soap and water, seek medical attention.

On contact with eyes:

Wash affected eyes for at least 15 minutes under running water with eyelids held open.

On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.

4.2. Most important symptoms and effects, both acute and delayed
Symptoms: Information, i.e. additional information on symptoms and effects may be included in the
GHS labeling phrases available in Section 2 and in the Toxicological assessments available in
Section 11.

Hazards: Information, i.e. additional information on symptoms and effects may be included in the
GHS labeling phrases available in Section 2 and in the Toxicological assessments available in
Section 11. (Further) symptoms and / or effects are not known so far

4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.

SECTION 5: Fire-Fighting Measures

5.1. Extinguishing media
Suitable extinguishing media:
water spray, dry powder, foam, carbon dioxide

Unsuitable extinguishing media for safety reasons:

No data available.

5.2. Special hazards arising from the substance or mixture

Advice: Highly flammable. Cool endangered containers with water-spray. See SDS section 7 -
Handling and storage.

5.3. Advice for fire-fighters

Special protective equipment:
Wear a self-contained breathing apparatus. Special protective equipment for firefighters

Further information:
Evacuate area of all unnecessary personnel. Fight fire from maximum distance.

Extend fire extinguishing measures to the surroundings. Dispose of fire debris and contaminated
extinguishing water in accordance with official regulations.
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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

SECTION 6: Accidental Release Measures

High risk of slipping due to leakage/spillage of product.

Release of substance/product can cause fire or explosion. Shut off or stop source of leak. Shut off or
stop released substance/product under safe conditions.

Pack in tightly closed containers for disposal.

6.1. Personal precautions, protective equipment and emergency procedures

Handle in accordance with good industrial hygiene and safety practice.

Avoid all sources of ignition: heat, sparks, open flame. Use antistatic tools.

6.2. Environmental precautions

Discharge into the environment must be avoided.

6.3. Methods and material for containment and cleaning up

Pick up with suitable appliance and dispose of. Spills should be contained, solidified, and placed in
suitable containers for disposal. Dispose of absorbed material in accordance with regulations.

6.4. Reference to other sections

Information regarding exposure controls/personal protection and disposal considerations can be
found in section 8 and 13.

SECTION 7: Handling and Storage

7.1. Precautions for safe handling
Handle in accordance with good industrial hygiene and safety practice.

Protection against fire and explosion:

Avoid all sources of ignition: heat, sparks, open flame. Ground all transfer equipment properly to
prevent electrostatic discharge.

7.2. Conditions for safe storage, including any incompatibilities

Suitable materials for containers: Stainless steel 1.4301 (V2), Stainless steel 1.4361, Stainless steel
1.4401, Stainless steel 1.4439, Stainless steel 1.4539, Stainless steel 1.4541, Stainless steel
1.4571, Stainless steel 1.4306 (V2A), Stainless steel 1.4307, Stainless steel 1.4311, Stainless steel
1.4404, glass

Storage stability:
May be kept indefinitely if stored properly.

7.3. Specific end use(s)

See exposure scenario(s) in the attachment to this safety data sheet.
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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

SECTION 8: Exposure Controls/Personal Protection

8.1. Control parameters

Components with occupational exposure limits

Observe the appropriate occupational exposure limit.

100-41-4: ethylbenzene (Content (W/W): 100 %)

Skin Designation (WEL/EH 40 (UK))
The substance can be absorbed through the skin.
TWA value 441 mg/m3 ; 100 ppm (WEL/EH 40 (UK))
Skin Designation (OEL (EU))
The substance can be absorbed through the skin.
STEL value 884 mg/m3 ; 200 ppm (OEL (EU))
indicative
TWA value 442 mg/m3 ; 100 ppm (OEL (EU))
indicative
STEL value 552 mg/m3 ; 125 ppm (WEL/EH 40 (UK))
Ceiling limit value/factor: 15 min

PNEC
freshwater: 0.1 mg/l

marine water: 0.01 mg/l

intermittent release: 0.1 mg/l

sediment (freshwater): 13.7 mg/kg

soil: 2.68 mg/kg

STP: 9.6 mg/l

oral (secondary poisoning): 0.02 mg/kg

DNEL
worker:
Short-term exposure - local effects, Inhalation: 293 mg/m3

worker:
Long-term exposure- systemic effects, Inhalation: 77 mg/m3, 17.73 ppm

worker:
Long-term exposure- systemic effects, dermal: 180 mg/kg

consumer:
Long-term exposure- systemic effects, Inhalation: 15 mg/m3

consumer:
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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Long-term exposure- systemic effects, oral: 1.6 mg/kg

8.2. Exposure controls

Personal protective equipment

Respiratory protection:
Gas filter for gases/vapours of organic compounds (boiling point >65 °C, e. g. EN 14387 Type A)

Hand protection:
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN ISO 374-1):
fluoroelastomer (FKM) - 0.7 mm coating thickness
Manufacturer's directions for use should be observed because of great diversity of types.

Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)

Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case
of dust)., Low flammability, oil resistant protective clothing (e.g. in accordance with EN 465),
protection boots (f.e. according to EN 20346), antistatic

General safety and hygiene measures

Avoid contact with the skin, eyes and clothing. Avoid inhalation of vapour. Keep away from food,
drink and animal feeding stuffs. At the end of the shift the skin should be cleaned and skin-care
agents applied.

Environmental exposure controls

All appropriate measures must be taken to prevent the release of this product to the environment
and to limit the dispersion of any release when it occurs. Suitable risk management measures should
be in place.

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Form: liquid
Colour: colourless, clear
Odour: aromatic
Odour threshold:
not determined
pH value:
not applicable
Melting point: -94.9 °C
(1,013 hPa)
Literature data.
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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Boiling point: 136.1 °C (measured)

(1,013.3 hPa)
Flash point: 23 °C (Directive 92/69/EEC, A.9,
closed cup)
Flammability: Highly flammable. (derived from flash - and boiling
point)
Lower explosion limit:
For liquids not relevant for
classification and labelling., The
lower explosion point may be 5 - 15
°C below the flash point.
Upper explosion limit:
For liquids not relevant for
classification and labelling.
Ignition temperature: 430 °C
Literature data.
Vapour pressure: 9.52 hPa (OECD Guideline 104)
(20 °C)
dynamic
Density: 0.86 - 0.87 g/cm3
(20 °C)
Literature data.
Relative density: 0.86 - 0.87
(20 °C)
Literature data.
Relative vapour density (air):3.66 (calculated)
(20 °C)
Heavier than air.
Solubility in water: (Directive 84/449/EEC, A.6)
0.2 g/l
(25 °C)
Partitioning coefficient n-octanol/water (log Kow): 3.6 (Directive 92/69/EEC, A.8)
(20 °C; pH value: 7.8)
Self ignition: Based on its structural properties the Test type: Spontaneous self-
product is not classified as self- ignition at room-temperature.
igniting.

Viscosity, dynamic: 0.671 mPa.s (OECD 114)

(20 °C)
The value was determined by
calculation from the detected
kinematic viscosity.
Viscosity, kinematic: 0.773 mm2/s (OECD 114)
(20 °C)
0.641 mm2/s (OECD 114)
(40 °C)
Explosion hazard: Based on the chemical structure
there is no indication of explosive
properties.
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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Fire promoting properties: Based on its structural properties

the product is not classified as
oxidizing.

9.2. Other information

Self heating ability: not applicable, the product is a liquid

pKA:
The substance does not dissociate.
Adsorption/water - soil: KOC: 518; log KOC: 2.71 (calculated)
Surface tension: 71.2 mN/m (Directive 92/69/EEC, A.5)
(23 °C; 0.0582 g/l)
Grain size distribution: The substance / product is marketed or used in a non solid or
granular form.
Molar mass: 106.17 g/mol

SECTION 10: Stability and Reactivity

10.1. Reactivity
When heated can give off ignitable vapours.

Corrosion to metals: Corrosive effects to metal are not anticipated.

Formation of Remarks: Forms no flammable gases in the
flammable gases: presence of water.

10.2. Chemical stability

The product is stable if stored and handled as prescribed/indicated.

10.3. Possibility of hazardous reactions

No hazardous reactions if stored and handled as prescribed/indicated.

10.4. Conditions to avoid

Avoid all sources of ignition: heat, sparks, open flame.

10.5. Incompatible materials

Substances to avoid:
inorganic acids, Friedel-Crafts catalysts

10.6. Hazardous decomposition products

No hazardous decomposition products if stored and handled as prescribed/indicated.

SECTION 11: Toxicological Information

11.1. Information on toxicological effects
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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Acute toxicity

Assessment of acute toxicity:

Of moderate toxicity after short-term inhalation. Virtually nontoxic after a single skin contact. Of low
toxicity after single ingestion.

Experimental/calculated data:
LD50 rat (oral): 3,500 mg/kg
Literature data.

LC50 rat (by inhalation): 17.2 mg/l 4 h

Literature data. The vapour was tested.

LD50 rabbit (dermal): 15,354 mg/kg

Literature data.

Irritation

Assessment of irritating effects:

May cause slight irritation to the skin. May cause slight irritation to the eyes.

Experimental/calculated data:
Skin corrosion/irritation
rabbit: non-irritant
Literature data.

Serious eye damage/irritation

rabbit: Irritant.

Respiratory/Skin sensitization

Assessment of sensitization:
The substance did not cause skin sensitization in humans.

Experimental/calculated data:
Patch-Test human: Non-sensitizing. (Human patch test)
Literature data.

Germ cell mutagenicity

Assessment of mutagenicity:
Most of the results from the available studies show no evidence of a mutagenic effect.

Carcinogenicity

Assessment of carcinogenicity:
Indication of possible carcinogenic effect in animal tests. The effect is caused by an animal specific
mechanism that has no human counter part. A clear indication of an increased risk of cancer in
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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

humans has so far not been shown. IARC (International Agency for Research on Cancer) has
classified this substance as group 2B (The agent is possibly carcinogenic to humans).

Reproductive toxicity

Assessment of reproduction toxicity:

The results of animal studies gave no indication of a fertility impairing effect. Repeated oral uptake of
the substance did not cause damage to the reproductive organs.

Developmental toxicity

Assessment of teratogenicity:
No indications of a developmental toxic / teratogenic effect were seen in animal studies.

Specific target organ toxicity (single exposure)

Assessment of STOT single:

Causes temporary irritation of the respiratory tract.

Repeated dose toxicity and Specific target organ toxicity (repeated exposure)

Assessment of repeated dose toxicity:

The substance may cause damage to the liver after repeated ingestion of high doses, as shown in
animal studies. The substance may cause deafness after repeated inhalation. The substance may
cause deafness after repeated ingestion.

Aspiration hazard

May also damage the lung at swallowing (aspiration hazard).

SECTION 12: Ecological Information

12.1. Toxicity

Assessment of aquatic toxicity:

Acutely toxic for aquatic organisms. Depending on local conditions and existing concentrations,
disturbances in the biodegradation process of activated sludge are possible.

Toxicity to fish:
LC50 (96 h) 4.2 mg/l, Oncorhynchus mykiss (OECD Guideline 203, semistatic)
Literature data.

Aquatic invertebrates:
EC50 (48 h) 1.8 - 2.4 mg/l, Daphnia magna (Daphnia test acute, static)
Literature data.

Aquatic plants:
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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

EC50 (72 h) 5.4 mg/l (growth rate), Selenastrum capricornutum (Algal growth inhibition test, static)
The statement of the toxic effect relates to the analytically determined concentration.

No observed effect concentration (96 h) 3.4 mg/l (growth rate), Selenastrum capricornutum (OECD
Guideline 201, static)
The statement of the toxic effect relates to the analytically determined concentration.

Microorganisms/Effect on activated sludge:

EC50 (24 h) 96 mg/l, Nitrosomonas sp. (Inhibition of nitrification, aquatic)
Literature data.

Chronic toxicity to fish:

Study scientifically not justified.

Chronic toxicity to aquatic invertebrates:

No observed effect concentration (7 d) 1 mg/l, Ceriodaphnia dubia (semistatic)
Literature data.

Assessment of terrestrial toxicity:

Toxic effects have been observed in studies with soil living organisms.

Soil living organisms:

LC50 (48 h) 0,047 mg/cm2, Eisenia foetida (OECD Guideline 207, filter paper)
Literature data.

Terrestrial plants:
No data available.

Other terrestrial non-mammals:

No data available.

12.2. Persistence and degradability

Assessment biodegradation and elimination (H2O):

Readily biodegradable (according to OECD criteria).

Elimination information:
70 - 80 % TIC of the ThIC (28 d) (ISO 14593) (aerobic, activated sludge) Readily biodegradable
(according to OECD criteria).

Assessment of stability in water:

According to structural properties, hydrolysis is not expected/probable.
Study scientifically not justified.
12.3. Bioaccumulative potential

Assessment bioaccumulation potential:

Does not significantly accumulate in organisms.

Bioaccumulation potential:
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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Bioconcentration factor (BCF): 1 (42 d), Oncorhynchus kisutch (other)

Literature data.

12.4. Mobility in soil

Assessment transport between environmental compartments:

Volatility: The substance will rapidly evaporate into the atmosphere from the water surface.
Adsorption in soil: Adsorption to solid soil phase is not expected.

12.5. Results of PBT and vPvB assessment

According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH): The product does not fulfill the criteria for PBT
(Persistent/bioaccumulative/toxic) and vPvB (very persistent/very bioaccumulative). Self
classification

12.6. Other adverse effects

The substance is not listed in Regulation (EC) 1005/2009 on substances that deplete the ozone
layer.

SECTION 13: Disposal Considerations

13.1. Waste treatment methods

Dispose of in accordance with national, state and local regulations.

The UK Environmental Protection (Duty of Care) Regulations (EP) and amendments should be noted
(United Kingdom).
This product and any uncleaned containers must be disposed of as hazardous waste in accordance
with the 2005 Hazardous Waste Regulations and amendments (United Kingdom)

Contaminated packaging:
Disposal must be made according to official regulations.

SECTION 14: Transport Information

Land transport

ADR
UN number or ID number: UN1175
UN proper shipping name: ETHYLBENZENE
Transport hazard class(es): 3
Packing group: II
Environmental hazards: no
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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Special precautions for Tunnel code: D/E

user:

RID
UN number or ID number: UN1175
UN proper shipping name: ETHYLBENZENE
Transport hazard class(es): 3
Packing group: II
Environmental hazards: no
Special precautions for None known
user:

Inland waterway transport

ADN
UN number or ID number: UN1175
UN proper shipping name: ETHYLBENZENE
Transport hazard class(es): 3
Packing group: II
Environmental hazards: no
Special precautions for None known
user:

Transport in inland waterway vessel

UN number or ID number: UN1175
UN proper shipping name: ETHYLBENZENE
Transport hazard class(es): 3, N3
Packing group: II
Environmental hazards: yes
Type of inland waterway N
vessel:
Cargo tank design: 2
Cargo tank type: 2

Sea transport

IMDG
UN number or ID number: UN 1175
UN proper shipping name: ETHYLBENZENE
Transport hazard class(es): 3
Packing group: II
Environmental hazards: no
Marine pollutant: NO
Special precautions for
user:
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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Air transport

IATA/ICAO
UN number or ID number: UN 1175
UN proper shipping name: ETHYLBENZENE
Transport hazard class(es): 3
Packing group: II
Environmental hazards: No Mark as dangerous for the environment is needed
Special precautions for None known
user:

14.1. UN number or ID number

See corresponding entries for “UN number or ID number” for the respective regulations in the tables
above.

14.2. UN proper shipping name

See corresponding entries for “UN proper shipping name” for the respective regulations in the tables
above.

14.3. Transport hazard class(es)

See corresponding entries for “Transport hazard class(es)” for the respective regulations in the
tables above.

14.4. Packing group

See corresponding entries for “Packing group” for the respective regulations in the tables above.

14.5. Environmental hazards

See corresponding entries for “Environmental hazards” for the respective regulations in the tables
above.

14.6. Special precautions for user

See corresponding entries for “Special precautions for user” for the respective regulations in the
tables above.

14.7. Maritime transport in bulk according to IMO instruments

Regulation: IBC-Code

Product name: Ethylbenzene

Pollution category: Y
Ship Type: 2
 Page: 17/51
BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Further information
This product is subject to the most recent edition of "The Carriage of Dangerous Goods and Use of
Transportable Pressure Equipment Regulations" and their amendments (United Kingdom).

SECTION 15: Regulatory Information

15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture

Directive 2012/18/EU - Control of Major Accident Hazards involving dangerous substances (EU):
List entry in regulation: P5b

If other regulatory information applies that is not already provided elsewhere in this safety data
sheet, then it is described in this subsection.

The data should be considered when making any assessment under the Control of Substances
Hazardous to Health Regulations (COSHH), and related guidance, for example, 'COSHH Essentials'
(United Kingdom).
This product may be subject to the Control of Major Accident Hazards Regulations (COMAH), and
amendments if specific threshold tonnages are exceeded (United Kingdom).

SECTION 16: Other Information

Assessment of the hazard classes according to UN GHS criteria (most recent version)

Aquatic Acute 2
Flam. Liq. 2
Acute Tox. 4 (Inhalation - vapour)
Acute Tox. 5 (oral)
STOT RE (Auditory organ) 2
Asp. Tox. 1
Aquatic Chronic 3

Full text of the classifications, including the hazard classes and the hazard statements, if mentioned
in section 2 or 3:
Asp. Tox. Aspiration hazard
Flam. Liq. Flammable liquids
Acute Tox. Acute toxicity
STOT RE Specific target organ toxicity — repeated exposure
Aquatic Chronic Hazardous to the aquatic environment - chronic
Skin Corr./Irrit. Skin corrosion/irritation
Repr. Reproductive toxicity
STOT SE Specific target organ toxicity — single exposure
Eye Dam./Irrit. Serious eye damage/eye irritation
Muta. Germ cell mutagenicity
Carc. Carcinogenicity
H225 Highly flammable liquid and vapour.
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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

H332 Harmful if inhaled.

H304 May be fatal if swallowed and enters airways.
H373 May cause damage to organs (Auditory organ) through prolonged or
repeated exposure.
H412 Harmful to aquatic life with long lasting effects.
H315 Causes skin irritation.
H336 May cause drowsiness or dizziness.
H361d Suspected of damaging the unborn child.
H319 Causes serious eye irritation.
H350 May cause cancer.
H340 May cause genetic defects.
H372 Causes damage to organs (Blood) through prolonged or repeated
exposure.

Abbreviations
ADR = The European Agreement concerning the International Carriage of Dangerous Goods by Road.
ADN = The European Agreement concerning the International Carriage of Dangerous Goods by Inland
waterways. ATE = Acute Toxicity Estimates. CAO = Cargo Aircraft Only. CAS = Chemical Abstract
Service. CLP = Classification, Labelling and Packaging of substances and mixtures. DIN = German
national organization for standardization. DNEL = Derived No Effect Level. EC50 = Effective
concentration median for 50% of the population. EC = European Community. EN = European Standards.
IARC = International Agency for Research on Cancer. IATA = International Air Transport Association.
IBC-Code = Intermediate Bulk Container code. IMDG = International Maritime Dangerous Goods Code.
ISO = International Organization for Standardization. STEL = Short-Term Exposure Limit. LC50 = Lethal
concentration median for 50% of the population. LD50 = Lethal dose median for 50% of the population.
TLV = Threshold Limit Value. MARPOL = The International Convention for the Prevention of Pollution
from Ships. NEN = Dutch Norm. NOEC = No Observed Effect Concentration. OEL = Occupational
Exposure Limit. OECD = Organization for Economic Cooperation and Development. PBT = Persistent,
Bioaccumulative and Toxic. PNEC = Predicted No Effect Level. PPM = Parts per million. RID = The
European Agreement concerning the International Carriage of Dangerous Goods by Rail. TWA = Time
Weight Average. UN-number = UN number at transport. vPvB = very Persistent and very
Bioaccumulative.

The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. This safety data sheet is neither a
Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification
agreement. Identified uses in this safety data sheet do neither represent an agreement on the
corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the
responsibility of the recipient of the product to ensure any proprietary rights and existing laws and
legislation are observed.

Vertical lines in the left hand margin indicate an amendment from the previous version.
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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Annex: Exposure Scenarios

Index
1. Manufacture of substance
IS; ERC1; PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC15

2. Formulation
IS; ERC2; PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC9, PROC15

3. Use as an intermediate
IS; ERC6a; PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC15

4. Use as solvent
IS; ERC4; PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC15

****************

1. Short title of exposure scenario

Manufacture of substance
IS; ERC1; PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC15

Control of exposure and risk management measures

Contributing exposure scenario
ESVOC SpERC 1.1.v1: ESVOC SpERC 1.1.v1
Use descriptors covered
Operational conditions
1,220 kt
Annual amount per site
Minimum emission days per year 350

0.1 %
Emission factor air
0.002 %
Emission factor water
0.01 %
Emission factor soil
18,000 m3/d
Receive Surf. Water (Flow Rate).
10
Dilution factor river
100
Dilution factor coast
Risk Management Measures
Air treatment measures considered suitable are, e.g. Adsorption
Acclimated biological
Wastewater treatment measures considered suitable are, e.g.
treatment
Soil treatment measures considered suitable are, e.g. No application of sludge to soil
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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Type of STP Municipal STP

Assumed sewage treatment plant flow (m3/d) 2,000 m3/d
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Environment
Risk Characterization Ratio (RCR) 0.234104
Risk from environmental exposure is driven by freshwater.
1,489
Maximum amount of safe use t/d

Risk from environmental exposure is driven by freshwater.

Contributing exposure scenario

PROC1: Chemical production or refinery in closed process
without likelihood of exposure or processes with equivalent
Use descriptors covered containment conditions.
Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 10000 Pa
during use
70 °C
Process temperature
Corresponds to a vapour pressure > 5.0 hPa ≤ 100.0 hPa.
480 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Ensure doors and windows are
opened (general ventilation).
In case of potential exposure:, Use
suitable chemically resistant gloves.,
Use suitable eye protection.
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - dermal, long-term - systemic
Exposure estimate 0.0343 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.00019
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - inhalation, long-term - systemic
Exposure estimate 0.0442 mg/m³
Risk Characterization Ratio (RCR) 0.000574
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra

Contributing exposure scenario

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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

PROC2: Chemical production or refinery in closed

continuous process with occasional controlled exposure or
Use descriptors covered processes with equivalent containment conditions
Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 10001 Pa
during use
70 °C
Process temperature
Corresponds to a vapour pressure > 100.0 hPa
60 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Provide extract ventilation to points
where emissions occur (LEV).
Reduce duration of activity to less
than 60 min, Alternatively:, Wear a
respirator conforming to EN140 with
Type A/P2 filter or better, In case of
potential exposure:, Use suitable
chemically resistant gloves., Use
suitable eye protection.
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - dermal, long-term - systemic
Exposure estimate 0.2743 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.001524
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - inhalation, long-term - systemic
Exposure estimate 22.1177 mg/m³
Risk Characterization Ratio (RCR) 0.287243
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra

Contributing exposure scenario

PROC3: Manufacture or formulation in the chemical
industry in closed batch processes with occasional
controlled exposure or processes with equivalent
Use descriptors covered
containment condition
Use domain: industrial

Operational conditions
Concentration of the substance ethylbenzene
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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 10001 Pa
during use
70 °C
Process temperature
Corresponds to a vapour pressure > 100.0 hPa
480 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Local exhaust ventilation Effectiveness: 90 %
Handle substance within closed
system. Provide extract ventilation to
points where emissions occur (LEV).
Ensure samples are obtained under
containment or extract ventilation.
In case of potential exposure:, Use
suitable chemically resistant gloves.,
Use suitable eye protection.
Exposure estimate and reference to its source
EASY TRA v4.1, ECETOC TRA v3.0, Worker, Reduction
Assessment method factor for local exhaust ventilation (LEV) has been used for
the calculation of dermal exposure estimates.
Worker - dermal, long-term - systemic
Exposure estimate 0.0686 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.000381
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - inhalation, long-term - systemic
Exposure estimate 22.1177 mg/m³
Risk Characterization Ratio (RCR) 0.287243
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra

Contributing exposure scenario

PROC4: Chemical production where opportunity for
exposure arises
Use descriptors covered
Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 10001 Pa
during use
70 °C
Process temperature
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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Corresponds to a vapour pressure > 100.0 hPa

480 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Local exhaust ventilation Effectiveness: 90 %
Provide extract ventilation to points
where emissions occur (LEV). Ensure
samples are obtained under
containment or extract ventilation.
Ensure material transfers are under
containment or extract ventilation
Use suitable chemically resistant
gloves., Use suitable eye protection.
Exposure estimate and reference to its source
EASY TRA v4.1, ECETOC TRA v3.0, Worker, Reduction
Assessment method factor for local exhaust ventilation (LEV) has been used for
the calculation of dermal exposure estimates.
Worker - dermal, long-term - systemic
Exposure estimate 0.6857 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.00381
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - inhalation, long-term - systemic
Exposure estimate 44.2354 mg/m³
Risk Characterization Ratio (RCR) 0.574486
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra

Contributing exposure scenario

PROC8a: Transfer of substance or mixture (charging and
discharging) at non-dedicated facilities
Use descriptors covered
Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 10001 Pa
during use
70 °C
Process temperature
Corresponds to a vapour pressure > 100.0 hPa
60 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Drain down and flush system prior to
equipment break-in or maintenance.
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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Transfer via enclosed lines Clear

transfer lines prior to de-coupling
Retain drain downs in sealed storage
pending disposal or for subsequent
recycle.
Use suitable chemically resistant
gloves., Use suitable eye protection.,
Reduce duration of activity to less
than 60 min, Alternatively:, Wear a
respirator conforming to EN140 with
Type A/P2 filter or better
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - dermal, long-term - systemic
Exposure estimate 2.7429 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.015238
EASY TRA v4.1, ECETOC TRA v3.0, worker, modified
Assessment method
version
Worker - inhalation, long-term - systemic
Exposure estimate 44.2354 mg/m³
Risk Characterization Ratio (RCR) 0.574486
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (see
exposure estimates)

Contributing exposure scenario

PROC8b: Transfer of substance or mixture (charging and
discharging) at dedicated facilities
Use descriptors covered
Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 952 Pa
during use
20 °C
Process temperature
480 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Local exhaust ventilation Effectiveness: 95 %
Provide basic employee training to
prevent/minimize exposures.
Provide extract ventilation to points
where emissions occur (LEV). Use
bulk or semi-bulk handling systems.
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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

In case of potential exposure:, Use

suitable chemically resistant gloves.,
Use suitable eye protection.
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - dermal, long-term - systemic
Exposure estimate 1.3714 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.007619
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - inhalation, long-term - systemic
Exposure estimate 5.5294 mg/m³
Risk Characterization Ratio (RCR) 0.071811
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra

Contributing exposure scenario

PROC8b: Transfer of substance or mixture (charging and
discharging) at dedicated facilities
Use descriptors covered
Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 952 Pa
during use
20 °C
Process temperature
60 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Use bulk or semi-bulk handling
systems.
Reduce duration of activity to less
than 60 min, Alternatively:, Wear a
respirator conforming to EN140 with
Type A/P2 filter or better, In case of
potential exposure:, Use suitable
chemically resistant gloves., Use
suitable eye protection.
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - dermal, long-term - systemic
Exposure estimate 2.7429 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.015238
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - inhalation, long-term - systemic
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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Exposure estimate 22.1177 mg/m³

Risk Characterization Ratio (RCR) 0.287243
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra

Contributing exposure scenario

PROC8b: Transfer of substance or mixture (charging and
discharging) at dedicated facilities
Use descriptors covered
Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 952 Pa
during use
20 °C
Process temperature
480 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Provide basic employee training to
prevent/minimize exposures.
Use bulk or semi-bulk handling
systems. Use dry break couplings for
material transfer Ensure material
transfers are under containment or
extract ventilation
In case of potential exposure:, Use
suitable chemically resistant gloves.,
Use suitable eye protection.
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - dermal, long-term - systemic
Exposure estimate 13.7143 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.07619
Assessment method EASY TRA v4.1, Workplace measurements
Worker - inhalation, long-term - systemic
Exposure estimate 36 mg/m³
Risk Characterization Ratio (RCR) 0.467532
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra

Contributing exposure scenario

PROC15: Use a laboratory reagent.
Use descriptors covered Use domain: industrial
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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 952 Pa
during use
20 °C
Process temperature
480 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Handle in a fume cupboard or under
extract ventilation
In case of potential exposure:, Use
suitable chemically resistant gloves.,
Use suitable eye protection.
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - dermal, long-term - systemic
Exposure estimate 0.3429 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.001905
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - inhalation, long-term - systemic
Exposure estimate 44.2354 mg/m³
Risk Characterization Ratio (RCR) 0.574486
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra

****************

2. Short title of exposure scenario

Formulation
IS; ERC2; PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC9, PROC15

Control of exposure and risk management measures

Contributing exposure scenario
ESVOC SpERC 2.2.v1: ESVOC SpERC 2.2.v1
Use descriptors covered
Operational conditions
840,000 kg
Annual amount used in the EU
Minimum emission days per year 300

1%
Emission factor air
Emission factor water 0.2 %
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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

0.01 %
Emission factor soil
18,000 m3/d
Receive Surf. Water (Flow Rate).
10
Dilution factor river
100
Dilution factor coast
Risk Management Measures
Wet scrubber - for dusts,
Filtration, Waste gas treatment
Air treatment measures considered suitable are, e.g.
by thermal oxidation,
Adsorption
Acclimated biological
Wastewater treatment measures considered suitable are, e.g.
treatment, Distillation
Type of STP Municipal STP
Assumed sewage treatment plant flow (m3/d) 2,000 m3/d
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Environment
Risk Characterization Ratio (RCR) 0.028473
Risk from environmental exposure is driven by soil.
9,833.8
Maximum amount of safe use kg/d

Risk from environmental exposure is driven by soil.

Contributing exposure scenario

PROC1: Chemical production or refinery in closed process
without likelihood of exposure or processes with equivalent
Use descriptors covered containment conditions.
Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 952 Pa
during use
20 °C
Process temperature
480 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Ensure doors and windows are
opened (general ventilation).
In case of potential exposure:, Use
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BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

suitable eye protection., Use suitable

chemically resistant gloves.
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - dermal, long-term - systemic
Exposure estimate 0.0343 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.00019
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - inhalation, long-term - systemic
Exposure estimate 0.0442 mg/m³
Risk Characterization Ratio (RCR) 0.000574
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra

Contributing exposure scenario

PROC2: Chemical production or refinery in closed
continuous process with occasional controlled exposure or
Use descriptors covered processes with equivalent containment conditions
Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 952 Pa
during use
20 °C
Process temperature
480 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Use dry break couplings for material
transfer
In case of potential exposure:, Use
suitable chemically resistant gloves.,
Use suitable eye protection.
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - dermal, long-term - systemic
Exposure estimate 1.3714 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.007619
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - inhalation, long-term - systemic
Exposure estimate 22.1177 mg/m³
Risk Characterization Ratio (RCR) 0.287243
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra
 Page: 30/51
BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Contributing exposure scenario

PROC3: Manufacture or formulation in the chemical
industry in closed batch processes with occasional
controlled exposure or processes with equivalent
Use descriptors covered
containment condition
Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 952 Pa
during use
20 °C
Process temperature
480 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Local exhaust ventilation Effectiveness: 90 %
Handle substance within closed
system. Provide extract ventilation to
points where emissions occur (LEV).
Ensure samples are obtained under
containment or extract ventilation.
In case of potential exposure:, Use
suitable chemically resistant gloves.,
Use suitable eye protection.
Exposure estimate and reference to its source
EASY TRA v4.1, ECETOC TRA v3.0, Worker, Reduction
Assessment method factor for local exhaust ventilation (LEV) has been used for
the calculation of dermal exposure estimates.
Worker - dermal, long-term - systemic
Exposure estimate 0.0686 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.000381
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - inhalation, long-term - systemic
Exposure estimate 4.4235 mg/m³
Risk Characterization Ratio (RCR) 0.057449
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra

Contributing exposure scenario

PROC4: Chemical production where opportunity for
exposure arises
Use descriptors covered
Use domain: industrial
 Page: 31/51
BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 952 Pa
during use
20 °C
Process temperature
480 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Local exhaust ventilation Effectiveness: 90 %
Handle substance within a
predominantly closed system provided
with extract ventilation. Provide
extract ventilation to points where
emissions occur (LEV). Ensure
samples are obtained under
containment or extract ventilation.
Use suitable chemically resistant
gloves., Use suitable eye protection.
Exposure estimate and reference to its source
EASY TRA v4.1, ECETOC TRA v3.0, Worker, Reduction
Assessment method factor for local exhaust ventilation (LEV) has been used for
the calculation of dermal exposure estimates.
Worker - dermal, long-term - systemic
Exposure estimate 0.6857 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.00381
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - inhalation, long-term - systemic
Exposure estimate 8.8471 mg/m³
Risk Characterization Ratio (RCR) 0.114897
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra

Contributing exposure scenario

PROC8a: Transfer of substance or mixture (charging and
discharging) at non-dedicated facilities
Use descriptors covered
Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 952 Pa
during use
 Page: 32/51
BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

20 °C
Process temperature
480 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Local exhaust ventilation Effectiveness: 90 %
Handle substance within closed
system. Ensure samples are obtained
under containment or extract
ventilation.
Use suitable chemically resistant
gloves., Use suitable eye protection.
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - dermal, long-term - systemic
Exposure estimate 0.1371 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.000762
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - inhalation, long-term - systemic
Exposure estimate 22.1177 mg/m³
Risk Characterization Ratio (RCR) 0.287243
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra

Contributing exposure scenario

PROC8a: Transfer of substance or mixture (charging and
discharging) at non-dedicated facilities
Use descriptors covered
Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 952 Pa
during use
20 °C
Process temperature
480 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Drain down and flush system prior to
equipment break-in or maintenance.
Transfer via enclosed lines Clear
transfer lines prior to de-coupling
Retain drain downs in sealed storage
pending disposal or for subsequent
 Page: 33/51
BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

recycle.
Use suitable chemically resistant
gloves., Use suitable eye protection.
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - dermal, long-term - systemic
Exposure estimate 13.7143 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.07619
EASY TRA v4.1, ECETOC TRA v3.0, worker, modified
Assessment method
version
Worker - inhalation, long-term - systemic
Exposure estimate 44.2354 mg/m³
Risk Characterization Ratio (RCR) 0.574486
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (see
exposure estimates)

Contributing exposure scenario

PROC8b: Transfer of substance or mixture (charging and
discharging) at dedicated facilities
Use descriptors covered
Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 952 Pa
during use
20 °C
Process temperature
480 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Provide basic employee training to
prevent/minimize exposures.
Provide extract ventilation to points
where emissions occur (LEV). Use
bulk or semi-bulk handling systems.
Use dry break couplings for material
transfer
In case of potential exposure:, Use
suitable chemically resistant gloves.,
Use suitable eye protection.
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - dermal, long-term - systemic
Exposure estimate 1.3714 mg/kg bw/day
 Page: 34/51
BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Risk Characterization Ratio (RCR) 0.007619

EASY TRA v4.1, ECETOC TRA v3.0, worker, modified
Assessment method
version
Worker - inhalation, long-term - systemic
Exposure estimate 11.0589 mg/m³
Risk Characterization Ratio (RCR) 0.143621
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (see
exposure estimates)

Contributing exposure scenario

PROC8b: Transfer of substance or mixture (charging and
discharging) at dedicated facilities
Use descriptors covered
Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 952 Pa
during use
20 °C
Process temperature
60 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Use bulk or semi-bulk handling
systems. Use dry break couplings for
material transfer
In case of potential exposure:, Use
suitable chemically resistant gloves.,
Use suitable eye protection., Reduce
duration of activity to less than 60 min,
Alternatively:, Wear a respirator
conforming to EN140 with Type A/P2
filter or better
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - dermal, long-term - systemic
Exposure estimate 2.7429 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.015238
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - inhalation, long-term - systemic
Exposure estimate 22.1177 mg/m³
Risk Characterization Ratio (RCR) 0.287243
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra
 Page: 35/51
BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Contributing exposure scenario

PROC9: Transfer of substance or preparation into small
containers (dedicated filling line, including weighing).
Use descriptors covered
Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 952 Pa
during use
20 °C
Process temperature
480 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Local exhaust ventilation Effectiveness: 90 %
Transfer via enclosed lines Ensure
that task is semi-automated or
automated. Provide extract ventilation
to material transfer points and other
openings.
In case of potential exposure:, Use
suitable chemically resistant gloves.,
Use suitable eye protection.
Exposure estimate and reference to its source
EASY TRA v4.1, ECETOC TRA v3.0, Worker, Reduction
Assessment method factor for local exhaust ventilation (LEV) has been used for
the calculation of dermal exposure estimates.
Worker - dermal, long-term - systemic
Exposure estimate 0.6857 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.00381
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - inhalation, long-term - systemic
Exposure estimate 22.1177 mg/m³
Risk Characterization Ratio (RCR) 0.287243
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra

Contributing exposure scenario

PROC15: Use a laboratory reagent.
Use descriptors covered Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance
Content: >= 0 % - <= 100 %
 Page: 36/51
BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Physical state liquid

Vapour pressure of the substance 952 Pa
during use
20 °C
Process temperature
480 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Handle in a fume cupboard or under
extract ventilation
In case of potential exposure:, Use
suitable chemically resistant gloves.,
Use suitable eye protection.
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - dermal, long-term - systemic
Exposure estimate 0.3429 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.001905
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - inhalation, long-term - systemic
Exposure estimate 44.2354 mg/m³
Risk Characterization Ratio (RCR) 0.574486
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra

****************

3. Short title of exposure scenario

Use as an intermediate
IS; ERC6a; PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC15

Control of exposure and risk management measures

Contributing exposure scenario
ESVOC SpERC 6.1a.v1: ESVOC SpERC 6.1a.v1
Use descriptors covered
Operational conditions
1,220 kt
Annual amount per site
Minimum emission days per year 350

0.02 %
Emission factor air
0.002 %
Emission factor water
0.1 %
Emission factor soil
 Page: 37/51
BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

18,000 m3/d
Receive Surf. Water (Flow Rate).
10
Dilution factor river
100
Dilution factor coast
Risk Management Measures
Wet scrubber - for dusts,
Air treatment measures considered suitable are, e.g.
Adsorption
Acclimated biological
Wastewater treatment measures considered suitable are, e.g.
treatment
Soil treatment measures considered suitable are, e.g. No application of sludge to soil
Type of STP Municipal STP
Assumed sewage treatment plant flow (m3/d) 2,000 m3/d
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Environment
Risk Characterization Ratio (RCR) 0.234104
Risk from environmental exposure is driven by freshwater.
1,489
Maximum amount of safe use t/d

Risk from environmental exposure is driven by freshwater.

Contributing exposure scenario

PROC1: Chemical production or refinery in closed process
without likelihood of exposure or processes with equivalent
Use descriptors covered containment conditions.
Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 10001 Pa
during use
70 °C
Process temperature
Corresponds to a vapour pressure > 100.0 hPa
480 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Ensure doors and windows are
opened (general ventilation).
Handle substance within closed
system.
In case of potential exposure:, Use
suitable chemically resistant gloves.,
 Page: 38/51
BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Use suitable eye protection.

Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - dermal, long-term - systemic
Exposure estimate 0.0343 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.00019
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - inhalation, long-term - systemic
Exposure estimate 0.0442 mg/m³
Risk Characterization Ratio (RCR) 0.000574
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra

Contributing exposure scenario

PROC2: Chemical production or refinery in closed
continuous process with occasional controlled exposure or
Use descriptors covered processes with equivalent containment conditions
Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 10001 Pa
during use
70 °C
Process temperature
Corresponds to a vapour pressure > 100.0 hPa
60 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Handle substance within closed
system. Provide extract ventilation to
points where emissions occur (LEV).
Ensure samples are obtained under
containment or extract ventilation.
Reduce duration of activity to less
than 60 min, Alternatively:, Wear a
respirator conforming to EN140 with
Type A/P2 filter or better, In case of
potential exposure:, Use suitable
chemically resistant gloves., Use
suitable eye protection.
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - dermal, long-term - systemic
Exposure estimate 0.2743 mg/kg bw/day
 Page: 39/51
BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Risk Characterization Ratio (RCR) 0.001524

Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - inhalation, long-term - systemic
Exposure estimate 22.1177 mg/m³
Risk Characterization Ratio (RCR) 0.287243
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra

Contributing exposure scenario

PROC3: Manufacture or formulation in the chemical
industry in closed batch processes with occasional
controlled exposure or processes with equivalent
Use descriptors covered
containment condition
Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 10001 Pa
during use
70 °C
Process temperature
Corresponds to a vapour pressure > 100.0 hPa
480 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Local exhaust ventilation Effectiveness: 90 %
Handle substance within closed
system. Provide extract ventilation to
points where emissions occur (LEV).
Ensure samples are obtained under
containment or extract ventilation.
In case of potential exposure:, Use
suitable chemically resistant gloves.,
Use suitable eye protection.
Exposure estimate and reference to its source
EASY TRA v4.1, ECETOC TRA v3.0, Worker, Reduction
Assessment method factor for local exhaust ventilation (LEV) has been used for
the calculation of dermal exposure estimates.
Worker - dermal, long-term - systemic
Exposure estimate 0.0686 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.000381
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - inhalation, long-term - systemic
Exposure estimate 22.1177 mg/m³
Risk Characterization Ratio (RCR) 0.287243
 Page: 40/51
BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Guidance to Downstream Users

For scaling see: http://www.ecetoc.org/tra

Contributing exposure scenario

PROC4: Chemical production where opportunity for
exposure arises
Use descriptors covered
Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 10001 Pa
during use
70 °C
Process temperature
Corresponds to a vapour pressure > 100.0 hPa
480 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Local exhaust ventilation Effectiveness: 90 %
Provide extract ventilation to points
where emissions occur (LEV). Ensure
samples are obtained under
containment or extract ventilation.
Ensure material transfers are under
containment or extract ventilation
Use suitable chemically resistant
gloves., Use suitable eye protection.
Exposure estimate and reference to its source
EASY TRA v4.1, ECETOC TRA v3.0, Worker, Reduction
Assessment method factor for local exhaust ventilation (LEV) has been used for
the calculation of dermal exposure estimates.
Worker - dermal, long-term - systemic
Exposure estimate 0.6857 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.00381
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - inhalation, long-term - systemic
Exposure estimate 44.2354 mg/m³
Risk Characterization Ratio (RCR) 0.574486
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra

Contributing exposure scenario

PROC8a: Transfer of substance or mixture (charging and
Use descriptors covered discharging) at non-dedicated facilities
Use domain: industrial
 Page: 41/51
BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 10001 Pa
during use
70 °C
Process temperature
Corresponds to a vapour pressure > 100.0 hPa
60 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Drain down and flush system prior to
equipment break-in or maintenance.
Transfer via enclosed lines Clear
transfer lines prior to de-coupling
Retain drain downs in sealed storage
pending disposal or for subsequent
recycle.
Use suitable chemically resistant
gloves., Use suitable eye protection.,
Reduce duration of activity to less
than 60 min, Alternatively:, Wear a
respirator conforming to EN140 with
Type A/P2 filter or better
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - dermal, long-term - systemic
Exposure estimate 2.7429 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.015238
EASY TRA v4.1, ECETOC TRA v3.0, worker, modified
Assessment method
version
Worker - inhalation, long-term - systemic
Exposure estimate 44.2354 mg/m³
Risk Characterization Ratio (RCR) 0.574486
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (see
exposure estimates)

Contributing exposure scenario

PROC8b: Transfer of substance or mixture (charging and
discharging) at dedicated facilities
Use descriptors covered
Use domain: industrial

Operational conditions
Concentration of the substance ethylbenzene
 Page: 42/51
BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 952 Pa
during use
20 °C
Process temperature
60 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Use bulk or semi-bulk handling
systems. Use dry break couplings for
material transfer
Reduce duration of activity to less
than 60 min, Alternatively:, Wear a
respirator conforming to EN140 with
Type A/P2 filter or better, In case of
potential exposure:, Use suitable
chemically resistant gloves., Use
suitable eye protection.
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - dermal, long-term - systemic
Exposure estimate 2.7429 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.015238
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - inhalation, long-term - systemic
Exposure estimate 22.1177 mg/m³
Risk Characterization Ratio (RCR) 0.287243
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra

Contributing exposure scenario

PROC8b: Transfer of substance or mixture (charging and
discharging) at dedicated facilities
Use descriptors covered
Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 952 Pa
during use
20 °C
Process temperature
480 min 5 days per week
Duration and Frequency of activity
 Page: 43/51
BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Indoor/Outdoor Indoor
Risk Management Measures
Provide basic employee training to
prevent/minimize exposures.
Ensure material transfers are under
containment or extract ventilation Use
dry break couplings for material
transfer
In case of potential exposure:, Use
suitable chemically resistant gloves.,
Use suitable eye protection.
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - dermal, long-term - systemic
Exposure estimate 13.7143 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.07619
Assessment method EASY TRA v4.1, Workplace measurements
Worker - inhalation, long-term - systemic
Exposure estimate 36 mg/m³
Risk Characterization Ratio (RCR) 0.467532
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra

Contributing exposure scenario

PROC8b: Transfer of substance or mixture (charging and
discharging) at dedicated facilities
Use descriptors covered
Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 10001 Pa
during use
70 °C
Process temperature
Corresponds to a vapour pressure > 100.0 hPa
480 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Wear suitable respiratory protection. Effectiveness: 90 %
Transfer via enclosed lines Provide
extract ventilation to points where
emissions occur (LEV). Clear transfer
lines prior to de-coupling Ensure
material transfers are under
containment or extract ventilation
 Page: 44/51
BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

In case of potential exposure:, Use

suitable chemically resistant gloves.,
Use suitable eye protection.
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - dermal, long-term - systemic
Exposure estimate 13.7143 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.07619
EASY TRA v4.1, ECETOC TRA v3.0, worker, modified
Assessment method
version
Worker - inhalation, long-term - systemic
Exposure estimate 13.2706 mg/m³
Risk Characterization Ratio (RCR) 0.172346
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (see
exposure estimates)

Contributing exposure scenario

PROC15: Use a laboratory reagent.
Use descriptors covered Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 952 Pa
during use
20 °C
Process temperature
480 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Provide extract ventilation to points
where emissions occur (LEV). Carry
out in a vented booth.
Alternatively:, In case of potential
exposure:, Use suitable chemically
resistant gloves., Use suitable eye
protection.
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - dermal, long-term - systemic
Exposure estimate 0.3429 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.001905
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - inhalation, long-term - systemic
Exposure estimate 44.2354 mg/m³
 Page: 45/51
BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Risk Characterization Ratio (RCR) 0.574486

Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra

****************

4. Short title of exposure scenario

Use as solvent
IS; ERC4; PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC15

Control of exposure and risk management measures

Contributing exposure scenario
ESVOC SpERC 4.3a.v1: ESVOC SpERC 4.3a.v1
Use descriptors covered
Operational conditions
840,000 kg
Annual amount used in the EU
Minimum emission days per year 300

98 %
Emission factor air
0.7 %
Emission factor water
0%
Emission factor soil
18,000 m3/d
Receive Surf. Water (Flow Rate).
10
Dilution factor river
100
Dilution factor coast
Risk Management Measures
Wet scrubber - for dusts,
Filtration, Waste gas treatment
Air treatment measures considered suitable are, e.g.
by thermal oxidation,
Adsorption
Acclimated biological
Wastewater treatment measures considered suitable are, e.g.
treatment, Distillation
Type of STP Municipal STP
Assumed sewage treatment plant flow (m3/d) 2,000 m3/d
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Environment
Risk Characterization Ratio (RCR) 0.102015
Risk from environmental exposure is driven by soil.
2,744.7
Maximum amount of safe use kg/d

Risk from environmental exposure is driven by soil.

 Page: 46/51
BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Contributing exposure scenario

PROC1: Chemical production or refinery in closed process
without likelihood of exposure or processes with equivalent
Use descriptors covered containment conditions.
Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 10001 Pa
during use
70 °C
Process temperature
Corresponds to a vapour pressure > 100.0 hPa
480 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Ensure doors and windows are
opened (general ventilation).
Handle substance within closed
system.
In case of potential exposure:, Use
suitable chemically resistant gloves.,
Use suitable eye protection.
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - dermal, long-term - systemic
Exposure estimate 0.0343 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.00019
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - inhalation, long-term - systemic
Exposure estimate 0.0442 mg/m³
Risk Characterization Ratio (RCR) 0.000574
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra

Contributing exposure scenario

PROC2: Chemical production or refinery in closed
continuous process with occasional controlled exposure or
Use descriptors covered processes with equivalent containment conditions
Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance
Content: >= 0 % - <= 100 %
 Page: 47/51
BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

Physical state liquid

Vapour pressure of the substance 10001 Pa
during use
70 °C
Process temperature
Corresponds to a vapour pressure > 100.0 hPa
60 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Ensure doors and windows are
opened (general ventilation).
Reduce duration of activity to less
than 60 min, Alternatively:, Wear a
respirator conforming to EN140 with
Type A/P2 filter or better, In case of
potential exposure:, Use suitable
chemically resistant gloves., Use
suitable eye protection.
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - dermal, long-term - systemic
Exposure estimate 0.2743 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.001524
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - inhalation, long-term - systemic
Exposure estimate 22.1177 mg/m³
Risk Characterization Ratio (RCR) 0.287243
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra

Contributing exposure scenario

PROC3: Manufacture or formulation in the chemical
industry in closed batch processes with occasional
controlled exposure or processes with equivalent
Use descriptors covered
containment condition
Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 10001 Pa
during use
70 °C
Process temperature
Corresponds to a vapour pressure > 100.0 hPa
 Page: 48/51
BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

480 min 5 days per week

Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Local exhaust ventilation Effectiveness: 90 %
Handle substance within closed
system. Ensure samples are obtained
under containment or extract
ventilation.
In case of potential exposure:, Use
suitable chemically resistant gloves.,
Use suitable eye protection.
Exposure estimate and reference to its source
EASY TRA v4.1, ECETOC TRA v3.0, Worker, Reduction
Assessment method factor for local exhaust ventilation (LEV) has been used for
the calculation of dermal exposure estimates.
Worker - dermal, long-term - systemic
Exposure estimate 0.0686 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.000381
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - inhalation, long-term - systemic
Exposure estimate 22.1177 mg/m³
Risk Characterization Ratio (RCR) 0.287243
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra

Contributing exposure scenario

PROC4: Chemical production where opportunity for
exposure arises
Use descriptors covered
Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 10001 Pa
during use
70 °C
Process temperature
Corresponds to a vapour pressure > 100.0 hPa
480 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Local exhaust ventilation Effectiveness: 90 %
Provide extract ventilation to points
where emissions occur (LEV). Ensure
samples are obtained under
 Page: 49/51
BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

containment or extract ventilation.

Ensure material transfers are under
containment or extract ventilation
Use suitable chemically resistant
gloves., Use suitable eye protection.
Exposure estimate and reference to its source
EASY TRA v4.1, ECETOC TRA v3.0, Worker, Reduction
Assessment method factor for local exhaust ventilation (LEV) has been used for
the calculation of dermal exposure estimates.
Worker - dermal, long-term - systemic
Exposure estimate 0.6857 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.00381
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - inhalation, long-term - systemic
Exposure estimate 44.2354 mg/m³
Risk Characterization Ratio (RCR) 0.574486
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra

Contributing exposure scenario

PROC8a: Transfer of substance or mixture (charging and
discharging) at non-dedicated facilities
Use descriptors covered
Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 10001 Pa
during use
70 °C
Process temperature
Corresponds to a vapour pressure > 100.0 hPa
60 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Drain down and flush system prior to
equipment break-in or maintenance.
Transfer via enclosed lines Clear
transfer lines prior to de-coupling
Retain drain downs in sealed storage
pending disposal or for subsequent
recycle.
Use suitable chemically resistant
gloves., Use suitable eye protection.,
Reduce duration of activity to less
than 60 min, Alternatively:, Wear a
 Page: 50/51
BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

respirator conforming to EN140 with

Type A/P2 filter or better
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - dermal, long-term - systemic
Exposure estimate 2.7429 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.015238
EASY TRA v4.1, ECETOC TRA v3.0, worker, modified
Assessment method
version
Worker - inhalation, long-term - systemic
Exposure estimate 44.2354 mg/m³
Risk Characterization Ratio (RCR) 0.574486
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (see
exposure estimates)

Contributing exposure scenario

PROC8b: Transfer of substance or mixture (charging and
discharging) at dedicated facilities
Use descriptors covered
Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 10001 Pa
during use
70 °C
Process temperature
Corresponds to a vapour pressure > 100.0 hPa
480 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Drain down and flush system prior to
equipment break-in or maintenance.
Transfer via enclosed lines Clear
transfer lines prior to de-coupling
Provide extract ventilation to material
transfer points and other openings.
In case of potential exposure:, Use
suitable chemically resistant gloves.,
Use suitable eye protection.
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - dermal, long-term - systemic
Exposure estimate 1.3714 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.007619
 Page: 51/51
BASF Safety data sheet according to Regulation UK SI 2019/758 and UK SI 2020/1577 as amended from
time to time.
Date / Revised: 28.08.2023 Version: 4.0
Date previous version: 18.12.2022 Previous version: 3.0
Date / First version: 25.08.2005
Product: ETHYLBENZENE
(ID no. 30054550/SDS_GEN_GB/EN)
Date of print 20.03.2025

EASY TRA v4.1, ECETOC TRA v3.0, worker, modified

Assessment method
version
Worker - inhalation, long-term - systemic
Exposure estimate 66.3531 mg/m³
Risk Characterization Ratio (RCR) 0.861729
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (see
exposure estimates)

Contributing exposure scenario

PROC15: Use a laboratory reagent.
Use descriptors covered Use domain: industrial

Operational conditions
ethylbenzene
Concentration of the substance Content: >= 0 % - <= 100 %

Physical state liquid

Vapour pressure of the substance 952 Pa
during use
20 °C
Process temperature
480 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Risk Management Measures
Handle in a fume cupboard or under
extract ventilation
In case of potential exposure:, Use
suitable chemically resistant gloves.,
Use suitable eye protection.
Exposure estimate and reference to its source
Assessment method EASY TRA v4.1, ECETOC TRA v3.0, Worker
Worker - dermal, long-term - systemic
Exposure estimate 0.3429 mg/kg bw/day
Risk Characterization Ratio (RCR) 0.001905
EASY TRA v4.1, ECETOC TRA v3.0, worker, modified
Assessment method
version
Worker - inhalation, long-term - systemic
Exposure estimate 4.4235 mg/m³
Risk Characterization Ratio (RCR) 0.057449
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (see
exposure estimates)

****************