11.

Sodium extract with FeCl3 will show red coloration if it contains

a. N b. S c. Cl d. N and S
Group 'B
Pre-board Examination-2080
Give short answer to the following questions [5x8=40]
Class: XI Faculty of Science
FM: 75 12. Alkenes are unsaturated hydrocarbon that contain double bond
Subject: Chemistry(3011) Time: 3:00Hrs. between two carbons. These compounds undergoes electrophilic
PM : 27 addition to form saturated compound.
candidates are required to answer in their own words as far as i. Define electrophile. [1]
practicable. credit shall be given to clarity and originality, not rote ii. Describe, with the curly arrows, the mechanism for the following
learning. reaction to show product. [2]
Set A CH3-CH=CH2 + HBr → Product
Group ‘A’ iii. Write with an example antimarkov-nikove’s addition [2]
Rewrite the correct answer. [1×11=11] 13. Sodium is s-block element. It is also called as alkali metal. Generally
1. The shape of methane on the basis of hybridization is alkali metal and its respective hydroxide are both manufactured by
a. Triangular b. Pyramidal c. Linear d. Tetrahedra electrolytic process.
2. An atom M has atomic number 19 and atomic mass 39. Its ion is i. Name the electrolytes used in the manufacture of caustic soda. [1]
represented as ii. Which compound is produced at anode during the manufacture of
a. M-1 b. M+1 c. M+2 d. M-2 NaOH? [1]
3. Which of following is an acidic oxide? iii. Write the reaction of preparation of NaOH at cathode [2]
a. P2O5 b.CO c. CaO d. PbO iv. Aqueous solution of sodium chloride cannot be electrolyzed?
4. What quantity of CaSO4 is present in 0.25 mole? Give reason. [1]
a. 136 g b. 13.6 g c. 68 g d. 34 g 14. i. Differentiate between limiting reagent and excess reagent in a
5. An element with atomic number 20 will be placed in which period of chemical reaction. [1+1]
the periodic table? ii. If 8 g of oxygen reacts with 4 g of hydrogen to form water, which
a. 1 b. 2 c. 3 d. 4 one is limiting reagent and why? [2]
6. Which one of the following combines with Fe++ to form a brown
complex? iii. What mass of water is formed in the reaction [1]
a. NO b. N2O c. N2O3 d. N2O5 OR
7. Lead tetraethyl is used as i. Derive the equation P1V1= P2V2 where the symbols have their
a. Fire extinguisher b. Pain killer usual meaning. [2]
c. Petroleum additive d. Mosquito repellent ii. Define Grahm’s law of diffusion. [2]
8. Law of electrolysis was given by iii. Calculate the ratio of rate of diffusion of methane gas and
a. Darwin b. Ostwald hydrogen gas. [1]
c. Faraday d. Arrhenius 15. During the manufacture of sulphuric acid in contact process, sulphur
9. Deviation from Markovnikov’s rule occurs in presence of dioxide reacts reversibly with oxygen to form sulphur trioxide.
a. Zn b. Zn.Hg/HCl i. Write an equation to show the reaction between sulphur dioxide
c. Peroxide d. Ni and oxygen. [l]
10. Electro metallurgy is employed for the extraction of ii. Give the name of catalyst and the values of temperature and
a, Cu b. Zn c. Na d. Ag pressure used. [2]
 iii. Write an equation to show sulphuric acid used in precipitation as 19. One of the raw materials for nitric acid production and urea
well as dehydration. [2] production is ammonia. Nitric acid is manufactured by Ostwald’s
16. Nitrogen means fertilizer producer. One of the important compound process.
of nitrogen is ammonia which is manufactured from hydrogen and i. Write principle with necessary conditions. [2]
nitrogen in the Haber process. ii. Draw diagram for the manufacture of nitric acid by Ostwald’s
N2 + 3H2 → 2 NH3, H= -92 KJ/mole process [1]
i. What do you mean by the term chemical equilibrium? [1] iii. What is aquaregia? Write its an application. [2]
ii. State the conditions employed industrially in the manufacture of Group 'C'
ammonia. [3] Give long answer to the following questions [8×3=24]
iii. Write the name of two possible fertilizers that are formed by 20. In the presence of sunlight NH3 is reduced to nitrogen gas. The
ammonia. [1] reaction is given below. NH3 + Cl2 → N2 + HCl
17. One of the examples of homologous series is given below. i. Balance the above reaction by O.N. method or ion electron
method. [3]
HCOOH
ii. What mass of nitrogen gas is formed if 2 moles of ammonia is
CH3COOH
completely reacted with excess chlorine? [2]
CH3CH2COOH o
iii. Calculate the volume of HCI gas required at 0 C and 780mm Hg
CH3CH2CH2COOH pressure which can completely react with 30 g of ammonia gas
i. Define homologous series. [1] to produce ammonium chloride. [3]
ii. Identify the third member with the help of functional group and 21. Hydrogen means water producer and Oxygen means acid producer.
Among these two elements oxygen readily forms oxides with other
write its IUPAC name. [1] elements. Some of the oxides are as:-P2O5 PbO NO2
iii. What happens when sodium salt of the third member is heated i. Identify these oxides with suitable reaction. [3]
with soda-lime? [2] ii. Write any two chemical test to demonstrate [H] is more reactive
than H2. [2]
iv. Write functional isomer of the fourth member in the given series.
iii. Why is water considered as universal solvent? [2]
[1]
iv. Draw the resonating structure of ozone. [1]
18. Rutherford’s model is based on positively charged ray scattering 22. If 2-methyl but-2-ene undergoes ozonolysis it gives two compounds
experiment. On the basis of this experiment, he was proposed the [X] and [Y].
structure of atom. i. Write the two-steps reaction for the formation of X and Y. [2]
i. Write any two observation of this experiment. [1] ii. Write the IUPAC name of X and Y. [1+1]
ii. How is that drawback justified by Bohr’s model? [2] iii. What happens when H2 in the presence of Ni catalyst is passed
over 2-methyl but-2-ene. [2]
iii. Give the electronic configuration of an atom 20X40and indicates iv. How will you convert X into propane. [2]
its group. [2]

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 a. 14 g b. 28 g c. 42 g d. 56 g
8. Law of multiple proportion is applicable for
a. PH3 and P2O5 b. NH3 and NO2
c. PCl5 and PCl3 d. All

Pre-board Examination-2080 9. Markovnikov’s rule occurs in

Class: XI Faculty of Science a. Symmetrical alkene b. Symmetrical alkyne
FM: 75 c. Symmetrical alkane d. Unsymmetrical alkene
Subject: Chemistry(3011) Time: 3:000 Hrs. 10. The compound having dipole moment is
PM : 27
a. H2O b. CCl4 c. CO2 d. C6H6
candidates are required to answer in their own words as far as
practicable. credit shall be given to clarity and originality, not rote
11. Sodium extract with (CH3COO)2Pb will show Black coloration if
learning. it contains
Set B a. N b. S c. Cl d. N and S
Group ‘A’ Group 'B
Rewrite the correct answer. [1×11=11] Give short answer to the following questions [5x8=40]
12. Reaction mechanism describes the successive steps at the
1. The IUPAC name of Cl3CCHO is
molecular level that takes place in a reaction.
a. 1,1,1-triodopropanal b. 1,1,1-trichloropropanal
Br+ CN-
c. 3,3,3-triodopropanal d. 2,2,2-trichloroethanal
i. Identify the electrophile and nucleophile from the above list. [1]
2. In Lassaigne test for nitrogen, the blue color is due to the
ii. Write the functional group of amide and aldehyde. [1]
formation of
iii. NaOH/CaO Cl2 /UV Na/ Dry ether
a. Ferric ferrocyanide b. Potassium ferrocyanide
CH3COONa → [A] → [B] → [C]
c. Sodium ferrocyanide d. Sodium cyanide
Identify compound A, B and C in the above reaction. [3]
3. Which of following is an amphoteric oxide?
13. Basic structure of atom was first described by Rutherford on the
a. P2O5 b.CO c. CaO d. PbO
basis of +vely charged ray scattering experiment.
4. In Haber’s process for the manufacture of ammonia, the catalyst
Result of this experiment was then enhanced by Bohr’s model
used is
i. An atom Z has 2 electrons in K shell, 8 electrons in L shell and 9
a. Finely divided Pt b. Finely divided Ni
electrons in M shell. Identify the element X and write the
c. Finely divided Fe d. Finely divided Mo
number of protons and neutrons in it. [3]
5. An element with atomic number 20 will be placed in which group
ii. Size of ion is smaller than that of X atom though both contain
of the periodic table?
the same number of protons. Give reason. [1]
a. I b. II c. III d. IV
iii. Write down the principle quantum number and azimuthal
6. When there is more deviation in the behavior from the ideal gas
quantum number for the valence electron of X. [1]
equation, PV=nRT?
14. When electricity is passed through the molten NaCl in the presence
a. At high temp. and low pressure
of CaCl2 in the ratio of 2:3 by weight using graphite anode and
b. At low temp. and high pressure
Iron cathode as electrodes, sodium metal is deposited at cathode
c. At high temp. and high pressure
and chlorine gas is liberated at anode in the electrolytic cell, called
d. at low temp. and low pressure
Down’s cell.
7. The weight of quick lime obtained by strongly heating 25 g of
CaCO3
 i. Write down the anode reaction and cathode reaction. [2] i. Name the hardest allotrope of carbon and its one use. [1]
ii. Find the mass of Na metal deposited at cathode when 20 ii.Give the chemical equation for the preparation of CO from
amperes of current is passed for half an hour if the process has oxalic acid. [2]
only 90% efficiency. [2] iii. What happens when CO is passed through heated Ni powder?
iii. Why does calcium metal not deposit instead of sodium at the [1]
cathode? [1] 19. Alkenes and alkynes are unsaturated hydrocarbon. They are widely
15. Ammonia reacts with sulphuric acid, it forms a salt [A] which has used in polymerization and in the synthesis of other organic
the following percentage composition by mass;- N=24.12%, compounds.
H=6.94%, S=27.61% and O=41.33% i. Write the reaction for the laboratory preparation of ethene. [2]
i. Define empirical formula. [1] ii.What happens when ethene is reacted with cold, dilute alkaline
ii. Calculate the empirical formula of compound [A] [2] KMnO4 ? [2]
iii. Write the balanced reaction for the formation of compound iii. Write the reaction of polymerization of ethene. [1]
[A]. [2] Group 'C'
16. Ammonium chloride is a salt which has covalent bond, co-ordinate Give long answer to the following question [8x3=24]
covalent bond and ionic bond. 20. Gas is one of the state of matter. In this state matters follow
i. Write a balanced equation for the preparation of ammonium different gas laws. among these laws, you can observe a real life
chloride. [1] application of Boyle’s law when you climb and reach mountain.
ii.What is a co-ordinate [dative] covalent bond? [1] i. State Boyle’s law. [1]
iii. Give the formulae of ions present in ammonium chloride. ii.Derive PV = nRT [2]
[1] iii. How long will it take 500 mL of hydrogen gas to diffuse
iv. Draw the lewis structure of ammonium chloride. [2] through a porous membrane if 250 mL of oxygen diffuses in 50
OR minutes under similar conditions through the same membrane?
Le- Chatelier’s principle can be used to predict the behavior of [3]
the position of equilibrium due tochanges in temparatures, iv. A liquid boils at 100oC at the sea level. What will happen its
pressures or concentration. boiling point if it is taken in Kathmandu and why? [2]
i. Write Kp and Kc for the reaction 3H2 + N2 → 2NH3. [1] 21. Metals are the main component in the construction. These metals
ii. Derive the relationship between Kp and Kc for the above are extracted from their respective ores.
reaction. [2] i. Define ores. Write any two ores of iron. [2]
iii. What is the effect of temperature and pressure on the following ii.What types of metal ores are concentrated by the froth floatation
reaction? [2] process? Why? [2]
2SO2 +O2 → 2SO3 , H = - 196 KJ/mole iii. Write two reactions which are involved in roasting. [2]
17. Ammonia is used as refrigerant gas for purification of water supply iv. What do you mean by hydrometallurgy? Write an example.
and in manufacture of plastics, explosives, dyes and other more [2]
compounds like nitric acid. 22. Benzene is aromatic compound. Its molecular formula is C6H6
i. Write the action of aqua regia on gold. [2] i. State Huckle’s law. [1]
ii.Write the reaction of ring test for nitrate radical. [2] ii. How is benzene aromatic compound? [1]
iii. Write two uses of nitric acid. [1] iii. What happens when H2 is passed into benzene? Write IUPAC
18. Graphite is used pencils, to make brushes in electric motors and in name of product. [2]
furnace lining. iv. Write any two methods of preparation of benzene. [3]
v. What product is obtained when benzene is nitrated. [1]

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