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CHEMISTRY

1 Which of the following has maximum – I effect ? 6 Which of the following is most acidic ?
(1) – F (2) ⊕ (1) CH3 – CH2 – OH
−NH3
(2)
(3) ⊕
(4) – OH
−NR3
2 Which of the following has highest pKa value ? (3)
(1)

(4)
(2)

(3)
7 Which of the following is most basic ?
(4) (1)

(2)
3 Which of the following has maximum pKa ?
(1) CF3 – COOH (2) CH3 – COOH
(3)
(3) (4)
(4)
4 Correct order of stability for following anions is :-
(1) Cl Θ < OH Θ < F Θ 8 Highest positive inductive effect show by -

(2) OH Θ < Cl Θ < F Θ (1) – CH3 (2) – CD3

(3) OH Θ < F Θ < Cl Θ (3) – H (4) – D

(4) F Θ < OH Θ < Cl Θ

9 Which of the following statement is correct ?

5 Which of the following is false for I-effect ?

(1) Inductive effect is due to partial displacement
of σ bonded electron
(1) It is a distance dependent phenomenon
(2) Inductive effect is due to complete transfer of
(2) Partial displacement of σ electrons take place. π bonded electrons
(3) It is a temporary effect (3) Resonating structure are real structure
(4) Group showing +I-effect increase e Θ density (4) NH3 act as electrophile
on carbon-chain

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10 Compound with the highest pKb value is :- 16 Most acidic hydrogen among the following :-
(1) (2)

(3) (4)

11 Which of following is lowest pKa value ?

(1) HC
(1) Cl – CH2 – CO2H
(2) Hb
(2)
(3) Ha
(3) Cl3C – CO2H (4) All are equally acidic
(4) CH3 – CO2H 17 Most stable carbanion is :-
12 Which of the following is not an electrophile :-
(1)
(2)
(1) (2)
(3) H2O (4) All of these (4)
13 Strongest – I group is :-
(3)

(1) – OH (2) – COOH 18 Which of the following intermediate is least stable :-

(3) – F (4) (1) (2)

14 What is correct method of heterolytic fission in

(3)
CH3 – Br :- (4)
(1)
(2) 19 Correct order of pKa :-
(3) (1)
(4)
15 Stability order of following carbanions is :-
(2)

(3)
(1) A > B > C > D
(2) A > B > D > C (4)
(3) A > D > B > C
(4) B > A > D > C

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20 Which of the following can behave as electrophile? 26 Select the acid with highest Ka
(1) Na ⊕ (2) H2O (1)
(3) BH3 (4)
21 Which of the following do not have trigonal planar (2)
shape?
(1) (2)
(3)
(3) BCl3 (4)
22 Which of the following cannot act as electrophile ?
(4)
(1) CO2 (2) : CCl2
(3) ⊕
N H4 (4) AlCl3 27 Among the following compounds, the strongest
acid is :
23 Which of the following is most acidic ?
(1) CH ≡ CH (2) C6H6
(1) Cyano acetic acid
(3) C2H6 (4) CH3OH
(2) Nitro acetic acid
28 Maximum – I effect is excerted by the group
(3) Formic acid
(1) C6H5 (2) – OCH3
(4) Acetic acid
(3) – CH3 (4) – NO2
24 Which of the following carbanion most stable?
29 Choose the weakest acid among the following :-
(1)
(1) F3C – COOH

(2) (2) F – CH2 – COOH

(3) CH3 – COOH
(3) (4)
(4)
25 Which of the following is correct order of 30 Arrange following compounds in increasing
decreasing inductive effect :- order of pK b value :-
∙ ∙ ∙ ∙

(1) – NH2 > – NO2 > – OH (I) Cl − N H2 (II) H − N H2 (III)

∙ ∙

(2) – OH > – NH2 > – NO2 CH3 − N H2

(3) – NO2 > – COOH > – OH (1) I < II < III
(4) – COOH > – NH2 > – NO2 (2) III < II < I
(3) I < III < II
(4) II < III < I

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31 Most acidic is :- 38 The number of electrons in central atom of carbon
(1) F3C – CH2 – CH2 – OH free radical :-

(2) NO2 – CH2 – CH2 – CH2 – OH (1) 6 (2) 7 (3) 8 (4) 4

(3) NC – CH2 – CH2 – CH2 – OH

39 The shape of and are respectively....
(4) Cl – CH2 – CH2 – CH2 – OH and....?

32 Which of the following has strong +I effect ?

(1) Planar, Planar

(1) – O Θ (2) – Et (2) Pyramidal, Pyramidal

(4) (3) Pyramidal, Planar

(3) – CH3
(4) Planar, Pyramidal
33 Which is maximum acidic ? 40 Which of the following acts as a nucleophile:-
(1) (2) (1) SO3 (2) NH3
(3) BH3 (4) AlCl3
(3) (4)
41 Which of the following carbocation is most stable :-
34 Which one of the following is most stable ?
(1)
(1)
(2) (2)

(3) (3)
(4)
(4)
35 Which is an electrophile ?
(1) CO2 (2) SO2 42 Which of the following species is an electrophile?
⊕

(3) SO3 (4) All of these (I) H2O (II) H3 O ⊕ (III) N H4

36
⊕ ⊕

Which show maximum – I effect ? (IV) C l (V) C H3

(1) – CHO (2) – F (1) II, III, IV, V (2) I, II, III, IV
(3) – NO2 (4) (3) II, V (4) IV, V
37 Correct order of – I effect is : 43 Find the most stable carbocation ?
(1) – > – COOH > – Cl > – NO2 (1) (2)
(2) – COOH > – Cl > – OH > – C ≡ N
(3) – NO2 > – > – Cl > – Ph (3) (4)
(4) – COOH > – Br > – OH > – NH2

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44 How many electrophile is present in given species :- 47 Which carbocation is most stable :-
(a) BH3 (b) Cl ⊕ (c) H3 O ⊕ (1)
⊕ ⊕
(2)
(d) CO2 (e) N H4 (f) Na
(1) 5
(2) 4
(3) 2 (4)
(3)
(4) 3
45 Correct order of Ka is :-
(a) CH3 – COOH
(b) CH3 – CH2 – COOH
(c) H – COOH 48 Which of the following can behave as Nucleophile ?
(1) a > b > c (1)
(2) b > c > a (2)
(3) c > a > b
(3)
(4) c > b > a
(4)
46 Arrange the following in the acidic strength order
? 49 Maximum negative inductive effect shown by :-
(1) – NO2 (2) CN

(a) (3) – F (4) – OH

50 Which of the following carbanion is least stable :-
(b) (1)
(c) (2)
(d)
(1) a > c > b > d (3)

(2) a > b > c > d (4)

(3) b > a > c > d
(4) d > a > b > c

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