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CH 2 Atomic Structure DPS 3303b712 809b 45dc 8b2d 4248bc0cc554

The document contains a dynamic practice sheet focused on atomic structure, featuring 25 multiple-choice questions with their respective answers. Topics covered include electron transitions, de Broglie wavelength, and properties of atomic orbitals. Each question is worth 4 marks, and the answers are indicated next to each question.

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razz0819
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22 views5 pages

CH 2 Atomic Structure DPS 3303b712 809b 45dc 8b2d 4248bc0cc554

The document contains a dynamic practice sheet focused on atomic structure, featuring 25 multiple-choice questions with their respective answers. Topics covered include electron transitions, de Broglie wavelength, and properties of atomic orbitals. Each question is worth 4 marks, and the answers are indicated next to each question.

Uploaded by

razz0819
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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Dynamic Practice Sheet (Atomic Structure)

1 Question – 4 Marks

Q-1 Which one of the following statements is correct? (Ans-c)


(a) Rutherford's alpha-particle scattering experiment lead to the discovery of electron
(b) J. J. Thomson suggested that the nucleus of an atom contains protons
(c) The atomic number of an element is the same as the number of protons in the nucleus of its atom
(d) The mass number of an atom is equal to the number of electrons in its shells

Q-2 The constancy of e/m ratio for electrons inspite of variations of gas present in the discharge tube or of the material of the
cathode shows that : (Ans-b)
(a) electrons are negatively charged
(b) electrons are universal constituents of matter
(c) electrons are the lightest of all particles
(d) mass of the electron is 1/1838 of the mass of H-atom

Q3 The wavelength of a spectral line emitted by hydrogen atom in the Lyman series is 16 15R cm. What is the value of n2? (R =
Rydberg constant) (Ans-c)
(a) 2 (b) 3 (c) 4 (d) 1

Q4 In which of the following options, the law of triad is applicable? (Ans-b)


(a) Na, K, Rb (b) Cl, Br, I (c) C, N, O (d) Ca, Sr
Q-5 If the velocity of the electron in the hydrogen atom in its first orbit is 2.18 × 106 ms–1, then will be the velocity of the electron
in the second orbit of Li2+ ? (Ans-b)
(a) 2.18 x 106ms− 1 (b) 3.27 x 106 ms−1 (c)6.54 x 106 ms−1 (d) 1.45 x 106 ms-1

Q-6 Which of the following transition of an electron in H-atom will emit maximum energy? (Ans-c)
(a) n6 n5 (b) n1 n2 (c) n3 n2 (d) n4 n3

Q-7 For d-electron, the orbital angular momentum is (Ans-a)


(a) √6h/2π (b) √2h/2π (c) √h/2π (d) √2h/π
Q-8 The longest wavelength present in Balmer series lines is [Given Rydberg constant = 1.097 x 107 m-1] (Ans-b)
(a) 640 nm (b) 656 nm (c) 662 nm (d) 670 nm

Q-9 A particle of mass 6.6 × 10–31 kg is moving with a velocity of 1 × 107 ms–1 . The de Broglie wavelength (in Å) associated with
the particle, is (h = 6.6 × 10-34 Js) (Ans-a)
(a) 1 (b) 10 (c) 5 (d) 2 (e) 4

Q-10 Two particles of masses m & 2m have equal kinetic energies. The de-Broglie wavelength are in the ratio of_____ (Ans-d)
(a) 1 : 1 (b) 1 : 2 (c) 1 : √2 (d) √2 :1

Q-11 A 150 watt bulb emits light of wavelength 6600 Å and only 8% of the energy is emitted as light. How many photons are
emitted by the bulb per second? (Ans-a)
(a) 4×1019 (b) 3.24×1019 (c) 4.23×1020 (d) 3×1020
Q-12 If the energies of two light radiations E1 and E2 are 25 eV and 100 eV respectively, then their respective wavelength λ1 and
λ2 would be in the ratio λ1 : λ2 = ______ (Ans-b)
(a) 2:1 (b) 4:1 (c) 1:4 (d) 1:2

Q-13 The ratio of slopes of Kmax vs v and v0 vs v curves in the photoelectric effects gives (v = frequency, Kmax = maximum kinetic
energy, v0 = stopping potential) (Ans-d)
(a) The ratio of Planck’s constant of electronic charge (b) Work function
(c) Planck’s constant (d) Charge of electron

Q-14 A near UV photon of 300 nm is absorbed by a gas and then re-emitted as two photons. One photon is red with wavelength
of the second photon is (Ans-b)
(a) 1060 nm (b) 496 nm (c) 300 nm (d) 215 nm

Q-15 The de- Broglie wavelength of an electron in the ground state of hydrogen atoms is: (K.E.= 13.6eV; 1ev=1.602×10−19 J)
(Ans-c)
(a) 33.28nm (b) 3.328nm (c) 0.3328nm (d) 0.0332 nm

Q-16 If uncertainty in position and momentum are equal, then uncertainty in velocity is (Ans-c)
Q-17 Which of the following electron transitions in the H-atom will release the largest amount of energy? (Ans-b)
(a) n=3 to n=2 (b) n=2 to n=1 (c) n=5 to n=2 (d) n=6 to n=2

Q-18 The graph between |ψ| 2 and r (radial distance) is shown below. This represents. (Ans-d)

(a) 1s-orbital (b) 2p-orbital (c) 3s-orbital (d) 2s-orbital

Q-19 The frequency of light emitted for the transition n = 4 to n = 2 of He+ is equal to the transition in H atom corresponding to
which of the following? (Ans-b)
(a) n = 3 to n = 1 (b) n = 2 to n = 1 (c) n = 3 to n = 2 (d) n = 4 to n = 3

Q-20 Which of the following orbitals will have zero probability of finding the electron in the yz plane? (Ans-a)
(a) Px (b) py (c) pz (d) dyz

Q-21 If the electron of a hydrogen atom is present in the first orbit, the total energy of the electron is: (Ans-c)
(a) –e2/r (b) –e2/r2 (c) –e2/2r (d) –e2/2r2

Q-22 Which orbital among the following has zero radial nodes and 2 angular nodes? (Ans-b)
(a) 4s (b) 3d (c) 2p (d) 5s
Q-23 What is the total number of electrons that can have the values n = 2, l = 1, s = ½ in the electronic configuration 1s2 2s2 2p3?
(Ans-b)
(a) 1 (b) 3 (c) 5 (d) 7

Q-24 The orbital diagram in which Aufbau principle is violated is (Ans-c)

Q-25 The orbital having two radial as well as two angular nodes is: (Ans-d)

(a) 3p (b) 4d (c) 4f (d) 5d

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