The Carnot theorem states that the efficiency of irreversible heat engines is always less than that of reversible engines operating between the same reservoirs, and all reversible engines have the same efficiency. The document also discusses temperature scales and provides examples of heat engine efficiency calculations, including the Clausius Inequality and its application in power plant cycles. It emphasizes the importance of understanding these principles for evaluating thermal efficiency in thermodynamic systems.
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Carnot
The Carnot theorem states that the efficiency of irreversible heat engines is always less than that of reversible engines operating between the same reservoirs, and all reversible engines have the same efficiency. The document also discusses temperature scales and provides examples of heat engine efficiency calculations, including the Clausius Inequality and its application in power plant cycles. It emphasizes the importance of understanding these principles for evaluating thermal efficiency in thermodynamic systems.
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CARNOT THEOREM
The efficiency of an irreversible heat engine is
always less than the efficiency of a reversible heat engine if they operating between the same two reservoirs
The efficiencies of all reversible heat engines
operating between the same two reservoirs are the same
• They are also known as the Carnot
principles THE CARNOT PRINCIPLES
The Carnot principles. Proof of the first Carnot principle.
1. The efficiency of an irreversible heat engine is always less than the
efficiency of a reversible one operating between the same two reservoirs. 2. The efficiencies of all reversible heat engines operating between the same two reservoirs are the same. 51 Temperature Scales P versus T plots • All temperature scales are based on some easily reproducible states such as of the the freezing and boiling points of water: experimental the ice point and the steam point. data obtained • Ice point: A mixture of ice and water from a constant- that is in equilibrium with air saturated volume gas with vapor at 1 atm pressure (0°C or thermometer 32°F). using four • Steam point: A mixture of liquid water different gases and water vapor (with no air) in equilibrium at 1 atm pressure (100°C or at different (but 212°F). low) pressures. • Celsius scale: in SI unit system • Fahrenheit scale: in English unit system • Thermodynamic temperature scale: A temperature scale that is independent of the properties of any substance. • Kelvin scale (SI) Rankine scale (E) • A temperature scale nearly identical to the Kelvin scale is the ideal-gas temperature scale. The temperatures on this scale are measured using a constant-volume gas thermometer. A constant-volume gas thermometer would read -273.15°C at absolute zero pressure. 53 CLAUSIUS INEQUALITY A reversible heat engine is supplied 900 kJ of heat from a heat source at 500 K. The engine develops 300 kJ of net work and rejects heat to two heat sinks at 400 K and 300 K. Determine the engine thermal efficiency and magnitude of heat interaction with each of the sink.
33.3 % 240 kJ 360 kJ
A reversible heat engine is supplied 900 kJ of heat from a heat source at 500 K. The engine develops 300 kJ of net work and rejects heat to two heat sinks at 400 K and 300 K. Determine the engine thermal efficiency and magnitude of heat interaction with each of the sink.
33.3 % 240 kJ 360 kJ
300 kJ/s of heat is supplied at a constant fixed temperature of 290C to a heat engine. The heat rejection takes place at 8.5C. The following results were obtained : (i) 215 kJ/s are rejected. (ii) 150 kJ/s are rejected. (iii) 75 kJ/s are rejected. Classify which of the result report a reversible cycle or irreversible cycle or impossible results. In a power plant cycle, the temperature range is 164C to 51C, the upper temperature being maintained in the boiler where heat is received and the lower temperature being maintained in the condenser where heat is rejected. All other processes in the steady flow cycle are adiabatic. The specific enthalpies at various points are given in Figure. Verify the Clausius Inequality. Find the maximum efficiency and actual efficiency. What would be the heat rejection if the cycle is assumed as Carnot cycle.