MSDS: LLDPE

MATERIAL SAFETY DATA SHEET

1. PRODUCT IDENTIFICATION
Chemical Names & Synonyms: Linear Low Density Polyethylene (LLDPE)

Trade name: G- LeneLL

Chemical Characterization: Polyolefin resin; PE

Formula: (C2H4)n
Manufacturer’s Name: GAIL (India) Limited
P.O. Pata
Dist. Auraiya
PIN- 206241 (Uttar Pradesh)

Telephone/ Fax No.: 91- 5683-282356

Corporate Site: www.gailonline.com

CAS No.: 25087-34-7

Component Content Hazard Data
Polyethylene >=99 wt % Non hazardous

Various additives (Antioxidants, <1 wt% Mixture. No hazards resulting from

UV Stabilizers, Anti-blocking material as supplied.
agents etc.)

2. PHYSICAL & CHEMICAL DATA

Form: Solid , Granular

Color: Translucent to White
Odor: Odorless
Melting Point: 115– 135 °C
Boiling Point: Not Applicable
Decomposition Temperature: > 300°C
Specific Gravity: 0.91 - 0.94
Vapour Pressure: Not Applicable
Vapour Density: Not Applicable
Solubility in water: Insoluble
Volatiles: <0.1% by volume
pH (Value): Not Applicable
Evaporation Rate: Not Applicable

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 MSDS: LLDPE

3. FIRE AND EXPLOSION HAZARD DATA

Flash Point: >300 °C

Auto Ignition temperature: >300 °C

Flammable Limits: Not Applicable

Extinguishing Media: Water, foam, dry chemical, Carbon dioxide.

Special Fire Fighting None.

procedure:
Protective equipment for Self-contained breathing apparatus may be necessary
Fire Fighters: to approach a fire, particularly in a confined area.

Unusual Fire and Explosion A fire involving polyethylene resin will generate large
Hazard: amounts of smoke, CO and other organic compounds.

.
4. REACTIVITY DATA

Chemical stability: This product is stable under normal use conditions for
shock, vibration, pressure or temperature. Decomposes at
prolonged heating above 300 °C.

Hazardous Polymerisation: Not likely to occur.

Corrosivity: Product is not corrosive
Condition to Avoid: Direct contact with open flames, self-igniting and
explosive materials. Avoid strong oxidizing agents.
Avoid Processing material over 300°C. Avoid Heat &
direct sunlight.
Dangerous products of decomposition:
No hazardous decomposition products known at room
temperature. At elevated temperature the material will
begin to decompose producing fumes that can contain
CO2, CO, dense smoke & other toxic vapours.

5. FIRST AID MEASURES

GENERAL INFORMATION: At room temperature the product is neither an irritant
nor gives off hazardous vapours. The measures listed
below apply to critical situations (Fire, incorrect process
conditions).
Skin Contact: If molten material contacts the skin it may cause thermal
burns, immediately flush with large amounts of cold

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 MSDS: LLDPE

water to cool the affected skin and polymer. Do not

attempt to peel the polymer from skin. Obtain
immediately emergency medical attention if burn is
deep or extensive.
Eye Contact: Dust, fines and process vapours may irritate the eyes.
Rinse immediately with plenty of water, also under the
eyelids, for at least 15 minutes. Seek medical attention
if discomfort persists.
Inhalation: Dust and process vapours may irritate the nose, throat
and respiratory tract. If symptoms are experienced,
move victim to fresh air. Obtain medical attention if
breathing difficulty persists.
Ingestion: Adverse health effects due to ingestion are not
anticipated. Do not induce vomiting. If symptoms
develop, obtain medical attention

Permissible Exposure Limit 10 mg/M3 (total dust) as an inert or nuisance

(ACIGH TLV/TWA): dust.
NFPA Ratings HEALTH: 0
FLAMMABILITY: 1
REACTIVITY: 0
SPECIAL: NA
Odor Threshold No value Available

6. PREVENTIVE MEASURES

PERSONAL PROTECTIVE EQUIPMENT:

Respiratory system:
Product processing, heat sealing of film or operations involving the use of wires or
blades heated above 300°C may produce dust, vapour or fumes. To minimize risk of
over exposure to dust, vapour or fumes it is recommended that a local exhaust system
is placed above the equipment, and that the working area is properly ventilated. If
ventilation is inadequate, use certified respirator that will protect against dust/mist.
Skin and body
Hot material: Wear heat-resistant protective gloves, clothing and face shield able to
withstand the temperature of the molten product. Cold material: None required;
however, use of gloves is good industrial practice.
Hand
Hot material: Wear heat-resistant protective gloves able to withstand the temperature
of the molten product.
Cold material: None required; however, use of gloves is good industrial practice.
The correct choice of protective gloves depends upon the chemicals being handled,
the conditions of work and use, and the condition of the gloves (even the best
chemically resistant glove will break down after repeated chemical exposures). Most
gloves provide only short time of protection before they must be discarded and

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 MSDS: LLDPE

replaced. Because specific work environments and material handling practices vary,
safety procedures should be developed for each intended application. Gloves should
therefore be chosen in consultation with the supplier/manufacturer and with a full
assessment of the working conditions.

Eyes
Safety glasses with side shields. Use dust goggles if high dust concentration is
generated.
Environmental Protection
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

HANDLING:
 No special requirements necessary, if handled at room temperature.
 Avoid spilling the product, as this might cause falls.
 Will accumulate static charges that may cause an electric spark (ignition source).
 Take precautionary measures against static discharges.
 Do not eat, drink or smoke at the work place.
 After handling, wash face and hands before eating, drinking or smoking.

STORAGE:
Requirements to be met by storerooms and containers:
 This product may react with strong oxidising agents & should not be stored near
such materials.
 Store the bags in areas protected with automatic sprinklers.
 Storage temperature should be ambient. (preferably below 50 °C)Open flames
prohibited.
 Store the product in bags, car silos, container, or large cartons to avoid
contamination.
Further information about storage conditions:
 Protect from heat and direct sunlight.
 Store container in a well ventilated position.
 Store under dry conditions.
 Specific applications: For industrial use only, for safe stacking follow the storage
recommendations specific for this product.

7. EMERGENCY MEASURES

ENGINEERING CONTROLS:
Use in a well-ventilated area. If handling results in dust generation, special ventilation
may be needed to minimize dust exposure. If heated material generates vapour or
fumes, use process enclosures, local exhaust ventilation, or other engineering controls
to control exposure.

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 MSDS: LLDPE

FIRE FIGHTING MEASURES

Suitable Extinguishing Media As appropriate for surrounding fire. Extinguish
preferably with foam, Carbon Dioxide, water/water
mist or dry chemical.
Unsuitable Extinguishing Media Do not direct a solid stream of water or foam into
burning molten material; this may cause spattering
and spread the fire.
Fire Fighting Protective Equipment A self-contained breathing apparatus and suitable
protective clothing, eye protection etc. should be
used in fire conditions.
Hazardous Decomposition Product Combustion or thermal decomposition will evolve
toxic and irritant vapours.
Unusual Fire & Explosion hazards Avoid accumulation & dispersion of dust in air to
reduce potential for dust ignition/ explosions.

ACCIDENTAL RELEASE MEASURES

Land spill Carefully sweep up or vacuum and transfer to a dry container.

Recover spillage for recycling or disposal.
Consult an expert on disposal of recovered material and ensure
conformity to local disposal regulations.
Water spill Consult an expert on disposal of recovered material and ensure
conformity to local disposal regulations.
Recover the spilled material and place in suitable containers for
recycling or disposal.
Waste Disposal Recycle (reprocess).
Method Do not allow to enter drains, sewers or watercourses.
Disposal through landfilled or controlled incineration or authorised
waste dump in accordance with Local, State or National
Regulations.
Waste generators must determine whether a discarded chemical is
classified as a hazardous waste.
Caution Polyethylene pellets on floors are slippery and may cause slipping
hazard.

8. ADDITIONAL INFORMATION/ REFERENCES

The information provided in this Material Safety Data Sheet has been based upon the current
level of information available, for the purpose of specifying the requirements regarding
environment, health and safety in conjunction with the product. GAIL, Pata shall not be
responsible for any damage or injury resulting from abnormal use of the Product, from any
failure to adhere to recommendations, or from any hazards inherent in the nature of the
Product. Appropriate warnings and safe handling procedures should be provided to all
handlers and users.

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