CHEMISTRY

Daily Practice Problems

Target IIT JEE 2012
CLASS : XI (J&K) MARKS : 42 DATE : 01-02/08/2010 TIME : 45 MIN. DPP. NO.-9
Only one correct
Q.1 Two elements C & D combine to form two compounds CxDy & CyDx. 0.5 mole of CyDx weigh 40 gm
& 1 molecule of CxDy weigh 1.66 × 10–25 kg. The atomic weight of C & D are 20 & 40 respectively.
'x' & 'y' are respectively. [3]
(A) 3, 2 (B) 1, 3 (C*) 1, 2 (D) 2, 2

Q.2 Select the correct statement for Ne. [3]

(A) It is not isoelectronic with H2O
(B) Last electron enters in s-orbital
(C) The value of ‘m’ must be zero for last electron
(D*) The value of ‘l’ must be ‘1’ for last electron

Q.3 For an element ‘A’. [3]

IE1 IE 2 IE3
A  A+  A2+  A3+  ...................
The IE1 and IE3 values are 27 kJ/mole and 51 kJ/mole respectively. Then the value of IE 2 is _____
kJ/mole.
(A) 21 (B*) 33 (C) 59 (D) 63

Q.4 Elements A,B,C,D and E are having the electronic configuration of: [6]
A : 1s2 , 2s2 , 2p1
B : 1s2 , 2s2, 2p6 , 3s2 , 3p2
C : 1s2 , 2s2, 2p6 , 3s1
D : 1s2 , 2s2, 2p6 , 3s2 , 3p1
E : 1s2 , 2s2, 2p6
From the above information answer the question No.(i) & (ii)
(i) Which among these will belong to same group in the periodic table.
(A) A and B (B*) A and D (C) B and D (D) C and E
(ii) The element having maximum ionisation energy is
(A) D (B) B (C*) E (D) C

Comprehension
Paragraph for question nos. 5 to 7
The radius of an element can be measured in three ways, covalent radii (rc), metallic radii (rm) and
Vander Waal’s radii (rv) because they are not available in a single state. Ionic radii (ri) also measured
from their crystal lattices and it depends upon their different arrangement also.

Q.5 The radius of F and Ne are respectively (approximately). [9]

(A) 1.6Å, 0.72Å (B) 0.72Å, 0.72Å (C*) 0.72Å, 1.6Å (D) 1.21Å, 1.05Å

Q.6 Which of the following order is correct for the radii of the species.
(A) Fe3+ > Fe2+ (B*) O 2  O  (C) S2– < Cl¯ (D) Ga >> Al
Q.7 For a particular element, the correct order of radii is
(A) rc < rv < rm (B) rc  rv > rm (C) rm > rv > rc (D*) rv > rm > rc

More than one may be correct

Q.8 ‘A+2 ’ is isoelectronic with ‘CO2’ and has (Z+2) neutron (Z is atomic number of A), then the select
the correct option(s). [4]
(A*) Mass number of A is 50+2

(B) Last electron enters in ‘s’orbital in element ‘A’

(C) Number of unpaired electron in ‘A’ is 4
(D*) During formation of A+2 electron(s) are removed from ‘s’ as well as ‘d’ subshell.

Q.9 Which of the following statements is/are incorrect. [4]

(A*) Boron is diagonally related to magnesium.
(B) Bi5+ ion has smaller radius compared to Bi3+.
(C*) last number of the seventh period of periodic table will have atomic number of 124 if
discovered.
(D) Al2O3 is an amphoteric oxide.

Subjective
Q.10 A gaseous mixture contains SO3 (g) and CH4(g) in 5 : 1 ratio by mass. [5]
Calculate Q.
Where Q = 200 × ratio of total number of atoms present in SO3(g) to total number of atoms present in
CH4(g). [Ans. 160]

Q.11 Find out the electronegativity difference between two atoms when the percentage ionic character is
19.5 %. [5]
[Ans. 1]
 CHEMISTRY
Daily Practice Problems
Target IIT JEE 2012
CLASS : XI (J&K) MARKS : 46 DATE : 03-04/08/2010 TIME : 45 MIN. DPP. NO.-10
Only one correct
Q.1 The electronegativity of ‘N’ is maximum in which of the following compound of N. [3]
(A) N2O (B) N2O3 (C) NO (D*) N2O4

Q.2 If the Aufbau principle is not followed and subshells of a shell are progressively filled according to their
energy which of the following elements is paramagnetic. [3]
(A) Mg (B*) Ca (C) Ni (D) Zn

Q.3 The correct order of the lattice energy of the following hypothetical ionic compounds AB, A2B & A2B3
where in all compounds B is in –2 oxidation state & A has variable oxidation state. [3]
(A) A2B > AB > A2B3 (B*) A2B3 > AB > A2B
(C) AB > A2B > A2B3 (D) A2B3 > A2B > AB

Comprehension
Paragraph for question nos. 4 & 6
Answer the following questions on the basis of the given energy (enthalpy) diagram.
Enthalpy (kJ) State of A and B2
+ 2–
s [2 A (g) + B (g)]
+ 1–
(positive) t [2 A (g) + B (g)]

(zero) 0 [2 A(s) + 1 B2 (g)]

2
+
(negative) p 2–
[2 A (g) + B (aq)]
+ 2–
q [2 A (aq) + B (g)]
+ 2–
r [2 A (aq) + B (aq)]

v [A2B (s)]

Q.4 egH [B¯ (g)] is [3]

(A) s + t (B) t – s (C*) s – t (D) 2s – t

Q.5 fH [A2B (s)] is [3]

(A) s + t (B*) v (C) t – s (D) s – t + v

Q.6 Hhydration [A+(g)] is [3]

q s r s
(A*) (B) r – s (C) (D) q – s
2 2
More than one may be correct
Q.7 Select the correct statement(s). [4]
(A*) According to Mulliken, electronegativity is related to the average of the ionization energy and
electron affinity of the atom when they are expressed in eV / atom.
(B) Electronegativity of an atom having half filled electronic configuration will be more in general.
(C*) HClO3 is stronger acid than HClO.
(D*) Electronegativity goes on increasing with increase in atomic number in general as we move along
a period.

Q.8 Select the correct order of Ionic radii . [4]

(A*) Mn2+ > Mn4+ (B) Mn4+ > Mn2+ (C) N > N3– (D*) N3– > N

Q.9 Select the correct statement. (HBE Stands for Bond enthalpy) [4]
(A) Hformation [H(g)] is equal to Hatomisation of H2(g)
(B) HBE (H–H) is equal to Hformation of H(g)
(C*) HBE (H–H) is equal to Hatomisation of H2(g)
(D*) Hformation of H(g) is equal to half of HBE (H–H)

Match the column [6]

Q.10 Column I Column II

(A) Si (P) Having diagonal relationship with B

(B) He (Q) p-block element

(C) O (R) Two unpaired electrons present in its ground state

(S) Having highest ionisation energy.

[Ans. (A) P,Q,R (B) S (C) Q,R]

Subjective
Q.11 Find the total number of species having magnetic moment value of 2.84 B.M. from following species.
Fe2+, Cr, Cr3+, Ti2+, Mn2+, V3+ [5]
[Ans. 2]

Q.12 The lattice enthalpy of solid NaCl is 772 kJmol–1 and enthalpy of solution is 2 kJmol–1. If the hydration
enthalpy of Na+ & Cl– ions are in the ratio of 3:2.5, what is the magnitude of enthalpy of hydration (in kJ)
of chloride ion? [5]
[Ans.350]