Material Safety Data Sheet

（MSDS）

This MSDS is authoring based on the data supplied by and

identified on behalf of the client.

Sample Name: Refrigerant R134a

Client Name: Dezhou Defu Environment Technology Co., Ltd

Client Address: 588#, Kangning Road, Tianqu Industry Park, Decheng

District, Dezhou City, Shandong Province, China

MSDS No.: 2024111808E

Issue Date: November 20, 2024

Signed for and on behalf of

JINHUA HEBIAO TESTING TECHNOLOGY CO., LTD

Approved signator: David Chen

WuCheng City Square, 2999 Binhong West Road, WuCheng District, Jinhua City, Zhejiang Province, China | +86-18768438565 |

The information and recommendations set forth are made in good faith and believed to be accurate as
of the date of preparation. We make no warranty, expressed or implied, with respect to this information
and disclaim all liabilities from reliance on it.
 Material Safety Data Sheet MSDS No.: 2024111808E
Creation Date: November 20, 2024
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1. Identification of the Substances/Preparation and of the Company/Undertaking

Product Identification:
Product Name: Refrigerant R134a
Relevant identified uses of the substance or mixture and uses advised against
Identified uses: Air cooling.
Use advised against: No data available.
Details of the Manufacturer or supplier
Supplier: Dezhou Defu Environment Technology Co., Ltd.
Address: 588#, Kangning Road, Tianqu Industry Park, Decheng District, Dezhou City,
Shandong Province, China.
Telephone: +86-13853486733
Email: [email protected]
Emergency telephone number
Emergency Telephone: +86- 400-6926-906

2. Hazards Identification

Classification of the substance or mixture

GHS Classification:
GASES UNDER PRESSURE - Liquefied gas
GHS Label elements, including precautionary statements

Pictogram(s):

Signal Word: Warning

Hazard Statement: H280 Contain gas under pressure. May explode if heated.
Precautionary statements： P410+403: Protect from sunlight. Store in a well ventilated place.
Description of any hazards not otherwise classified
If gas released, In high concentrations may cause asphyxiation. Do not enter confined space unless
adequately ventilated. In case of inadequate ventilation wear respiratory protection. Direct contact
with the cold gas or liquid can cause freezing of exposed tissues.

3. Composition/Information on Ingredients
 Material Safety Data Sheet MSDS No.: 2024111808E
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Chemical Characterization
Substance. Consist of the following ingredients.
Composition:
Components Name CAS No. Weight (%w/w)
1,1,1,2-TETRAFLUOROETHANE;
HFC 134A;
811-97-2 ≧99.9
Norflurane;
KLEAT34A.

4. First-Aid Measures

Description of first aid measures:

Exposed to expressed gas, see first aid measure as following:
Skin Contact: Treat as frostbite if necessary.Flush exposed skin with lukewarm water (not hot), or
use other means to warm skin slowly. Get medical attention if frostbitten by liquid or
if irritation persists.
Eye Contact: Treat as frostbite if necessary. Rinse cautiously with warm water for several
minutes. If discomfort persists, contact a doctor immediately
Inhalation: Remove victim to fresh air wearing self contained breathing apparatus. Apply
artificial respiration if victim is not breathing. Administer oxygen if breathing is
difficult. Get medical attention.
Ingestion: Ingestion is not considered a potential route of exposure. Refer to the inhalation
section.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in section 2 and section 11.

Indication of any immediate medical attention and special treatment needed

Treat symptomatically and supportively. In case of frostbite, place the frostbitten part in warm water.
If warm water is not available or impractical to use, wrap the affected parts gently in blankets. DO
NOT USE HOT WATER

5. Fire-Fighting Measures

Extinguishing media
Suitable extinguishing media: Use extinguishing agent appropriate to other materials involved. Keep
containers and surroundings cool with water spray as containers may rupture or burst in the heat of a
fire.
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Special hazards arising from the substance or mixture

Contains gas under pressure. In a fire or if heated, a pressure increase will occur and the container
may burst or explode. Decomposition products may include the following materials: carbon dioxide,
carbon monoxide, halogenated compounds, carbonyl halides.
Advice for firefighters
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No
action shall be taken involving any personal risk or without suitable training. Move containers from fire
area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
Firefighters must wear fire resistant protective equipment. Wear self-contained breathing apparatus.
Firefight at upwind.
Further information
No data available.

6. Accidental Release Measures

For guidance on selection of personal protective equipment see Chapter 8 of this Material Safety Data
Sheet. See Chapter 13 for information on disposal. Observe the relevant local and international
regulations.
Personal precautions, protective equipment and emergency procedures:

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding
areas. Keep unnecessary and unprotected personnel from entering. Avoid breathing gas. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate
personal protective equipment.
Environmental precautions:
Attempt to stop leak if without undue personnel hazard.
Methods and materials for containment and cleaning up:
Evacuate area. Keep upwind. Stop leak if without risk. Prevent from entering sewers, basements and
workpits, or any place where its accumulation can be dangerous. Clean up methods-Ventilate area.

7. Handling and Storage

Precautions for safe handling:

The operator must go through specialized training, strict compliance with operating procedures.
Avoid the gas current directive contact with skin and eyes. Avoid breathing gas. Wear self-contained
breathing apparatus if necessary.
Empty containers retain product residue and can be hazardous. Do not puncture or incinerate
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container. Use equipment rated for cylinder pressure. Close valve after each use and when empty.
Protect cylinders from physical damage; do not drag, roll, slide, or drop.Use a suitable hand truck for
cylinder movement.
Conditions for safe storage, including any incompatibilities:
Store in cool place. Prevent direct sunlight. Keep container tightly closed in a dry and well-ventilated
place.
Contents under pressure. Avoid heating above: 52℃.

8. Exposure Controls/Personal Protection

Exposure Limits: Not established.

Exposure controls

Engineering Control: In emergency, Use process enclosures, local exhaust ventilation or other
engineering controls to keep worker exposure to airborne contaminants
below any recommended or statutory limit.
Personal protective equipment:

Respiratory Protection: In emergency, wear self-contained breathing apparatus.

Eyes Protection: Not required normally. In emergency, wear safety glasses/chemical
splash goggles.
Body Protection: Not required normally. In emergency, wear protective clothing to prevent
contact.
Hands Protection: Not required normally. In emergency, wear protective gloves to prevent
contact.
Other Protections: Handle in accordance with good industrial hygiene and safety practice.

9. Physical and Chemical Properties

Information on basic physical and chemical properties

Appearance Colorless liquefied gas.
Odor Odorless.
pH Not applicable.
Melting point/freezing point Not available.
Initial boiling point and boiling range -46.1℃- lit.
Critical temperature: 72.4℃.
Critical pressure: 3688.7 KPa
Flash point Not available.
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Evaporation rate (CL4 = 1) Greater than 1.

Flammability Not flammable.
Upper explosive limit %(V/V) Not applicable.
Lower explosive limit %(V/V) Not applicable.
Vapor pressure Not available.
Vapor density Not available.
Relative density Not available.
Solubility(ies) Water：Insoluble.
Partition coefficient: n-octanol/water Not available.
Ignition temperature Not available.
Decomposition temperature Not applicable.
Viscosity Not applicable.

10. Stability and Reactivity

Stability: Stable under normal conditions.

Conditions to Avoid: Overheat, flame.
Incompatible materials: Strong oxides. Avoid magnesium, aluminium and their alloys, brass and
steel.
Hazardous Decomposition Products: Other decomposition products- no data available. In the event
of fire:see section 5.
Possibility of hazardous reactions: None hazardous reactions known under normal condition.

11. Toxicological Information

Acute Toxicity: No data available.

Skin Corrosion/Irritation: Based on available data, the classification criteria are not
met.
Serious Eye Damage/Eye Based on available data, the classification criteria are not
Irritation： met.
Respiratory or Skin Sensitization No sensitizing effects known.
Germ Cell Mutagenicity Based on available data, the classification criteria are not
met.
Carcinogenicity： None of the components of this product is listed as a
carcinogen by IARC, NTP, US OSHA or the European
Directive (67/548/EEC).
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Reproductive Toxicity： Based on available data, the classification criteria are not
met.
Specific Target Organ Toxicity - No known human health effects upon single exposure.
Single Exposure (Globally
Harmonized System):
Specific Target Organ Toxicity - No known human health effects upon repeated exposure.
Repeated Exposure (Globally
Harmonized System):
Aspiration Hazard: Based on available data, the classification criteria are not
met.
Potential Health Effects:
Inhalation: In high concentrations may cause asphyxiation. Symptoms
may include loss of mobility/consciousness. Victim may not
be aware of asphyxiation.
Skin Contact: Direct contact with expressed gas may cause frostbite.
Eye Contact: Direct contact with expressed gas may cause frostbite.
Ingestion: Ingestion is not considered a potential route of exposure.

12. Ecological Information

Toxicity

No data available
Persistence and degradability
Ingredient Persistence:Water/Soil Persistence: Air
R-134A HIGH HIGH
Bioaccumulative potential
Ingredient Bioaccumulation
R-134A LOW (LogKOW = 1.68)
Mobility in soil
No data available
Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative
and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Other adverse effects
ODP(OZONE DEPRESSION POTENTIAL): 0
GWP(global warming potential): 3850
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13. Disposal Considerations

Safe handling and methods of disposal

Product
Do not puncture or incinerate container. Recycle if possible. Offer surplus and non-recyclable
products to a licensed disposal company. Observe according to the national and local related
regulations.
Contaminated packaging
Empty containers should be taken for local recycling, recovery or waste disposal. Return to supplier
for recycling if possible.

14. Transport Information

For equipment containing refrigerants:

ADR/RID Information
ADR-UN Number: Not regulated for transport
ADR-Class: Not regulated for transport
ADR-Shipping Name: Not regulated for transport
ADRPacking Group: Not regulated for transport
IATA/ICAO Information
The product is not subject to IATA DGR.
Suggestion according to IATA DGR:
The substance is not subject to IATA DGR according to special provision A26.
IATA-UN Number: Not regulated for transport
IATA-Class: Not regulated for transport
IATA-Shipping Name: Not regulated for transport
IATA-Label: None
IATA-Packing Group: Not regulated for transport
IATA-S.P.: None
IATA-ERG: None
IMO/IMDG Information
The product is not subject to IMO/ IMDG Code.
Suggestion according to IMO IMDG Code：
The substance is not subject to IMO IMDG Code according to special provision 119.
IMDG-Marine Pollutant: No
IMDG-UN Number: Not regulated for transport
IMDG-Class: Not regulated for transport
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IMDG-Shipping Name: Not regulated for transport

IMDG-Packing group: Not regulated for transport
IMDG-Storage Category: Not regulated for transport

For refrigerants:

UN Number： 3159
ADR/RID, IMDG, IATA

UN proper shipping name: 1,1,1,2-TETRAFLUOROETHANE(REFRIGERANT GAS

ADR/RID, IMDG, IATA R 134a)

Transport hazard class(es):

ADR/RID, IMDG, IATA 2.2

Packing group: Not applicable.

ADR/RID, IMDG, IATA

Environmental hazards: No.

Special precautions for user： No information available.

15. Regulatory Information

International Regulations
Safety, health and environmental regulations/legislation specific for the substance or mixture
No information available.
Chemical safety assessment
For this product a chemical safety assessment was not carried out.

16. Other Information

Further Information:
 Material Safety Data Sheet MSDS No.: 2024111808E
Creation Date: November 20, 2024
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·This information is based on our present knowledge. However, this shall not constitute a guarantee
for any specific product features and shall not establish a legally valid contractual relationship.
·This safety data sheet was prepared in accordance with Globally Harmonized System of
Classification and Labeling of Chemicals (GHS) Rev.10.
Department Issuing MSDS: Dezhou Defu Environment Technology Co., Ltd.
Issue Date: November 20, 2024
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