9724219216

DEV Institute, Gandhinagar

Chapter : 2 Std 12 : Chemistry Date : 08/02/25
Total Marks : 100 MCQs Practice Time : 1 Hour
//X Section A
• Choose correct answer from the given options. [Each carries 1 Mark] [100]
1. Which cell will measure standard electrode potential of copper electrode ?
(A) Pt(s) | H2(g, 0.1 bar) | H+(aq, 1M) || Cu2+
(aq, 1M) | Cu (B) Pt(s) | H2(g, 1 bar) | H+(aq, 1M) || Cu2+
(aq, 2M) | Cu
+ 2+
(C) Pt(s) | H2(g, 1 bar) | H (aq, 1M) || Cu (aq, 1M) | Cu +
(D) Pt(s) | H2(g, 1 bar) | H (aq, 0.1M) || Cu2+
(aq,1M) | Cu
2. Electrode potential for Mg electrode varies according to the equation :

d
– 0.59 1
E = E – log .
Mg 2+ | Mg Mg 2+ | Mg 2 [Mg 2+ ]

The graph of E Mg 2+ | Mg ® log [Mg ] is

2+

®
®
®
®

Mg2+ | Mg
Mg2+ | Mg
Mg2+ | Mg
Mg2+ | Mg

(A) (B) (C) (D)

E
E
E
E

log [Mg 2+ ] ® log [Mg 2+ ] ® log[Mg2+ ] ® log [Mg2+ ] ®

3. Which of the following statement is correct ?

(A) Ecell and ´rG of cell reaction both are extensive properties.
(B) Ecell and ´rG of cell reaction both are specific properties.
(C) Ecell is an specific property while ´rG of cell reaction is an extensive property.
(D) Ecell is an extensive property while ´rG of cell reaction is an specific property.
4. The difference between the electrode potentials of two electrodes when no current is drawn through
the cell is called....
(A) cell potential (B) cell emf (C) potential difference (D) cell voltage
5. Which of the following statement is not correct about an inert electrode in a cell ?
(A) It does not participate in the cell reaction.
(B) It provides surface either for oxidation or for reduction reaction.
(C) It provides surface for conduction of electrons.
(D) It provides surface for redox reaction.
6. An electrochemical cell can behave like an electrolytic cell when .......
(A) Ecell = 0 (B) Ecell > Eext (C) Eext > Ecell (D) Ecell = Eext
7. Which of the statements about solutions of electrolytes is not correct ?
(A) Conductivity of solution depends upon size of ions.
(B) Conductivity depends upon viscosity of solution.
(C) Conductivity does not depend upon solvation of ions present in solution.
(D) Conductivity of solution increases with temperature.
8. Using the data given below find out the strongest reducing agent.
d
– d
–
E 2 - | Cr3+ = 1.33V; E = 1.36V
Cr2O7 Cl 2 | Cl –
d
– d
–
E = 1.51V; E = –0.74V
MnO-
4 | Mn
2+ Cr3+ | Cr

(A) Cl– (B) Cr (C) Cr3+ (D) Mn2+

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 9724219216
9. Use the data given in Q.8 and find out which of the following is the strongest oxidising agent.
(A) Cl– (B) Mn2+ (C) MnO4– (D) Cr3+
10. Using the data given in Q.8 find out in which option the order of reducing power is correct ?
(A) Cr3+ < Cl– < Mn2+ < Cr (B) Mn2+ < Cl– < Cr3+ < Cr
(C) Cr3+ < Cl– < Cr2O2– –
7 < MnO4 (D) Mn2+ < Cr3+ < Cl– < Cr
11. Use the data given in Q.8 and find out the most stable ion in its reduced form.
(A) Cl– (B) Cr3+ (C) Cr (D) Mn2+
12. Use the data of Q.8 and find out the most stable oxidised species.
(A) Cr3+ (B) MnO4– (C) Cr2O2–
7 (D) Mn2+
13. The quantity of charge required to obtain one mole of aluminium from Al2O3 is ...........
(A) 1F (B) 6F (C) 3F (D) 2F
14. The cell constant of a conductivity cell.....
(A) changes with change of electrolyte.
(B) changes with change of concentration of electrolyte.
(C) changes with temperature of electrolyte
(D) remains constant for a cell.
15. While charging the lead storage battery.....
(A) PbSO4 anode is reduced to Pb. (B) PbSO4 cathode is reduced to Pb.
(C) PbSO4 cathode is oxidised to Pb. (D) PbSO4 anode is oxidised to PbO2.
16. æom(NH is equal to ..........
4OH)
o o o o o o
(A) æ m(NH4OH) ö æ m(NH 4Cl) – æ(HCl) (B) æ m(NH4Cl) ö æ m(NaOH) - æ(NaCl)
o o o o o o
(C) æ m(NH 4Cl) ö æ m(NaCl) – æ(NaOH) (D) æ m(NaOH) + æ m(NaCl) – æ(NH4Cl)
17. In the electrolysis of aqueous sodium chloride solution which of the half-cell reaction will occur at
anode ?
d– + d–
+
(A) Na(aq) + e– ® Na(s) ; E cell = –2.71V (B) 2H 2O(l ) ® O2(g) + 4H(aq) + 4e – ; E cell = –1.23V
1 d– – 1 d–
+
(C) H(aq) ö e– ® H 2(g) ; E cell = 0.00V (D) Cl(aq) ® Cl 2(g) + e– ; E cell = 1.36V
2 2
18. ) Which of the following represents nernst equation for given cell.
Mg(s) | Mg2+
(0.130 M) || Ag+(0.000M) | Ag(s)

RT [Mg 2+ ]2 RT [Mg 2+ ]
(A) Ecell = Eocell – log (B) Ecell = Eocell – log
2F [Ag + ] 2F [Ag+ ]2
2.303 RT [Mg 2+ ] RT [Mg 2+ ]
(C) Ecell = Eocell – log (D) Ecell = Eocell – log
2F [Ag + ] 2F [Ag + ]
197)
19. L om for CH3COONa, NaCl and HCl are 91.0, 126.4 and 425.9 S cm2 mol–1 respectively. Calculate L om
CH3COOH.
(A) 390.5 S cm2 mol–1 (B) 208.5 S cm2 mol–1 (C) 461.3 S cm2 mol–1 (D) 643.3 S cm2 mol–1
20. ) What will be the products obtain on anode and cathode during electrolysis of an aqueous solution
of CuCl2 using platinum electrodes.
(A) Cl2(g) liberates on anode and Cu(s) deposites on cathode.
(B) O2(g) liberates on anode and Cu(s) deposites on cathode.
(C) O2(g) liberates on anode and H2(g) liberates on cathode.
(D) Cu(s) dissolve on anode and Cu(s) deposites on cathode.
21. ) Can we use iron container to store Nickel sulphate solution ?
Eo = - 0.44 V, Eo = - 0.25 V
Fe2+ | Fe Ni 2+ | Ni

Wish You
(A) No, As iron acts as anode and nickel acts- All The Best
as cathode.
(B) Yes, As iron acts as anode and nickel acts as cathode.
 ) Can we use iron container to store Nickel sulphate solution ? 9724219216
Eo = - 0.44 V, Eo = - 0.25 V
Fe2+ | Fe Ni 2+ | Ni
(A) No, As iron acts as anode and nickel acts as cathode.
(B) Yes, As iron acts as anode and nickel acts as cathode.
(C) Yes, As iron acts as cathode and nickel acts as anode.
(D) No, As iron acts as cathode and nickel acts as anode.
22. ) In which of the following condition reduction potential of hydrogen half cell will be negative ?
(A) PH2 = 1 atm and [H+] = 1M (B) PH2 = 2 atm and [H+] = 1M
(C) PH2 = 2 atm and [H+] = 2M (D) PH2 = 1 atm and [H+] = 2M
193) If E° Fe3+/Fe = xV and E° Fe2+/Fe = yV then what will be the value of E° Fe3+/Fe2+ ?
23.
(A) 2x + y (B) 3x + 2y (C) x – y (D) 3x – 2y
24. ) Which substance is used as cathode in mercury cell ?
(A) HgO + KOH (B) ZnO + Pt (C) HgO + C (D) ZnO + NaOH
25. ) Which species is obtained at anode on electrolysis of aqueous solution containing higher
concentration of H2SO4.
(A) S2O28– (B) SO23– (C) SO2 (D) S2O23–
26. ) The molar conductivity of 0.025 M methanoic acid is 46.1 S cm 2 mol–1 . Calculate its degree of
dissociation. [l° (H+) = 349.6 S cm 2 mol–1 and l° (HCOO–) = 54.6 S cm 2 mol–1 ]
(A) 0.414 (B) 0.114 (C) 8.767 (D) 7.867
27. ) Which compound acts as an oxidising agent in dry cell ?
(A) MnO2 (B) Zn (C) Mn2O3 (D) NH4Cl
28. ) How much electricity is required in Faraday to produce 40.0 g of Al from molten Al2O3 ? (Atomic
mass of Al = 27 g mol –1)
(A) 4.44 (B) 2.96 (C) 0.225 (D) 1.48
29. ) On which of the following factors, electronic conductance does not depend ?
(A) The nature and structure of metal (B) The number of valance electrons per atom
(C) Temperature (D) Pressure
30. ) How much electricity in terms of Faraday is required to reduce 2 mol of MnO4– to Mn2+ ?
(A) 5 (B) 10 (C) 3 (D) 6
31. ) What is the potential of hydrogen electrode in contact with a solution whose pH is equal to 1 ?
(A) 0.059 V (B) 0.59 V (C) 0.0059 V (D) 5.9 V
32. ) At 298 temperature, in Nernst equation 0.059 value is of :
2.303RT RT RT 2.303R
(A) (B) (C) (D)
F F 2.303F TF
33. ) If current of 0.5 ampere flows through a metallic wire for 2 hours, then how many coloumbs would
have flown through the wire ?
(A) 3000 C (B) 36000 C (C) 360 C (D) 3600 C
34. ) In the following reaction, which is the value of equilibrium constant ?
Cu(s) + 2Ag+(aq) ® Cu2+ o
(aq) + 2Ag(s)E cell = 0.46 V
(A) 3.92 ´ 1015 (B) 39.2 ´ 1015 (C) 3.92 ´ 1010 (D) 3.92 ´ 1014
35. ) For the following cell, standard electrode potential [Eocell] is ...........
Zn / Zn2+ || Cu2+ / Cu
é Eo o ù
êë Zn 2+/Zn = - 0.76 V, ECu2+/Cu = 0.34 V úû
(A) –0.76 V (B) 1.10 V (C) 0.34 V (D) –0.42 V
36. ) Using the data given below find out the strongest reducing agent.
d
– d–
E +4
Mn +2 = 1.23 V ;
| Mn E +3 +2 = 1.81 V
Co | Co
d d
–
E Fe+2 | Fe = –0.44 V ;
–
E Pb+2 | Pb =Wish
–0.13You
V - All The Best
(A) Mn+2 (B) Co+2 (C) Fe (D) Pb
 ) Using the data given below find out the strongest reducing agent. 9724219216
d– d
–
E +4
Mn +2 = 1.23 V ;
| Mn E +3 +2 = 1.81 V
Co | Co
d– d–
E Fe+2 | Fe = –0.44 V ; E Pb+2 | Pb = –0.13 V
(A) Mn+2 (B) Co+2 (C) Fe (D) Pb
179) L°m (NH OH) = ..........
37.
4
(A) L°m(NH + L°m(NH – L°m(HCl) (B) L°m(NH + L°m(NaOH) – L°m(NaCl)
4OH) 4Cl) 4Cl)
(C) L°m(NH + L°m(NaCl) – L°m(NaOH) (D) L°m(NaOH) + L°m(NaCl) – L°m(NH
4Cl) 4Cl)
38. ) While charging the lead storage battery :
(A) PbSO4 on cathode is changed to Pb. (B) PbSO4 on anode is changed to Pb.
(C) PbSO4 on cathode is changed to PbO. (D) PbSO4 on anode is changed to PbO2.
39. ) Which is increasing order of the reducing power of the following metals on the basis of standard
electrode potential ?
Ag+ | Ag = 0.80 V ; Mg2+ | Mg = –2.37 V
Hg2+ | Hg = 0.79 V ; Cr3+ | Cr = –0.74 V
(A) Hg < Ag < Mg < Cr (B) Cr < Mg < Ag < Hg (C) Mg < Cr < Hg < Ag (D) Ag < Hg < Cr < Mg
176) L°
40. m(HAc) is equal to ..........
(A) L°m(AcH) + L°m(KAc) + L°m(NaAc) (B) L°m(HCl) + L°m(NaAc) – L°m(NaCl)
(C) L°m(KCl) + L°m(KAc) – L°m(HCl) (D) L°m(KCl) + L°m(NaAc) – L°m(NaCl)
41. ) An electrochemical cell can behave like an electrolytic cell when .............
(A) Ecell < Eext (B) Ecell > Eext (C) Ecell = Eext (D) Ecell = 0
42. ) What is true for Lom (NH OH) ?
4
(A) Lom(NaOH) + Lom(NH – Lom(HCl) (B) Lom(NH + Lom(NaOH) – Lom(NaCl)
4Cl) 4Cl)
(C) Lom(NH + Lom(NaCl) – Lom(NaOH) (D) Lom(NaCl) + Lom(NH – Lom(NaOH)
4Cl) 4Cl)
43. ) On charging lead storage cell…
(A) Pb of electrode utilize. (B) Solution becomes diluted.
(C) H2SO4 of solution is utilized. (D) PbO2 is deposited on one electrode.
44. ) Ionic conductivity of solution does not depend on which of the following parameter ?
(A) Nature of electrolyte. (B) Nature of solvent.
(C) Concentration of electrolyte. (D) Size of particle obtained in solution.
45. ) Which of the following reaction can be possible with electrochemical cell by using

EoCl – = 1.36 V and EoBr – = 1.09 V

2 | 2Cl 2 | 2Br
(A) Br2 + 2Cl– ® 2Br– + Cl2 (B) 2Br– + Cl2 ® Br2 + 2Cl–
(C) 2Cl– + 2Br– ® Cl2 + Br2 (D) Cl2 + Br2 ® 2Cl– + 2Br–
46. ) Ionic conductivity of electrolyte in water is not depending on which of the following ?
(A) Temperature (B) Concentration of electrolyte
(C) Type of solvent and its viscosity (D) Pressure
47. ) Electrolysis of aqueous solution of Na2SO4 is carried out in presence of graphite electrode.
(A) Na is obtained at cathode. (B) O2 gas is obtained at cathode.
(C) H2 gas is obtained at anode. (D) O2 gas is obtained at anode.
48. ) Which electrode is reactive ?
(A) Graphite (B) Carbon (C) Platinum (D) Silver
49. ) Which solution is filled in salt bridge ?
(A) Solution of dilute CuCl2 (B) Solution of aqueous copper nitrate
(C) Solution of dilute KCl (D) Solution of aqueous ammonium nitrate.
50. ) Determine true statement for Zn – Cu electrochemical cell.
[E° +2 = - 0.76 V, E° +2 = - 0.34 V]
Zn | Zn Cu | Cu Wish You - All The Best
(A) Zinc act as cathode and copper act as anode.
(B) Conduction of electron from copper to zinc electrode.
 ) Determine true statement for Zn – Cu electrochemical cell. 9724219216
[E° +2 = - 0.76 V, E° +2 = - 0.34 V]
Zn | Zn Cu | Cu
(A) Zinc act as cathode and copper act as anode.
(B) Conduction of electron from copper to zinc electrode.
(C) Zinc act as anode and copper act as cathode.
(D) Standard reduction potential of zinc is more than copper.
51. ) How much chlorine is obtained when 0.5 Faraday current is pass through aqueous solution of NaCl ?
(Atomic weight of Cl = 35.5 gm/mol)
(A) 71.0 gm (B) 35.5 gm (C) 142.0 gm (D) 17.75 gm
52. ) What is the SI unit of specific conductivity ?
(A) Sm2 (B) Sm–2 (C) Sm–1 (D) Sm3
53. ) 3 gm of copper metal in cathode is deposited on electrode when 3 ampere current is pass for 2 hours
through aqeous solution of CuSO4. Then what is the efficiency of current ? (Atomic weight of Cu = 63.5
gm/mol)
(A) 33% (B) 48.7% (C) 42.2% (D) 54.4%
54. ) 1.234 gm gold is deposited on electrode when 3 ampere current is pass through solution containing
AuCl–4 ions. So calculate for how long such current should be passed ?
(Atomic weight of Au = 197 gm / mol)
(A) 20 min. (B) 10 min. (C) 30 min. (D) 10 min. 40 sec.
55. ) How much faraday current is required for reduction of 1.5 mol Cr O –2 to Cr3+ ?
2 7
(A) 15 F (B) 9 F (C) 6 F (D) 3 F
56. ) When 6 faraday electricity is pass through aqueous solution of silver nitrate, copper sulphate and
gold chloride (AuCl3), then what ratio of mole of metals obtained at cathode ?
(A) 1 : 1 : 1 (B) 3 : 2 : 1 (C) 1 : 2 : 3 (D) 6 : 3 : 2
57. ) Resistance of conductor having unit meter length and 1 square meter cross sectional area is known
as ...........
(A) Specific resistance (B) Conductivity
(C) Specific conductivity (D) Molar conductivity
58. ) Which products are obtained on electrolysis of concentrated NaCl solution by using graphite as inert
electrode ?
(A) H2 on anode, Cl2 on cathode and NaOH in solution.
(B) O2 on anode and H2 on cathode
(C) Cl2 on anode, Na on cathode and NaOH in solution.
(D) Cl2 on anode, H2 on cathode and NaOH in solution.
59. ) Give symbolic representation of following reaction : Mg(s) + Co2+ 2+
(aq) ƒ Mg (aq) + Co(s)

(A) d- Co(s) | Co(1M) | Mg(s)Å (B) d- Co(s) | Co(1M) || Mg(s) | Mg (aq)(1M)Å

2+ 2+ 2+
|| Mg(s)
2+ Å
(C) d- Mg(s) | Mg(1M)
2+
|| Co(aq) | Co(1M) (D) d- Mg(s) | Mg(1M)
2+ 2+
|| Co(1M) | Co(s)Å
60. ) Which of the following cell has following reaction ?

2H2(g) + O2(g) ® 2H2O(l) + 571.7 kJ

(A) Voltaic cell (B) Galvanic cell (C) Fuel cell (D) Leclanche cell
61. ) Calculate cell potential of electrochemical cell made up of Cr and Na.
Eo = - 0.74V, Eo = - 2.71V
Cr+3/Cr Na+/Na
(A) 3.45 V (B) –1.97 V (C) –3.45 V (D) 1.97 V
62. ) What is the composition of electroconductive pest used in mercury cell ?
(A) Zn-Hg and HgO (B) KOH and Zn-Hg (C) KOH and ZnO (D) HgO and ZnO

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 9724219216
63. ) Molar conductivity of KCl, NaCl and KNO3 are 150, 126 and 109 S cm2 mol–1 respectively, then what is
the molar conductivity of NaNO3 ?
(A) 385 S cm2 mol–1 (B) 133 S cm2 mol–1 (C) 167 S cm2 mol–1 (D) 85 S cm2 mol–1
64. ) Which products are obtained on anode and cathode respectively when electrolysis of concentrated
NaCl solution is carried out using graphite as electrodes ?
(A) Cl 2 and H2 (B) O2 and Na (C) O2 and H2 (D) Cl2 and Na
65. ) Which of the following is responsible for transportation of negative ions in galvanic cell ?
(A) Electrodes (B) Salt bridge
(C) External path with copper wire. (D) Electrons
66. ) The electrochemical cell in which electrodes are same but their electrolytic solutions has different
concentrations, then such solutions are known as……
(A) Electrochemical cell (B) Concentration cell (C) Daniell cell (D) Lead storage cell
67. ) When value of equilibrium constant is more than 1, then for spontaneous reaction…
(A) Concentration of reactant and product is same. (a) > 1
(B) Less product is obtained.(b) 0
(C) More product is obtained.(c) < 1
(D) No product is possible. (d) < 0
68. ) What is the density of H2SO4 solution when lead storage cell stop producing electricity ?
(A) 1.25 – 1.30 gm/ml (B) 1.20 – 1.25 gm/ml (C) 1.10 – 1.15 gm/ml (D) 1.15 – 1.20 gm/ml
69. ) Which of the following chemical reaction occur at anode during electrolysis of higher concentrated
H2SO4 solution ?
– 1 –
(A) H2 O(l ) + e ®
2– 2– –
H 2(g) + 2OH(aq) (B) 2SO 4(aq) ® S 2 O8(aq) + 2e
2
+ –
(C) 2H2O(l ) ® O2(g) + 4H(aq) + 4e (D) S 2 O82– + 2e – ® 2SO 2–
4(aq)
(aq)

70. ) Which of the following is correct Nernst equation for the given electrochemical cell ?
2+ -
Mg(s) | Mg(aq)(0.1M)||Cl(aq)(0.1M)| Cl 2(g)(1 bar)| Pt(s)
– 2
o 0.059 1 o 0.059 [Cl ]
(A) Ecell = Ecell – log 2+ – 2 (B) Ecell = Ecell – log 2+
2 [Mg ][Cl ] 2 [Mg ]
o 0.059 [Mg 2+ ] o 0.059
log[Mg 2+ ][Cl – ]2
(C) Ecell = Ecell – log (D) Ecell = Ecell –
2 – 2
[Cl ] 2
71. ) Resistance of a conductivity cell filled with 0.1 M KCl solution is 100 W and conductivity of solution
is 1.29 s/m. Then what will be the value of conductivity cell constant ?
(A) 1.24 cm–1 (B) 1.29 cm–1 (C) 1.29 m–1 (D) 0.248 m–1
72. ) Which substance is used as oxidizing agent in nickel-cadmium cell ?
(A) Ni (B) Cd (C) Ni(OH)3 (D) CdO
73. ) What is proper value of x for the following to increase cell potential ?
Zn(s) | Zn(2+ 2+
x M) || Cu(0.02M) | Cu (s)
(A) x > 0.02 M (B) x < 0.02 M (C) x = 0.02 M (D) x > 0.02 M
74. ) How much electricity in terms of Faraday is required for reduction of 2 mol of Cr2O72– to Cr3+ in
acidic medium ?
(A) 6 F (B) 3 F (C) 12 F (D) 9 F
2+ -
75. ) Which is symbolic representation for following Mg(s) + Cl2(g) ® Mg(aq) + 2Cl(aq)
2+ – 2+ –
(A) Mg |Mg(aq)(1M) | | Cl(aq)(1M)| Cl2(g)(1 bar) | Pt (B) Mg |Mg(aq) (1M)| | Cl2(g)(1 bar) |Cl(aq)(1M)| Pt
– 2+ – 2+
(C) Pt |Cl(aq)(1M)| Cl2(g)(1 bar)| |Mg(aq)(1M)| Mg (D) Pt |Cl2(g)(1 bar) |Cl(aq)(1M)| |Mg(aq)(1M)| Mg
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 2+ – 2+ –
(A) Mg |Mg(aq)(1M) | | Cl(aq)(1M)| Cl2(g)(1 bar) | Pt (B) Mg |Mg(aq) (1M)| | Cl2(g)(1 bar) |Cl(aq)(1M)| Pt
9724219216
– 2+ – 2+
(C) Pt |Cl(aq)(1M)| Cl2(g)(1 bar)| |Mg(aq)(1M)| Mg (D) Pt |Cl2(g)(1 bar) |Cl(aq)(1M)| |Mg(aq)(1M)| Mg
76. ) Using the data given below find out the strongest reducing agent.
Eo Eo
Cr2O72- /Cr 3+ = 1.33 V ; Cl2 /Cl -
= 1.36 V

Eo Eo
MnO-
4 /Mn
2+ = 1.51 V ; Cr 3+ /Cr
= –0.74 V
(A) Cl– (B) Cr (C) Cr3+ (D) Mn2+
77. ) Which products are obtained during electrolysis of aqueous solution of sodium chloride ?
(A) NaOH, O2 and H2 (B) NaOH, Cl2 and H2 (C) NaOH, Na and H2 (D) Na, Cl2 and H2
78. ) On electrolysis of aqueous solution of a halide of a metal ‘M’ by passing 1.5 ampere current for 10
minutes deposits 0.2938 g of metal. If the atomic mass of the metal is 63 gm/mole, then what will
be the formula of the metal halide ?
(A) MCl2 (B) MCl3 (C) MCl (D) MCl4
79. ) For which of the following electrolytes the graph of Lm against C gives a negative slope ?
(A) Acetic acid (B) Sodium acetate
(C) Ammonium hydroxide (D) Water
80. ) On the basis of the given following electrode potentials, which one is strongest reducing agent ?
Eo o
= 1.33 V ; E MnO-4 | Mn 2+ = 1.51 V
Cr2O72 - | Cr 3+

Eo o
= 1.09 V ; E Zn 2+ | Zn = –0.76 V
Br2 | Br -
(A) Cr3+ (B) Mn2+ (C) Br– (D) Zn
81. ) At what temperature ceramic substance will act as super conductors ?
(A) 0 K (B) 15 K (C) 200 K (D) 150 K
134) If from AlCl3, AgNO3 and MgSO4 solution 1 mole electron is passed, then at what ratio of weight Al,
82.
Ag and Mg will deposit on electrode ?
(A) 3 : 6 : 2 (B) 2 : 6 : 3 (C) 1 : 2 : 3 (D) 3 : 2 : 1
133) Zn(s) |
83. Zn2+
(aq) (1M) || Ni2+
(aq) (1M) | Ni(s),
which of the following is incorrect for a cell ?
(A) Electrochemical cell (B) Voltaic cell (C) Galvanic cell (D) Daniell cell
84. ) To obtain 5.85 gm nickel how long 10 ampere current should be passed through dilute solution of
NiSO4 during electrolysis by inert electrodes ? (Atomic weight of Ni = 58.5 gm)
(A) 965 second (B) 3860 second (C) 1930 second (D) 9650 second
85. ) What is the oxidation potential of given hydrogen half cell at 1 bar pressure and 25°C temperature ?

Pt | H2(g) | HCl(aq) pH = 3
1bar

(A) 0.059 V (B) 0.188 V (C) 0.177 V (D) 0.000 V

86. ) In which metal vessels aqueous CuSO4 solution can be store ?
Eo = 0.34V
Cu 2+ | Cu
Eo o
= 0.44V, E Al | Al 3+ = 1.66V
Fe | Fe 2+

Eo o
= 0.25V, E Ag+ | Ag = 0.80V
Ni | Ni 2+
(A) Ag (B) Ni (C) Fe (D) Al
87. ) During electrolysis of dilute aqueous CuSO4 solution by inert electrode, the pH of solution is …....…

(A) Decreases (B) Increases

(C) Remains constant (D) Decreases after increases.
88. ) Choose correct option for working given cell :

Pt | Cl 2(g) | Cl -(c1 ) || Cl -(c2 ) | Cl 2(g) | Pt

Wish You - All The Best
1 bar 1 bar
(A) C2 > C1 (B) C1 > C2 (C) Eocell = 0 (D) DG = –ve
 ) Choose correct option for working given cell : 9724219216

Pt | Cl 2(g) | Cl -(c1 ) || Cl -(c2 ) | Cl 2(g) | Pt

1 bar 1 bar
(A) C2 > C1 (B) C1 > C2 (C) Eocell = 0 (D) DG = –ve
89. ) Which of the following aqueous solution does not show straight line graph of C ® Lm ?
(A) NaCN (B) HCN (C) NaCl (D) HCl
90. ) How much moles of oxidizing agents are reduced by complete reaction of 63.5 gm of Cu with
concentrated HNO3 solution ?
(Atomic weight of Cu = 63.5 gm mol–1)
(A) 8 (B) 4 (C) 2 (D) 1
91. ) What is the complete charging reaction of Ni-Cd storage cell ?
(A) Cd(s) + 2Ni(OH)4(s) ®CdO2(s) + 2Ni(OH)2 + 2H2O(l)
(B) CdO(s) + Ni(OH)2(s) + H2O(l) ®Cd(s) + 2Ni(OH)3(s)
(C) Cd(s) + 2Ni(OH)3(s) ®CdO(s) + Ni(OH)2(s) + H2O(l)
(D) CdO2(s) + 2Ni(OH)2 + 2H2O(l) ®Cd(s) + 2Ni(OH)4(s)
92. ) Standard reduction potential of x, y and z are 0.75, –0.80 and –0.25 volt respectively. Then which of
the following statement is not true ?
(A) Oxidation of y is carried out by x and y.
(B) Oxidation of x and reduction of z is carried out by y.
(C) Reduction of x and oxidation of y is carried out by z.
(D) Reduction of x is carried out by y and z.
93. ) Oxidation potential of given hydrogen half cell at 25°C is 0.118 V then what is the pH of H+ ion
solution ?
Pt | H2(g) |H+(xM)
1 bar
(A) 1 (B) 2 (C) 3 (D) 4
94. ) Electrolytic cell containing molten nickel chloride and aluminium chloride solutions are arranged in
a series. If on passing same current through both the solution, if 18 gm Al is obtained then how much
Ni is obtained ? (Atomic mass of Al = 27 and Ni = 58.5 gm mol– 1)
(A) 58.5 gm (B) 29.25 gm (C) 117 gm (D) 5.85 gm
95. ) Metals A, B and C has reduction potentials, 0.34 volt, –0.80 volt and –0.46 volt respectively. So give
order of their capacity as reducing agent.
(A) C > A > B (B) A > B > C (C) B > C > A (D) C > B > A
96. ) Resultant solution of electrolysis of concentrated NaCl solution is……
(A) Do not change colour of red or blue litmus paper.
(B) It converts blue litmus to red.
(C) It remains colourless with phenolphtheleine.
(D) It converts red litmus to blue.
97. ) Which of the following cell is concentration cell ?
2+ 2+
(A) Cu(s) |Cu(aq,1M) || Cu(aq,1M) | Cu(s)
2+ 2+
(B) Zn(s) |Zn(aq,0.5M) || Cu(aq,0.1M) | Cu(s)
2+ 2+
(C) Cu(s) |Cu(aq,0.5M) || Cu(aq,0.5M) | Cu(s)

(D) -
d
Pt|H 2 | HCl(aq,0.002M) || HCl(aq,0.005 M) | H2 | Pt Å
(g,1bar) (g,1bar)

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98. ) Which of the following statement is wrong with respect to metallic or electronic conductivity ?
(A) Metallic conductivity is depend on structure and its characteristic.
(B) Conductivity increases with increase in temperature.
(C) Metallic conductivity depends on number of valence electron present in valence cell.
(D) No change is observed in structure of metal during conduction of current.
99. ) Which of the following gives H2 on cathode and O2 on anode on electrolysis by using platinum
electrode ?
(A) Molten NaCl (B) Dilute solution of NaCl
(C) Concentrated solution of NaCl (D) Solid NaCl
100. ) Product of electrolytic cell does not depend on which of the following matter ?

(A) Nature of solvent (B) Temperature

(C) Nature of electrode (D) Concentration of solution

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