Revision date: 16/10/2021

SAFETY DATA SHEET

M1 CLEANING DETERGENT CONCENTRATE

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name M1 CLEANING DETERGENT CONCENTRATE

Product number HLM42

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Detergent. For professional use only.

Uses advised against Not for direct contact with Food or Beverage stuffs. Not for oral consumption.

1.3. Details of the supplier of the safety data sheet

Supplier UK - Holchem Laboratories Ltd. Gateway House, Pilsworth Road,
Bury, BL9 8RD
Tel : +44 (0) 1706 222288; e-mail [email protected]
EU - Kersia Deutschland GmbH, Marie-Curie-Straße 23
53332 Bornheim - Sechtem

1.4. Emergency telephone number

Emergency telephone Emergency Information:-
For accidents and spillages involving this product that pose a threat to the environment, or
human health, or require immediate first aid advice call:- +44(0) 1865 407333.
Note:- This number will not accept order queries or calls dealing with equipment breakdowns.
This product is registered with the NPIS. UK Environment Agency 24hour Advisory Service
0800 807060. Irish Environmental Protection Agency 1890 335599 (This is a Lo Call Number)
This product is registered with the Irish National Poison Centre (NPIC at Beaumont Hospital -
Dublin). The Poison Centre can be contacted between 8am and 10pm, telephone +00353 1
8092566.

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Eye Dam. 1 - H318

Environmental hazards Aquatic Chronic 3 - H412

2.2. Label elements

Hazard pictograms

Signal word Danger

Hazard statements H318 Causes serious eye damage.

H412 Harmful to aquatic life with long lasting effects.

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Precautionary statements P273 Avoid release to the environment.

P280 Wear protective clothing, gloves, eye and face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P313 Get medical advice/ attention.
P404 Store in a closed container.
P501 Dispose of contents/ container in accordance with international regulations.

Contains ETHYLENEDIAMINETETRAACETIC ACID TETRASODIUM SALT, ISO TRIDECANOL

ALCOHOL ETHOXYLATE, COCONUT DIETHANOLAMIDE, LAURYL BETAINE, D-
GLUCOPYRANOSE, OLIGOMERS, DECYL OCTYL GLYCOSIDES

Detergent labelling 5 - < 15% EDTA and salts thereof, 5 - < 15% non-ionic surfactants, < 5% amphoteric
surfactants, < 5% anionic surfactants, < 5% polycarboxylates

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

ETHYLENEDIAMINETETRAACETIC ACID TETRASODIUM 5-9%

SALT
CAS number: 64-02-8 EC number: 200-573-9 REACH registration number: 01-
2119486762-27

Classification
Met. Corr. 1 - H290
Acute Tox. 4 - H302
Acute Tox. 4 - H332
Eye Dam. 1 - H318
STOT RE 2 - H373

ISO TRIDECANOL ALCOHOL ETHOXYLATE 5-10%

CAS number: 69011-36-5 EC number: 931-138-8 REACH registration number: 02-
2119552461-55-0000

Classification
Acute Tox. 4 - H302
Skin Irrit. 2 - H315
Eye Dam. 1 - H318
Aquatic Chronic 3 - H412

COCONUT DIETHANOLAMIDE 1-5%

CAS number: 68603-42-9 EC number: 203-868-0 REACH registration number: 01-
2119490100-53

Classification
Skin Irrit. 2 - H315
Eye Dam. 1 - H318
Aquatic Chronic 2 - H411

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BETA-ALANINE, N-(2 CARBOXYETHYL)-N-DODECYL 1-5%

MONO SODIUM SALT
CAS number: 90170-43-7 EC number: 290-476-8

Classification
Eye Irrit. 2 - H319

LAURYL BETAINE 1-5%

CAS number: 683-10-3 EC number: 211-669-5

Classification
Acute Tox. 4 - H302
Acute Tox. 4 - H312
Skin Irrit. 2 - H315
Eye Dam. 1 - H318

D-GLUCOPYRANOSE, OLIGOMERS, DECYL OCTYL 1-5%

GLYCOSIDES
CAS number: 68515-73-1 EC number: 500-220-1 REACH registration number: 01-
2119488530-36-XXXX

Classification
Eye Dam. 1 - H318

GLYCERINE <1%
CAS number: 56-81-5 EC number: 200-289-5 REACH registration number: 01-
2119471987-18-XXXX

Classification
Not Classified

SODIUM HYDROXIDE <1%

CAS number: 1310-73-2 EC number: 215-185-5 REACH registration number: 01-
2119457892-27

Classification
Met. Corr. 1 - H290
Skin Corr. 1A - H314
Eye Dam. 1 - H318

The full text for all hazard statements is displayed in Section 16.
Composition comments To the best of our knowledge, all of the substances used in this product are being supported
for the relevent application in REACH.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information For immediate First Aid advice in the UK, dial 111. When it is safe to do so, remove victim
immediately from source of exposure. However, consideration should be given as to whether
moving the victim will cause further injury.

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Inhalation Remove affected person from source of contamination. Move affected person to fresh air and
keep warm and at rest in a position comfortable for breathing. If breathing stops, provide
artificial respiration. Get medical attention if any discomfort continues.

Ingestion Do not induce vomiting. Rinse mouth thoroughly with water. Place unconscious person on the
side in the recovery position and ensure breathing can take place. Get medical attention.

Skin contact Remove contaminated clothing that is not stuck to the skin. Flush area with clean water. Get
medical attention if any discomfort continues.

Eye contact Remove any contact lenses and open eyelids wide apart. Rinse immediately with plenty of
water. Continue to rinse for at least 15 minutes and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
General information Neat product may cause irritation to skin and eyes. Dilute chemical may result in mild
irritation to skin. Contact of dilute chemical with eyes should still be treated as outlined above.

Inhalation Unlikely route of exposure. Inhalation of sprayed droplets may result in soreness of the throat,
mouth and nose.

Ingestion Unlikely route of exposure without deliberate abuse. If neat chemical is ingested, irritation of
the mouth, throat and GI tract may occur. If dilute chemical is ingested some soreness of the
mouth, throat and GI tract may occur.

Skin contact Prolonged or repeated contact with skin may cause irritation, redness and dermatitis.

Eye contact May cause irritation to the eyes. May result in permanent eye damage.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Rinse well with water to neutral pH.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media The product is non-combustible. Use fire-extinguishing media suitable for the surrounding fire.

5.2. Special hazards arising from the substance or mixture

Specific hazards The product is non-combustible. Irritating gases or vapours.

5.3. Advice for firefighters

Protective actions during Protective clothing and respiratory protection should be worn when tackling fires involving this
firefighting product. Control run-off water by containing and keeping it out of sewers and watercourses.

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet.

6.2. Environmental precautions

Environmental precautions Spillages or uncontrolled discharges into watercourses must be reported immediately to the
Environmental Agency or other appropriate regulatory body. Avoid or minimise the creation of
any environmental contamination.

6.3. Methods and material for containment and cleaning up

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Methods for cleaning up Stop leak if possible without risk. Absorb in vermiculite, dry sand or earth and place into
containers. Collect and place in suitable waste disposal containers and seal securely. For
waste disposal, see Section 13. Containers with collected spillage must be properly labelled
with correct contents and hazard symbol.

6.4. Reference to other sections

Reference to other sections See sections 8,12 & 13

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Wear suitable protective equipment for prolonged exposure and/or high concentrations of
vapours, spray or mist. Read and follow manufacturer's recommendations.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Keep container tightly closed. Keep only in the original container. Store in a demarcated
bunded area to prevent release to drains and/or watercourses.

7.3. Specific end use(s)

Specific end use(s) Detergent, refer to Product Information Sheet for full details.

Usage description This product is suitable for cleaning food process plants, it is not suitable for direct food
contact.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Occupational exposure limits
GLYCERINE
Long-term exposure limit (8-hour TWA): WEL 10 mg/m³ mist
SODIUM HYDROXIDE
Short-term exposure limit (15-minute): WEL 2 mg/m³
WEL = Workplace Exposure Limit.

Ingredient comments Where an exposure level is quoted, a risk assessment should consider if there is a need to
monitor the atmosphere of the working environment. Results should be compared against the
WEL and/or DNEL information provided. The Long Term WEL refers to total exposure of a
worker to a specific substance averaged out over an 8 hour period.
The Short Term WEL refers to a single exposure of a worker to a specific substance over a 15
minute period.
If the Short Term WEL is exceeded and no Long Term Limit is set, further exposure during the
working shift is not permitted. Further controls should be implemented to ensure that future
exposure to the substance is reduced below the levels set before the activity is
repeated/continued. Where no Short Term WEL exists, guidance from the HSE is to use a
value of three times the Long Term WEL.
The WEL limits are laid down in the EH40 list as supplied by the HSE. Where a worker is
exposed to levels approaching a limit, further exposure control measures should be
considered to reduce exposure to the substance. DNEL and/or PNEC information is supplied
by manufacturers of substances in accordance with REACH legislation (Regulation (EC) No
1907/2006) , and is used to provide suitable risk reduction measures to limit exposure of the
user of the substance to a non hazardous level. If the measured level of exposure by a route
divided by the DNEL for the route is greater than 1, then further exposure controls should be
implemented as described in section 8.2. Where new information becomes available under
REACH, this will be passed on as revisions to the Safety Data Sheet.

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ETHYLENEDIAMINETETRAACETIC ACID TETRASODIUM SALT (CAS: 64-02-8)

DNEL Professional - Inhalation; Long term systemic effects: 1.5 mg/m³

PNEC - Fresh water; 2.86 mg/l

- marine water; 0.286 mg/l
- Intermittent release; 1.56 mg/l
- Soil; 0.937 mg/kg, mg/kg dwt
- STP; 55.94 mg/kg

COCONUT DIETHANOLAMIDE (CAS: 68603-42-9)

DNEL Professional - Dermal; Long term systemic effects: 4.16 mg/kg/day

Professional - Dermal; Short term local effects: 0.09 mg/cm2
Professional - Inhalation; Long term systemic effects: 73.4 mg/m³

PNEC - Intermittent release; 0.024 mg/l

- Fresh water; 0.0024 mg/l
- marine water; 0.00024 mg/l
- STP; 0.83 mg/l

SODIUM ARYL SULPHONATE (CAS: 1300-72-7)

DNEL Workers - Dermal; Long term systemic effects: 136.25 mg/kg/day

Workers - Inhalation; Long term systemic effects: 26.9 mg/m³
Workers - Dermal; Long term local effects: 0.096 mg/cm²
General population - Inhalation; Long term systemic effects: 6.6 mg/m³
General population - Dermal; Long term systemic effects: 68.1 mg/kg
General population - Dermal; Long term local effects: 0.048 mg/cm²
General population - Oral; Long term systemic effects: 3.8 mg/kg/day

PNEC - Fresh water; 0.23 mg/l

- marine water; 0.023 mg/l
- Intermittent release; 2.3 mg/l
- Sediment, Fresh water; 0.862 mg/kg
- Sediment, marine water; 0.0862 mg/kg
- Soil; 0.037 mg/kg
- STP; 100 mg/l

GLYCERINE (CAS: 56-81-5)

DNEL Industry - Inhalation; Long term local effects 56mg/m3

PNEC
Fresh water 0.885 mg/l
Marine water 0.0885 mg/l
Sediment (Freshwater); 3.3 mg/Kg
Sediment (Marinewater); 0.33mg/Kg
STP; 1000mg/l
Soil; 0.141 mg/Kg

SODIUM HYDROXIDE (CAS: 1310-73-2)

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DNEL Industry - Inhalation; Long term local effects: 1.0 mg/m³

DNEL data for Professional users is not yet available, but it is assumed to be the
same as for Industrial users.
Industry - Dermal; Short term local effects: 2%

PNEC No information is available for PNEC data for Sodium Hydroxide

8.2. Exposure controls

Protective equipment

Appropriate engineering Provide adequate general and local exhaust ventilation.

controls

Personal protection The PPE indicated above is not a COSHH assessment. It represents PPE that should be
considered during the manufacture, distribution, use and final disposal stages of this product's
life cycle. It is the responsibility of employers to conduct a COSHH/risk assessment to
determine appropriate PPE levels. The information given below should be used to support
this assessment. Where possible replace manual processes with automated or closed
processes to minimise contact with the product.

Eye/face protection The following protection should be worn: Chemical splash goggles. Refer to EN Standard 166
to select appropriate level of protection.

Other skin and body Provide eyewash station. Wear suitable protective clothing as protection against splashing or
protection contamination. Reference to EN 13832 and EN 943 is useful when selecting footwear and
clothing.

Hygiene measures Promptly remove non-impervious clothing that has become contaminated, provided it is not
adhered to the skin. Wash contaminated clothing before reuse. Provide eyewash station and
safety shower.

Respiratory protection No specific recommendation made, but respiratory protection must be used if the general
level exceeds the Workplace Exposure Limit. In the case of dust or aerosol formation (eg
spraying), or vapour from hot vessels, use respiratory protection with an approved filter (P2).

Environmental exposure Do not allow the substance to contaminate surface water/ground water. See points 6, 12 &13.
controls

General Health and Safety Normal use solutions will be unclassified. A full Risk Assessment should be carried out before
Measures. handling any chemical(s). Risk Assessments should refer to COSHH, and any other relevant
legislation or industry specific guidelines governing the use of chemicals. Use of gloves and
eye protection is recommended as minimum PPE for use solutions.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Clear liquid.

Colour Green

Odour Indistinct.

Odour threshold Not applicable.

pH Concentrated Solution pH 10 - 11 Use Solution pH 8.5 - 9.5

Melting point Not applicable.

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Initial boiling point and range Not applicable.

Flash point Not applicable. Contains no Flammable Components

Evaporation rate Not applicable.

Evaporation factor Not applicable.

Flammability (solid, gas) Not applicable.

Upper/lower flammability or Not applicable.

explosive limits

Other flammability Not applicable.

Vapour pressure Not applicable.

Vapour density Not applicable.

Relative density 1.055 - 1.065 @ 20 Degrees C

Bulk density Not applicable.

Solubility(ies) Soluble in water.

Partition coefficient Not applicable. Not technically practical for mixtures.

Auto-ignition temperature Not applicable.

Decomposition Temperature Not applicable.

Viscosity Not determined.

Explosive properties Not applicable.

Explosive under the influence Not considered to be explosive.

of a flame

Oxidising properties Not applicable. Contains no Oxidising Components.

9.2. Other information

Refractive index Not applicable.

Particle size Not applicable.

Molecular weight Not applicable.

Volatility Not applicable.

Saturation concentration Not applicable.

Critical temperature Not applicable.

Volatile organic compound Not applicable.

Explosive Properties Not Classified as Explosive

Storage Temperature Range 0 to 40 Degrees C

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity Not expected to react when correctly stored and used. Mixing with other chemicals may
produce unexpected reactions.

10.2. Chemical stability

Stability Stable at normal ambient temperatures and when used as recommended. - See note 10.6.

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10.3. Possibility of hazardous reactions

Possibility of hazardous Refer to section 10.1. Do not mix with Hypochlorite based chemicals, this could result in a
reactions dangerous heating of the solution.

10.4. Conditions to avoid

Conditions to avoid Avoid excessive heat for prolonged periods of time.

10.5. Incompatible materials

Materials to avoid Strong acids. Chlorinated detergents.

10.6. Hazardous decomposition products

Hazardous decomposition Does not decompose when used and stored as recommended. - See section 10.5.
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity - oral
ATE oral (mg/kg) 7,292.14

Acute toxicity - dermal

ATE dermal (mg/kg) 53,921.57

Acute toxicity - inhalation

ATE inhalation (dusts/mists 24.67
mg/l)

Respiratory sensitisation
Respiratory sensitisation No evidence of respiratory sensitisation for any component of this formulation.

Skin sensitisation
Skin sensitisation No evidence of skin sensitisation for any component of this formulation.

Carcinogenicity
Carcinogenicity The components of this formulation will not be systemically available in the body under normal
conditions of handling. As a consequence it is not expected to cause cancer.

Reproductive toxicity
Reproductive toxicity - fertility The components of this formulation will not be systemically available in the body under normal
conditions of use and handling. As a consequence it is not expected to be toxic to the
reproductive system or developing foetus.

General information See section 4.2.

Inhalation Unlikely route of exposure. Inhalation of sprayed droplets may result in soreness of the throat,
mouth and nose. - See section 4.2.

Ingestion Will cause severe irritation to mouth, throat and GI-Tract.

Skin contact Prolonged contact may cause redness, irritation and dry skin.

Eye contact Risk of serious damage to eyes. May cause permanent eye injury.

SECTION 12: Ecological information

Ecotoxicity Harmful to aquatic life with long lasting effects.

12.1. Toxicity

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Acute aquatic toxicity

Acute toxicity - fish Normal use of diluted product is unlikely to pose a risk.

12.2. Persistence and degradability

Persistence and degradability The surfactant(s) used in this preparation complies (comply) with the biodegradability criteria
as laid down in the European Detergents Regulation No 648/2004 as amended.

12.3. Bioaccumulative potential

Bioaccumulative potential Not expected to bioaccumulate.

Partition coefficient Not applicable. Not technically practical for mixtures.

12.4. Mobility in soil

Mobility The product contains substances which are water soluble and may spread in water systems.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects

Other adverse effects Not determined.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information When handling waste, the safety precautions applying to handling of the product should be
considered. Disposal of this product, process solutions, residues and by-products should at all
times comply with the requirements of environmental protection and waste disposal legislation
and any local authority requirements. Do not mix with other chemicals.

Disposal methods Small volumes of use solution can be disposed of to sewers.

SECTION 14: Transport information

General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, ADR/RID).

14.1. UN number
Not applicable.

14.2. UN proper shipping name

Not applicable.

14.3. Transport hazard class(es)

No transport warning sign required.

14.4. Packing group

Not applicable.

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

No.

14.6. Special precautions for user

Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code

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Transport in bulk according to Not applicable.

Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations UK Adoption and Implementation of the UN Globally Harmonised System (GHS) on
Classification and Labelling of Chemicals (GB CLP) and considers UK National REACH
legislation.

EU legislation European Regulation (EC) No 1272/2008 (as amended) on Classification, Labelling and
Packaging of Substances and Mixtures.
Also considered is the REACH Regulation (EC) No.1907/2006 (as amended).

15.2. Chemical safety assessment

Pcs Information

No chemical safety assessment has been carried out.

SECTION 16: Other information

Abbreviations and acronyms (EC) No. 1272/2008 : EU Regulation on Classification, Labelling and Packaging of
used in the safety data sheet Substances and Mixtures.
NPIS - National Poisons Information Service.
vPvB - Very Persistent, Very bioaccumulative.
PBT - Persistent, Bioaccumulative & Toxic.
REACH - Registration, Evaluation, Authorisation & restriction of CHemicals (Regulation EC
1907/2006).
DNEL - Derived No Effect Limit.
PNEC - Predicted No Effect Concentration.
COSHH - Control of Substances Hazardous to Health.
Industry - Refers in section 8 to application of the substance in an industrial process.
Professional - Refers in section 8 to application/use of the preparation/product in a skilled
trade premises.

General information This document is a Safety Data Sheet, NOT a CoSHH assessment. It is the customer's
responsibility to conduct a full CoSHH assessment, taking into account the information held
within this document along with other local factors considered in a risk assessment. The Risk
and Hazard statements listed below are the full text of abbreviations used in this document.
They are not the final classification, for this refer to section 2.

Revision comments Amendment to the emergency phone number in Section 1.4.

Revision date 16/10/2021

SDS number 23676

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Hazard statements in full H290 May be corrosive to metals.

H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H373 May cause damage to organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

REACH extended MSDS REACH requires that persons handling chemicals should take the necessary risk
comments management measures, in accordance with assessments from manufacturers and importers
of chemical substances. The relevent recommendations must be passed along the supply
chain. These assessments are generally reported in Exposure Scenarios.
Where Exposure Scenarios have been provided for substances used in this product, the
relevent information is incorporated into the safety data sheet.

END OF SAFETY DATA

SHEET

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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