1 2 Guided Notes TE Kinetic Molecular Theory of Matter
1 2 Guided Notes TE Kinetic Molecular Theory of Matter
Matter is made up of particles which are in constant, random motion. It can be defined as anything
which has mass or occupies space. Matter is classified by its state and type, of which there are three
main types – solid, liquid and gas.
Liquid Gas
Solid
These substances take These substances
These substances have the shape of their spread out to occupy
their own shape. container. available space within
e.g. sulfur, copper their container.
e.g. water, alcohol,
wire, ice bromine, mercury. e.g. oxygen, carbon
dioxide and helium
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In the liquid state, there are weak forces which hold it together. The greater energy of the
particles and the weaker forces allows for the disruption of the lattice and particles are,
therefore able to slide past one another.
In the gaseous state, particles possess even higher energy levels and the forces which hold
the gas together are negligible. This explains why gases are able to isolate themselves
completely from one another and have no fixed size or shape.
Changes in State
Changes in state (also called phase transitions) involve
heat energy being supplied to or removed from the
substance. Increasing the amount of heat energy in a
substance increases its kinetic energy since
temperature is a measure of the amount of kinetic
energy possessed by a substance. In a solid, heat
energy causes the particles to vibrate at a greater rate
until they possess sufficient energy to break away from
their fixed position and become a liquid (known as
melting). The temperature at which this occurs is called
a substances melting point. As heat is removed from
the liquid, the particles return to their closely-packed,
fixed positions, this process is called freezing.
When heat energy is supplied to a liquid, the particles also take on more heat energy which causes
them to move around at a greater speed. Fast-moving particles at the surface of the liquid
eventually have sufficient energy to escape from the liquid and move into the gaseous state. Here,
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these particles move rapidly, at a large distance from the other particles. This process is known as
vaporisation. The point at which a substance moves from the liquid to the gas state is known as its
boiling point. As heat is removed from the substance the particles move closer together once more,
this process is called condensation.
Some substances e.g. iodine crystals are able to change from a solid directly into a gas, without
moving through the liquid state. This process is called sublimation. Deposition is the reverse of
sublimation and occurs when a substance moves directly from a gas to a solid, omitting the liquid
state. An example of this can be seen in sub-zero temperatures, where water vapor in the air
changes directly into ice, without first becoming a liquid.
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