Plsnt Desing Assignmnet
Plsnt Desing Assignmnet
Group 05
SUBMITTED TO:
DR AHSAN
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ABSTRACT
This report presents the detailed design of a 100 MMSCFD acid gas removal unit
(AGRU) for natural gas processing, focusing on the removal of hydrogen sulfide (H₂S)
and carbon dioxide (CO₂) using amine-based solvent technology. The process design
includes absorber column, a flash separator, and a lean/rich amine heat exchanger,
with both tray and packed column configurations evaluated. The report outlines key
design parameters such as column diameter, stage numbers, pressure drops, and
equipment specifications, aligning with industrial standards and safety requirements.
Optimization strategies such as lean amine polishing filters and oxygen scavenger
dosing are proposed to address solvent degradation and corrosion in the regeneration
section. Furthermore, the design incorporates future-ready features including modular
equipment layout, integration potential for carbon capture utilization and storage
(CCUS), and Industry 4.0 technologies for predictive maintenance. Overall, this
design ensures operational efficiency, environmental compliance, and scalability for
future demands in gas treatment facilities.
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Table of Contents
ABSTRACT ...................................................................................................................... 2
INTRODUCTION ............................................................................................................. 5
3.1.7 Tray vs. Packed Column Comparison for Amine-Based Acid Gas Removal....... 20
3.3.3 Comparison: Shell and Tube vs. Plate and Frame Heat Exchangers .................... 26
3.3.4 HTRI Report for Shell and Tube Heat Exchanger ................................................ 27
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CREATIVE OPTIMIZATION ........................................................................................ 29
5.2 Decarbonization: Utilization Potential of Acid Gases in Future Plant Designs ........... 32
CONCLUSION ............................................................................................................... 35
REFERENCE .................................................................................................................. 36
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INTRODUCTION
Acid gas refers to any gas mixture that contains significant amounts of acidic components,
primarily hydrogen sulfide (H₂S) and carbon dioxide (CO₂). These gases are commonly
found in natural gas reservoirs, refinery off-gases, biogas, and various industrial
processes. H₂S is particularly hazardous due to its high toxicity , while CO₂, though non-
toxic, contributes to corrosion and lowers the heating value of fuel gases. Other minor
acidic components like carbonyl sulfide (COS), carbon disulfide (CS₂), and sulfur dioxide
(SO₂) may also be present in trace quantities. [1]
The presence of acid gases poses several challenges. They are corrosive, especially when
moisture is present, as they form weak acids that attack pipelines, compressors, and
process equipment. H₂S is highly toxic; exposure to even small concentrations can cause
serious health risks or be fatal. Additionally, acid gases contribute to environmental
pollution, including acid rain and greenhouse gas emissions, making their removal from
gas streams both a safety and environmental necessity. [1]
To remove acid gases from process streams, several technologies are employed. The most
common is amine treating, where chemical solvents like monoethanolamine (MEA),
diethanolamine (DEA), or methyldiethanolamine (MDEA) absorb H₂S and CO₂. Other
methods include physical solvents like the Selexol process, membrane separation for
selective removal, cryogenic processes for CO₂ removal, and solid bed adsorption using
materials such as activated carbon or molecular sieves. [2]
Globally, environmental agencies such as the EPA and occupational health organizations
like OSHA have set strict limits on the emissions and workplace exposure levels of H₂S
and CO₂. Compliance with these regulations, along with the use of advanced treatment
technologies, ensures that acid gas is managed in a way that protects both human health
and the environment.
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PROCESS DESCRIPTION
The process begins with the sour gas feed entering the absorber column from the bottom.
Inside the absorber, the sour gas flows upward in counter-current contact with a lean
amine solvent entering from the top. As they interact, the acid gases are absorbed into
the solvent. The treated sweet gas exits from the top of the absorber
The rich solvent, now loaded with absorbed acid gases, exits from the bottom of the
absorber. It is depressurized through a valve and sent to a flash drum, where light
hydrocarbons and flash gases are separated and removed from the system as flash gas.
The liquid phase, referred to as the regen feed, continues to a lean/rich heat exchanger,
where it is preheated by exchanging heat with the hot regenerated solvent stream.
The preheated rich solvent enters the stripper column. At the bottom of the stripper, a
reboiler supplies heat (with steam input) to strip the acid gases from the solvent. The acid
gases rise to the top of the stripper and pass through a condenser, where vapors are
partially condensed. The mixture enters a reflux drum, where the condensed liquid is
separated and returned to the stripper as reflux, while the uncondensed acid gas exits the
system.
The regenerated lean amine leaves the bottom of the stripper. It is pressurized by a booster
pump, passes through the lean/rich heat exchanger (providing heat to the incoming rich
solvent), and is then cooled in a lean solvent cooler. The cooled lean amine is pumped
by a lean amine pump back into the absorber, completing the continuous loop. Make-up
solvent is introduced before the solvent returns to the absorber to maintain the system's
solvent balance and compensate for any losses.
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2.1 Process Flow Diagram
V-101
8
7
T-101
P-100
6
MIX-100
E-100
9
10
P-101
5
V-100
11
4
E-101
3
T-100
VLV-100
2
Figure 2.1 Process Flow Diagram of Acid Gas Removal Unit Using Chemical Solvent
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Abbreviation Sheet of PFD
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EQUIPMENT DESIGN
3.1 Absorber
The absorber operates based on the principle of mass transfer, facilitated by the
difference in partial pressure of the target gas component between the gas and
liquid phases. Typically, the gas stream enters the bottom of a vertical absorption
column, while the liquid solvent commonly an amine solution enters from the top.
This creates a counter-current flow, maximizing contact time and driving force for
mass transfer.
4. Flooding: Excessively high vapor flow rates can push the liquid upward, causing
a buildup of liquid within the column. This results in a sharp pressure drop, loss
of separation efficiency, and potential equipment damage.
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3.1.3 Standard Design steps:
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3.1.4 Absorber Design Calculation of Tray Column [3],[4]
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12
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15
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3.1.5 Key Findings from Absorber Tray Column Design
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3.1.6 Calculation for Packed Column Absorber
Parameter Value
2. Packing Type
3. Summary of Results
Height 20 m 10.1 m
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3.1.7 Tray vs. Packed Column Comparison for Amine-Based Acid Gas
Removal
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3.2 FLASH SEPARATOR
A flash separator, also known as a rich amine flash tank, is an essential unit operation
within Acid Gas Removal Units (AGRUs). It functions as a gravity-based phase separator,
primarily used to remove light hydrocarbons and flash gases from the rich amine stream
before it enters the regenerator.
The rich amine stream exiting the absorber enters the flash separator, where it
undergoes a pressure reduction. This pressure drop causes partial vaporization
(flashing) of light hydrocarbons and dissolved gases. The vapor phase, containing
flash gases and hydrocarbons, exits from the top of the vessel and is typically
routed to a flare or recovery system. The degassed rich amine is withdrawn from
the bottom of the separator and pumped to the regenerator for acid gas removal.
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3.2.3 Comparison: Vertical vs. Horizontal Flash Separator in AGRU
Typical Use in AGRU Less common for amine Most common for amine
flash tanks. flash tanks.
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3.2.4 Design Calculation of Horizontal Separator [3], [5]
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3.3 Lean Amine Heat Excahnger
The shell and tube heat exchanger is a widely utilized type of indirect heat exchanger,
designed to facilitate heat transfer between two fluid streams without direct contact. One
fluid flows through a bundle of tubes, while the other flows across the shell side, enabling
efficient thermal exchange. Due to its robust design, ease of maintenance, and high
thermal efficiency, it is extensively used in industrial gas processing applications,
including acid gas removal units (AGRUs).
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3.3.2 Operating Principle
The exchanger typically operates with hot lean amine (from the regenerator)
flowing through the tube side, while the cold rich amine (from the absorber) flows
through the shell side. As the two streams pass in counter-current or cross-flow
configuration, heat is transferred from the lean to the rich amine:
The rich amine stream increases in temperature, enhancing desorption efficiency
in the stripper.
The lean amine stream is cooled before re-entering the absorber, improving
absorption performance.
This heat recovery step is essential for maximizing thermal efficiency and
maintaining the economic and operational sustainability of the AGRU.
3.3.3 Comparison: Shell and Tube vs. Plate and Frame Heat Exchangers
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3.3.4 HTRI Report for Shell and Tube Heat Exchanger
2.1
5.0
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CREATIVE OPTIMIZATION
4.1 Optimization of Regeneration System
One of the primary operational challenges in amine-based acid gas treatment systems is
corrosion and chemical degradation in the regeneration section, particularly in the
stripper column, reboiler, and heat exchangers. These issues not only affect the longevity
of the equipment but also lead to excessive amine losses, increased operating costs, and
unexpected shutdowns. Corrosion in this section is primarily driven by degraded amine
products, heat-stable salts (HSS), organic acids, and dissolved metal ions—many of
which accumulate as the solvent ages and cycles through the process.
To mitigate these issues without modifying the core acid gas removal process, two
complementary and innovative solutions are proposed for integration:
1. Lean Amine Polishing Filter System
2. Oxygen Scavenger Dosing in the Rich Amine Line
These solutions aim to break the degradation-corrosion cycle at its root, thereby reducing
regeneration energy consumption indirectly (by maintaining a healthier solvent) and
significantly lowering corrosion and fouling rates in the hot parts of the plant.
While corrosion occurs primarily in the regeneration section (due to heat and acidic
conditions), the causes of corrosion originate from chemical contaminants that
circulate throughout the entire amine loop. Over time, the solvent accumulates
degradation products such as organic acids, heat-stable salts, metallic ions (e.g.,
Fe²⁺, Cu²⁺), and fine particulates that enter from upstream gas or form in situ due
to oxidation or thermal breakdown.
The lean amine polishing filter system, although physically installed on the lean
amine line before it re-enters the absorber, plays a key role in preventing this
damage in the stripper and reboiler. This is because the filtered lean amine, once
injected into the absorber, becomes the rich amine that flows into the regeneration
section. Therefore, if the lean amine is clean, the rich amine entering the stripper
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will also be clean, thus carrying fewer corrosive impurities into the high-
temperature zone.
Thus, even though the polishing filter is physically upstream of the absorber, its
benefit is directly realized downstream in the regeneration section, where the
thermal degradation reactions are most severe. This proactive solvent
conditioning helps maintain a chemically stable, less corrosive rich amine that
greatly reduces corrosion risk in the stripper and associated equipment.
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To eliminate this threat, the proposed design includes controlled injection of
oxygen scavengers, such as sodium sulfite (Na₂SO₃) or hydrazine (N₂H₄), into the
rich amine stream ideally after the flash drum and just before the lean/rich amine
exchanger. These scavengers chemically react with and neutralize dissolved
oxygen, preventing it from reaching the high-temperature regeneration zone.
The reaction between oxygen and sodium sulfite, for instance, proceeds as:
This process converts a corrosive component (O₂) into a stable and non-corrosive
sulfate salt. In practice, oxygen scavenger dosing systems are compact,
inexpensive, and easily controlled through inline sensors that monitor dissolved
oxygen concentration. They require no modification to existing process piping and
can be installed as skid-mounted units during plant construction or added as
retrofits.
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FUTURE-READY PLANT DESIGN
To ensure long-term efficiency, scalability, and compliance with evolving industry
standards, the 100 MMSCFD natural gas treatment plant has been designed with a future-
ready approach. Key considerations include modularity for expansion, potential utilization
of acid gases in decarbonization strategies, and integration of Industry 4.0 technologies
for advanced operations and maintenance.
The plant layout is developed with a modular design philosophy, in which critical
processing units such as absorbers, regenerators, and heat exchangers are configured as
skid-mounted modules. These modules are self-contained units that can be prefabricated,
easily installed, and replaced or duplicated to scale up capacity.
This modular approach ensures that future capacity increases can be implemented with
reduced capital expenditure, minimized downtime, and enhanced operational flexibility.
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5.2.1 Potential Utilization Pathways
1. Economic Value Creation: Converts what would otherwise be waste streams into
saleable products, diversifying revenue sources.
2. Environmental Compliance and Decarbonization: Enhances the plant’s
sustainability by reducing emissions and supporting global climate objectives.
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3. Integration with CCUS Strategies: Aligns with emerging trends in carbon
management through Carbon Capture, Utilization, and Storage (CCUS).
4. Operational Flexibility and Future-readiness: Prepares the plant for integration
with low-carbon technologies and evolving market demands.
5. Reduction of Environmental Liabilities: Minimizes risks associated with flaring
or venting of acid gases, improving the plant’s environmental performance.
The plant incorporates Industry 4.0 principles by integrating IoT-enabled sensors for
continuous monitoring of critical process and mechanical equipment. Sensors are
installed on assets such as compressors, pumps, and heat exchangers to measure key
parameters including vibration, temperature, pressure, and flow rate.
This real-time data is analyzed using predictive maintenance software that detects
anomalies and anticipates equipment failures before they occur. Maintenance activities
can therefore be scheduled proactively, reducing the risk of unplanned shutdowns and
improving overall plant reliability. Additionally, remote monitoring capabilities enhance
operator safety and operational transparency, especially for remote or offshore
installations.
The use of IoT and predictive analytics reduces maintenance costs, extends equipment
life, and ensures consistent, safe, and efficient plant operation.
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CONCLUSION
The design of the 100 MMSCFD acid gas removal plant successfully addresses the
technical, operational, and environmental challenges associated with treating sour
natural gas. By employing amine-based absorption and regeneration systems, the plant
achieves effective removal of CO₂ and H₂S, ensuring that the treated gas meets
pipeline and environmental specifications. Detailed equipment sizing and
performance evaluation for both tray and packed columns confirm that the design falls
within industry-recommended parameters, offering flexibility for implementation
based on operational priorities. Creative optimization through lean amine filtration
and oxygen scavenging significantly enhances system reliability and solvent
longevity, while reducing corrosion risks and maintenance costs. The integration of
modular design elements and smart sensor technologies ensures the plant is adaptable
to future expansion, decarbonization goals, and digital operational strategies. This
forward-thinking design not only fulfills current processing needs but also aligns with
the evolving landscape of sustainable and intelligent natural gas treatment.
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REFERENCE
[1] R. M. R. S. S. M. L. A. S. F. M. Z. S. S. M. W. u. H. N. e. H. a. B. A. Abid Salam
Farooqi, "Removal of Carbon Dioxide and Hydrogen Sulfide from Natural Gas
Using a Hybrid Solvent of Monoethanolamine and N-Methyl 2-Pyrrolidone,"
ACS Omega , vol. 9, p. 25704−25714, 2024.
[4] E. E. Ludwig, Applied Process Design for Chemical and Petrochemical Plants, vol.
2, 3rd ed. Butterworth-Heinemann, 1997.
[5] Gas Processors Suppliers Association, GPSA Engineering Data Book, 12th ed. Tulsa,
OK: Gas Processors Suppliers Association, 2004
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