The document is a chemistry assignment covering basic concepts including calculations of mass, significant figures, definitions of mole, molality vs molarity, and various chemical reactions. It includes questions on stoichiometry, limiting reagents, and laws of chemical combinations, such as the law of multiple proportions. Additionally, it requires calculations related to solutions, molarity, and gas volumes at STP.
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Chemistry Assignment
The document is a chemistry assignment covering basic concepts including calculations of mass, significant figures, definitions of mole, molality vs molarity, and various chemical reactions. It includes questions on stoichiometry, limiting reagents, and laws of chemical combinations, such as the law of multiple proportions. Additionally, it requires calculations related to solutions, molarity, and gas volumes at STP.
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CHEMISTRY ASSIGNMENT
SOME BASIC CONCEPTS OF CHEMISTRY (UNIT-1)
1. What will be the mass of one atom of C-12 in grams? 2. How many significant figures should be present in the answer of the following calculations? 2.5×1.25×3.5/ 2.01 3. What is the symbol for SI unit of mole? How is the mole defined? 4. What is the difference between molality and molarity? 5. Calculate the mass per cent of calcium, phosphorus and oxygen in calcium phosphate Ca3(PO4)2. 6. 4 L of dinitrogen reacted with 22. 7 L of dioxygen and 45.4 L of nitrous oxide was formed. The reaction is given below: 2N2(g) + 02(g) —> 2N20(g) Which law is being obeyed in this experiment? Write the statement of the law. 7. If two elements can combine to form more than one compound, the masses of one element that combine with a fixed mass of the other element, are in whole number ratio. (a) Is this statement true? (b) If yes, according to which law? (c) Give one example related to this law 8. Hydrogen gas is prepared in the laboratory by reacting dilute HC1 with granulated zinc. Following reaction takes place: Zn + 2HCl → ZnCl2 + H2 Calculate the volume of hydrogen gas liberated at STP when 32.65 g of zinc reacts with HCl. 1 mol of a gas occupies 22.7 L volume of STP; atomic mass of Zn = 65.3 u. 9. The density of 3 molal solution of NaOH is 1.110 g mL -1 . Calculate the molarity of the solution. 10. Volume of a solution changes with change in temperature, then, will the molality of the solution be affected by temperature? Give reason for your answer. 11. The reactant which is entirely consumed in reaction is known as limiting reagent. In the reaction 2A + 4B —> 3C + 4D, when 5 moles of A react with 6 moles of B, then (i) which is the limiting reagent? (ii) calculate the amount of C formed. 12. If 4 litres of water are added to 2 litres of 6M hydrochloric acid solution. What will be the change in the molarity of the solution? 13. How much lime would be obtained by heating 200 kg of 95% limestone? 30. If a 500 mL 5 M solution is diluted to 1500 mL, what will be the molarity of the final solution? 14. The molar mass and empirical formula of a compound are CH2O and 180g. What will be its molecular formula? 15. Calcium carbonate reacts with aqueous HC1 to give CaCl2 and C02 according to the reaction given below: CaCO3(s) + 2HCl(aq) → CaCl2(aq) + CO2(g) + H2O(l) What mass of CaCl2 will be formed when 250 mL of 0.76 M HC1 reacts with 1000 g of CaC03? Name the limiting reagent. Calculate the number of moles of CaCl2 formed in the reaction. 16. Define the law of multiple proportions. Explain it with two examples. How does this law point to the existence of atoms? 17. A box contains some identical red coloured balls, labelled as A, each weighing 2 grams. Another box contains identical blue coloured balls, labelled as B, each weighing 5 grams. Consider the combinations AB, AB2, A2B and A2B3 and show that law of multiple proportions is applicable. 18. If 4 litres of water are added to 2 litres of 6M hydrochloric acid solution. What will be the change in the molarity of the solution? 19. How much carbon dioxide would be obtained by heating 10 kg of 90% limestone? 20. If a 500 mL 5 M solution is diluted to 1500 mL, what will be the molarity of the final solution? 21. The molar mass and empirical formula of a compound are CH2O and 180g. What will be its molecular formula? 22. If 4 g of NaOH dissolves in 36 g of H2O, calculate the mole fraction of each component in the solution. Also, determine the molarity of solution (specific gravity of solution is 1g ml-1 ) 23. What volume of 10M HCl and 3M HCl should be mixed to obtain 1L of 6M HCl solution?