ASSIGNMENTS ON SOLUTION CHAPTER

One mark (very short answer questions)

1.Define mole fraction.
2.What is the similarity between Raoults law and Henrys law?
3. out of two 0.1 molal solution of glucose and of potassium chloride ,which one will have a higher boiling point and why?
4. What is isotonic solution?
5. How is that measurement of osmotic pressure is more widely used for determining molar masses of macromolecules than the elevation in boiling or depressionin
freezing point of their solution?
6.How does the molarity of a solution change with temperature?
7.When and why is molarity preferred over molarity in handling solutionsin chemistry?
8.Why is the vapour pressure of solution of glucose in water lower than that of water?
9.What are the characteristics of non ideal solution.What type of liquids form ideal solution?
10.Under what condition do non ideal solutions show negative deviations?
11.What are maximum boiling azeotropes ?Give one example.
12.Define molal depression constant or cryoscopic constant.
13.What is an antifreeze?
14.What is de-icing agent?How does it work?
15.Why is osmotic pressure of 1M KCl higher than 1M urea solution?
16. What is the vant’s Hoff factor for a compound which undergoes dimerisation in an organic solvent?
17.What would be the value of vant’s Hoff factor for a dilute solution Of K2SO4 in water?
18. Why is ethylene glycol and water mixture used in car radiator in cold countries ?
19.Why are aquatic species more comfortable in cold water than in warm water?
20.What will happen to freezing point of KI aqueous solution when mercuric iodide is added to solution?
21. what role molecular interaction play in the solution of alcohol and water?
22.Why do gases always tend to be less soluble in liquid as the temperature is raised?
23.State Raoult’s law?
24.Define molality?
25. Define azeotropes?
26. Why red blood cells shrink when placed in saline water but swell in distilled water?
26. Define term osmotic pressure?
27. Define abnormal molar mass?
28. Define vant Hoff’s factor?
29. What is the signifance of Henry’s law constant KH?
30. Write two lacunas of Henry’s law.
31.What is the unit of ebullioscopy constant?
32.What is reverse osmosis?
33.What is colligative properties?
34.The solute K2SO4 is 70% dissociated,calculate the vant Hoff’s factor.
35.Explain the painful condition known as bends.
Two and three marks questions.
36. Asolution prepared by dissolving 8.95 mg of gene fragments in 35.0 ml of water has an osmotic pressure of 0.335 torr at 25c.Assuming that the gene fragments is
a nonelectrolyte,calculate its molar mass.
37.Henry’s law constantfor the solution of methane in benzene at 298k is 4.27x10 5mm of Hg .calculate the solubility of methane in benzene at 298k under 760 mm 0f
Hg.
38. Derive thr relation ship between relative lowering of vapour pressure and molar mass of the solute.
39.Calculate the freezing point of solution containing 60g of glucose in 250g of water( Kf of water=1.86k.kgmol-1)
40.whe n 1.5 g of nonvolatile solute was dissolved in 90g of benzene ,the boiling point of benzene raised from 353.23k to 353.93k.calculate the molar mass of the
solute.
41.state raoult’s law for a solution containing nonvolatile solute .What type of deviation from raoults lae is shown by solution of chloroform and acetone and why?
42. Derive the relation ship between relative lowering of vapour pressure and molar mass of the solute.
43. Why is an increase in temperature observed on mixing chloroform and acetone?Why does sodium chloride solution freeze at lower temperature than water.?
44.i)What happens when we place the blood cell in water (hypotonic solution)
ii)gas A is more soluble in water than gas B at the same temperature.Which one of the two gases will have higher value of K H and why?
45.i) What is the similarity of Raoult’s law and Henry’s law?
ii)In non ideal solution ,what type of deviation shows the formation of max:boiling azeotropes.
46.At 25°C the saturated vapour pressure of water is 3.165kPa(23.75mm Hg). Find the saturated vapour pressure of a 5%aqueous solution of urea (carbamide) at the
same temperature. (Molar mass of urea=60.05mol^-1).
47. Calculate the frezzing point of solution when 3g of CaCl2(M=111g/mol) was dissolved in 100 g of water, assuming CaCl2 undergoes complete ionisation.(Kf for
water=1.86K kg/mol)
48. 3.9g of benzoic acid dissolved in 49g of benzene shows a depression in freezing point of 1.62K. Calculate the van't Hoff factor and predict the nature of solute
(associated or dissociated).
(Given: Molar mass of benzoic acid=122g/mol,Of for benzene=4.9K kg/mol)
49. A solution of glucose (molar mass=180g/mol) in water has boiling point of 100.20°C. Calculate the freezing point of the same solution. Molal constants of water Of
and KB are 1.86K kg/mol and 0.512K kg/mol respectively.
50. Calculate the boiling point of solution when 2g of Na2SO4 (M=142g/mol) was dissolved in 50 God water,assuming Na2SO4 undergoes complete ionisation.
(Kb for water=0.52 K kg/mol)
51. Calculate the mass of NaCl (molar mass=58.5g/mol) to be dissolved in 37.2 g of water to lower the freezing point by 2°C, assuming that NaCl undergoes complete
dissociation. (Of for water=1.86K kg/mol)
52. A solution containing 1.9g per 100ml of KCl (M=74.5 g/mol) is isotonic with solution containing 3g per 100 ml of urea (M=60g/mol). Calculate the degree of
dissociation of KCl solution. Assume that both the solution have same temperature.
53. At 300K, 30g of flucose, C6H12O6 present per litre in its solution has an osmotic pressure of 4.98bar. If the osmotic pressure of another glucose solution is 1.52bar
at the same temperature, calculate the concentration of other solution.
54. (i) Why a person suffering from high blood pressure is advised to take minimum quantity of common salt?
(ii) 2g of benzoic acid (C6H5COOH) dissolved in 25g benzene shows a depression in freezing Point equal to 1.62K. Molal depression of constant for benzene is 4.9 K
kg/mol. What is the percentage association of acid if it forms dimer in a solution?
55. (i) Give reasons for the following:
(a) At higher altitudes, people suffer from a disease called anoxia. In this disease they became weak and cannot think clearly.
(b) When mercuric iodide is added to an aqueous solution of KI, the freezing point is raised.
(ii)0.6 ml of acetic acid (CH3COOH), having density 1.06g/ml, is dissolved in 1lit of water. The depression in the freezing point observed for this strength of acid
was 0.0205°C. Calculate the van't Hoff factor and the dissociation constant of acid.
Prepared by-Alok Sen
PGT chemistry