ATOMIC STRUCTURE

CHEMISTRY
Target
IIT-JEE 2023 D P P

COURSE: JEE Nurture EMR & Bohr's Theory No. 2

DPP-2
Multiple Choice Questions with only one correct answer
1. Electromagnetic radiation travels through vacuum at C 11. Of the following transitions in the Bohr hydrogen B
a speed of __________ m/s. atom, the __________ transition results in the
(A) 186,000 (B) 125 emission of the highest-energy photon.
(C) 3.00 x 108 (D) 10,000 (A) n = 1 → n = 6 (B) n = 6 → n = 1
2. The wavelength of light that has a frequency of 1.20 B (C) n = 6 → n = 3 (D) n = 3 → n = 6
x 1013 s-1 is __________ m. 12. Using Bohr's equation for the energy levels of the A
(A) 25.0 (B) 2.50 x 10-5 electron in the hydrogen atom, determine the energy
(C) 0.0400 (D) 12.0 (J) of an electron in the n = 4 level.
3. What is the frequency(s-1) of electromagnetic A (A) ˗1.36 x 10˗19 (B) ˗5.45 x 10˗19
radiation that has a wavelength of 0.53 m? (C) ˗7.34 x 1018 (D) ˗1.84 x 1029
(A) 5.7 x 108 (B) 1.8 x 10-9 13. An electron in a Bohr hydrogen atom has an energy D
8
(C) 1.6 x 10 (D) 1.3 x 10-33 of ˗1.362 x 10˗19J The value of n for this electron is
4. The wavelength of a photon that has an energy of A __________.
5.25 x 10-19 J is __________ m. (A) 1 (B) 2
(A) 3.79 x 10-7 (B) 2.64 x 106 (C) 3 (D) 4
23
(C) 2.38 x 10 (D) 4.21 x 10-24
14. The energy (J) required for an electronic transition in B
5. The energy of a photon that has a wavelength of 9.0 A a Bohr hydrogen atom from n = 2 to n = 3 is
m is __________ J. __________ J.
(A) 2.2 x 10-26 (B) 4.5 x 1025 (A) 4.00 x 10˗19 (B) 3.00 x 10˗19
-23
(C) 6.0 x 10 (D) 2.7 x 109 (C) ˗3.00 x 10˗19 (D) ˗7.90 x 10˗19
6. The frequency of a photon that has an energy of 3.7 x A 15. Calculate the energy (J) change associated with an D
10-18 J is __________s-1. electron transition from n = 2 to n = 5 in a Bohr
(A) 5.6 x 10015 (B) 1.8 x 10-16 hydrogen atom.
(C) 2.5 x 10-15 (D) 5.4 x 10-8 (A) 6.50 x 10˗19 (B) 5.50 x 10˗19
(C) 8.70 x 10˗20 (D) 4.60 x 10˗19
7. The energy of a photon that has a frequency of 8.21 C
x 1015s-1 is __________ J. 16. The frequency of electromagnetic radiation required B
(A) 8.08 x 10-50 (B) 1.99 x 10-25 to promote an electron from n = 2 to n = 4 in a Bohr
(C) 5.44 x 10-18 (D) 1.24 x 1049 hydrogen atom is __________ Hz.
(A) 4.13 x 10˗19 (B) 6.17 x 1014
8. A mole of red photons of wavelength 725 nm has D
(C) 5.46 x 10˗19 (D) 8.22 x 1014
__________ kJ of energy.
(A) 2.74 x 10-19 (B) 227 17. A spectrum containing only specific wavelengths is A
(C) 6.05 x 10-3 (D) 165 called a __________ spectrum.
(A) line (B) continuous
9. It takes 254 kJ/mol to eject electrons from a certain A (C) visible (D) Rydberg
metal surface. What is the longest wavelength of light
(nm) that can be used to eject electrons from the 18. When the electron in a hydrogen atom moves from n D
surface of this metal via the photoelectric effect? = 6 to n = 2, light with a wavelength of __________
(A) 471 (B) 233 nm is emitted.
(C) 165 (D) 725 (A) 93.8 (B) 434
(C) 487 (D) 410
10. Which one of the following is considered to be C
ionizing radiation? 19. The n = 2 to n = 6 transition in the Bohr hydrogen B
(A) visible light (B) radio waves atom corresponds to the __________ of a photon
(C) X-rays (D) microwaves with a wavelength of __________ nm.
(A) emission, 410 (B) absorption, 410
(C) absorption, 660 (D) emission, 94

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 Daly Practice Paper “Atomic Structure”
20. The equation for energy of photon so emitted: A 30. Ionization energy of hydrogen is 13.6 eV the C
 1 ionization energy of Li+2 will be:
1 
(A) ∆E = Rhcz2  2  2  (A) 13.6 eV (B) 54.4 eV
n 
 1 n2  (C) 122.4 eV (D) None of these
Rhc  1 1  31. If the energy (PE) of hydrogen electron is – 3.02 eV C
(B) ∆E = 2  2  2  in which of the following energy levels is electron
Z  n1 n2 

present?
Rz 2  1 1  (A) 1st (B) 2nd
(C) ∆E =  2  2  (C) 3rd (D) 4th
hc  n1 n2 
32. 200 units of energy is required to take away an C
R  1 1  electron from lowest energy level to infinity, the
(D) ∆E =  2  2  energy required to take away an electron from 2nd
hcz 2  n1 n2  shell to infinity will be:
21. The radius of an orbit of H is 8.510 –10 m. Then the C (A) 100 units (B) 400 units
angular momentum of an electron in this orbit is: (C) 50 units (D) 25 units
(A) h (B) h (C) 2h (D) 3h 33. The potential energy of hydrogen electron is – 3.02 A
2   
eV, its kinetic energy will be:
22. If the energy of an electron in the 2nd orbit of H-atom B (A) 1.51 eV (B) 15.10 eV
is – 3.4 eV. Then the angular momentum of electron (C) 13.6 eV (D) 1.36 eV
is:
34. An equation which determines the energy of an A
(A) h (B) h (C) 2h (D) 3h electron in an atom?
2   
2
23. The ratio of the radius of 2nd orbit of H atom to that B (A) En = 13.6  Z 2 eV
of its 3rd orbit: n
2
(A) 0.3333 (B) 0.444 (B) En = 13.6  n 2 eV
(C) 0.555 (D) 0.25 Z
2
24. The potential energy of an electron in an orbit of an A (C) En = 13.6  Z 2 eV
n
atom is proportional to:
2
ze 2 ze 2 z2e2 z2e2 (D) En = 13.6  Z 2 eV
(A)  (B)  2 (C)  (D)  2 n
r r r r 35. Correct expression of the following: A
25. The wavelength associated with an electron moving A n2 Z 2
with a velocity of 103 m sec –1 is: (A) r = 0.529 x Z Ǻ (B) r = 0.529 x n Ǻ
(A) 7.25  10 –7 m (B) 7.25  10 –8 m Z Z 2
(C) 7.25  10 m (D) 7.25  10 –10m
–9
(C) r = 0.529 x n Ǻ (D) r = 0.529 x n Ǻ
26. A moving electron has 4.55  10 –25 Joules of kinetic D 36. Orbital motion of electron is associated with: A
energy. The velocity of this electron is: (A) Kinetic as well as potential energy
(A) 106 m sec -1 (B) 105 m sec-1 (B) Only kinetic energy
(C) 104 m sec -1 (D) 103 m sec -1 (C) Only potential energy (D) No energy
<

37. The energy of hydrogen electron in excited state is – C

27. The radii of two of the first four Bohr orbits of the B
1.5 eV. In which excited level electron is present?
hydrogen atom are in the ratio 1: 4. The energy
(A) first level (B) second level
difference between them may be:
(C) third level (D) fourth level
(A) either 12.0 eV or 3.4 eV <<
(B) either 2.5 eV or 10.2 eV 38. The radius of H atom in ground state is 0.53 Ǻ. The A
(C) either 13.6 eV or 3.4 eV radius of Li2+ ion (atomic number = 3) is:
(D) either 3.4 eV or 0.85 eV (A) 0.17 Ǻ (B) 0.265 Ǻ
28. The ionization energy of He+ is 19.6  10 – 18J. The D (C) 0.53 Ǻ (D) 0.53 Ǻ
energy of first stationary state of Li2+ is: 39. Bohr model can explain: B
(A) – 4.9  10 – 18 J (B) – 9.8  10 – 18 J (A) The spectrum of hydrogen atom only
(C) – 3.9  10 – 18 J (D) – 4.41  10 – 18 J (B) Spectrum of an atom or ion containing one
electron only
29. The energy required to excite an electron of H-atom A
(C) The spectrum of hydrogen molecule
from first orbit to second orbit is:
(D) The solar spectrum
(A) ¾ of its ionization energy
(B) ½ of its ionization energy 40. If the velocity of an electron is V1, in the first orbit of C
(C) ¼ of its ionization energy (D) None hydrogen atom, then the velocity in the second orbit
will be:
(A) V1 (B) V1/2 (C) V1/4 (D) 2V1

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 Daly Practice Paper “Atomic Structure”
41. If the radius of third orbit (n =3) of hydrogen atom is B 51. Radius of first Bohr’s orbit of H like atom made by B
476 pm, then the radius of the fourth orbit (n = 4) of fusion hydrogen and helium nuclei is:
hydrogen atom will be: 1
(A) 0.529 Ǻ (B)  0.529 Ǻ
476  4 476  16 3
(A) pm (B) pm
3 9 1
(C) 9  0.529 Ǻ (D)  0.529 Ǻ
476  3 476  9 9
(C) pm (D) pm
4 16 Answers
42. The energy of an electron in the first orbit of D (1)C (2)B (3)A (4)A (5)A (6)A
hydrogen atom is – 2.176 × 10 -18J. The energy (7)C (8)D (9)A (10)C (11)B (12)A
required to remove an electron from the third orbit of (13)D (14)B (15)D (16)B (17)A (18)D
He+ ion will be: (19)B (20)A (21)C (22)B (23)B (24)A
(A) – 2.42 x10 – 19J (B) + 2.42 x 10 – 19J (25)A (26)D (27)B (28)D (29)A (30)C
(C) – 9.671 x 10 J– 19
(D) + 9.671x10 – 19J (31)C (32)C (33)A (34)A (35)A (36)A
(37)C (38)A (39)B (40)C (41)B (42)D
43. Bohr advanced the idea of: (43)C (44)A (45)D (46)A (47)C (48)B
(A) Stationary electrons (B) Stationary nucleus (49)B (50)B (51)B
(C) Stationary orbits (D) Elliptical orbits “Success is the sum of small efforts,
44. If r is the radius of first orbit, the radius of nth orbit A repeated day in and day out.”
of the hydrogen atom will be:
(A) rn2 (B) rn
(C) r/n (D) r2n2
45. Which point does not pertain to Bohr’s model of D
atom?
(A) Angular momentum is an integral multiple of
h
2
(B) The path of the electron is circular
(C) Force of attraction towards nucleus = centrifugal
force
(D) The energy changes are taking place
continuously
46. The distance between 3rd and 2nd orbits in the A
hydrogen atom is:
(A) 2.646 x 10–8cm (B) 2.116 x 10–8cm
–8
(C) 1.958 x 10 cm (D) 0.529 x 10–8cm
47. The ratio of difference between 1st and 2nd Bohr’s C
orbits energy to that between 2nd and 3rd orbits
energy is:
(A) 1/2 (B) 1/3
(C) 27/5 (D) 5/27
48. The velocity of electron in the fourth Bohr orbit of B
hydrogen atom is v. The velocity of the electron in
the first orbit would be:
(A) 16 v (B) 4v
(C) v/4 (D) v/16
49. Three photons originating from excited atomic B
hydrogen atoms are found to have energies of 0.66
eV, 1.89 eV, and 2.55 eV respectively. The minimum
no. of atoms that must be present are
(A) One atom (B)Two atoms
(C)Three atoms (D) can’t say
50. The radii of two of the first four Bohr orbits of the B
hydrogen atom are in the ratio 1:4. The energy
difference between them may be:
(A) either 12.09 e V or 3.4e V
(B) either 2.55 e V or 10.2e V
(C) either 13.6e V or 3.4 e V
(D) either 3.4 e V or 0.85 e V

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