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TOPIC: Atomic structure PHASE– I CLASS: XI (Chemistry)

NAME…………………….. ENROLL NO……………. BATCH…………………

ONLY ONE CORRECT OPTION:

1. Three isotopes of an element have mass numbers, m,m  1 and m  2 . If the mean mass

number is m  0.5 then which of the following ratios may be accepted for m,m  1, m  2 in

that order?
(A) 1: 1: 1 (B) 4: 1: 1
(C) 3: 2: 1 (D) 2: 1: 1
2. The radii of two of the first four Bohr’s orbits of the hydrogen atom are in the ratio 1: 4. The energy
difference between them may be
(A) either 12.09 eV or 3.4 eV (B) either 2.55 eV or 10.2 eV
(C) either 13.6 eV or 3.4 eV (D) either 3.4 eV or 0.85 eV
3. Which of the following are the limitation of Bohr’s model?
(i) It could not explain the intensities or the fine spectrum of the spectral lines.
(ii) No justification was given for the principle of quantisation of angular momentum.
(iii) It could not explain why atoms should combine to form bond.
(iv) It could not successfully applied to single electron atoms.
(A) (i) , (ii) , (iv) (B) (ii) , (iii)
(C) (i), (iii), (iv) (D) (i), (ii), (iii)
4. The ratio of de Broglie wavelength of molecules of H2 and He at 27C and 127C respectively is

(A) 1.633 (B) 0.612

(C) 1.265 (D) 0.79
5. Ratio of masses of electrons moving with a velocity 0.9 times of speed of light and 0.8 times of
speed of light respectively are

19 64 81 36
(A) (B) (C) (D)
36 81 64 19
6. The magnetic moment order is correctly given in
(A) Fe2  Fe3  Mn4  Cr 3 (B) Cr 3  Mn4  Fe2  Fe3
(C) Cr 3  Mn4  Fe3  Fe2 (D) Fe2  Cr 3  Fe3  Mn4
7. The orbital represented by  4,2,0 is

(A) 4dz2 (B) 4p x (C) 4p z (D) 4dxy

8. The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom is:
a0 is Bohr radius

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h2 h2 h2 h2
(A) (B) (C) (D)
42ma02 162ma02 322ma02 642ma02
ONE OR MORE THAN ONE CORRECT OPTION(S)
9. The stationary Bohr’s orbit can be readily explained on the basis of wave nature of electron if it is
assumed that:
(A) wave in any of the orbits is the stationary wave
(B) the position of maxima and minima of wave does not change with time
(C) the length of the circular orbit must be an integral multiple of the wavelength
(D) wave in any of the orbit is not stationary wave
10. The restriction of emission line spectrum for H-atom/H-like species is given by selection rule. For
H-like species the transitions which do not follow the restrictions given below are forbidden.
Rule: n  any value; l  1; m  0,  1

According to this rule following transitions are not allowed

(A) 4p to 3p (B) 4f to 3d
(C) 4p to 3d (D) 4d to 3s
11. Select the correct statements.
(A) The degeneracy of orbitals of a shell in H-like atoms exists only in absence of magnetic field
(B) An orbital can be defined by three quantum numbers only
(C) The process involving 0
1 e  10 e 
 hv is called pair production

(D) The line spectrum of two elements can never be identical

12. Select the correct statements.
(A) Rest mass of photon is zero and increases with its speed
(B) Angular momentum of electron in ground state orbital of an element is zero
(C) The d-orbitals with two nodal surfaces forming cones is dz2

h
(D) For an electron uy  x 2 
4m
13. Select the correct statements.
(A) 3 d-orbital are more closer to nucleus than 4s-orbital.
(B) 3 d-orbital possesses more energy than 4s-orbital.
(C) 3 d-orbitals are seven fold degenerate in presence of magnetic field
(D) The probability for finding electron between two lobes of p-orbitals is zero
INTEGER ANSWER TYPE
1
14. The wave function of atomic orbital of H like species is given by:  2s  Z3 2  2  zr  e zr 2
4 2

The radius for nodal surface of He ion in A is..............

15. The number of protons in an ion from which  Z  1 electrons are removed having its ionisation
–
energy 11800 kJ mol is:

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ANSWER

1. B
2. B
3. D
4. A
5. D
6. B
7. (A)
8. C
9. ABC
10. A,D
11. A,B,C, D
12. A,B,C
13. A,B,D
14. 1
15. 3

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ANSWER & HINTS

ONLY ONE CORRECT

1. B
Hints: Average mass = m  0.5

m  4   m  1  1  m  2   1

6

6m  3

6
2. B
Hints: The two orbits are either I and II or II and IV
rn2 4
 and rn  n2
rm1 1

13.6
Thus, E2  E1   13.6  10.2eV
4
13.6 13.6
and E4  E2    2.55eV
16 4
3. D
Hints: Bohr’s model was successfully applied to single electron system, e.g., H, He  , Li2  ,etc.

4. A
h
Hints: 
mu
h
H2 
3RT1
mH2 
mH2

h
He 
3RT2
mHe 
mHe

H2 T2  mHe
 
He T1  mH2

400  4 103 8
   1.633
300  2  103 3
5. D

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m
Hints: m'e 
  ue 2 
1    
  c  
1   0.8 
2
m' 36
  
1   0.9 
2
m" 19

6. B
Hints: Cr 3  , Mn4  ,Fe2  and Fe3  have 3, 3, 4, 5 unpaired electrons.

7. (A)
Hints:  4,2,0 means n = 4, l  2, m  0  4dz2

8. C
Hints: As per Bohr’s postulate, kinetic energy in II orbit
e2 e2
 
2r2 2a0  22
 r2  r1  n2 
e2

8a0

h2
Since, a0 
4 me2
2

h2 1 h2
 Kinetic energy in II orbit =  
42ma0 8a0 322ma02

ONE OR MORE THAN ONE CORRECT

9. ABC
10. A,D
11. A,B,C, D
12. A,B,C
13. A,B,D
INTEGER TYPE
14. 1
15. 3

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FIITJEE Ltd., Plot No. 47, Sector – 12B, Opposite Bal Bhawan International School, Dwarka, New Delhi – 110 075,
Ph. : 011-28035963/64/65 website : www.fiitjee.com