solution important question
solution important question
1. Which of the following liquid pairs exhibits positive deviation from the Raoult’s law?
a) n-hexane & n-heptane b) Ethanol & Chloroform c) Phenol & Aniline d) Chloroform & Acetone
2. The value of Henry’s constant (KH) _____________ with increase in temperature.
a) increases b) decreases c) remains constant d) increase then decrease
3. Which of the following solution has the lowest freezing point?
a) 0.1 M KNO3, b) 0.1 M Na3PO4 c) 0.1 M BaCl2 d) 0.1 M K2SO4
4. Which of the following interaction will be exhibited by the mixture of n-hexane & n-heptane?
a) Ion dipole b) Dipole-dipole c) London force d) H-bonding
5. Which of the following solution has the lowest boiling point?
a) 0.1 M KCl, b) 0.1 M K4[Fe(CN)6] c) 0.1 M BaCl2 d) 0.1 M K2SO4
6. 750 mL 0.5 M HCl mixed with 250 mL 2 M HCl. What will be the molarity of the resulting solution?
a) 0.975M b) 0.875M c) 1.00M d) 1.75M
7. The expression relating molarity (M) & molality (m) of a solution is-
(Where d is density & A is molecular weight)
a) m=(1000M)/(1000d+MA) b) m=(1000M)/(1000d-MA)
c) m=(1000d+MA)/(1000M) d) m=(1000d-MA)/(1000M)
8. Which of the following is correct for molecular association in an aqueous solution?
a) i =1 , M>M’ b) i >1 , M>M’ c) i < 1 , M<M’ d) i <1, M>M’
0
9. The freezing point of 0.02 m of an ionic salt Co(NH3)5(NO2)Cl is -0.00732 C.The number of ions formed when
1 mol of the salt is dissolved in water is- (kf = 1.86 KKg/mol)
a) 2 b) 3 c) 4 d) 1
10. The temperature at which 10% aqueous solution of (W/V) of glucose show the osmotic pressure of 16.4 atm
is –
a) 3600c b) 180 k c) 300 k d) 360 k
11. Calculate the mass of urea (NH2CONH2) required in making 2.5 kg of 0.25 molal aqueous solution.
12. 10 g of an unknown polymer dissolved in 2 L of water generating osmotic pressure of 0.05 bar at 27oC.
Calculate the molecular weight of the polymer. (R = 0.082 L.bar/mol/K)
13. Calculate the mass of ascorbic acid (vitamin C, C 6H8O6) to be dissolved in 75 g of acetic acid to lower its
melting point by 1·5°C. (Kf for CH3COOH = 3·9 K kg mol-1).
14. Calculate the mass of a non-volatile solute (molecular mass 40 g mol-1) that should be dissolved in 114 g of
octane to reduce its pressure to 80%.
15. 2.0 g of benzoic acid dissolved in 25 g of benzene shows depression in freezing point 1.62 K. What is the
amount of % of association of the acid? (given Kf of benzene is 4.9 K Kg/mol)
16. Determine the amount of CaCl2 (i = 2.47) dissolved in 2.5 litre of water such that its osmotic pressure is
0.75 atm at 27°C.
17. Write the differences between Ideal & Non-ideal Solution.
18. Why does aquatic creatures feels comfort in cold water rather than hot water?
19. A solution of 3.8 g of Sulphur in 100 g of CS2 (boiling point 46.30C) boils at 46.660C. What is the molecular
formula of Sulphur molecule present in solution? (Given atomic mass of Sulphur is 32 g/mol & k b of CS2 is
2.40K.Kg.mol-1).
20. Assertion (A) : Blood cells put in 0.4% NaCl solution starts swelling called edema.
Reason (R) : 0.4% NaCl solution is hypotonic with respect to the fluid inside the blood cells.
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