Class: XIi CHEMSITRY CHAPTER#09

1. Functional group present in aldehyde is :

A. –CO- B. –CHO C. –COOR D. –COOH E. –COR
2. Aliphatic aldehydes are called as:
A. Alkanols B. Alkanals C. Alkenols D. Alkenals
3. Aldehydes are oxidation products of:
A. Primary alcohols C. Tertiary alcohols E. Esters
B. Secondary alcohols D. Carboxylic acids
4. Simple aliphatic saturated aldehydes have general formula:
A. CnH2nO2 B. CnH2n+2O2 C. CnH2n+2O D. CnH2nO E. CnH2n+1O
5. The formula for metaformaldehyde is:
A. (HCHO)n B. (HCHO)3 C. (HCHO)4 D. (HCHO)6 E. (HCHO)8
6. Hybridization in carbon of carbonyl group is:
A. sp B. sp2 C. sp3 D. no hybridization
7.

Correct IUPAC name of the following compound is?

A. 1,2-dimethyl hexanone C. 5-methyl-6-heptanone E. 2-methylheptan-2-one
B. 1,3-dimethyl heptanone D. 3-methyl heptan-2-one
8. General name for the compound formed as a result of reaction b/w an
aldehyde & alcohol is
A. Ketal B. Acetal C. Aldol D. None of these
9. Which of the following undergoes aldol condensation reaction?
A. HCHO C. (CH3)3C-CH2-CHO E. Both C & D
B. (CH3)3-CHO D. CH3-CH2-CH2-CHO
10. Which of the following produce cyclonite?
A. CH3CHO, conc. HNO3 C. CH3CHO, fuming HNO3 E. HCHO, fuming H2SO4
B. HCHO, fuming HNO3 D. HCHO, conc.HNO3
11. Formaldehyde is used in:
A. Preparation of Bakelite C. Preparation of Antipolio vaccine E. All of These
B. Preparation of Melamine D. Silvering of mirror
12. Which of the following pair gives same product?
A. Oxidation of alcohol, dehydrogenation of aldehyde
B. Oxidation of methanol, dehydrogenation of methanol
C. Oxidation of methanol, hydrogenation of formic acid
D. Hydrogenation of formic acid, dehydrogenation of formic acid
13. Formaldehyde on heating with Fehling’s solution form:

A. Black ppt B. White ppt C. Red ppt D. Silver mirror E. Yellow ppt
14. Reduction of phenol with zinc dust will produce.

A. Benzene C. Zinc phenoxide E. Carbolic acid

B. Benzoic acid D. Phenoxide ion
15. Bakelite is a polymer of:

A. Ethene & ethyne C. Phenol & formaldehyde E. Ethene only

B. Methanol & phenol D. Formaldehyde only
16. Lucas reagent is used to distinguish:

A. Alkane & alkene C. Aldehyde & ketone E. 1o,2o & 3o alcohols

B. Alcohol & ether D. Alkene & alkyne
17. Formalin is 40% aqueous solution of:

A. Methanol B. Methanal C. Ethanol D. Acetone E. Ethanol

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Class: XIi CHEMSITRY CHAPTER#09

18. Which compound is used in processing of anti-polio vaccine?

A. Acetone C. Formalin
E. Ethyl alcohol
B. Formaldehyde D. Methyl alcohol
19. Complete oxidation of ethyl alcohol using oxidizing mixture K2Cr2O7& conc.
H2SO4 produces:

A. Formaldehyde C. Acetic acid

E. Acetone
B. Acetaldehyde D. Formic acid
20. Cannizzaro’s reaction is:

A. Addition reaction C. Elimination reaction E. Oxidation reaction

B. Redox reaction D. Self-Redox reaction
21. Tollen’s test is also known as:

A. Fehling’s test B. Benedict’s test C. Silver mirror test D. Iodoform test

22. Nitration of phenol with dil. HNO3at low temperature produces:

A. o-nitrophenol B. p-nitrophenol C. m-nitrophenol D. Both A & B

23. Acid catalyzed hydration of alkenes except ethene leads to the formation of:
A. Primary alcohol
D. Mixture of primary & secondary alcohol
B. Secondary alcohol
E. Both B & C
C. Tertiary alcohol
24. Which one among the following on hydration produce ter-butyl alcohol?
A. CH3-CH=CH-CH3 C. CH3-CH=CH2 E. (CH3)2CH-CH=CH2
B. CH3-CH2-CH=CH2 D. (CH3)2C=CH2
25. Consider the following reaction: C2H5OH + H2SO4→ product. Which one of the
following cannot be formed as a product under any condition?
A. Ethylene C. Diethyl ether E. Ethyl hydrogen sulphate
B. Acetylene D. Ethyl alcohol
26. Denatured alcohol is:
A. Ethanol + methanol C. Rectified spirit + methanol
E. Undistilled ethanol
B. Rectified spirit D. Rectified spirit + ethanol
27. Ethyl alcohol shows acidic nature on reacting with:
A. PCl5 B. CH3COOH C. H2SO4 D. Na E. K2Cr2O7
28. ⎯⎯⎯⎯⎯⎯ ⎯⎯⎯
In the following sequence of reactions CH3CH2OH ⎯ . The

compound C is:
A. Butanol C. Propanal
E. n-butyl alcohol
B. Isopropyl alcohol D. n-propyl alcohol
29. The enzymes which bring about the conversion of starch into ethyl alcohol
are:
A. Diastase, sucrase, zymase D. Diastase, invertase, zymase
B. Diastase, zymase E. Diastase, maltase, zymase
C. Invertase, diastase
30. When phenyl magnesium bromide reacts with ter-butyl alcohol, which of the
following is formed?
A. Ter-butyl benzene C. Phenol E. Both B & D
B. Benzene D. Ter-butyl methyl ether
31. Which of the following alcohol is not oxidized by K2Cr2O7/conc. H2SO4?
A. Iso-butyl alcohol C. Neo-pentyl alcohol E. Sec. butyl alcohol
B. 2-methyl-2-propanol D. Iso propyl alcohol
32. Conditions for the conversion of ethanol to ethene are:
A. Conc. H2SO4/100℃ C. conc. H2SO4/170℃ E. conc.H2SO4/400℃

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Class: XIi CHEMSITRY CHAPTER#09

B. Dil.H2SO4 /170℃ D. conc.H2SO4/450℃

33. CH3-CH2-CHO on hydrogenation produces:
A. sec-propyl alcohol C. n-propyl alcohol E. Both A & B
B. Iso-propyl alcohol D. Sec-butyl alcohol
34. Which of the following produce ketone on oxidation with K2Cr2O7/conc. H2SO4?
A. n-butyl alcohol C. sec-butyl alcohol E. Both B & C
B. isobutyl alcohol D. ter-butyl alcohol
35. Which one is incorrect about reaction of Zn (dust) with phenol?
A. Zn reduces phenol C. Phenol undergoes reduction E. None of these
B. Zn undergoes oxidation D. Benzene is formed
36. IUPAC name for m-cresol is:
A. 4-methyl phenol C. 3-hydroxy toluene E. 1-hydroxy-3-methyl benzene
B. 3-methyl phenol D. 4-hydroxy toluene
37. Which one is incorrect about Williamson synthesis?
A. Produces symmetrical ethers only
B. Uses Na metal & H2SO4
C. Ethyl alcohol gives diethyl ether on reacting with Na followed by reacting with ethyl
bromide
D. None of these
38. ⎯⎯⎯⎯⎯⎯ ⎯⎯⎯⎯⎯ , :

A. Methyl alcohol C. Propyl alcohol

B. Ethyl alcohol D. Isopropyl alcohol
39. Which one of the following reactions will yield propan-2-ol?
I. CH2=CH-CH3+H2O

II. CH3CHO ⎯⎯⎯⎯

III. HCHO ⎯⎯⎯⎯

IV. CH2=CH-CH3 ⎯⎯⎯⎯⎯⎯⎯⎯

A. I & II B. II & III C. I & III D. II & IV E. I Only

40. Phenol on reduction with H2 in the presence of Ni catalyst gives:
A. Benzene C. Cyclohexanol E. Cyclohexenol
B. Cyclohexane D. Toluene
41. After the reaction of C6H5SO3Na with NaOH it is hydrolysed by acid. The
product formed is:
A. Benzene C. Sodium benzoate E. Benzene sulphonic acid
B. Benzoic acid D. Phenol
42. p-phenol sulphonic acid is major product when phenol reacts with conc. H2SO4
at:
A. 20℃ B. 50℃ C. 100℃ D. 200℃ E. 400℃
43. Total number of isomeric alcohols for a compound with molecular formula
C4H10O is:
A. 3 B. 4 C. 5 D. 6 E. 8
44. Pyroligneous acid contains:
A. Methanol, ethanol, acetone, acetic acid
B. Methanol, acetone, acetic acid, methyl acetate
C. Ethanol, acetone, acetic acid, methyl acetate
D. Methanol, acetone, acetic acid, acetaldehyde
E. Methanol, acetone, benzene, toluene
45. Industrial preparation of methanol from carbon monoxide and hydrogen uses
catalyst:

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Class: XIi CHEMSITRY CHAPTER#09

A. Fe2O3 B. ZnO C. Cr2O3 D. CoO E. Mixture of ZnO & Cr2O3

46. Starting material in Dow’s process is:
A. Chlorobenzene & NaOH D. Sodium phenoxide & NaOH
B. Chlorobenzene & HCl E. Sodium benzene sulphonate & NaOH
C. Sodium phenoxide & HCl
47. IUPAC name for isopropyl ter-butyl ether is:
A. 2-methyl-2-isopropoxy propane D. 2,2-dimethyl-2-isopropoxy propane
B. 2-terbutoxy propane E. 2-propoxy propane
C. 2-isopropoxy propane
48. Phenol is a:
A. Low boiling liquid C. Highly volatile liquid E. Crystalline solid
B. High boiling liquid D. Wax like solid
49. Ethyl alcohol reacts with thionyl chloride to give ethyl chloride &
A. SO, Cl2 B. SO2, HCl C. SO3, HCl D. POCl3, HCl E. H3PO3, HCl
50. Which one is incorrect about esterification reaction between C2H5OH &
CH3COOH?
A. C2H5OH loses H D. CH3COOH loses OH
B. H2SO4 act as catalyst E. None of These
C. Ester formed is methyl acetate
.
51.
In the reaction sequence CaC2 ⎯ A ⎯⎯⎯⎯⎯⎯ B C the product C is:

A. C2H6 B. CH3CHO C. C2H5OH D. C2H4 E. C2H5 – HSO4

52. Iodoform test is not given by:
A. Methanol B. Ethanol C. Acetaldehyde D. Acetone E. Both A & C
53. Aldol condensation is:
A. Self condensation of aldehydes only having at least one alpha hydrogen
B. Self condensation of ketones only having at least one alpha hydrogen
C. Self condensation of both aldehydes and ketones having at least one alpha hydrogen
D. Self condensation of both aldehydes and ketones having no alpha hydrogen
54. Cannizzaro’s reaction is not given by:
A. Acetaldehyde B. Formaldehyde C. Benzaldehyde D. Triethyl acetaldehyde
55. Which compound does not give yellow ppt. with iodine and alkali?
A. 2-propanol B. Acetophenone C. Methanol D. Acetone
56. Which of the following is incorrect:
A. FeCl3 is used in the detection of phenols
B. Fehling’s solution is used in the detection of glucose
C. Tollen’s reagent is used in detection of unsaturation
D. NaHSO3 is used in the detection of carbonyl compounds
57. C2H5CHO and (CH3)2CO can be distinguished by testing with:
A. Phenyl hydrazine B. Hydroxylamine C. Fehling’s solution D. Sodium bisulphite
58. Acetaldehyde cannot show:
A. Iodoform test B. Lucas test C. Benedict’s test D. Tollen’s test
59. Silver mirror is a test for:
A. Aldehydes B. Alcohols C. Ketones D. Ethers
CH 3
60. Does not show aldol condensation because:
CH3 C CHO

CH3

A. Carbon is bonded to three bulky methyl groups

B. Due to the absence of -hydrogen
C. It is a neutral molecule
D. Due to hindrance created by methyl group for carbanion
61. Identify the correct statement:
A. Aldehydes on reduction give secondary alcohols
B. Ketones on reduction give primary alcohols

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Class: XIi CHEMSITRY CHAPTER#09

C. Ketones reduce Fehling’s solution and give cuprous oxide

D. Ketones do not react with monohydric alcohol
62. Arrange the following compounds in increasing order of the reactivity in
nucleophilic additions:
(I)Ethanal (II)Propanal (III)Propanone (IV)Butanone
A. III<II<I<IV B. IV<III<II<I C. II<I<III<IV D. I<II<III<IV
63. In the presence of a dilute base, C6H5CHO and CH3CHO react together to give
______ product:
A. C6H5CH3 B. C6H5CH2CH2OH C. C6H5CH2OH D. C6H5-CH=CH-CHO

64. Oxidation of with K2Cr2O7 & conc. H2SO4 gives:

A. Acetic acid and formic acid C. Acetone and formic acid
B. Propanoic acid and formic acid D. Acetic acid only
65. One of the following named reaction is an example of “disproportionation
reaction”. Identify it:
A. Birch reduction B. Aldol condensation C. Wurtz reaction D. Cannizzaro reaction
66. Acetone and acetaldehyde are differentiated by:
A. NaOH + I2 B. Ag(NH3)2+ C. HNO3 D. NaHSO3
67. Which is not true about acetophenone?
A. Reacts with 2,4-DNPH to form 2,4-dinitrophenyl hydrazone
B. Reacts with Tollen’s reagent to form silver mirror
C. Reacts with I2/NaOH to form iodoform
D. None of these
68. Which of the following pairs can be distinguished by iodoform test:
A. CH3CHO and CH3COCH3 C. CH3CH2OH and CH3CH2CH(OH)CH3
B. CH3CH2CHO and CH3COCH3 D. CH3OH and CH3CH2CHO
69. CH3CHO and C6H5CH2CHO can be distinguished chemically by:
A. Fehling’s test B. Iodoform test C. Tollen’s test D. Both A & C
70. Ethanal is treated with excess of ethanol in the presence of hydrochloric acid.
The product is:

A. B. C. D.

71. Clemmensen reduction of a ketone is carried out in the presence of which of

the following?
A. H2 and Pt as Catalyst C. Zn-Hg with HCl
B. N2H4 with KOH D. LiAlH4
72. When ethanal is treated with Fehling’s solution it gives a precipitate of:
A. Cu2O B. Cu C. Cu(OH)2 D. CuO
73. Which of the following compounds containing carbonyl group will give

coloured crystalline compound with:

A. CH3COCl B. CH3COCH3 C. CH3CO(OC2H5) D. CH3CONH2
74. Ethyl methyl ketone is prepared by the oxidation of:
A. 2-propanol B. 1-butanol C. 2-butanol D. n-butyl alcohol
75. Fehling’s test is positive for:
A. Acetaldehyde B. Benzaldehyde C. Acetone D. Alcohol
76. An aldehyde on oxidation gives:
A. An alcohol B. An acid C. A ketone D. An ether
77. Aldehydes are first oxidation products of:
A. Primary alcohols C. Tertiary alcohols

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Class: XIi CHEMSITRY CHAPTER#09

B. Secondary alcohols D. Monohydric alcohols

78. Isopropyl alcohol on oxidation forms:
A. Acetone B. Ether C. Acetaldehyde D. Ethylene glycol
79. The products formed when PCl5 reacts with acetic acid are:
A. CH3COCl, H3PO3 C. CH3COCl, HCl
B. CH3COCl, H3PO4 D. CH3COCl, POCl3,HCl
80. Which of the following reduces carboxylic acid directly to primary alcohols?
A. LiAlH4 B. Na+C2H5OH C. Lindlar’s Catalyst D. Zn-Hg/HCl
81. An organic compound reacts (I) with metallic sodium to liberate hydrogen and
(II) with Na2CO3 solution to liberate CO2. The compound is:
A. An alcohol B. A carboxylic acid C. An ether D. An ester
82. Formalin is an aqueous solution of:
A. Formic acid B. Acetaldehyde C. Formaldehyde D. Furfural
83. Predict the product “B” in the sequence of reaction:

A. CH3COONa B. CH3COOH C. CH3CHO

D.
84. Identify the reactant X and the product Y.

A. X=MgCl2: Y=CH3CH=CH2 C. X=CH3MgCl: Y=(CH3)3C-OH

B. X=CH3MgCl: Y=C2H5COCH3 D. X=C2H5MgCl: Y=(CH3)3C-OH
85. Benzaldehyde + NaOH →
A. Benzyl alcohol B. Phenol C. Hydrobenzamide D. Salicylic acid
86. Dry heating of calcium acetate gives:
A. Acetaldehyde B. Ethanal C. Acetic acid D. Acetone
87. A fruity smell is produced by the reaction of C2H5OH with:
A. PCl5 B. CH3COCH3 C. CH3COOH D. None of these
88. Acetic acid on heating in presence of P2O5 gives:
A. Acetic anhydride B. Acetylene C. Peracetic acid D. No reaction
89. Benzoic acid gives benzene on being heated with X and phenol gives benzene
on being heated with Y. Therefore X and Y are respectively:
A. Soda-lime and copper C. Zn dust and soda-lime
B. Zn dust and NaOH D. Soda-lime and Zn dust
90.
product “P” in this reaction is:
A. CH3CH2CH2CHO B. CH3CH2CH2CH2CHO C. CH3CH2CH2CH3 D. CH3CH2CH3
91. Methyl ketones are usually characterized through:
A. Tollen’s test C. Fehling’s test
B. Iodoform test D. Benedict’s test
92. Acetone when reacted with conc. HCl and Zn-Hg gives:
A. CH3CH3 B. CH3CH2CH3 C. CH3COOH D. CH3CHOHCH3
93. Reduction of a carbonyl group to a methylene group by alkaline decomposition
of the hydrazine is known as:
A. Rosenmun’ds reduction C. Clemmensen’s reduction
B. Wolf-Kishner’s reduction D. Sabatier and Senderen’s reduction
94. Saponification of ethyl benzoate with caustic soda as alkali gives:
A. Benzyl alcohol and ethanoic acid C. Benzoic acid and sodium ethoxide
B. Sodium benzoate and ethanol D. Phenol and ethanoic acid
95. What will happen if LiAlH4 is added to an ester?
A. Two units of alcohols are obtained
B. One unit of alcohol and one unit of acid is obtained
C. Two units of acid are obtained
D. None of these

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Class: XIi CHEMSITRY CHAPTER#09

96. In CH3COOH molecule, the C-C bond is formed by:

A. sp3-sp3 overlap C. sp3-sp2 overlap
B. sp2-sp2 overlap D. sp3-sp overlap
97. -Chlorobutyric acid is named by IUPAC system as:
A. 2-Chlorobutanoic acid C. 3-Chlorobutanoic acid
B. 2-Chlorobutyric acid D. 3-Chlorobutyric acid
98. The correct structural representation of carboxylate ion is:

A. B. C. D.
99. The hybridization of the C–atom of the carboxyl group is:
A. sp B. sp2 C. sp3 D. none of these
CH COOH
100. IUPAC name of 2

A. Benzoic acid C. Benzene-1, 2-carboxylic acid

B. 2-phenylethanoic acid D. 1-Phenylethanoic acid
101. Which one of the following cannot be formed by the reaction of dry ice with
Grignard’s reagent?
A. Acetic acid B. Formic acid C. Propanoic acid D. All of these
102. An organic compound of molecular formula, C3H6O did not give a silver mirror
with Tollen’s reagent, but gave an oxime with hydroxylamine. It may be
A. CH3CH2CHO C. CH3COCH3
B. CH2=CHCH2OH D. HOC-CH2-CHO
103. Which one of the following on treatment with 50% aqueous sodium hydroxide
yields the corresponding alcohol and acid?
A. C6H5CHO B. CH3CH2CH2CHO D. C6H5CH2CHO
C.

104. The product formed in Aldol condensation is:

A. A beta-hydroxy aldehyde or a beta-hydroxy ketone
B. An alpha-hydroxy aldehyde or ketone
C. An alpha, beta unsaturated ester
D. A beta-hydroxy acid
105. Which is false about acetic acid?
A. It is a polar molecule
B. It forms H bonds
C. It is stronger acid than mineral acids
D. It has higher boiling point than corresponding alcohols
106. Which of the following is most acidic?
A. ClCH2COOH B. FCH2COOH C. NO2CH2COOH D. CH3COOH
107. Heating sodium salt of propanoic acid with soda-lime (CaO+NaOH) gives:
A. n-butane B. Propane C. Ethane D. Methane
108. Which statement is incorrect about carboxylic acids?
A. They evolve H2 gas with active metals
B. They release CO2 on reacting with carbonates & bi-carbonates
C. They exist in dimeric form due to intermolecular hydrogen bonding
D. They are less soluble in water due to intermolecular hydrogen bonding
109. Identify pyruvic acid among following:
C. D. CH2=CH-COOH

A. B.
110. Hydrolysis of ester in basic medium is called as:
A. Acidification B. Esterficaiton C. Saponificaiton D. Neutralization

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Class: XIi CHEMSITRY CHAPTER#09

111. Which of the following will result in the formation of an ester?

A. CH3COCl + CH3CH2ONa → C. CH3COCl + NH3 →
B. CH3COCl + CH3COONa → D. CH3COCl + CH3COOH →
112. Which of the following test is positive for ketones?
A. Fehling’s test C. Tollen’s test
B. Benedict’s test D. Sodium nitroprusside test
113. Addition of water to alkynes occurs in acidic medium and in the presence of
ions as a catalyst. Which of the following products will be formed on addition
of water to but-1-yne under these conditions?
O

A. B. CH3 CH2 C CH3 C. D.

114. What happens when a carboxylic acid is treated with lithium aluminum
hydride?
A. Aldehyde is formed C. Ketone is formed
B. Primary alcohol is formed D. Grignard reagent is formed
115. The correct order of increasing acidic strength is____.
A. Phenol<Ethanol<Chloroacetic acid< acetic acid
B. Ethanol<Phenol<Chloroacetic acid<acetic acid
C. Ethanol<Phenol<Acetic acid<Chloroacetic acid
D. Chloroacetic acid<Acetic acid<Phenol<Ethanol
116. Wolf-Kishner reduction is:
A. Reduction of carbonyl compound into alcohol
B. Reduction of carbonyl compound into alkane
C. Reduction of carboxyl compound into alkane
D. Reduction of nitro compound into aniline
117. Tollen’s reagent is:
A. Ammonical CuSO4
B. Ammonical AgNO3
C. Alkaline solution containing complex of copper nitrate
D. None of these

118. Compounds of general formula are called:

A. Diesters B. Hemiacetals C. Acid anhydrides D. Acetals
119. Which reaction is used for detecting the presence of carbonyl group?
A. Reaction with hydrazine C. Reaction with hydroxylamine
B. Reaction with phenyl hydrazine D. All of the above
120. Two compounds benzyl alcohol and benzoic acid are formed form this
compound, when this compound is heated in the presence of conc. NaOH, this
compound is:
A. Benzaldehyde B. Benzylalcohol C. Acetophenone D. Benzophenone
121. The reagent which does not react with both, acetone and benaldehyde is:
A. Sodium hydrogensulphite C. Fehling’s solution
B. Phenyl hydrazine D. Grignard reagent
122. Which of the following compound is most reactive towards nucleophilic
addition reactions?

A. B. C. D.

123. The reagent which can be used to distinguish acetophenone form

benzophenone is:
A. 2, 4-dinitrophenylhydrazine C. Benedict reagent
B. Aqueous solution of NaHSO3 D. I2 and Na2CO3

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Class: XIi CHEMSITRY CHAPTER#09

124. Iodoform test is not given by:

A. 2-pentanone B. Ethanol C. Ethanal D. 3-pentanone
125. Methyl phenyl ketone can be converted into ethyl benzene in one step by
which of the following reagents?
A. LiAlH4 B. N2H4/KOH C. Zn-Hg/HCl D. CH3Mgl
126. O2N CHO

The IUPAC name of is:

OCH3

A. 2-Methoxy-4-nitro benzaldehyde C. 4-Nitro anisaldehyde

B. 3-Methoxy-4-formyl nitro benzene D. 2-Formyl-4-nitro anisole
127. Which of the following statements is correct?
A. Formaldehyde on heating with I2 and alkali gives a yellow ppt
B. Ethanol is the only primary alcohol which gives halo form reaction
C. All secondary alcohols give halo form reaction
D. All ketones give halo form reaction
128. In the sequence of reactions, CH3CH2CH2OH A B . The product B is:
A. Propyne B. Propylene C. Propane D. Propanol
129. Which reducing agent is used in Clemmensen reduction:
A. Zn/HCl B. LiAlH4 C. Zn-Hg/HCl D. Na/C2H5OH
130. Which of the following will not produce ethane:
A. Reduction of CH3COOH with HI/P4
B. Reduction of CH3COCH3 with HI/P4
C. Decarboxylation of sodium propionate with soda lime
D. Hydrogenation of ethene in the presence of Ni
131.
The reaction is an example of:
A. Electrophilic addition C. Electrophilic substitution
B. Nucleophilic substitution D. Nucleophilic addition
132. Which reagent of the following is not used in reduction reactions?
A. NaBH4 B. LiAlH4 C. HI/Red P D. K2Cr2O7/conc. H2SO4
133. Acetic acid when treated with NaBH4 & LiAlH4 separately, it gives:
A. Acetaldehyde & ethanol respectively C. Acetaldehyde with both
B. Acetaldehyde & ethane D. Ethanol with LiAlH4 only
134.
In the given reaction sequence product ‘C’ is:
A. n-propyl benzene B. Cumene C. Toluene D. Ethyl benzene
135. When CH3OCH2CH3 is treated with one mole of HI, it gives:
A. CH3OH & CH3CH2I C. CH3I, CH3CH2I & H2O
B. CH3I & CH3CH2OH D. CH3OH, CH3CH2OH & I2
136. The given compounds can be correctly arranged in decreasing order of acidity

as follows:
A. I>II>III>IV B. II>III>I>IV C. II>I>III>IV D. II>I>IV>II
137. A + B  Picric acid. A & B are respectively:
A. Benzene, conc. HNO3 C. Phenol, conc. HNO3
B. Benzene, dil. HNO3 D. Phenol, dil. HNO3
138. When butan-2-ol is heated with H2SO4, the major product is:
A. But-1-ene B. But-2-ene C. 2-methyl propene D. Buta-1,3-diene
139. IUPAC name of the 3 H C CH CH 2 CHOH CH 3 compound is:

C2 H5
A. 4-Methylhexan-3-ol C. 4-Methylhexan-2-ol
B. Heptanol D. 4-Ethylpentan-2-ol
140. Alcohols, which have two hydroxyl (-OH) groups are called:

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Class: XIi CHEMSITRY CHAPTER#09

A. Allylols B. Glycols C. Diols D. Either “b” or “c”

141. The enzyme which converts glucose to ethylalcohol is:
A. Zymase B. Invertase C. Maltase D. Diastase
142. An alkyl iodide on refluxing with aqueous KOH solution gives isopropyl alcohol.
The structure of alkyl iodide can be:
A. CH3CH2CH2l B. CH3CHlCH3 C. lCH2CH2CH2l D. lCH2CHlCH2l
143. Primary alcohols are obtained by the reaction of Grignard reagent with:
A. CH3COCH3 B. HCOOH C. HCHO D. CH3CHO
144. Ethyl alcohol is manufactured by the fermentation of:
A. Molasses B. Starch C. Both A and B D. Glucose
145. HCHO on reaction with ‘A’ followed by hydrolysis gives CH3CH2CH2OH. ‘A’ is
_______.
A. CH3MgI B. C2H5MgI C. Na-Hg/H2O D. H2, Ni, 200°C
146. Which of the following alcohol is most reactive with HCl in the presence of
ZnCl2?
A. (CH3)3COH B. (CH3)2CHCH2OH C. (CH3)2CHOH D. CH3OH
147. Tertiary alcohols are resistant to oxidation:
A. Due to large +I effect of alkyl group
B. Because they do not have −hydrogen atom
C. Due to greater steric hindrance
D. Because of all the above
148. The presence of the –OH group in alcohols is shown by the reaction:
A. ROH + HX → RX+ H2O C. ROH + SOC 2 → RCl + SO2 + HC
B. ROH + PC 5 → RCl + POC 3+ HC D. All of these
149. The order of ease of rupture of C-O bond in 1°, 2°and 3° alcohols is:
A. Tert. > Sec. > Prim C. Tert. > Prim. < Sec.
B. Tert. <Sec.<Prim D. Cannot predict
150. When excess of alcohol is heated with conc. H2SO4 at low temperature, the
product formed is:
A. Ethane C. Ethyl hydrogen sulphate
B. Ether D. Ethene
151. Ethers are inert because they:
A. Are not reactive
B. Are not easily attacked by alkalies and dilute mineral acids
C. Contain O-atom with full Octet
D. Do not contain an active group in their molecules
152. Formation of oxonium salts shows that ethers are:
A. Basic in nature C. Neutral in nature
B. Acidic in nature D. Amphoteric in nature
153. In the reaction; Ether ⎯ ROH+R’I, if R contains 3 carbon atoms, the number of
carbon atoms in R’ may be:
A. 1 or 2 only B. 4 C. 1, 2 or 3 D. 2 or 4
154. In the reactions:

Then the ether is:

A. Simple
B. Mixed
C. Simple or mixed
D. Cannot be predicted unless the nature of alkyl radicals is known
155. What is the functional group isomer of ‘X’ in the following reaction: C2H5I +
NaOC2H5 → X+Nal
A. C2H5I B. C2H4 C. C4H9OH D. C2H5OC2H5
156. Which of the following statement is correct?

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Class: XIi CHEMSITRY CHAPTER#09

A. C2H5Br reacts with alc. KOH to from C2H5OH

B. C2H5Br when treated with metallic sodium give ethane
C. C2H5Br when treated with sodium ethoxide form diethyl ether
D. C2H5Br with Ag2O forms ethyl methyl ether
157. Ethers are obtained by:
A. Reaction of alkyl halide with dry ZnO C. Reaction of alkyl halide with dry Ag2O
B. Reaction of alkyl halide with moist ZnO D. Reaction of alkyl halide with moist Ag2O
158. Ethers can be prepared by:
A. Dehydration of acids C. Hydrolysis of alkyl halides
B. Dehydrogenation of alcohols D. Dehydration of alcohols
159. Dehydration of methanol with conc. H2SO4 at 140°C gives:
A. Dimethyl ether B. Ethene C. Methanol D. Methyl hydrogen sulphate
160. From Williamson’s synthesis preparation, which of the following is possible?
A. Symmetrical ethers only
B. Unsymmetrical ethers only
C. Symmetrical as well as unsymmetrical ether
D. Symmetrical esters
161. Which of the following is not an oxonium ion?
A. H O+ H B. R O+ R C. R O+ R D. None of these

H R H

162. In the Williamson’s synthesis of ethers given by the general equation:

R-X+R’ONa →R-O-R’ the order of reaction for RX is_____.
A. CH3>1°>2°>3° B. CH3<1°<2°<3° C. CH3<1°<2°>3° D. CH3>1°<2°<3°
163. In the Williamson’s synthesis for diethyl ether, which species works as a
nucleophile?
A. Halide ion B. Ethoxide ion C. Oxonium ion D. Hydride ion
164. Heating of methyl phenyl ether with Hl gives:
A. Methanol + iodobenzene C. Methyl alcohol + benzyl alcohol
B. Methyl iodide + iodobenzene D. Methyl iodide + phenol
165. The reaction of an ether with Hl, under suitable conditions, gives three
products, then the ether is:
A. Symmetrical C. Either symmetrical or unsymmetrical
B. Unsymmehical D. Unpredictable in nature
166. In the reaction:

‘A’ is:
A. CH3-CH2-CH2OH B. CH3-CH=CH2 C. CH3-CHOH-CH3 D. CH3-CH=CH-CH3
167. Correct order for acidity of alcohols is:
A. CH3OH>1°>2°>3° C. 1°>CH3OH>2°>3°
B. CH3OH<1°<2°<3° D. 3°>2°>1°>CH3OH
168. Which of the following is most acidic?
OH OH
A. B. OH C. D. OH

NO2

NO2

NO2

169. Strongest base among following is:

- -
A. RO B. C. RCOO D.

170. Following compounds can be arranged in decreasing order of acidity as:

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Class: XIi CHEMSITRY CHAPTER#09
OH
I. II. III.

A. I>II>III C. II>I>III
B. III>I>II D. III>II>I
171. Which one is not a dihydric phenol?
A. Resorcinol C. Catechol
B. Hydroquinone D. Pyrogallol
172. Methanol & ethanol can be distinguished by:
A. Lucas test C. Oxidation reaction
B. Iodoform test D. Both A & B
173. C-O sigma bond in phenol involves overlapping?
2 2 3 2
A. sp -sp C. sp -sp
2 3 3 3
B. sp -sp D. sp -sp
174. Benzyl alcohol belongs to category of alcohols:
A. 1° B. 2° C. 3° D. Phenols
175. Glycerol is a:
A. Monohydric alcohol C. Trihydric alcohol
B. Dihydricalcohol D. Polyhydric alcohol
176. When tertiary alcohol is heated with mixture of K2Cr2O7 & conc. H2SO4 it gives:
A. Aldehyde C. Carboxylic acid
B. Ketone D. Alkene
177. Which of the following is cresol?
OH OH
A. B. OH C. D. OH
Br Cl
CH3 NH2

178. Which statement is incorrect?

A. C-O bond length in phenol is less than alcohol
B. Conjugate base of phenol is more stable than that of alcohol
C. Phenols are more acidic than carboxylic acids
D. Phenol liberates H2 gas with Na
179. Cumene hydroperoxide on decomposition by dil. acid gives mixture of:
A. Phenol and acetaldehyde C. Phenol and water
B. Phenol and acetone D. Phenol and ethyl alcohol
180. Phenol on treatment with conc. HNO3 gives:
A. picric acid C. o-and p-nitrophenol
B. o-and p-nitrophenol D. none of these
181. In the reaction ‘Y’ is:

A. C6H5CHO B. C6H5Cl C. C6H6 D. C6H5OH

182. On distilling 2-hydroxy benzoic acid with Zn dust it gives:
A. Phenol C. Benzaldehyde
B. Benzoic acid D. A polymeric compound
183. Bromination of phenol in non-polar solvent form____.
A. o-bromophenol C. mixture of o and p-bromophenol
B. p-bromophenol D. m-bromophenol
184. An organic compound ‘X’ reacts with excess of HI to give ‘Y’. Further ‘Y’ can
combine with sodium metal to form ethane, then what are ‘X’ and ‘Y’?
A. CH3-O-CH3 and CH3-OH C. CH3-O-CH3 and C2H5-I
B. C2H5-O-C2H5 and C2H5-I D. CH3-O-CH3 and CH3-I
185. Propan-2-ol on oxidation first forms ketones with:
A. Same number of carbon atoms C. Two carbon atoms less

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Class: XIi CHEMSITRY CHAPTER#09

B. One carbon atom less D. Two carbon atoms

186. 3-Methylbutan-2-ol on treatment with HCl gives mainly:
A. 2-Chloro-2-methyl butane C. 2-Chloro-3-methyl butane
B. 2-Chloro-2-methyl propane D. 2,2-dimethyl pentane
187. Wood alcohol is:
A. C6H5OH B. CH3OH C. C2H5OH D. CH3COOH
188. In the reaction:

A. Butane B. n-butane C. Isobutane D. 2-Methyl butane

189. Which one of the following reagents cannot cause C-O bond fission in alcohols:
A. HCl+ZnCl2 B. PCl5 C. SOCl2 D. Na
190. CH3COOH+C2H5OH H2SO4 CH3COOC2H5+H2O
The above reaction is kwon as:
A. Hydrolysis C. Saponification
B. Esterification D. Dehydration
191. Which reaction of phenol does not involve benzene ring?
A. Reaction with dil.HNO3 C. Reaction with H2SO4 at low T
B. Reaction with NaOH D. Reaction with Br2 in H2O
192. Major product for reaction of phenol with dilute HNO3 at low temperature &
reaction with Br2 in carbon disulphide is respectively:
A. ortho, para B. para, ortho C. ortho, ortho D. para, para
193. CH3OOCH reacts with excess of Grignard reagent completely to give final
product:
A. Aldehyde B. Ketone C. Primary alcohol D. Secondary alcohol
194. Which of the following is invert sugar?
A. Maltose B. Sucrose C. Glucose D. Fructose

195. Glycerol is a:
A. Monohydric alcohol C. Trihydric alcohol
B. Dihydric alcohol D. Polyhydric alcohol
196. Which of the following is also known as carbinol?
A. C6H5OH B. CH3OH C. C2H5OH D. HO-CH2-CH2-OH
197. Conversion of glucose to ethyl alcohol in fermentation process of starch is brought about by
enzyme:
A. Diastase B. Invertase C. Zymase D. Amylase
198. Reactivity of alcohols towards nucleophile follows the order:
A. CH3OH>1o>2o>3o C. 1o>2o>3o>CH3OH
o o o
B. CH3OH<1 <2 <3 D. CH3OH>1o>3o>2o
199. Which alcohol of the following reacts at fastest rate with Lucas reagent?
A. CH3CH2CH2OH B. (CH3)2CHOH C. (CH3)3COH D. CH3OH
200. Oxidation product of isopropyl alcohol is:
A. Propanal C. Propanone
B. Propanoic acid D. Ehthanoic acid and formic acid
201. In Dow’s process phenol is prepared from:
A. Sodium benzene sulphonate C. Cumene
B. Chlorobenzene D. Benzene diazonium chloride
202. Decreasing order of acidic strength of ROH, C6H5OH, RCOOH and H2O is:
A. RCOOH>C6H5OH>ROH>H2O C. RCOOH> C6H5OH>H2O>ROH
B. RCOOH>H2O > C6H5OH >ROH D. RCOOH>ROH>C6H5OH>H2O
203. Most acidic among following is:

A. B. C. D.
204. When phenol is treated with dilute HNO3,major product formed is:
A. o-nitrophenol B. p-nitophenol C. Picric acid D. Both A and B
205. When a mixture of methyl alcohol and ethyl alcohol is treated with conc. H2SO4 at 140oC,
product formed is:
A. CH3OCH3 B. C2H5OC2H5 C. CH3OC2H5 D. A.O.T
206. Benzyl alcohol is treated completely with mixture of K2Cr2O7 and conc. H2SO4 to form:

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Class: XIi CHEMSITRY CHAPTER#09
A. Phenol B. Benzoic acid C. Benzaldehyde D. Catechol
207. Catechol and resorcinol are:
A. Functional isomers B. Position isomers C. Metamers D. Tautomers
208. Reduction of salicylic acid with zinc dust produces:
A. Phenol B. Benzene C. Benzoic acid D. Benzyl alcohol
209. Which of the following compound on reduction does not give 1o-alcohols?
A. Aldehyde B. Carboxylic acids C. Esters D. Ketones
210. Products of the given reaction are: CH3OC2H5 + HI→
A. CH3OH and C2H5I C. CH3I, C2H5I and H2O
B. CH3I and C2H5OH D. CH3OH and C2H5OH
211. Esters are produced when:
A. Alcohols react with carboxylic acids
B. Phenols react with carboxylic acids
C. Phenols react with acid halide
D. Both A and C
212. Which one is correct for phenol?
A. Gives white precipitate with aqueous Br2
B. Forms violet coloured solution with FeCl3
C. Gives H2 gas with Na-metal
D. Evolves CO2 gas from carbonates and bicarbonates
213. Reaction of sodium salt of phenol with CO2 is called as:
A. Kolbe-Schmitt reaction C. Etard reaction
B. Gatterman reaction D. Reimer-Tiemann reaction
214. Aldehydes can be reduced to primary alcohols by:
A. NaBH4 B. LiAlH4 C. H2/Ni D. A.O.T
215. Intermolecular dehydration of alcohols leads to the formation of:
A. Ethers B. Alkene C. Alkyne D. Aldehyde
216. Tertiary alcohols are resistant towards oxidation because of:
C. Absence of -H
A. Steric hindrance
D. Hyper conjugating effect of alkyl groups 3o-
B. Low reactivity
alcohols are highly reactive
217. Electrophile in nitrosation of phenol is:
A. NO B. NO C. NO D. NO
218. Catalytic reduction of phenol gives:
A. Cyclohexane B. Benzene C. Cyclohexanol D. Cyclohexene
219. Lucas reagent is a mixture of:
A. conc.HCl and ZnCl2 C. conc. H2SO4 and ZnCl2
B. dil. HCl and ZnCl2 D. dil. H2SO4 and ZnCl2
220. Correct order for acidity of given compounds is:

I. II. III.
A. I > II > III B. III > II > I C. II > I > III D. II > III > I
221. Which of the following statement is incorrect?
A. C-O bond in phenol is shorter than that in alcohols
B. C-O bond in phenol is stronger than that in alcohols
C. C-O bond in phenol is formed by sp2-sp2 overlap
D. C-O bond in alcohol is formed by sp3-sp3 overlap
222. Which of the following possess most acidic H?
A. CH3CH2OH B. (CH3)2CHOH C. CH3OH D. H2O
223. Major product for reaction of phenol with conc. H2SO4 at low temperature is:
A. o-hydroxy benzene sulphonic acid
B. p-hydroxy benzene sulphonic acid
C. equimolar mixture of A and B
D. phenol does not undergo sulphonation with H2SO4
224. Anisole is:
A. A primary alcohol C. An aromatic ether
B. A phenol D. A symmetrical ether

225. Which of the following does not contain ketone group?

A. Camphor C. Glucose
B. Fructose D. All of these
226. Which of the following does not give white precipitate with sodium bisulphite?
A. HCHO C. CH3COCH3
B. CH3CHO D. C2H5COC2H5
227. Compound which gives aldol when treated with 10% NaOH solution is:
A. (CH3)3C-CHO C. C6H5CHO
B. Cl3C-CHO D. CH3-CH2-CHO
228. Reaction of aldehyde with Fehling’s solution is a type of:
A. Nucleophilic addition reaction B. Substitution reaction
A. Condensation reaction C. Redox reaction

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Class: XIi CHEMSITRY CHAPTER#09
229. Compound which does not respond to iodoform test is:

A. CH3-CHO B. CH3COCH3 C. D. H-CHO

230. CH3-CHO CH3-CH2-CH3 Reaction is known as:
A. Oxidation C. Clemmenson reduction
B. Wolf-Kishner Reduction D. Addition reaction
231. Benzaldehyde when treated with 50% NaOH solution it gives:
A. Sodium benzoate & benzyl alcohol
B. Sodium benzoate & phenol
C. Benzoic acid & benzyl alcohol
D. Benzoic acid & sodium phenoxide
232. Alkaline solution of cupric hydroxide complexed with tartarate ions is called as:
A. Fehling’s solution C. Tollen’s reagent
B. Benedict’s solution D. Brady’s reagent
233. Aldehydes does not give alkanes with:
A. Zn-Hg/HCl B. N2H4/KOH C. HI/red P D. LiAlH4
234. Formaldehyde & acetone can be differentiated by:
A. Fehling’s test C. Iodoform test
B. Tollen’s test D. All of these
235. A compound with molecular formula C3H6O gives yellow orange precipitate with 2,4-DNPH.
Gives red precipitate of cuprous oxide with Fehling’s solution. Hence compound is:
A. CH2=CH-CH2OH C. CH3COCH3
B. CH3CH2CHO D. Both B & C
236. When CH3COCH2CH3 is oxidized with K2Cr2O7 & conc. H2SO4 it gives:
A. Formic acid & propanonic acid C. Acetic acid only
B. Formic acid & acetic acid D. Propanoic acid only
237. Oxidation product & catalytic reduction product of CH3CHO is respectively:
A. CH3COOH, CH3CH2OH C. CH3CH2OH, CH3CH2OH
B. CH3COOH, CH3COOH D. CH3CH2OH, CH3COOH
238. A silver mirror is formed in:
A. Fehling’s test C. Tollen’s test
B. Benedict’s test D. 2,4-DNPH test
239. Decreasing order for reactivity of compounds is:
I. CH3-CHO II. CH3COCH3 III. H-CHO IV. C2H5COC2H5
A. II>IV>I>III B. I>III>II>IV C. III>I>II>IV D. I>III>IV>II
240. Acetaldehyde (CH3CHO) & benzaldehyde (C6H5-CHO) can be differentiated by:
A. NaHSO3 C. Tollen’s test
B. 2,4-DNPH test D. Fehling’s test
241. Iodofrom test can not differentiate between:
A. Methanol & Ethanol C. Propanone & butanone
B. Formaldehyde & acetaldehyde D. None of these
242. Which compound does not give Cannizzaro’s reaction?

A. CCl3CHO B. C. H-CHO D. CH3-CHO

243. Which statement is incorrect?
A. -bond of CO group involves sp2-sp2 overlapp
B. C-O bond of CO group is polar in nature
C. Carbon of CO group is electrophilic in nature
D. Carbonyl group undergoes electrophilic addition reaction
244. Catalytic reduction of acetone produces:
A. Propane B. 1-propanol C. 2-propanol D. Propanoic acid
245. Acid catalyzed hydration of ethynyl benzene in presence of mercuric ions gives:
A. Benzophenone C. Benzoic acid
B. Acetophenone D. Methyl benzoate
246. Formalin is a _____ solution of formaldehyde.
A. 60% B. 40% C. 80% D. 20%
247. Which one does not react with Fehling’s solution?
A. Acetone B. Glucose C. Fructose D. Formic acid
248. Paraldehyde is a polymer of:
A. Formaldehyde C. Benzaldehyde
B. Acetaldehyde D. Propion aldehyde
249. Which combination of the following produce wine red or brick red ppt?
A. Ketone +2,4-DNPH C. Methyl ketone + I2+NaOH
B. Aldehyde +Fehling’s solution D. Ketone + sodium nitroprusside
250. Compound which gives both iodoform test & Fehling’s test positive is:
A. Formaldehyde B. Acetone C. Ethanol D. Acetaldehyde
251. Aldols are the organic compounds that contain functional group:

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Class: XIi CHEMSITRY CHAPTER#09
A. –CHO, -CO- B. –COOH, -CHO C. –CO-, -OH D. –CHO, -OH
252. Product of the given reaction CH2=CH-CHO ⎯⎯⎯ P is:
E. Propanol F. Propenol G. Propane H. Propene
253. Acetaldehyde on aldol condensation forms product:
A. 3-hydroxy butanal C. But-2-enal
B. Crotonaldehyde D. Both B & C
254. Aldol condensation can occur between:
A. Two aldehydes C. Aldehyde & Ketone
B. Two ketones D. All of these

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Class: XIi CHEMSITRY CHAPTER#09

ANSWER KEY
CHEMISTRY XII CHAPTER# 09
1. B 46. A 91. B 136. C 181. B 226. D
2. B 47. A 92. B 137. C 182. C 227. D
3. A 48. E 93. B 138. B 183. D 228. C
4. D 49. B 94. B 139. C 184. A 229. D
5. B 50. E 95. A 140. C 185. C 230. C
6. B 51. A 96. C 141. A 186. B 231. A
7. D 52. A 97. C 142. B 187. B 232. A
8. C 53. C 98. D 143. C 188. B 233. D
9. E 54. A 99. B 144. C 189. D 234. D
10. B 55. C 100. B 145. B 190. B 235. B
11. E 56. C 101. B 146. D 191. B 236. C
12. B/C 57. C 102. C 147. B 192. A 237. A
13. C 58. B 103. A 148. D 193. D 238. C
14. A 59. A 104. A 149. A 194. B 239. C
15. C 60. B 105. C 150. B 195. B 240. D
16. E 61. D 106. C 151. D 196. B 241. C
17. B 62. B 107. C 152. A 197. C 242. D
18. B 63. D 108. D 153. A 198. B 243. D
19. C 64. D 109. B 154. A 199. C 244. C
20. D 65. D 110. C 155. C 200. C 245. B
21. C 66. B 111. A 156. C 201. B 246. B
22. D 67. B 112. D 157. C 202. C 247. A
23. E 68. B 113. B 158. D 203. C 248. B
24. D 69. A 114. B 159. A 204. A 249. D
25. B 70. D 115. C 160. C 205. D 250. D
26. C 71. C 116. B 161. D 206. B 251. D
27. D 72. A 117. B 162. A 207. B 252. A
28. D 73. B 118. D 163. B 208. C 253. C
29. E 74. C 119. D 164. D 209. D 254. D
30. B 75. A 120. A 165. B 210. B
31. B 76. B 121. C 166. C 211. D
32. C 77. A 122. A 167. A 212. D
33. C 78. A 123. D 168. D 213. A
34. C 79. D 124. D 169. A 214. D
35. E 80. A 125. A 170. B 215. A
36. B 81. B 126. A 171. D 216. C
37. A 82. C 127. B 172. B 217. A
38. B 83. A 128. B 173. B 218. C
39. A 84. C 129. C 174. A 219. A
40. C 85. A 130. B 175. C 220. D
41. A 86. D 131. D 176. B 221. C
42. C 87. C 132. D 177. C 222. C
43. B 88. A 133. D 178. B 223. A
44. B 89. D 134. D 179. A 224. C
45. E 90. C 135. B 180. D 225. C

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