E

E
AC

AC

AC
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E

E
AC

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CH102 Practice Exam #1 ____ 17. The addition of bromine (Br2) to an alkene
results in an alkane because one bond of the multiple

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WAY longer than actual exam,
E

E
bond is broken.
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answers are at the end
____ 18. One of the halogenation reactions occurs
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True/False when a halogen, a member of group VIIA, reacts with

E
alkene.

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AC
Indicate whether the sentence or statement is true or
false.
____ 19. Cyclic compounds do not undergo
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E

E
____ 1. Organic chemistry can be defined as the halogenation reactions.
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chemistry of carbon-containing compounds.
____ 20. Markovnikov's rule states that when a
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hydrogen and a different molecule (OH-, Br-) add to a
E

E
____ 2. Organic compounds can contain other
double bond the hydrogen goes to the end of the double
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AC
elements such as oxygen or nitrogen.
bond that already had more hydrogens
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____ 3. Organic compounds are always derived from a
E

E
living source. ____ 21. An alkene with one multiple bond can be
AC

AC

AC
converted to an alkane by hydration.
____ 4. An unlimited number of carbon atoms can
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____ 22. Polymers are compounds that are composed
E

E
bond together to form chains.
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AC
of repeating units chemically bound to each other.
____ 5. Most organic compounds contain ionic bonds.
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____ 23. The chemical properties of alkynes are very
E

E
____ 6. There are more inorganic compounds than different from those of alkenes.
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AC

AC
organic compounds.
____ 24. 2-butyne can exist as cis- and trans- isomers.
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E

E
____ 7. Most inorganic compounds have a higher
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AC
melting point than organic compounds. ____ 25. Two moles of hydrogen gas would be
required to convert one mole of 2-butyne into butane.
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E

E
____ 8. Inorganic compounds are never found in living
____ 26. Benzene is an alkene with more than one
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AC

AC
systems.
multiple bond.
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____ 9. Isomers differ from each other in the number
E

of neutrons present in each.

E
____ 27. Phenyl is the name given to benzene when it
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AC
is a substituent of a larger molecule.
____ 10. Isomers always have the same empirical
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____ 28. Aromatic compounds dissolve well in a

E

E
(molecular) formula.
nonpolar solvent.
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AC

AC
____ 11. Isomers have identical physical and chemical
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properties. Multiple Choice
E

Identify the letter of the choice that best completes the

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AC

____ 12. Carbon-carbon bonds are usually strong and statement or answers the question.
covalent.
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____ 29. What is the reason why there are so many

E

E
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AC

AC
____ 13. A characteristic of the alkanes is that they burn organic compounds?
in air. a. Organic compounds are produced by living things.
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b. There are cyclic organic compounds, and none of the

E

inorganic compounds are cyclic.

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AC

____ 14. CH3CH2CH2CH2 is the formula for a saturated

hydrocarbon. c. Carbon atoms can form stable covalent bonds with other
carbon atoms.
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E

____ 15. Alkenes must have at least two carbon atoms. d. Organic compounds can be larger than inorganic compounds.
AC

AC

AC

____ 16. Alkenes only have one double bond.

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E

E
AC

AC
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CE

CE
AC
A

A
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 E

E
AC

AC

AC
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E

E
AC

AC
____ 30. Which applies to the manner in which by IUPAC rules.
carbon bonds in alkanes? c. The naming system for hydrocarbons requires the

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E

E
a. The bonds are formed with carbon using an sp3 configuration. identification of the longest carbon chain.
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AC

AC
b. The bonds between carbon and other atoms are ionic. d. The naming system for organic compounds requires
c. carbon to carbon bonds are expected to be double bonds. and IUPAC name and a common name.
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d. The bonds formed by carbon all use p orbitals.

E
AC

AC
____ 37. Identify the correct statement. Cycloalkanes
____ 31. Which statement referring to functional groups a. can have as few as two carbons.
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E

E
is correct? Functional groups are b. are unsaturated hydrocarbons.
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AC
a. where nothing happens in a chemical reaction c. have more hydrogens than straight chain alkanes with
b. the parts of molecules used to classify organic molecules the same number of carbons
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c. where most chemical reaction occur d. these are all wrong
E

E
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d. both b and c

____ 38. Which of the following terms applies to the

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E

E
____ 32. Identify the correct statement: The alkanes alkanes?
AC

AC

AC
represent one family of organic compounds composed of a. hydrophobic
carbon compounds b. hydrophilic
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a. in which the halogens are a major component c. soluble
E

E
AC

AC
b. in which there is at least one double bond between d. bases
carbons
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c. that are composed only of carbon and hydrogen
E

E
d. in which hydrogens can be bonded to other hydrogens ____ 39. What is a characteristic shared by the alkanes?
AC

AC

AC
a. solids
b. polar
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E

E
____ 33. Which of the following formulas represents an c. flammable
AC

AC
organic compound? d. colored
a. CH4
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b. CH4CH2CH3 GR
E

E
c. CH3CH3CH3 ____ 40. Which of the following is a used for alkanes?
AC

AC

AC
d. they all do a. fuel
b. lubricant
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GR
E

c. solvent E
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AC
____ 34. Which of the following is an alcohol? d. all of the above
a. CH3CH2COOH
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b. CH3CH2OH
E

E
____ 41. Which of the following formulas represents a
AC

AC

AC
c. CH3COCH3
d. CH3CH2Br saturated hydrocarbon?
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a. C 2H6
E

b. C 2H4
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AC

____ 35. What is meant by the term "saturated" when c. C 3H6

describing hydrocarbons? d. C 5H10
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a. The hydrocarbons are saturated with water and are wet.

E

E
AC

AC

AC
b. The hydrocarbons are saturated with carbons in its
parent chain. ____ 42. All of the members of the alkane series of
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c. The hydrocarbons are saturated with hydrogens and hydrocarbons have the general formula
E

have only single bonds between carbons. a. C nH2n

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AC

d. The compound is pure b. C nHn

c. C nH2n+2
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E

d. C nH2n-2
AC

AC

AC

____ 36. The naming of organic compounds is specific.

Which is an incorrect statement?
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a. The smaller of the compounds have been known long

E

enough to have common names.

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AC

b. The naming system of organic compounds is set out

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CE

CE
AC
A

A
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GR
 E

E
AC

AC

AC
GR

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GR
E

E
AC

AC
____ 43. Which of the following structural formulas b. butane
represents an unbranched alkane? c. hexane

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E

E
a. d. octane
AC

AC

AC
b.
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____ 49. Which is the longest carbon chain?

E
c.

AC

AC
d.
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E

E
AC

AC

AC
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E

E
____ 44. Which of the following compounds exhibits a. 9
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AC
structural isomerism? b. 6
a. propane c. 7
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E

E
b. methane d. 10
AC

AC

AC
c. butane
d. ethane
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E

E
____ 50. The IUPAC name for is
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AC
____ 45. How many structural isomers are possible for a. 2-ethylbutane
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butane (molecular formula C4C 10)? b. 2-methylbutane
E

E
a. 2 c. 3-methylpentane
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AC
b. 3 d. 3-ethylbutane
c. 4
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E

E
d. 5
AC

AC
____ 51. The compound has
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____ 46. Which of the following compounds is a the IUPAC name GR

E

E
structural isomer of 2-methylbutane? a. 4-isopropyloctane
AC

AC

AC
a. propane b. 5-isopropyloctane
b. w-methylpropone c. 5-sec-butyloctane
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GR
E

c. butane d. 4-propyloctane E
AC

AC
d. pentane
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____ 52. The structural formula of 1-bromo-2,2-

E

E
dimethylpropane is
AC

AC

AC
____ 47. A structural isomer of is a.
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E

a.
AC

AC

b.
b.
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GR
E

E
c. c.
AC

AC

AC
d.
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GR

d.
E

E
AC

AC

____ 48. The name for the following structure will end
with
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E

E
AC

AC

AC
GR

GR

GR
E

E
AC

AC

a. ethane
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CE

CE
AC
A

A
GR

GR

GR
 E

E
AC

AC

AC
GR

GR

GR
E

E
AC

AC
____ 53. A general formula for cycloalkanes is c. carbon dioxide and carbon monoxide
a. C 2H2n+2 d. carbon monoxide and carbon

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E

E
b. C nH2n
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AC

AC
c. C nH2n-2
d. C nH2n-4 ____ 60. Alkanes react readily with
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a. sodium hydroxide

E
b. hydrochloric acid

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AC
c. sulfuric acid
d. none of the above
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E

E
____ 54. The IUPAC name of
AC

AC

AC
contains an ethyl group located at position
____ 61. Name a difference between a saturated and an
a. 1
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unsaturated hydrocarbon.
E

E
b. 2
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AC
a. Saturated hydrocarbons are composed of only carbon
c. 3
and hydrogen, and unsaturated hydrocarbons include
d. 4
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other atoms than just carbon and hydrogen.
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E
b. Saturated hydrocarbons do not contain multiple bonds
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AC

AC
between carbons, but unsaturated hydrocarbons do
contain multiple bonds.
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____ 55. A correct IUPAC name for is c. Unsaturated hydrocarbons a flammable, but saturated
E

E
AC

AC
a. 1-bromo-3-ethyl-1-methylcyclopropane hydrocarbons aren't flammable.
b. 1-bromo-2-ethyl-1-methylcyclopropane d. Saturated hydrocarbons are essentially insoluble.
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c. 1-bromo-1-ethyl-2-methylcyclopropane Unsaturated hydrocarbons are soluble.
E

E
d. 2-bromo-1-ethyl-2-methylcyclopropane
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AC
____ 62. What number would be used to indicate the
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E

E
double bond position in the IUPAC name for CH 3CH2CH
AC

AC
= CHCH3?
a. 1
____ 56. The component is _____-1,2-
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b. 2 GR
E

E
dimethylcyclopropane.
c. 3
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AC
a. cis
b. trans d. 4
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c. tis
E

d. crans
E
AC

AC
____ 63. In the IUPAC name for the following
compound, the -Br group is located at position
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E

E
____ 57. An alkane with 10 carbon atoms is a _____ at
.
AC

AC

AC
room temperature.
a. solid a. 1
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b. liquid b. 2
E

c. gas c. 3
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AC

d. not possible to tell d. 4

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E

E
AC

AC

AC
____ 58. Alkanes are _____ in water and _____ than
water. ____ 64. The IUPAC name of is
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E

a. insoluble, less dense a. 3-ethyl-1-butene

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AC

b. soluble, less dense b. 2-ethyl-2-butene

c. insoluble, more dense c. 3-ethyl-3-butene
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d. soluble, more dense d. 2-ethyl-1-butene

E

E
AC

AC

AC

____ 59. Complete combustion of pentane produces

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E

a. carbon monoxide and water

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AC

b. carbon dioxide and water

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CE

CE
AC
A

A
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GR
 E

E
AC

AC

AC
GR

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E

E
AC

AC
CH3—CH=CH2 + H2O
____ 65. The IUPAC name of is

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E

E
a. 2-methyl-1,4-pentadiene a.
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AC

AC
b. 2-methyl-2,4-dipentene
c. 4-methyl-1,3-pentadiene b. CH3CH2CH2—OH
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d. 4-methyl-2,4-pentadiene c. CH3CH2CH3

E
AC

AC
GR d. CH3CH2CH2—SO4

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E

E
____ 71. Select the major product that would result
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AC

AC
____ 66. A correct IUPAC name for is from the reaction:
a. 5-bromo-1,3-cyclohexadiene
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b. 2-bromo-1,3-cyclohexadiene
E

E
c. 2-bromo-1,4-cyclohexadiene CH3CH2CH=CH2 + HBr−>
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AC
d. 3-bromo-1,5-cyclohexadiene
a.
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E

E
b. CH2CH2CH2CH3
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AC

AC
____ 67. Which of the following compounds could exist c.
in the form of two geometric isomers?
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a. d. CH3CH2CH2CH2Br
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E
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AC
b.
____ 72. The conversion of cyclohexene to cyclohexane
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c.
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E
requires the reagent(s)
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AC

AC
a. HCl
b. H2O and H2SO4
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d. c. H2 and H 2SO4
E

E
d. H2 and Pt
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AC
GR

____ 68. Which of the following compounds is trans-3- GR

E

E
____ 73. The addition polymer produced from
hexene?
AC

AC

AC
CH3—CH=CH—Cl is
a.
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a.
E

E
AC

AC
b.
b.
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GR
E

E
c.
AC

AC

AC
c.
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GR

d.
GR
E

d.
AC

AC
GR

GR
E

E
AC

AC

AC
____ 69. Which of the following represents an addition
____ 74. The monomer of teflon (polytetrafluoroethene)
reaction?
is
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a. HX + C4H8−>C 4H9X
E

b. X2 + C3H6−>C 3H5X + HX
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AC

a.
c. C 4H8−>C 4H6 + H2
d. more than one response is correct b.
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E

E
AC

AC

AC

c.
____ 70. Select the major product that would result d. CF2=CF2
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from the reaction:

E

E
AC

AC
GR

GR
CE

CE
AC
A

A
GR

GR

GR
 E

E
AC

AC

AC
GR

GR

GR
E

E
AC

AC
____ 75. Which is the formula for an alkene? b.
a. CH3CHCH2

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E

E
b. CH3CH2CH2
AC

AC

AC
c. CH3CH3CH2 c.
d. all of these.
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d.

E
AC

AC
____ 76. Which is the formula for an alkyne?
a. CH3CH2CCH 2
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E

E
b. CH3CH2C2CH 3
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AC

AC
c. CH3CH2CHCH ____ 82. Acetylene (ethyne gas) is commercially useful
d. CH3CH2CCH 2 as:
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GR
a. a starting material for plastics
E

E
b. a fuel for torches
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AC
____ 77. Which is a difference between butane and c. an ingredient in pesticides
butene? d. a component in paint formulations
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E

E
a. butane burns and butene does not
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AC

AC
b. the presence of a double bond
c. they are isomers ____ 83. What is the characteristic of aromatic
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d. the presence of a triple bond compounds that is responsible for them being named
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E
aromatic compounds?
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AC
a. The compounds have a pleasant smell.
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____ 78. Which is a difference between butene and b. These compounds contain a benzene ring.
E

E
cyclobutene? c. It must contain a hydrocarbon chain that is either
AC

AC

AC
a. They are isomers. saturated or unsaturated and at least 3 carbons long.
b. Cyclobutene has 2 double bonds, butene does not. d. There is more than one correct response.
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GR
E

E
c. The phase varience of the infrared transconductance
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AC
is asymetric.
d. Cyclobutene has fewer hydrogens than butene. ____ 84. Which of the following compounds is not
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considered to be aromatic? GR
E

E
a.
AC

AC

AC
____ 79. Which is a difference between butyne and
cyclobutyne?
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b.
E

a. Cyclobutyne can't exist! E

AC

AC
b. Butyne's multiple bond is not as strong as that of
cyclobutyne. c.
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c. Cyclobutyne burns much hotter than butyne because

E

E
AC

AC

AC
of the greater unsaturation.
d.
d. Both b and c are differences between the molecules.
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GR
E

E
AC

AC

____ 80. The correct IUPAC name for the compound

CH2—C C—CH 2—CH2—Br is ____ 85. Which of the following structures is wrong?
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E

a. 4-bromopentyne a.
E
AC

AC

AC
b. 1-bromo-2-pentyne
c. 1-bromo-3-pentyne
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d. 5-bromo-2-pentyne b.
E

E
AC

AC

____ 81. Select the product of the following reaction: c.

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E

E
AC

AC

AC

d.
GR

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GR

a.
E

E
AC

AC
GR

GR
CE

CE
AC
A

A
GR

GR

GR
 E

E
AC

AC

AC
GR

GR

GR
E

E
AC

AC
GR

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E

E
Answer Section 21. T 42. C 64. D
AC

AC

AC
TRUE/FALSE 22. T 43. B 65. C
1. T 23. T 44. C 66. A
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2. T 24. F 45. A 67. D

E
3. F 25. T 46. D 68. C

AC

AC
4. T 26. T 47. D 69. A
5. F 27. T 48. B 70. A
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GR
E

E
6. F 28. T 49. A 71. C
AC

AC

AC
7. T MULTIPLE CHOICE 50. C 72. D
8. F 29. C 51. A 73. B
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GR
9. F 30. A 52. A 74. D
E

E
10. T 31. D 53. B 75. A
AC

AC
11. F 32. C 54. C 76. C
12. T 33. D 55. B 77. B
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GR
E

E
13. T 34. B 56. A 78. D
AC

AC

AC
14. F 35. C 57. B 79. A
15. T 36. D 58. A 80. D
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GR
16. F 37. D 59. B 81. B
E

E
AC

AC
17. T 38. A 60. D 82. B
18. T 39. C 61. B 83. B
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19. F 40. D 62. B 84. C
E

E
20. T 41. A 63. C 85. B
AC

AC

AC
GR

GR

GR
E

E
AC

AC
GR

GR
E

E
AC

AC

AC
GR

GR

GR
E

E
AC

AC
GR

GR
E

E
AC

AC

AC
GR

GR

GR
E

E
AC

AC
GR

GR
E

E
AC

AC

AC
GR

GR

GR
E

E
AC

AC
GR

GR
E

E
AC

AC

AC
GR

GR

GR
E

E
AC

AC
GR

GR
CE

CE
AC
A

A
GR

GR

GR