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Ci-25 - MSDS

This document summarizes the components, properties, and handling requirements of a chemical blend used as an acid inhibitor. The product contains several hazardous chemicals requiring protective equipment for handling. It is flammable and corrosive, with acute health effects including burns and blindness. Chronic exposure may cause cancer due to a naphthalene component. The product must be stored and shipped following regulations for flammable and corrosive materials.

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Atif Aslam
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515 views4 pages

Ci-25 - MSDS

This document summarizes the components, properties, and handling requirements of a chemical blend used as an acid inhibitor. The product contains several hazardous chemicals requiring protective equipment for handling. It is flammable and corrosive, with acute health effects including burns and blindness. Chronic exposure may cause cancer due to a naphthalene component. The product must be stored and shipped following regulations for flammable and corrosive materials.

Uploaded by

Atif Aslam
Copyright
© Attribution Non-Commercial (BY-NC)
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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BJ SERVICES COMPANY MATERIAL SAFETY DATA SHEET

SECTION I - GENERAL INFORMATION


PRODUCT NAME: ITEM NUMBER: CHEMICAL DESCRIPTION: PRODUCT USE: SUPPLIER: ADDRESS: EMERGENCY TELEPHONE NUMBER PREPARED BY: DATE PREPARED:

Region USA

CI-25
423445, 488052 A blend of quaternary salts, alcohols, formamide, and ethoxylated nonylphenol Inhibitor Acid BJ Services Company 11211 FM 2920 Tomball, TX 77375 (800)424-9300 for CHEMTREC (703)527-3887 for International BJ Services Environmental Group (281)351-8131 September 3, 2003 Supersedes: August 4, 2000
HMIS HAZARD INDEX HEALTH: FLAMMABILITY: REACTIVITY: PERSONAL PROTECTION: 3 3 0 i

SECTION II - HAZARDOUS COMPONENTS


HAZARDOUS COMPONENTS
Methanol Isopropanol Substituted alcohol Haloalkyl heteropolycycle salt Propargyl alcohol Formamide Ethoxylated 4-nonylphenol Heavy aromatic naphtha Pine oil Naphthalene

CAS #
67-56-1 67-63-0 Proprietary Proprietary 107-19-7 75-12-7 26027-38-3 64742-94-5 8002-09-3 91-20-3

PERCENT
10 30 10 30 15 10 30 15 10 30 5 10 15 15 0.1 1

HAZARD
Flammable, systemic effects Flammable, irritant Corrosive, combustible Corrosive Sensitizer, toxic Exposure limit Irritant Combustible, irritant Irritant, combustible Combustible, suspect cancer agent

SECTION III - FIRE AND EXPLOSION HAZARD DATA


FLASHPOINT (METHOD): UPPER EXPLOSION LIMIT(% BY VOL): LOWER EXPLOSION LIMIT(% BY VOL): AUTO-IGNITION TEMPERATURE: EXTINGUISHING MEDIA: 64F / 17.8C (TCC) 36.0 0.8 N.E. Dry powder, alcohol foam, carbon dioxide or other extinguishing agent suitable for Class B fires. For large fires use water spray or fog, thoroughly drenching the burning material. Water mist may be used to cool closed containers. In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit. Flammable liquid; may release vapors that form flammable mixtures at or above the flash point. Empty product containers may contain product

SPECIAL FIRE FIGHTING PROCEDURES: EXPLOSION DATA:

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HAZARDOUS COMBUSTION PRODUCTS:

residue. Do not pressurize, cut, weld, or expose containers to flame or other sources of ignition. Oxides of carbon, oxides of nitrogen

SECTION IV - HEALTH HAZARD DATA


PRIMARY ROUTES OF ENTRY: Skin and eye contact

ACUTE OVEREXPOSURE EFFECTS: SKIN CONTACT: SKIN ABSORPTION: May cause severe irritation or tissue damage depending on the length of exposure and the type of first aid administered. Methanol may be absorbed through the skin and cause central nervous system effects which may result in permanent visual changes including blindness. Corrosive. Will cause eye burns and permanent tissue damage. Not a likely route of exposure. Irritating, in high concentrations, to the eyes, nose, throat and lungs. Not a likely route of exposure. Corrosive; causes chemical burns to the mouth, throat and stomach. Can cause blindness. This product contains naphthalene. The IARC has evaluated naphthalene and determined it to be possibly carcinogenic to humans (Group 2B).

EYE CONTACT: INHALATION: INGESTION:

CHRONIC OVEREXPOSURE EFFECTS:

EXPOSURE LIMITS: HAZARDOUS COMPONENT Methanol Isopropanol Substituted alcohol Haloalkyl heteropolycycle salt Propargyl alcohol Formamide Ethoxylated 4-nonylphenol Heavy aromatic naphtha Pine oil Naphthalene ACGIH TLV 200 ppm 400 ppm N.E. N.E. 1 ppm 10 ppm N.E. N.E. 5 mg/m3 (oil mist) N.E. OSHA PEL 200 ppm 400 ppm N.E. N.E. 1 ppm 20 ppm N.E. N.E. 5 mg/m3 (oil mist) N.E.

CARCINOGENICITY, REPRODUCTIVE EFFECTS: This product contains naphthalene. The IARC has evaluated naphthalene and determined it to be possibly carcinogenic to humans (Group 2B, based on sufficient evidence in experimental animals and inadequate evidence in humans). TERATOGENICITY, MUTAGENICITY: No effects listed.

TOXICITY STUDIES: LD(50) N.E. LC(50) N.E.

SECTION V - FIRST AID PROCEDURES


FOR EYES: FOR SKIN: Immediately flush eyes with large amounts of water for at least 15 minutes. Get prompt medical attention. Immediately flush with large amounts of water; use soap if available. Remove contaminated clothing, including shoes, after flushing has

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FOR INHALATION: FOR INGESTION:

begun. Get prompt medical attention. Remove to fresh air. If breathing has stopped, give artificial respiration. Keep person warm, quiet and get medical attention. DO NOT induce vomiting. If conscious, wash out mouth and give water to drink. Never give anything by mouth to an unconscious person. Contact a physician at once.

SECTION VI - PHYSICAL DATA


APPEARANCE AND ODOR: SPECIFIC GRAVITY: VAPOR PRESSURE: VAPOR DENSITY (air=1): EVAPORATION RATE: BOILING POINT: FREEZING POINT: SOLUBILITY IN H20: pH: Dark red-amber liquid, alcoholic odor. 0.99 at 60F N.E. N.E. 2.1 (calculated) 169F / 76C N.E. Dispersible N.E.

SECTION VII - REACTIVITY DATA


CHEMICAL STABILITY: INCOMPATIBLE MATERIALS: HAZARDOUS POLYMERIZATION: HAZARDOUS DECOMPOSITION PRODUCTS: Stable Strong oxidizers Does not polymerize May evolve oxides of carbon, oxides of nitrogen under fire conditions.

SECTION VIII - SPECIAL/PERSONAL PROTECTION


VENTILATION: The use of mechanical ventilation is recommended whenever this product is used in a confined space. Where engineering controls are not feasible, assure use is in an area where there is natural air movement. Where concentrations in air may exceed the limits given, the use of a half face filter mask or air supplied breathing apparatus is recommended. In event of emergency or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. Nitrile, Viton, polyvinyl alcohol gloves Wear a face shield with chemical splash goggles. Eyewash bottles or other rinsing equipment should be easily accessible. A full slicker suit is recommended if gross exposure is possible.

RESPIRATORY PROTECTION:

PROTECTIVE GLOVES: EYE PROTECTION: OTHER PROTECTIVE EQUIPMENT:

SECTION IX - HANDLING PRECAUTIONS


LEAK AND SPILL PROCEDURES: Wear specified protective equipment. Eliminate all sources of ignition. Dike and pump large spills into DOT approved salvage containers. Soak up residue and small spills with an inert absorbent and place in DOT approved containers for disposal. If this product becomes a waste it meets the requirements of a RCRA hazardous waste with the waste code D001. Always dispose of according to all local, state, and federal laws and regulations. Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Avoid release

WASTE DISPOSAL:

HANDLING & SPECIAL EQUIPMENT:

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STORAGE REQUIREMENTS:

of vapors or mists into workplace air. Store in well-ventilated area away from heat, sparks and ignition sources. Keep container closed when not in use. Store in a cool area.

SECTION X - REGULATORY INFORMATION


SHIPPING INFORMATION PROPER SHIPPING NAME: HAZARD CLASS: UN/NA NUMBER: PACKING GROUP W/ "PG": SUBSIDIARY RISK: REPORTABLE QUANTITY (RQ): EMERGENCY RESPONSE GUIDE #: ENVIRONMENTAL INFORMATION SARA TITLE III SECTION 302/304 SECTION 311/312 SECTION 313 This product does not contain ingredients listed as an Extremely Hazardous Substance. Immediate, Delayed, Fire This product contains the following ingredients (at a level of 1% or greater) which appear on the List of Toxic Chemicals: Methanol CAS# 67-56-1 10 30 % Propargyl alcohol CAS# 107-19-7 1 5 % Isopropanol CAS# 67-63-0 10 30% Flammable liquids, corrosive, n.o.s. (contains methanol and quaternary ammonium compound) 3 UN 2924 PG II Corrosive 18,760 lbs. (naphthalene) 132

OTHER REGULATORY INFORMATION TSCA INVENTORY: CALIFORNIA PROP 65: All of the components in this product appear on the TSCA inventory. This product contains the following components (in trace quantities) that are regulated under California Proposition 65: Naphthalene < 1%

The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof. Vendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, vendor assumes no responsibility for injury to vendee or third persons proximately caused by abnormal use of the material even if reasonable safety procedures are followed. Furthermore, vendee assumes the risk in his use of the material.

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