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Metals and Alloys

Metals are highly valuable materials that are used in hundreds of products. They have properties like strength, conductivity, and malleability that make them useful for many applications. The document discusses factors that determine which metals are used, like cost of extraction and availability. It also covers the structure of metals at an atomic level and how this relates to their properties. Metals can be recycled to save energy and resources compared to extracting raw materials. Alloys are mixtures of metals that can be engineered to have tailored properties.
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0% found this document useful (0 votes)
214 views45 pages

Metals and Alloys

Metals are highly valuable materials that are used in hundreds of products. They have properties like strength, conductivity, and malleability that make them useful for many applications. The document discusses factors that determine which metals are used, like cost of extraction and availability. It also covers the structure of metals at an atomic level and how this relates to their properties. Metals can be recycled to save energy and resources compared to extracting raw materials. Alloys are mixtures of metals that can be engineered to have tailored properties.
Copyright
© Attribution Non-Commercial (BY-NC)
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PPT, PDF, TXT or read online on Scribd
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What are metals used for?


How many different uses of metal can you spot?

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Why are metals important?


Metals are a highly valuable group of materials, used for hundreds of products and produced in huge quantities.

35,500,000 tons of aluminium were produced in 2005.


The production of copper increased by more than 20 times in the 20th century. Gold is worth more than 10,000 per kilogram. Metals have played a vital role in human development. Periods of civilization are even classified by the metals that were used during those times, such as the Iron Age.
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Using metals

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Uses of metals activity

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What else can metals be used for?


It is easy to find products made from metals, but there are other uses of metals that are less obvious. Metals are used as catalysts to speed up reactions. Nickel is used as a catalyst to make margarine. Platinum is used in catalytic converters in car engines to clean up exhaust fumes and reduce pollution. Compounds containing metals have many uses. For example, metal compounds are used to colour materials including stained glass and even make-up! Can you find any other uses of metals?
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What decides what metals are used for?


It is not only the properties of a metal that determines its use. Cost. A metal may have the best properties for a job but it might be too expensive.

For example, silver is a better conductor than copper but it is too expensive to be used for electric wires.
Extraction method. This can greatly affect the price and availability of a metal. For example, aluminium only became a commonly used metal in the late 19th century as better extraction methods made it cheaper. What other factors might determine how metals are used?
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Do all metals behave in the same way?


What are the properties of different metals?

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What are the typical properties of metals?


Metals are known to have certain properties: solid at room temperature high melting point good conductors of electricity and heat malleable: they can be hammered into sheets ductile: they can be drawn into wires strong dense. Why do metals have these particular properties?

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What is the structure of metals?


The properties of metals can be explained by examining the structure of their atoms. lattice structure Metals have a lattice structure. The atoms in a pure metal are arranged in closely-packed layers. This makes them strong. The outer electrons of each atom separate from the atom and become delocalized. These form a sea of electrons free to move in the lattice, which allows metals to conduct heat and electricity.

sea of electrons

The sea of electrons also produces strong bonds between atoms. This is why metals have high melting points.
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Why can metals be shaped?


When a metal is hit, the layers of atoms are able to move over each other. metal before it is hit metal after it is hit

force

force

Bonds between atoms are not broken because the electrons are free to move, but the shape of the metal can be changed. This behaviour is what makes metals: malleable they can be shaped ductile they can be drawn into wires.
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What is corrosion?
Corrosion is the gradual destruction of a metal due to reactions with other chemicals in its environment. Over time, corrosion changes the appearance of the metal as it breaks down and it becomes weaker. Corrosion can seriously damage metallic objects and structures. Coating the surface of a metal with paint and certain chemicals can protect it from corrosion. What happens if the protective coating becomes damaged?

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Do all metals corrode?


Metals behave differently when exposed to the environment.

Gold is an unreactive metal and does not corrode easily. In many cultures, gold is considered a precious metal and is used to make sacred and decorative objects.
Items made from gold can survive for thousands of years and have even been found in good condition underwater. In general, objects made from metals that corrode easily, do not survive for as long.
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Why doesnt aluminium corrode?


Aluminium is a very reactive metal. However, it does not corrode in the presence of oxygen. Why is this? oxygen in the atmosphere coating of oxygen atoms

aluminium atoms
The outer aluminium atoms react with oxygen in the atmosphere. This forms a thin layer of aluminium oxide on the metals surface, which protects the metal from corrosion.
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What is rusting?
Rusting is the specific name given to the corrosion of iron. It is a chemical reaction between iron, oxygen and water. The chemical name for rust is hydrated iron oxide. Rust can form on cars and buildings, making them unsafe. It is an expensive problem. Salt can increase the rate of rusting. This iron bolt is on a seaside structure and is nearly completely corroded. What is the word equation for the formation of rust? iron
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oxygen

water hydrated iron oxide


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Rate of corrosion experiment

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Finding metals
Are some metals easier to find than others?

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Where do metals come from?


Metals can be found in the Earths crust combined with other elements or uncombined as pure substances. Some unreactive metals, like gold, silver and copper, can be found uncombined as elements.

Metals that are found in a pure form are said to occur native.
Most metals are actually found combined with other elements, as compounds in ores. These metals must be extracted from their ores before they can be made useful.

Highly reactive metals, such as titanium, require complicated extraction. This can increase the cost of the pure metal.
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How does reactivity affect extraction?


The reactivity of a metal determines how it is extracted. potassium sodium calcium magnesium aluminium (carbon) zinc iron lead (hydrogen) copper silver gold platinum Metals above carbon in the reactivity series must be extracted using electrolysis. Electrolysis can also be used to purify copper. Metals below carbon can be extracted from their ores by reduction using carbon, coke or charcoal. Platinum, gold, silver and copper can occur native and do not need to be extracted.
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increasing reactivity
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How is carbon used to extract metals?


Metals that are less reactive than carbon can be extracted from their ores by burning with carbon. Iron is extracted by this method in a blast furnace. The iron ore is heated with carbon-rich coke at very high temperatures.

raw materials

The iron collected from a blast furnace is only 96% pure.


Usually, this product needs to be treated further because the impurities make the iron molten iron brittle.
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hot air

molten slag
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What is electrolysis?
Metals that are more reactive than carbon are extracted using electrolysis. This process uses an electrical current to extract the metal. Aluminium is extracted from its ore, bauxite, using this method. Electrolysis is also used to further purify metals, such as copper, after extraction with carbon. Electrolysis is more expensive than using a blast furnace, and this increases the price of the metal.

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Extraction quiz

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Can metals be recycled?


Metals are easy to recycle and do not change their properties. What are the benefits of recycling metals?

Saves energy Uses less resources Reduces waste

Recycling aluminium uses 95% less energy than extracting it from its ores. Recycling one car saves over 1000 kg of iron ore and over 600 kg of coal. 14 million fewer dustbins would be filled per year by recycling aluminium in the UK.

Less damage Recycling reduces the need to mine to environment sensitive areas for new ores.

Profitable

Recycled copper can be resold for up to 90% of what it was worth when new.
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What are the drawbacks of recycling?


Metallic materials are often mixtures of different metals. Pure metals can be obtained by purifying recycled materials but this can be expensive and may use more electricity than extracting metals from ores. Recycled copper is too impure for electric wires. However, scrap copper can be used in products, such as coins and ornaments, that do not need pure metal. Sorting mixed metals for recycling can be difficult. Iron and steel (a mixture of iron with other elements) are exceptions. These materials can be separated from waste using a magnet.
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Recycling or extraction?

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Guess the metal activity

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What is an alloy?
An alloy is a mixture of a metal with at least one other element. Steel is a common example of an alloy. It contains iron mixed with carbon and other elements. Adding other elements to a metal changes its structure and so changes its properties. The final alloy may have very different properties to the original metal. By changing the amount of each element in an alloy, material scientists can custom-make alloys to fit a given job.
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What types of alloys are there?


Alloys have been used for thousands of years. Bronze, an alloy of copper and tin, was commonly used by civilizations before iron extraction methods were developed. Other well-known alloys are: brass an alloy of copper and zinc. It does not tarnish and is used for door knobs, buttons and musical instruments. solder an alloy of zinc and lead. It is used in electronics to fix components to circuit boards. amalgam an alloy of mercury with silver or tin. It is used for dental fillings because it can be shaped when warm and resists corrosion.
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Is gold an alloy?
Although pure gold is sometimes used in electronics, gold jewellery is always a mixture of gold and other metals. Pure gold is actually quite soft. Adding small amounts of other metals makes the gold hard enough to use in jewellery. Alloying gold with different metals also affects its colour. The familiar yellow gold is an alloy of gold mixed with copper and silver. Adding more copper than silver gives redder shades. White gold is an alloy of gold with nickel, platinum or palladium. Around 12% of people may be allergic to the nickel in white gold.
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When is a copper coin not a copper coin? When it is a copper-coated alloy! Copper coins used to be made from pure copper but most copper coins used around the world are now made from copper alloys. Previously, as the value of copper increased, the metal used to make the coin became worth more than the actual coins. A melted-down, pure copper coin could have been sold for more than the face value of the coin! Since 1992, UK copper coins have been made from copper-plated steel and are magnetic. A magnet can be used to separate copper coins by age.
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What is steel?
Steel is an alloy of iron and other elements, including carbon, nickel and chromium. Steel is stronger than pure iron and can be used for to suspension bridges! everything from sauce pans

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Why is steel stronger than iron?


The atoms in pure iron are arranged in densely packed layers. These layers can slide over each other. This makes pure iron a very soft material. The atoms of other elements are different sizes. When other elements are added to iron, their atoms distort the regular structure of the iron atoms. It is more difficult for the layers of iron atoms in steel to slide over each other and so this alloy is stronger than pure iron.
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What types of steel are there?


Steel can contain up to 2% carbon. Varying the amount of carbon gives steel different properties. For example, increasing the carbon content, increases the hardness of the steel. Different types of steel are classified by how much carbon they contain: low carbon steel contains less than 0.25% carbon. high carbon steel contains more than 0.5% carbon. Two other important types of steel are:

stainless steel an alloy of iron that contains at least 11% chromium and smaller amounts of nickel and carbon. titanium steel an alloy of iron and titanium.
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Using different types of steel

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Using different types of steel activity

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Whats so clever about smart alloys?


A smart material can change one or more of its physical characteristics under the influence of an external stimulus. Shape memory alloy is a type of smart material made from metals that returns to its original shape after being deformed. Nitinol is a type of shape memory alloy made from nickel and titanium. This material can be used to make a pair of glasses that remembers its shape and does not break when crushed. Nitinol has also been used to hold badly broken bones in place whilst they heal.
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Glossary (1/2) alloy A mixture of a metal with at least one other element. amalgam An alloy of mercury that is used for dental
fillings.

blast furnace A tall oven used to extract iron from iron


ore by burning it with carbon at high temperatures.

brass An alloy of copper and zinc that is used for


ornaments.

corrosion The destruction of a metal caused by


reactions with chemicals in the environment.

ductile The ability of metals to be drawn into wires. electrolysis A process that uses electricity to extract or
purify metals.

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Glossary (2/2) malleable The ability of metals to be bent or hammered


into different shapes.

native The natural occurrence of a metal as an element


in the environment.

ore A rock that contains a metal combined with other


elements in concentrations that make it profitable to mine.

rusting The specific name for the corrosion of iron and


iron-containing alloys, such as steel.

shape memory alloy A type of alloy that can return to


its original shape after being deformed.

solder An alloy of lead and tin that is used in electronics. steel An alloy containing iron and other elements.
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Anagrams

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Multiple-choice quiz

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