Engineering

Metallurgy
Sushil Varma
140100035

Introduction

Material science & engineering can be divided into 2 parts :

(1)Material science

(2)Material engineering

Materials science involves investigating the relationships that

exist between the structures and properties of materials.

Materials engineering is, on the basis of these structureproperty

correlations, designing or engineering the structure of a
material to produce a predetermined set of properties.

Structure :The structure of a material usually relates to the

arrangement of its internal components.

Property : A property is a material trait in terms of the kind and

magnitude of response to a specific imposed stimulus.
Generally, definitions of properties are made
independent of material shape and size.

Virtually all important properties of solid materials may be

grouped into six different categories: mechanical, electrical,
thermal, magnetic, optical, and deteriorative.
In addition to structure and properties, two other important
components are involved in the science and engineering of
materialsnamely, processing and performance.
Relationship of these four components is shown in following
chart
Processin
g

Structure

Properties

Performan
ce

Classification of Materials

Solid materials have been conveniently grouped into three

basic classifications: metals, ceramics, and polymers

This scheme is based primarily on chemical makeup and

atomic structure, and most materials fall into one distinct
grouping or another, although there are some intermediates.

Along with these three groups of materials, materials can be

classified into one more group named as composites, which
is combination of two or more materials from three above
groups.

Ceramics

Ceramics are compounds between metallic and nonmetallic elements;

they are most frequently oxides, nitrides, and carbides

Inorganic solid with crystalline properties or crystalline amorphous

solid

High moduli

Very hard but brittle

Their strength in tension (brittle fracture strength) < strength in

compression ( crushing strength) [about 15 times larger]

Ceramic materials are relatively stiff and strongtheir stiffness and

strengths are comparable to those of the metals

Resistive to heat and electricity, typically good insulators.

May be transparent, translucent, or opaque

Metals

Good strength and high modulus

Relatively high density

Good electrical and thermal conductivity

Good ductility and reflectivity

Ions attract giving a closed pack structure of short bonds

Good Lustrous appearance after polishing

Crystalline material

Metal is a crystalline material in which ions are connected indirectly

through the field of free electrons surrounding them

Composites

A composite is composed of two (or more) individual materials, which

come from the categories like metals, ceramics, and polymers

Composite displays the properties of combination which are not

displayed by single component. Also it incorporates best
characteristics of each component.

The Carbon fiber reinforced polymer CFRP composites (carbon fibers

that are embedded within a polymer) are used in some aircraft and
aerospace applications, as well as high-tech sporting equipment (e.g.,
bicycles, golf clubs, tennis rackets, and skis/snowboards). These
materials are stiffer and stronger than the glass fiber-reinforced
materials ,yet they are more expensive.

One of the most common and familiar composites is fiberglass, in

which small glass fibers are embedded within a polymeric material
(normally an epoxy or polyester).The glass fibers are relatively strong
and stiff (but also brittle), whereas the polymer is ductile (but also
weak and flexible). Thus, the resulting fiberglass is relatively stiff,
strong, flexible, and ductile. In addition, it has a low density

Elastomers

Elastomer is a type of polymer

It has viscoelasticity (both elasticity and viscosity)

Has very weak inter-molecular forces

Generally have low elastic moduli

Has high failure strength

Amorphous materials

High extensibility and flexibility

Polymers

Large molecule composed of repeating structural units.

Many of them are organic compounds that are chemically based on

carbon, hydrogen, and other nonmetallic elements (viz. O,N, and Si).

Low moduli (about 50 times less than metals)

Large elastic deflections

Low density

Low stiffness and strength

Extremely ductile and pliable

Low electrical conductivity and are nonmagnetic

In general chemically inert and unreactive in many environments

One major drawback to the polymers is their tendency to soften

and/or decompose at modest temperatures, which, in some
instances, limits their use.

Porous Materials

Porous and foamed metals exhibit various characteristics

that differ from bulk metals, including possessing a low
density and large surface area. These metals are expected
to be used as lightweight materials, catalyst carriers,
electrodes, vibration and acoustic energy damping
materials, impact energy absorption materials,
etc.However, porous and foamed metals all suffer from
deteriorating mechanical properties such as strength,
stiffness, and fatigue due to the inhomogeneous pore
number density distribution and pore size.

Examples: RocksandSoil(e.g.,aquifers,petroleum
reservoirs),Zeolites,Biological
tissues(e.g.bones,wood,cork), and man made materials
such as CementsandCeramics

Here is a small chart comparing

properties of metals, ceramics and
polymers.
PROPERTIES

METALS

CERAMICS

POLYMERS

DUCTILITY

HIGH

VERY LOW

LOW

CONDUCTIVITY

HIGH

VERY LOW

VERY LOW

APPEARANCE

LUSTROUS

ELASTICITY

HIGH

VERY LOW

LOW

FREE
ELECTRONS

HIGH

--------

---------

DENSITY

HIGH

LOW

VERY LOW

NON LUSTROUS NON LUSTROUS

The 4 Main Steps for material selection

The rst task is that of translation:

converting the design requirements into a
prescription for selecting a material. This
proceeds by identifying the constraints that
the material must meet and the objectives
that the design must fulll.

The second task screening: eliminating the

material that cannot meet the constraints.

This is followed by the ranking step, ordering

the survivors by their ability to meet a
criterion of excellence, such as that of
minimizing cost.

The nal task is to explore the most

promising candidates in depth, examining
how they are used at present, how best to
design with them, case histories of failures
and a step we call documentation

Thespecific strengthis
a
material'sstrength(forc
e per unit area at
failure) divided by its
density. It is also known
as
thestrength-toweight
ratio
orstrength/weight
ratio. In fiber or textile
applications, tenacity is
the
usual
measure
ofspecific
strength.
The SI unit forspecific
strengthis Pa/(kg/m3),
or N

Stress and Strain

DEFINITIONS OF STRESS AND

STRAIN

when external forces are applied to objects made of elastics

materials, they produce changes in size and shape of the object

STRAIN: it is the relative change in the shape or size of an

object externally applied forces

STRESS: it is the inertial force(per unit area) associated with a

strain

Engineering Stress and True

Stress
Engineering Stress

Engineering

stress
is the load divided
by the initial crossarea.

True Stress

True

stress is the
load divided by the
cross-area at that
instant.

Engineering Strain and True

Strain
Engineering Strain
Engineering
strainis the
amount that a
material deforms
per unit length in
a tensile test.
Also known as
nominal strain.

True Strain
True

strain is
rate of
instantaneous
increase in
instantaneous
gauge length

TRUE STRESS STRAIN CURVE

A comparison of typical
tensile engineering
stressstrain and
true stressstrain
behaviors. Necking
begins at point M
on the engineering
curve, which corresponds
to on the
true curve.
The corrected true stress
strain curve takes
into account the
complex stress state
within the neck
region.

STRESS-STRAIN CURVE

ELASTIC ZONE
HOOKES LAW:

it states that, for relatively smalldeformationsof an object, the

displacementor size of the deformation is directly proportional to
the deforming force or load. Under these conditions the object returns
to its original shape and size upon removal of the load.
In the early (low strain) portion of the curve, many materials obey
Hookes law to a reasonable approximation, so that stress is
proportional to strain The region up to which this
proportionality(linear) holds is called the ELASTIC ZONE constant of
proportionality being
the modulus of elasticity or Youngs modulus
=E
the deformation is called elastic deformation

MODULUS OF ELASTICITY

Modulus of elasticity is
proportional to the slope of the
interatomic forceseparation
curve

The magnitude of the modulus of

elasticity is a measure of the
resistance to separation of
adjacent atoms

The modulus of elasticity

diminishes
with increasing temperature

ELASTIC LIMIT: the elastic limit is strain below which

the material can regain its original shape if the forces
are released.

doesn't matter if the stress-strain relation is linear or

not i.e. is not concerned with the proportional limit.

Eg:rubber. the strain-strain law is highly non-linear

(and hence not
"proportional") but still elastic.

PLASTIC DEFORMATION

The part of the stress-strain diagram after the yield point.

At the yield point, the plastic deformation starts.

Plastic deformation is permanent. It is due to the application of sustained stress

beyond the elastic limit.

Work hardening: also known asstrain hardeningorcold working, is the

strengtheningof a metal byplastic deformation.

This strengthening occurs because ofdislocationmovements and dislocation

generation within thecrystal structureof the material.

YIELDING AND YIELD STRENGTH

YIELD STRESS: As mentioned above, From this point on in the

tensile test, some permanent deformation occurs in the material
and is said to react plastically to any further increase in load or
stress. The material will not return to its original, unstressed
condition when the load is removed

The yield strength is defined as the stress required to produce a

small, amount of plastic deformation

This can also be defined as the point after which, stress and strain
are no longer proportional
In the best way,

Yield stress is the single point on the stress strain curve at which
the tangent modulus is changing at the greatest rate with respect
to increasing strain

ULTIMATE TENSILE STRESS

Theultimate tensile strength(UTS) is the
maximum resistance to fracture.
It is equivalent to the maximum stress that a
material can withstand while
stretched or pulled before falling or breaking
Ultimate tensile strength is also known as
tensile strength or the ultimate.

Atomic Structure

All matter is made up of atoms

containing a nucleus of protons and
neutrons and surrounding clouds, or
orbits, of electrons.

Atoms can transfer or share

electrons; in doing so, multiple
atoms combine to form molecules.
Molecules are held together by
attractive forces called bonds

Atomic structure-arrangement of atoms

within the metals

One early outgrowth of quantum

mechanics was the simplified Bohr
atomic model, in which electrons are
assumed to revolve around the atomic
nucleus in discrete orbitals, and the
position of any particular electron is
more or less well defined in terms of its
orbital.

Atomic bonding in solids

Types:
Primary
Ionic
Covalent
Metallic
Secondary
Dipole-dipole
H -bonds
Dipole-induced-dipole
Fluctuating dipoles

Ionic Bonding
Occurs between + and - ions.
Requires electron transfer.
Large difference in electronegativity required.
Example: NaCl
Na
(metal)
unstable
Na
(cation)
stable

Cl
(nonmetal
) unstable

electron

Coulombi
c
Attraction

Cl
(anion)
stable

Since z1 = +1 for Na+ and z2= -1 for Cl

Negative energy means attraction .
Will the atoms collapse on themselves?

Repulsive
energy
(e.g. e-e
repulsion)

B and n depend on atoms involved.

In many cases n ~ 8.

Covalent bonding
Requires shared electrons
Electronegativities are comparable.

Atomic Orbitals:

Hybridizatio
n:

Example:
CH4

Metallic Bonding
Arises from a sea of donated valence electrons
(1, 2, or 3 from each atom).

+
+
+
+
+
+

Fixed ion cores

(nuclei and inner
electrons)

+
+

sea of
electrons

Adapted from Fig. 2.11, Callister

6e.

Primary bond for metals and their alloys

Large atomic radius and small IP will more likely lead to metallic
bonding.

Secondary Bonding: Intermolecular forces

Van der Waals
Dipole-dipole interaction: secondary bond between
molecules with permanent dipole moments
secondary
+ + bonding

H Cl

secondar
y
bondin
rg bon
ding

secon
da

Hydrogen
Bonding

H Cl

Bohr Model of Zinc Atom

Number of Protons/Electrons:30
Number of Neutrons:35
Number of Energy Levels:4
First Energy Level:2
Second Energy Level:8
Third Energy Level:18
Fourth Energy Level:2

Zinc: Crystal Structures

Space group:P63/mmc

Space group number:194

Structure:hcp (hexagonal close-packed)

Cell parameters:

a: 266.49 pm

b: 266.49 pm

c: 494.68 pm

: 90.000

: 90.000

: 120.000

Metallic Bonds in Solid Mg

Magnesium has the outer electronic structure 3s2. Both

of these electrons become delocalised, so the "sea" has
twice the electron than the kernel. The remaining "ions"
also have twice the charge and so there will be more
attraction between "ions" and "sea".

More realistically, each magnesium atom has 12 protons

in the nucleus. The nucleus is screened from the
delocalised electrons by the 10 electrons in the
1s22s22p6orbitals.

That means that there will be a net pull from the

magnesium nucleus of 2+.

Crystal Structures
Thecrystal latticecan be thought of as an array of 'small boxes' infinitely
repeating in all three spatialdirections. Such aunit cellis the smallest unit of
volume that contains all of the structural and symmetry information to buildup the macroscopic structure of the lattice bytranslation.

Atomic packing factor(APF),packing efficiencyorpacking fractionis

the fraction of volume in acrystal structurethat is occupied by
constituent particles.
It is dimensionless and always less than unity.

BRAVAIS LATTICES
Name

Number of Bravais lattices

Conditions

Triclinic

a1a2a3

Monoclinic

a1a2a3
== 90

a1a2a3
=== 90

Tetragonal

a1= a2a3
=== 90

Cubic

a1= a2= a3
=== 90

Trigonal

Hexagonal

Orthorhombic

a1= a2= a3
==<12090

a1= a2a3
== 90
= 120

SIMPLE CUBIC LATTICE

The simple cubic lattice contains 1

lattice point per unit cell.

The simple cubic lattice consists of

the lattice points identified by the
corners of closely packed cubes.

PACKING FRACTION : 52 %

Coordination no. = 6
(# nearest neighbors)

BODY CENTERED CUBIC

The body centered lattice equals the simple cubic lattice with the
addition of a lattice point in the center of each cube.

The body centered cubic lattice contains 2 lattice point per unit cell.

PACKING FRACTION : 68 %

Coordination no. =
8
All of the metals in Group IA (Li, Na, K, and
so on), the heavier metals in Group IIA (Ca,
Sr, and Ba), and a number of the early
transition metals (such as Ti, V, Cr, Mo, W,
and Fe) pack in a body-centered cubic
structure.

FACE CENTERED CUBIC

The face centered lattice equals the simple cubic lattice

with the addition of a lattice point in the center of each
of the six faces of each cube.

The face centered cubic lattice contains 4 lattice point

per unit cell.

PACKING FRACTION : 74 %

Coordination no. =
12

Eg. Ag, Al, Au, Ca, Co, Cu, Ni, Pb, and Pt

Hexagonal Close Packing

ABAB... Stacking Sequence
3D Projection

2D Projection

Top layer
Middle layer
Bottom layer
Adapted from Fig. 3.3,
Callister 6e.

Coordination # = 12
APF = 0.74

Eg. Be, Co, Mg, and Zn, as well as the rare

gas He at low temperatures
10

Density computations for a

crystal structure

A knowledge of the crystal structure of a metallic solid

permits computation of its theoretical density through
the relationship

n = number of atoms associated with each unit cell

A = atomic weight
V = volume of the unit cell
N = Avogadros number

Polymorphism and Allotropy

Some metals, as well as nonmetals, may have more than one

crystal structure, a phenomenon known as polymorphism.
When found in elemental solids, the condition is often termed
allotropy.

The prevailing crystal structure depends on both the

temperature and the external pressure.

One familiar example is found in carbon: graphite is the

stable polymorph at ambient conditions, whereas diamond is
formed at extremely high pressures.

Also, pure iron has a BCC crystal structure at room

temperature, which changes to FCC iron at 912 C ( 1674 F).

Most often a modification of the density and other physical

properties accompanies a polymorphic transformation.

Idealized cooling curve for pure

iron at atmospheric pressure

Radius Ratio Rule

Miller Indices

A shorthand most common convention for expressing

specific points, directions and planes in the crystallattice systems

Specific point coordinate for all

atom position for a BCC unit cell

Different Direction Within a

Unit Cell

FCC and BCC

Atomic packing fraction different in the two cases

Family of planes: all planes that are crystallograhically

equivalent- that is having the same atomic packing,
indicated as {hkl}

For example, {100} includes (100),(010),(001) planes

{110} includes (110),(101),(011) etc

For some crystal structures, several non-parallel

directions with different indices are actually
equivalent; this means that the spacing of atoms along
each direction is same. For example, in cubic crystals,
all the directions represented by the following indices
are equivalent: [100,[-100],[0-10],[010].

Equivalent directions are grouped into a family, which

are enclosed in the angle brackets, thus <100>

Three Important Crystal

Plane

Three Important Crystal Plane

Parallel planes are equivalent

Miller indices of planes

A miller index is a series of coprime integers that are

inversely proportional to the intercepts of the crystal
face or crystallographic planes with the edge of the unit
cell.

It describes the orientation of a plane in the 3-D lattice

with respect to the axes.

The general form of the Miller index is (hkl) where h, k

and l are integer relatedto the unit cell along the a, b,c
crystal axes.

Miller Indices

Rules for determining Miller Indices:

1. Determine the intercepts of the face along the

crystallographic axes, in terms of unit cell dimensions.

2. Take the reciprocals

3. Clear fractions

4. Reduce to lowest terms

Procedure for determining h k and l

If planes passes through origin, translate plane or choose new origin

Determine intercepts of planes on each of the axes in terms of unit

cell edge lengths (lattice parameters) Note: if plane has no intercept
to an axis(i.e, it is parallel to that axis, intercept is infinity)

Determine reciprocal of the three intercepts

If necessary, reduce these three numbers by a common factor which

converts all the reciprocals to small integers

The three indices are not separated by commas and are enclosed in
curved brackets

If any of the indices is negative, a bar is placed in top of that index

Linear and Planar Densities

Linear density (LD) is defined as the number of atoms per unit length whose
centers lie on the direction vector for a specific crystallographic direction
LD = number of atoms centered on direction vector
length of direction vector

LD110 = 2 atoms = 1
4R

2R

Planar Density (PD) is taken as the number of atoms per unit area that are
centered on a particular crystallographic plane

PD = number of atoms centered on a plane

area of plane

PD= 2 atoms/8R22 =1/4R22

Lecture-4

Crystallograpic planes and

directions in HCP unit cells

The procedure described previously for selecting miller

indices of planes and directions in cubic unit cells also
apply to the HCP UNIT CELL. However, we use a fourdigit notation (hkil) for hexagonal crystals.

The indices describing planes and directions in

hexagonal unit cells are called Mille-Bravais
indices(instead of simply Miller indices as in the cubic
system).

In the HCP cell, three axes (a1,a2,a3) are arranged at

120 degrees to each other in the basal plane and the
fourth axes (c) is perpendicular to this plane

Crystallographic Planes and

direction in HCP Unit Cells

Indices for HCP Planes

The miller-Bravais indices of a plane in the HCP system

refer to the four axes a1,a2,a3 and c and are
represented as (hkil). a1-h, a2-k, a3-i, c-l.

The indices of the plane must comply with the condition

that

i=-(h+k) or h+k+i=0

To determine the MillerBravais indices of a HCP plane

Indices for HCP DIRECTIONS

Defects in the crystalline

Structure

Defects in the crystalline structure can have a

tremendous effect on a material behavior

We can modify and improve many of the physical,

electrical, magnetic and optical properties of crystalline
materials by controlling the imperfections in their
lattice structure.

CLASSIFICATION OF DEFECTS BASED ON DIMENSIONALITY

0D
(Point defects)

1D
(Line defects)

2D
(Surface / Interface)

3D
(Volume defects)

Vacancy

Dislocation

Surface

Twins

Impurity

Disclination

Interphase
boundary

Precipitate

Frenkel
defect

Dispiration

Schottky
defect

Grain
boundary

Faulted
region

Twin
boundary

Voids /
Cracks

Stacking
faults

Thermal
vibration

Defects

Point Defects: Vacancies, Interstitial and Substitutional.

Line Defects(Dislocations): Edge and screw dislocations

Surface Defects: Grain Boundaries and Material Surface.

Vacancy Defects

A vacancy defect is formed when an atom is missing

from a normal atomic site in a crystalline structure.

The number of vacancies present in a material increases

exponentially as the temperature increases.

nv= n exp(-Q/RT)

Simple point defects in mono

elemental substances

Diffusion in Ionic crystals

1. Vc with an equal number of Va Schottky Pair

2. Interstital A with equal number of Va anion

Frenkel pair

3. Interestital C with an equal number of Vc .

Cation Frenkel pair

4. Interestital C with an equal number of interestital A

Anti-schottky Pair

Diffusion Mechanisms

1. Excahange Mechanisms

2. Ring Mechanisms

3. Interstitial Mechanisms

4. Interstitialcy Mechanisms

5. Crowdion Mechanisms

6. vacancy Mechanisms

7.Di-Vacancy Mechanisms

8.Relaxation Mechanisms

9. Ascending Mechanisms

10.Dislocation Pipe diffusion

11. Grain Boundary Diffusion Mechanisms

12. Surface Diffusion Mechanisms

Dislocations

1.Edge

2. Mixed

3. Screw

Edge dislocation: an extra portion of a plane of atoms

or half plane, the edge of which terminates within the
crystal. This is termed as edge dislocation.

DISLOCATIONS
Edge dislocation
Screw dislocation

Plastic Deformation in Crystalline Materials

Slip
(Dislocation
motion)

Twinning

Phase Transformation

Creep Mechanisms

Grain boundary sliding

Vacancy diffusion
Dislocation climb

Plastic deformation of a crystal by shear

S h e a r s tre s s
a

S h e a r in g s tre s s ()

Sinusoidal
relationship
Realistic curve

D is p la c e m e n t

As a first approximation the

stress-displacement curve can be
written as

2x
m Sin

At small values of displacement

Hookes law should apply

x
G G
a

For small values of x/b

2x
m

Hence the maximum shear

stress at which slip should occur

G b
m
2 a

If b ~ a

G
m :
2

 The shear modulus of metals is in the range 20 150 GPa

G
m :
2

The theoretical shear stress will be

in the range 3 30 GPa

Actual shear stress is 0.5 10 MPa

I.e. (Shear stress)theoretical > 100 * (Shear stress)experimental !!!!

DISLOCATIONS
Dislocations weaken the crystal

A dislocation has associated with it two vectors:

t A unit tange nt vector along the dislocatio n line

b The Burgers vector

DISLOCATIONS

EDGE

MIXED

SCREW

Usually dislocations have a mixed character and Edge and Screw

dislocations are the ideal extremes
DISLOCATIONS

Random

Structural
Geometrically necessary dislocations

Burgers Vector

Edge dislocation

Crystal with edge dislocation

Perfect crystal

RHFS:
Right Hand Finish to Start
convention

Edge dislocation

Direction of t vector
dislocation line vector

Direction of bb vector

 Dislocation is a boundary between the slipped and the unslipped parts

of the crystal lying over a slip plane
The intersection of the extra half-plane of atoms with the slip plane
defines the dislocation line (for an edge dislocation)
Direction and magnitude of slip is characterized by the Burgers vector
of the dislocation
(A dislocation is born with a Burgers vector and expresses it even in
its death!)
The Burgers vector is determined by the Burgers Circuit
As the periodic force field of a crystal requires that atoms must move
from one equilibrium position to another b must connect one
lattice position to another (for a full dislocation)
Dislocations tend to have as small a Burgers vector as possible
The edge dislocation has compressive stress field above and tensile
stress field below the slip plane

Compressive stress
field

Tensile stress
field

Conservative
(Glide)

Motion of dislocations
On the slip plane

Motion of
Edge
dislocation
Non-conservative
(Climb)

Motion of dislocation
to the slip plane

Climb involves addition or subtraction of a row of atoms below the

half plane
+ve climb = climb up removal of a plane of atoms
ve climb = climb down addition of a plane of atoms

Edge Dislocation Glide

Shear stress

Surface
step

Edge Climb

Positive climb
Removal of a row of atoms

Negative climb
Addition of a row of atoms

Screw dislocation

[1]

Slip plane 2

Screw dislocation cross-slip

b
Slip plane 1

The dislocation is shown cross-slipping from the blue plane to the green plane

 b
MIXED DISLOCATIONS

Mixed dislocations

Pure screw

Pure Edge

Motion of a mixed dislocation

[1]

We are looking at the plane of the cut (sort of a semicircle centered in the lower left corner). Blue circles denote
atoms just below, red circles atoms just above the cut. Up on the right the dislocation is a pure edge dislocation
on the lower left it is pure screw. In between it is mixed. In the link this dislocation is shown moving in an
animated illustration.

[1] http://www.tf.uni-kiel.de/matwis/amat/def_en/kap_5/backbone/r5_1_2.html

Role of Dislocations

Slip

es
Deformation Process
Creep
Fatigue
Fracture

Diffusion
(Pipe)

Structural
Incoherent Twin
Grain boundary
(low angle)

Semicoherent Interfaces
Disc of vacancies
~ edge dislocation

Dislocation Motion
Dislocation motion leads to plastic deformation.
An edge dislocation moves in response to a shear stress applied in a
direction perpendicular to its line.
Extra half-plane at A is forced to the right; this pushes the top halves
of planes B, C, D in the same direction.
By discrete steps, the extra 1/2-plane moves from L to R by
successive breaking of bonds and shifting of upper 1/2-planes.
A step forms on the surface of the crystal as the extra 1/2-plane
exits.

98

c08f03

Slip

The process by which plastic deformation is produced by

dislocation motion is called slip (movement of dislocations).

The extra -plane moves along the slip plane.

Dislocation movement is similar to the way a caterpillar

moves. The caterpillar hump is representative of the extra
-plane of atoms.
99

Energy of Dislocations

The presence of dislocation distorts the bonds and costs energy to the
crystal lattice . Hence dislocations have distortion energy associated with
them .

The energy is expressed as Energy per unit length of dislocation line

Units[J/m]

Edge Compressive and tensile stress fields

Screw Shear stress fields

The energy of dislocation can approximately be calculated from linear

elastic theory. The distortions are very large near the dislocation line and
the linear elastic description fails in this region called the core of
dislocation

ESD Gb2/2

EED Gb2/2(1-v)

G ()Shear Modulus
b |b|
v Poisson ratio

Slip Systems

In single crystals there are preferred planes where

dislocations move (slip planes). Within the slip planes
there are preferred crystallographic directions for
dislocation movement (slip directions).The set of slip
planes and directions constitute slip systems.

The slip planes and directions are those of highest

packing density . Since the distance between atoms is
shorter than the average , the distance perpendicular to
the plane has to be longer than average. Being
relatively far apart , the planes can slip more easily
relatively to each other.

FCC and BCC crystals have more slip systems as

compared to HCP. Thus FCC and BCC crystals are more
ductile.

FCC

Pure edge dislocation

The extra- half plane consists of two planes of atoms

BCC

Pure edge dislocation

Dislocation line vector

1

[1
12]

2
(1 10),(111)

[1
1
1]

2
(1 10)
Burgers vector
Extra half plane

(111)

1
1 12
2

1
111
2

(1 10)

(1 10)
Slip plane

Burgers vectors of dislocations in cubic crystals

Crystallography determines the Burgers vector
fundamental lattice translational vector lying on the slip plane
Monoatomic FCC

<110>

Monoatomic BCC

<111>

Monoatomic SC

<100>

Close packed volumes tend to remain close packed,

close packed areas tend to remain close packed &
close packed lines tend to remain close packed

Slip systems

Crystal

Slip plane(s)

Slip direction

FCC

{111}

<110>

HCP

(0001)

<11 20>

BCC
Not close packed

{110}, {112}, {123}

[111]

Anisotropic

No clear choice
Wavy slip lines

Role of Dislocations

Slip

es
Deformation Process
Creep
Fatigue
Fracture

Diffusion
(Pipe)

Structural
Incoherent Twin
Grain boundary
(low angle)

Semicoherent Interfaces
Disc of vacancies
~ edge dislocation

Questions:

Q1) If the angle of the burger vector be 37 degrees with

the slip plane in mixed dislocation, what would be the
ratio of burger vector corresponding to edge dislocation
and screw dislocation?

Ans: burger vector in screw dislocation is parallel with

slip plane and perpendicular in edge dislocation.

So, b(screw)= bcos37

B(edge)=bsin37

Ratio= tan37= 0.6!

Questions:

Q2) What is the difference between positive and

negative dislocation climb?

Ans: During positive climb, the crystal shrinks in the

direction perpendicular to the extra half plane of atoms
because atoms are being removed from the half plane.
Since negative climb involves an addition of atoms to
the half plane, the crystal grows in the direction
perpendicular to the half plane. Therefore, compressive
stress in the direction perpendicular to the half plane
promotes positive climb, while tensile stress promotes
negative climb. This is one main difference between slip
and climb, since slip is caused by only shear stress.