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Uygfc

This document discusses key concepts in thermodynamics including: 1. Total pressure in a system is equal to the sum of partial pressures of each component. 2. Fugacity is a measure of escaping tendency and has the same units as pressure for ideal gases. It is used to study phase and chemical reaction equilibrium. 3. Fugacity coefficient is defined as the ratio of fugacity to pressure and is a measure of how non-ideal a gas is.

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40 views10 pages

Uygfc

This document discusses key concepts in thermodynamics including: 1. Total pressure in a system is equal to the sum of partial pressures of each component. 2. Fugacity is a measure of escaping tendency and has the same units as pressure for ideal gases. It is used to study phase and chemical reaction equilibrium. 3. Fugacity coefficient is defined as the ratio of fugacity to pressure and is a measure of how non-ideal a gas is.

Uploaded by

PRAVIN
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PPTX, PDF, TXT or read online on Scribd
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Ptotal = p1+ p2

Where,
Ptotal -Total pressure
p1 ,p2 -Partial pressure of component.
yi P = xi i Pisat ( i= 1,2,..,N)

Where
i = Activity coefficient.
Fugacity: It is derived from Latin, expressed as
fleetness or escaping tendency. It is used
to study extensively phase and chemical reaction
equilibrium.
G = RT ln f +

- Is an constant depends on temperature and nature


of gas.
fugacity has same units as pressure for an ideal gas.
Fugacity coefficient () :
Fugacity coefficient is defined as the ratio of fugacity
of component to its pressure.
=f/P

- Is the measure of non ideal behavior of the gas.


efficient :
It measure the extent to which real solution depart from
ideality.
ln=bx
ln=bx
Wohls three suffix equation
Margules equation
Van laar equation
Wilson equation
Non random two liquid (NRTL)equation
Universal quasi chemical (UNIQUAC)equation
Universal functional activity coefficient (UNIFAC)
method
Using slope of ln curves
Using data at mid point
Redlich kister method
Using the coexistence equation
Using partial pressure data

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