SS COCr
SS COCr
Seminar by
Dr.Sandeep
Dentofacial orthopaedics
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svsids
CONTENTS
Introduction
Classification
History
Gold Alloys
Stainless Steel
Cobalt Chromium
conclusion
References
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INTRODUCTION
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For the correct use of orthodontic appliances one
must have thorough knowledge of materials from
which these appliances are made.
knowledge of orthodontic wires allows to perform
more efficient movements and avoid damage to
teeth and supporting tissues.
The light, continuous pressure produced by
these appliances stimulate osseous development
in the desired direction.
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CLASSIFICATION OF ARCHWIRES
Alpha titanium
Aesthetic wires
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HISTORY
In the first half of the 20th century, precious
metal alloys were used routinely for orthodontic
purposes, primarily because nothing else would
tolerate intraoral conditions.
later half of 20th century,led to substantial
changes to dental materials.
FACTORS
economy aesthetics
performance
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till late 20th century,gold was trade under
government,which was abandoned later as a result gold
was open trade commodity which rised the prices.
This led to the development of newer materials by
replacing gold with other low cost metals.(iron)
Later development of STAINLESS STEEL largely
replaced other metals.
Further,development in metallurgical processes
introduced other alloys.(co-cr,niti).
In 21st century,development of aesthetic wires is seen.
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GOLD ALLOYS
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COMPOSITION
Metal % properties
Gold 55-65% Major component
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HEAT TREATMENT
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Advantages Disadvantages
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USES
Crozat appliance- early 1900
Arch wire
round 20 to 22 guage
rectangular 22 x 28
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STAINLESS STEEL
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PAST
Discovered by chance few years before world war I.
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DEVELOPMENT
303,304L,316L,630(17-4),631(17-7),SAP
2205,Mezanium,Noninium,Ni free, NoNi,18-
8 +,431,AL 29-4C.
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PLAIN CARBON STEELS
Contain < 2.1% Carbon
BCC FCC
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STAINLESS STEEL
CLASSIFICATION:
Martensite SS
Austentite SS
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COMPOSITION
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MARTENSITE SS ( AISI 400)
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AUSTENTITE SS (AISI-300)
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AISI -302 SS 304 SS
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316L –LOW CARBON CONTENT
Chromium 16-18
Nickel 10-14
Carbon 0.03
Molybdenum 2-3
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Austentite is preferred over ferrite due to following:
1) greater ductility
2) Strengthening during cold working
3) Ease of welding
4) Overcome sensitisation
5) Ease in forming
6) Less critical grain growth
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PHYSICAL PROPERTIES OF STAINLESS STEEL
STIFFNESS
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SPRING BACK
greater spring back as compared to the gold alloys but lower than
those of newer titanium based alloys.
RESILIENCE
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FORMABILITY
JOINABILITY
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SOLDERING & WELDING OF SS
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Soldering flux for SS
In addition to usual oxidising & reducing agents,
fluoride is added for soldering SS.
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WELDING
SS bands & brackets are usually welded.
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BIOCOMPATIBILITY
Resistant to corrosion.
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Characterization and cytotoxicity of ions released from stainless
steel and nickeltitanium orthodontic alloys.
Am J Orthod Dentofacial Orthop 2004;125:24-9
Conclusion:
The results indicated no ionic release for niti alloy aging solution,
whereas measurable nickel and traces of chromium were found in
the SS bracket-aging medium.
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Friction
STUDIES
Graner et al (1986)
SENSITISATION
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METHODS TO MINIMIZE SENSITISATION
1) Reduce carbon content
(CrFe4)C at dislocations
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Annealing
The metal is heated to a temperature below its melting point.
(half of the melting temperature)
3stages(skinners)
Recovery
Recrystalization
Grain growth
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HEAT TREATMENT
Stress relieving heat treatment
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Funk (1951)
Methods of heating
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Drawbacks of heating
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ADVANTAGES
High yield strength
High resilience
Good formability
Good joinability
Biocompatible
Corrosion resistant
Economical
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DISADVANTAGES
Soldering is demanding.
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MECHANICAL PROPERTIES
Tensile strength- at which wire fractures is of
metallurgical interest & has no clinical significance.
UTS – 2.1 Gpa
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USES
SS arch wires
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TYPES OF SS
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Multistranded SS wires
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TWISTED AND COAXIAL
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STUDIES
Kusy and Dilley
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Types
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Rose , Frucht & Jonas
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Clinical applications
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Availability
Braided
Forms Twisted
Co-axial
Cross sections Round
Rectangular
No. of strands 3,6,8,9 stranded
Dimensions
Round:- 0.015, 0.0175, 0.0195,0.0215
Rectangular : 0.016 x 0.022 to 0.021 x 0.025
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Duplex steels – assembly of austentite & ferrite grains.
Ductility
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Australian Arch wires
History
Wilcock archwires have been the mainstay of Begg
technique.
In 1940S, Dr. Begg met Mr.Arthur J. Wilicock Sr. of
Whittlesea, Victoria who was directing metallurgical
research projects at University of Melbourne.
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Special properties of Australian Arch wires are
Hardness
Tensile strength
Springback
Resiliency
Zero stress relaxation
Yield strength
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Recent advances in Australian wires
Spinner straightening.
Pulse straightening.
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SPINNER STRAIGHTENING
Mechanical process of straightening materials usually
in cold hard drawn condition.
Wires are straightened by process of reverse straining.
Flexing in a direction opposite to that of original bend
(This is what is done manually in clinical setting).
In conventional manufacturing wire is pulled through
high speed rotating Bronze rollers which torsionally
twist the wire into straight condition.
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Disadvantages
Resultant deformation.
Decreased yield strength in tension and compression as
compared to that of the “as drawn” material. This
phenomenon of strain softening/work softening due to
reverse straining is known as “BAUSCHINGER EFFECT”.
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Regular Regular Plus Special Special plus
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PULSE STRAIGHTENING
The wire is pulsed in a special machine that permits high
tensile wires to be straightened.
This process was developed to overcome previous
difficulties.
Advantages over other straightening method.
Less or no deformation.
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Newer grades of Wilcock wires
Premium Grade
Premium Plus Grade
Supreme Grade
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Premium Premium plus Supreme Grade
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PROPERTIES
More resilient.
Can be welded.
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Wire Bending With High Tensile Pliers
The Mollenhauer bending plier is strongly recommended for
bending Wilcock wire as it helps to minimise breakages.
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Properties
Springback (YS/E)
Newer grade wires have better springback than lower
grade wires.
Can be deflected more without deformation.
Resiliency (YS2/2E)
Higher yield strength results in greater resiliency.
This means that higher grade wires store or absorb more
energy per unit volume before they get permanently
deformed.
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Zero Stress Relaxation
Ability of wire to deliver over long periods a constant
force when subjected to an external load.
Newer wires maintain their configuration over long
periods against deforming forces (forces of occlusion).
Higher yield strength prevents grain slippage.
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Formability
For the same material greater resiliency lesser the
formability.
These wires are more brittle than lower grade wires and
need to be bent in specific way.
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Clinical use
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Large resistance to deformation is required
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When a low load deflection rate is required.
Supreme grade arch wires of sizes 0.008 – 0.011
are used for
Unravelling of crowded anterior teeth.
MAA (Mollenhauer aligning auxiliary)
Miniuprighting springs.
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PRECIPITATION- HARDENABLE STAINLESS
STEEL:
Can be hardened by heat treatment.
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Uses – to manufacture attachments
Prestige
Nu- Edge LN
Repalcement of Ni by Mn.
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HIGH TEMPERED GOLD TREATED SS
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COBALT-CHROMIUM (CO-CR) ALLOYS
History
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COMPOSITION
ELEMENT %
Cobalt 40
Chromium 20
Molybdenum 7
Manganese 2
Nickel 15
Iron 15.8
Carbon 0.15
Beryllium 0.04
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Cobalt-chromium (Co-Cr) alloys are available commercially
as Elgiloy,Azura and Multiphase Elgiloy
manufactured in four tempers:
soft (blue)
ductile(yellow)
semiresilient(green)
red (resilient)
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Blue Elgiloy
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Yellow Elgiloy
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Green Elgiloy
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Red elgiloy
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Properties
SPRINGBACK
With exception of red temper elgiloy, springback
is less than SS wires.
But this property can be improved by adequate
heat treatment.
.0045-.0065 for , as received wire
.0054-.0074 after heat treatment
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STIFFNESS
160-190GPa as received
180-210GPa heat treated
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FORMABILITY
Good formability.
Modified by heat treatment.
Once appliance has been fabricated,inherent
elasticity of material which could be achieved by
heat treatment,ie,resilience.
YIELD STRENGTH
830-100MPa as received.
1100-1400MPa heat treated.
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JOINABILITY
Precaution
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FRICTION
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HEAT TREATMENT OF ELGILOY
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Heat treatment at temp above 1200 F (749C) results
in partial annealing - in resistance to deformation.
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Mechanism of Precipitation hardening
Results in
resistance of wire to deformation.
Increased resilience.
Wire demonstrates properties similar to SS.
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Procedure
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Martin et al (1984)
Investigated effect of heat treatment on various properties
of Blue Elgiloy.
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Clinical applications
Elgiloy is easier to bend than SS, NiTi and -Ti
in its as received state.
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Advantages over SS wires
Greater Resilience.
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DRAWBACKS
Lower spring back than stainless steel.
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AVAILABILITY
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CONCLUSION
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REFERENCES
Graber TM, Vanarsdall, Orthodontics current principles
and techniques, ed 4
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Kapila & Sachdeva. Mechanical properties and clinical
applications of orthodontic wires. AJO 89;96:100-109.
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Arthur J Wilcock. JCO interviews. JCO 1988;22: 484-489
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THAT’S ALL…
Thank you.
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